Abstract: The present invention relates to novel 1-hydroxy-6-substituted-pyridone compounds. Also disclosed is a process for producing the compound(s) and an antimicrobial composition comprising the compound(s) and at least one component selected from the group consisting of soaps, adhesives, coatings, elastomers, sealants, shampoos, skin care medicaments, cosmetics, paints and other polymer compositions.
Abstract: An apparatus for suppressing a fire comprises a gas generator containing a propellant and a fire suppressant as a mixture of compacted powders. The average diameter of a fire suppressant particle is larger than the average diameter of a propellant particle and the larger fire suppressant particles form discrete cooling sites that do not dramatically reduce the propellant burn rate.
Type:
Grant
Filed:
May 25, 1994
Date of Patent:
June 13, 1995
Assignee:
Olin Corporation
Inventors:
Lyle D. Galbraith, Gary F. Holland, Donald R. Poole, Robert M. Mitchell
Abstract: An apparatus and method for dissolving a chlorine containing treating material such as calcium hypochlorite in which water is fed to a container preferably in the form of a column containing the treating material. The water is caused to cyclically rise in the container to a predetermined height to dissolve a portion of the material and then discharge to a storage container to empty the material containing container. The height at which the water rises within the container, the cross-sectional area of the container and the length of time the liquid is in contact with the material during the cycle is set to produce a solution having a concentration of from between about 2 to about 18% available chlorine at a feed rate of at least about 2 lbs/hr available chlorine. The cyclical action is preferably achieved through the use of a siphon tube connected to the material holding container and through which the fluid in the container is discharged.
Abstract: There is provided a lead-free primer mix having high sensitivity. The primer mix contains an initiating explosive, a sensitizer, a propellant, calcium silicide and an oxidizer. The ignition exhaust products are essentially free of toxic oxides such as lead oxide, barium oxide and antimony oxide.
Abstract: There is provided heat exchange tube formed from a ductile metal strip which is formed into a generally circular configuration with the opposing longitudinal edges of the strip welded together. Both surfaces of the strip are enhanced. On one surface, the enhancement constitutes parallel rows of vertical fins separated by channels. Conduits which run along the channels and are located at the base of one side of the fins facilitate bending of the fins about the fin base to form a nucleate boiling surface. On the opposing surface of the tube, the enhancement constitutes parallel rows of protrusions separated by a distance effective to generate turbulence in a fluid passing along the second surface. In a preferred embodiment, the protrusions are in the form of truncated cones.
Abstract: A bipolar water ionizing electrode and a process employing such an electrode in an electrodialytic cell are disclosed. The cell has a plurality of ion exchange compartments separated by cation permselective membranes and the bipolar water ionizing electrode. The bipolar electrode is permeable to gas and electric current and impervious to liquid.
Abstract: A process for producing manganese dioxide and zinc metal comprising the steps of:(1) reacting a mixture of zinc oxide and manganese oxide with an aqueous chloric acid solution wherein the chloric acid is in molar excess of the manganese oxide in a reaction zone to form a reaction mixture in the zone comprising chlorine gas, a solid phase containing manganese dioxide, and a liquid phase containing zinc oxide, chloric acid and water; the concentration of chloric acid in the liquid phase is greater than about 1% by weight of the liquid phase upon leaving the reaction zone;(2) separating the chlorine gas from the solid phase and the liquid phase;(3) separating the solid phase containing manganese dioxide from the liquid phase containing zinc ions, chlorate ions, chloric acid, and water thereby forming a separated solid phase and a separated liquid phase;(4) subjecting the separated liquid phase to electrolysis in an electrochemical cell, thereby producing zinc metal at the cathode and oxygen at the anode;(5) remo
Abstract: A process for dissolving calcium carbonate solids in the presence of an aqueous chlorine-containing solution without the formation of chlorine gas comprising adding a sufficient amount of lactic acid to the solution dissolving said solids.
Abstract: A process for removing alkaline earth metal impurities (e.g. calcium and magnesium ions) from an aqueous alkali metal chlorate solution which includes adding sufficient alkali metal carbonate or hydroxide or both to the impure solution to raise the pH to above 9 and form alkaline earth metal precipitates which are then removed from the pH-adjusted solution (e.g. by microfiltration). This process can lower the level of these impurities from about 1-20 ppm to less than about 0.3 ppm or less.
Type:
Grant
Filed:
March 18, 1994
Date of Patent:
April 25, 1995
Assignee:
Olin Corporation
Inventors:
Jerry J. Kaczur, David W. Cawlfield, Julian F. Watson
Abstract: Machinable alpha beta brass having a reduced lead concentration is claimed. The alloy contains bismuth to improve machinability. Either a portion of the zinc is replaced with aluminum, silicon or tin, or a portion of the copper is replaced with iron, nickel or manganese.
Type:
Grant
Filed:
November 22, 1993
Date of Patent:
April 25, 1995
Assignee:
Olin Corporation
Inventors:
David D. McDevitt, Jacob Crane, John F. Breedis, Ronald N. Caron, Frank N. Mandigo, Joseph Saleh
Abstract: The present invention relates to a novel compound which is the hydroxylammonium or lower alkyl hydroxylammonium salt of 3-nitro-1,2,4-triazol-5-one, together with processes for preparation thereof. One process comprises a two-step reaction comprising: (a) reacting 3-nitro-1,2,4-triazol-5-one with an aqueous alkali metal or alkaline earth metal hydroxide to form an aqueous solution of an alkali metal or alkaline earth metal salt of 3-nitro-1,2,4-triazol-5-one, and (b) reacting said alkali metal or alkaline earth metal salt of 3-nitro-1,2,4-triazol-5-one with an aqueous solution of hydroxylammonium salt or lower alkyl-substituted hydroxylammonium salt to form the hydroxylammonium salt of 3-nitro-1,2,4-triazol-5-one.
Type:
Grant
Filed:
August 25, 1993
Date of Patent:
April 11, 1995
Assignee:
Olin Corporation
Inventors:
Eugene F. Rothgery, Francis W. Migliaro, Jr.
Abstract: A process for producing electronic package components from an aluminum alloy is disclosed. The components have a black color through integral color anodization. The desired color, thickness and surface finish are achieved by regulation of amperage during anodization. The amperage is rapidly raised to in excess of 80 amps per square foot and then allowed to gradually decrease as a function of oxide growth.
Type:
Grant
Filed:
August 31, 1993
Date of Patent:
April 4, 1995
Assignee:
Olin Corporation
Inventors:
Anthony M. Pasqualoni, Deepak Mahulikar, Satish K. Jalota, Andrew J. Brock
Abstract: A process for producing manganese dioxide comprising the steps of:(1) reacting manganese oxide with a molar excess of an aqueous chloric acid solution in a reaction zone to form a reaction mixture in said zone comprising chlorine gas, a solid phase containing manganese dioxide, and a liquid phase containing chloric acid and water; the concentration of chloric acid in said liquid phase is greater than about 5% by weight of said liquid phase upon leaving the reaction zone;(2) separating said chlorine gas from said solid phase and said liquid phase;(3) separating said solid phase containing manganese dioxide from liquid phase containing chloric acid and water;(4) removing water from said separated liquid phase to concentrate said chloric acid in said separated liquid phase; and(5) returning said separated and concentrated liquid phase back to said reaction zone for further reaction with manganese oxide.
Abstract: A composite lead-free bullet is disclosed comprising a heavy constituents selected from the group of tungsten, tungsten carbide, carballoy, and ferro-tungsten and a second binder constituent consisting of either a metal alloy or a plastic blend.
Type:
Grant
Filed:
September 23, 1993
Date of Patent:
March 21, 1995
Assignee:
Olin Corporation
Inventors:
Brian Mravic, Deepak Mahulikar, Gerald N. Violette, Eugene Shapiro, Henry J. Halverson
Abstract: There is provided an electronic package where the package components define a cavity. A semiconductor device and a portion of a leadframe occupy part of the cavity. Substantially the remainder of the cavity is filled with a compliant polymer, such as a silicone gel. Since the cavity is no longer susceptible to gross leak failure, the seal width of adhesives used to assemble the package may be reduced, thereby increasing the area available for mounting the semiconductor device.
Type:
Grant
Filed:
September 27, 1993
Date of Patent:
March 21, 1995
Assignee:
Olin Corporation
Inventors:
Derek E. Tyler, Deepak Mahulikar, Anthony M. Pasqualoni, Jeffrey S. Braden, Paul R. Hoffman
Abstract: There is disclosed methods for the manufacture of a metal matrix composite having a metal or metal alloy matrix and a uniform dispersion of a second phase. The second phase is either a refractory metal or a nonmetal. An element which reacts with both the matrix and the second phase is added to increase the loathing density of the second phase and to improve adhesion between the components of the composite. When the metal alloy matrix is copper or a copper based alloy, suitable reactive elements include zirconium, titanium, chromium and mixtures thereof.
Type:
Grant
Filed:
January 29, 1993
Date of Patent:
February 21, 1995
Assignee:
Olin Corporation
Inventors:
Sankaranarayanan Ashok, William G. Watson, Harvey P. Cheskis
Abstract: The present invention relates to a process for making a polyol which comprises the steps of: (a) fabricating a propoxylated polyhydric initiator by reacting propylene oxide with a polyhydric initiator in the presence of an acid catalyst, said reaction being conducted in the absence of a KOH catalyst, to produce a propoxylated polyhydric initiator containing acid catalyst residue(s) and free of KOH catalyst residue, and (b) reacting said propoxylated polyhydric initiator containing acid catalyst residue(s) with an alkylene oxide in the presence of a double metal cyanide complex catalyst to produce a polyol.
Type:
Grant
Filed:
March 30, 1990
Date of Patent:
February 21, 1995
Assignee:
Olin Corporation
Inventors:
Kiran B. Chandalia, John W. Reisch, Michael M. Martinez
Abstract: The present invention relates to an electrochemical process for the removal of excess or residual nitric acid from aqueous hydroxylammonium nitrate (HAN) solutions. The process utilizes a multi-compartment electrochemical membrane cell in which the HAN solution flows through a central ion exchanging compartment bounded by anion membranes on either side. Electrochemically generated OH-ions formed at the cathode are used to displace and remove the nitric acid from the HAN solution. In use, the residual nitric acid content in the HAN is suitably reduced to a specified safe level before the HAN is concentrated to a 13.0 molar final composition.
Type:
Grant
Filed:
July 20, 1994
Date of Patent:
February 21, 1995
Assignee:
Olin Corporation
Inventors:
Jerry J. Kaczur, Kenneth E. Woodard, Jr., David W. Cawlfield, Elizabeth K. Muse
Abstract: This invention relates to a process for coating a substrate which comprises contacting the substrate with a low volatility organic (so-called "low VOC") coating composition having a viscosity as measured by ZAHN cup 2 of less than about 200 seconds and consisting essentially of at least one polyisocyanate prepolymer which is the reaction product of a polyisocyanate with an active hydrogen-containing compound selected from the group consisting of monoahls, polyols, imines, oxazolidines, and combinations thereof, a solvent in an amount of between 0% and 45% by weight based upon the amount of said polyisocyanate in said composition, and a tertiary amine catalyst, said composition being essentially free of any volatile mono- and di-isocyanates, and said composition being moisture curable upon exposure to atmospheric moisture. Also claimed is the coating composition itself.
Type:
Grant
Filed:
July 14, 1994
Date of Patent:
February 21, 1995
Assignee:
Olin Corporation
Inventors:
Kiran B. Chandalia, Michael J. Morgan, Michael M. Martinez, James M. O'Connor, Stephen P. Noe
Abstract: A method system for treating water in which the incoming effluent water is pre-filtered, passed through a reverse osmosis unit, post filtered to remove taste and odor and then passed to a holding tank. The holding tank is provided with a source of ultraviolet light to provide disinfection in the holding tank to eliminate bacterial growth prior to consumption of the water therein.