Abstract: A phase stabilized ammonium nitrate mixed crystal structure is produced by the addition of potassium fluoride. Thus the undesirable abrupt expansion and contraction of ammonium nitrate in the temperature range of use in rocket motor propellants and explosives (-55.degree. C. to .lambda..degree. C.) is eliminated. The mixture is made by the addition of between about 3% to 5% and preferably about 3.5% by weight potassium fluoride to the ammonium nitrate by a nonhazardous aqueous method.

Abstract: A metal liner for a shaped charge device having a ductile metal matrix and a discrete second phase is provided. The allow composition is selected so the second phase is molten when the liner is accelerated following detonation. The molten phase reduces the tensile strength of the matrix so that the liner slug is pulverized on striking a well casing. The slug does not penetrate the hole perforated in the well casing by the liner jet and oil flow into the well bore is not impeded. The liner is formed by directly casting the desired alloy to the desired shape.

Abstract: A long rod penetrator projectile comprises an elongated main penetrator body, a stabilizing fin assembly attached to the rear of the main body, and a perforated canister carried within the fin assembly. A pyrotechnic material such as pyronol is contained within the canister. The pyronol ignites during impact. The burning pyrotechnic material spews forth through the perforations in the canister to provide improved after armor effects.

Abstract: This invention relates to a method of fabricating a thermoplastic elastomer which comprises the steps of: (a) fabricating a polyol having a molecular weight of between about 2,000 and about 20,000 and having a level of end group unsaturation of no greater than 0.04 milliequivalents per gram of polyol, said polyol being fabricated in the presence of a double metal cyanide catalyst, (b) reacting said polyol with a diisocyanate to produce an isocyanate-terminated prepolymer, and (c) reacting said isocyanate-terminated prepolymer with a difunctional isocyanato-reactive chain extender in a mold or in an extruder in order to produce a soft elastomer characterized by a Shore A hardness of between about 10 and about 70. Also claimed is the elastomer produced by the above method utilizing a one-shot technique.

Abstract: A composite copper alloy having a modified surface is provided. An element or combination of elements both soluble in copper and reactive with nitrogen are cast with copper or a copper alloy forming a solid state solution. The alloy is reacted with a nitride former to modify the surface. A continuous surface film is formed by heating in a nitrogen containing gas. A dispersion of nitride precipitate in a copper matrix is formed by implanting nitrogen ions.

Abstract: A process for electrolytically producing an aqueous solution of chlorine dioxide in an electrolytic cell having an anode compartment, a cathode compartment, and at least one ion exchange compartment between the anode compartment and the cathode compartment, the process comprising feeding an aqueous solution of an alkali metal chlorite to the ion exchange compartment, electrolyzing an anolyte in the anode compartment to generate hydrogen ions, passing the hydrogen ions from the anode compartment through a cation exchange membrane into the ion exchange compartment to displace alkali metal ions and produce an aqueous solution of chlorine dioxide, and passing alkali metal ions from the ion exchange compartment into the cathode compartment.

Abstract: Described herein is a process for the chlorination of amide containing oligomers and/or polymers by reacting the oligomers and/or polymers with an aqueous hypochlorous acid solution containing at least 5% by weight of hypochlorous acid and being essentially free of chlorine, chlorate, and alkali metal ions, said process being conducted in an aqueous medium.

Abstract: A calcium hypochlorite composition consists essentially of at least 75 percent by weight of Ca(OCl).sub.2, from about 6 to about 14 percent by weight of water, and less than 1.5 percent by weight of an alkali metal chloride. The novel composition provides increased amounts of sanitizing and disinfecting to, for example, water bodies while remaining safe with respect to thermal decomposition. Further, the composition reduces the rate of chlorine evolution during storage.

Abstract: An improved sample-holding platform for a stabilized temperature platform furnace in atomic absorption spectroscopy is provided having a recessed base and elevated sidewalls to retain an organic liquid sample and concentrate the atomized elements in a confined area for analysis after vaporization.

Abstract: A process for producing chlorine dioxide by oxidizing a hypochlorous acid solution to produce a chloric acid solution, and, electrolyzing the chloric acid solution to produce chlorine dioxide.The novel process of the present invention provides a commercially viable process for producing the chloric acid and eliminates the formation of an acidic salt solution in the production of chlorine dioxide which requires disposal. Further, the process permits a reduction in the amount of acid required in the generation of chlorine dioxide.

Abstract: An improved plural component dispensing apparatus having a chemical flow stream separator to ensure separation of the isocyanate and polyol plural components is disclosed to permit solventless operation and the cleaning by an aqueous cleaning medium followed by a gaseous drying purge stream to prevent the reaction of water and the isocyanate component.

Abstract: A process and apparatus utilizing the process of the present invention are provided to produce a fast dissolving, thermally sensitive granular product. The process employs a fluidized spray dryer having a fluidized bed of granular particles into which recycled off-sized product is fed after being agglomerated to adjust particle size. The spray dryer optionally can employ a second nozzle positioned above the fluidized bed. The process can be employed in the production of calcium hypochlorite water sanitizing chemical wherein the chlorine is supplied from a hypochlorous acid reactor and lime hypochlorinator.

Abstract: A process for electrolytically producing an aqueous solution of chloric acid and alkali metal chlorate in an electrolytic cell having an anode compartment, a cathode compartment, and at least one ion exchange compartment between the anode compartment and the cathode compartment. The process includes the steps of feeding an aqueous solution of an alkali metal chlorate to the ion exchange compartment, electrolyzing an anolyte in the anode compartment to generate hydrogen ions, passing the hydrogen ions from the anode compartment through a cation exchange membrane into the ion exchange compartment to displace alkali metal ions and produce an aqueous solution of chloric acid and alkali metal chlorate, and passing alkali metal ions from the ion exchange compartment into the cathode compartment.

Abstract: An electrochemical process and electrolytic cell for manufacturing chlorine-free chlorine dioxide from a dilute alkali metal chlorite solution in a single step is disclosed. The electrolytic cell uses a porous flow-through anode and a cathode separated by a suitable separator. The alkali metal chlorite solution has a conductive salt additive.

Abstract: A frangible projectile made from powdered metals comprising a body of either iron and carbon, or of iron and alumina. The powdered metals are compacted, sintered, and cooled.

Abstract: An arcjet thruster comprises a cathode body and anode body tandemly arranged and separated by an insulative propellant injection ring. The cathode body has a cathode cavity therein having a convergent and a divergent portion forming a throat therebetween. The anode body has a divergent cavity therein for producing thrust. The divergent cavity has an upstream portion and a downstream portion. The divergent portion of the cathode and the upstream portion of the anode cavity form a constrictor. A power supply connected between the anode and the cathode bodies is used to produce an arc between the anode and cathode that passes through the constrictor. Propellant is injected in a vortex flow radially into the constrictor so that it divides. A portion of the flow is directed upstream through the throat into the convergent portion of the cathode cavity thus also pushing the cathode arc attachment point into the convergent portion to cause diffuse attachment thereof.

Abstract: The invention provides a process for the manufacture of copper alloys having improved processability. The alloys are melted and atomized into droplets which are spray cast into a coherent deposit. The spray cast alloys are characterized by a finer dispersion of intermetallic than is possible by conventional casting. The alloys are capable of being cold rolled to a reduction of up to 70%. The spray cast alloys exhibit good electrical conductivity and a high yield strength. They are particularly suited for electrical spring contacts.

Abstract: A composite valving rod is provided for use in a foam dispensing apparatus having a low friction plastic sleeve portion that is retained by a steel tip which both maintains the physical dimensions of the plastic sleeve and serves as a scraper when drawn through the bore of the foam dispensing cartridge. The cartridge is all metal.

Abstract: A method for the assembly of an adhesively sealed tape package having base and cover components is provided. An electronic device is first bonded to the inner leads of a tape leadframe. The chip on tape is then disposed between the base component and the cover component and adhesively sealed to both. The electronic device and a portion of the inner leads are thereby encapsulated. In one embodiment the base and cover components are an aluminum base alloy having an anodization layer over at least those surfaces exposed to the external environment of the adhesive.

Abstract: The present invention provides for a method for the preparation of colored magnetic particles for multicomponent toner compositions in which colors are produced by means of a chemical reaction of different metallic oxides formed on the surface of the magnetic particles.