Abstract: A monopolar membrane electrolytic cell is comprised of a plurality of anodes wherein each anode is comprised of a first foraminous surface and a second foraminous surface positioned in parallel and spaced apart, and a frame enclosing the first and the second foraminous surfaces. The frame has two side members, a top member, and a bottom member attached to the foraminous surfaces. A chamber is formed between the foraminous surfaces and bounded by the frame. Conductor rods pass through one of the side members of the frame into the chamber, the conductor rods being spaced apart from the foraminous surfaces. Foraminous conductive connectors are positioned in the chamber and attached to the conductor rods and to the foraminous surfaces; a plurality of cathodes wherein each cathode is comprised of at least one foraminous surface, and a frame which encloses the foraminous surface.

Abstract: Disclosed are compositions comprising the reaction products of poly(oxyalkylated) hydrazine and at least one compound selected from the group consisting of phosphorylation agents, thiophosphorylation agents, and mixtures thereof; wherein the poly(oxyalkylated) hydrazine has the formula: ##STR1## wherein each R is individually selected from hydrogen, lower alkyl groups having 1 to 4 carbon atoms, phenyl and mixtures thereof; the sum of w, x, y and z is from about 4 to about 25, and wherein the mole ratio of said poly(oxyalkylated) hydrazine to said compound being from about 0.1:1 to about 10:1. These compositions are shown to be effective corrosion inhibitors in corrosive aqueous solutions such as brines and acid metal-treating baths.

Abstract: A continuous lubrication casting mold for use in a process of continuously casting molten metals and alloys wherein a parting and/or lubricating agent reservoir is provided in the mold body. The agent is continuously applied over the inner surface of the mold after being introduced through passages within or through the mold section. The lubricant passages may be an intrinsic characteristic of the mold material or may be provided in the form of feed holes through the mold section. The ability to transmit lubricant through to the internal surface of the mold can be varied within the length of the casting mold to provide for variable lubricant transfer rates to different parts of the casting surface.

Abstract: A process and apparatus for bonding lead wires to a metal substrate. A lead wire is positioned on the substrate and a spot of metal is deposited over a portion of the lead wire and metal substrate to firmly bond the wire to the substrate.

Abstract: An electrode for use in the electrolysis of aqueous solutions of ionizable compounds is produced by a method which comprises affixing filaments to a support fabric to form a network of filaments. An electroconductive metal is deposited on the filaments to form metal coated filaments. During the metal deposition, interfilament bonding takes place at contact sites between adjacent filaments. Removing the support fabric from the metal coated filament network produces a reticulate electrode having a porosity of at least about 80 percent. The three dimensional electrodes are highly conductive, have high internal surface area, and are mechanically strong.

Abstract: Described is an electrolytic process for producing sodium ferrate [Fe(VI)] in a membrane-type electrolysis cell. The anolyte chamber of the cell is charged with an aqueous solution of sodium hydroxide and a sodium ferrate-stabilizing proportion of at least one sodium halide salt. The anolyte chamber additionally contains ferric ions [Fe(III)]. The catholyte chamber contains an aqueous sodium hydroxide solution during operation. The source of ferric ion in the anolyte may be either an iron-containing anode or at least one iron-containing compound present in the anolyte solution or both. The preferred membrane material for separating the anolyte chamber from the catholyte chamber is comprised of a gas- and hydraulic-impermeable, ionically-conductive, chemically-stable ionomeric film (e.g., a cation-exchange membrane) with carboxylic, sulfunic or other inorganic exchange sites.

Abstract: An apparatus and process for casting a material comprising a coolant application device comprising a fluidized bed coolant system. The casting is carried out utilizing a casting mold which defines a casting zone. A soundwave generating system is provided for enhancing the flow of the fluidized bed into the vicinity of the casting zone.

Abstract: Described is a process for making potassium ferrate by the formation of sodium ferrate in a membrane-type electrolysis cell. The anolyte chamber of the cell is charged with an aqueous solution of sodium hydroxide and a sodium ferrate-stabilizing proportion of at least one sodium halide salt. The anolyte chamber additionally contains ferric ions [Fe(III)]. The catholyte chamber contains an aqueous sodium hydroxide solution. The source of ferric ion in the anolyte may be either an iron-containing anode or at least one iron-containing compound present in the anolyte solution or both. The preferred membrane material for separating the anolyte chamber from the catholyte chamber is comprised of a gas- and hydraulic-impermeable, ionically-conductive, chemically-stable ionomeric film (e.g., a cation-exchange membrane) with carboxylic, sulfonic or other inorganic exchange sites.

Abstract: A wrapper is provided for smoking articles such as cigarettes, cigars and the like having incorporated therein at least 1% by weight of certain ceramic fibers in the paper furnish in combination magnesium oxide and/or magnesium hydroxide fillers, whereby the combination acts to significantly reduce visible sidestream smoke emanating from the smoking article during static burning, and improves ashing. Wrappers made according to this invention may be made by incorporating the magnesium hydroxide, magnesium oxide and the other fillers in the wrapper pulp furnish containing the ceramic fibers or either or both of the fillers may be applied to the improved wrapper as a coating for the papers. In the case of cigarette papers, the ceramic fibers may be added to an ordinary paper furnish such as pulped wood or flax fibers. The furnish of fiber pulp and ceramic fibers and fillers are used to make a paper sheet on conventional papermaking machines.

Abstract: An improved copper base alloy for use in electrical springs and a process of treating the alloy provide improved resistance to stress relaxation when the alloy is in a solution treated and aged condition having a discontinuous precipitate. The alloy consists essentially of from about 10% to about 15% nickel, from about 1% to about 3% aluminum, up to about 1% manganese, from about 0.05% to less than about 0.5% magnesium and the balance copper. The alloy is readily hot workable if held within a critical temperature range of from about 880.degree. C. to about 980.degree. C. prior to hot working.

Abstract: A procedure for conditioning new composite laminated membranes in chlor-alkali cells producing KOH, said membrane being comprised of a laminated composite made from individual perfluorosulfonyl and perfluorocarboxylic acid layers, so that said membrane will not delaminate during startup operation of the cell. The procedure comprises charging the cathode compartment of the cell with a KOH solution of less than about 27 percent by weight KOH before startup and gradually raising the KOH concentration during the first 12 to about 20 hours of operation to about 30 percent after which the cell can be operated at higher KOH concentrations which provide better current efficiencies.

Abstract: A process for producing a concentrated aqueous solution of an alkali metal chlorate and an alkali metal chloride comprises feeding an aqueous alkali metal chloride solution to a first electrolysis zone at an initial feed rate. The aqueous alkali metal chloride is electrolyzed to produce a concentrated chlorate solution comprised of an alkali metal chlorate and the alkali metal chloride. A portion of the concentrated solution is fed to an analysis zone and analyzed to measure the ratio of the concentration of the chlorate ion to the concentration of the chloride ion. The measured ratio is compared in a processing zone with a predetermined value range for the ratio and, where the measured ratio falls outside of the predetermined value range, altering the initial feed rate of alkali metal chloride to the first electrolysis zone. The concentrated alkali metal is removed from the first electrolysis zone to a product solution collection zone.

Abstract: In an apparatus for determining the amount of compressive force exerted on an elastomeric material, there is provided an elastomeric material retainer, compression apparatus cooperative with the elastomeric material retainer and compressive force measuring apparatus and deflection apparatus to measure the amount of compressive force exerted on the elastomeric material and the amount of compression which the elastomeric material experiences.

Abstract: A current distributor for an electrode for an electrolytic cell for the electrolysis of aqueous solutions of ionic compounds is provided which comprises an electrically conductive material having a front surface comprised of a plurality of electrode-engaging means projecting from it for attachment to a foraminous electrode. The rear surface of the current collector is suitable for attachment to an electrical conductor. The novel current distributors are particularly suitable for use with reticulate electrodes.

Abstract: The invention relates to an electrolytic cell which is comprised of a first frame member housing an electrode and a second frame member housing an electrode. A separator is positioned between the first frame member and the second frame member. A first sealing means contacts a side of the first frame member and one side of the separator. Contacting the second frame member and the opposite side of the separator is a second sealing means. The first sealing means and the second sealing means are elastomeric solids having a substantially rectangular cross-sectional area where the first sealing means is from about 1.1 to about 3 times the width of the second sealing means. Pressing means are provided which press the frames together against the sealing means and the separator to form a substantially fluid-tight seal. The novel electrolytic cells provide the advantages of simultaneously:a. controlling gasket compression pressures,b. controlling gasket frame surface structural forces,c.

Abstract: Disclosed is a method of determining which membrane in a multiple unit filter press membrane electrolytic cell is structurally damaged after cell operating conditions and monitorings indicate the problem exists.

Abstract: A method for assembling a filter press type of electrolytic cell is disclosed wherein tightening apparatus is employed at preferably multiple points about the periphery of the stacked electrodes to substantially simultaneously apply a substantially uniform pressure to compress the cell to permit the compressed stack of electrodes to be retained in this compressed state while the cell is assembled in a fluid-tight manner.

Abstract: A process for producing particles of a non-friable eutectic mixture of sodium nitrate and potassium nitrate for solar power station use is disclosed. In one embodiment of the invention, the particles are produced by shock chilling a molten stream of mixed nitrate material and crushing the resulting flakes to a size range of between about -5 mesh and about +30 mesh. In a second embodiment, particles of this size are produced by spray granulation of a concentrated solution of mixed nitrate salts onto a fluidized bed to produce dry, free-flowing, solid spheres. In both embodiments, the particles are extremely hard, resistant to moisture pickup and adaptable to being readily shipped by bulk containers.

Abstract: An electrolyte cell having an improved hydrogen evolution cathode said cathode being characterized by a conductive metal core and an integral Raney-type catalytic surface predominantly derived from an adherent ternary aluminide Beta structured intermetallic crystalline precursory outer portion of the metal core is disclosed. The precursory outer portion preferably has molybdenum and titanium added to give a precursor alloy having the formula Ni.sub.x Mo.sub.y Ti.sub.z Al.sub.3 where x is within the range of from about 75 to about 94 weight percent, y is within the range of from about 5 to about 20 weight percent and z is within the range of from about 1 to about 5 weight percent of the Ni-Mo-Ti portion of the alloy. Also disclosed is a method of producing a low overvoltage cathode.