Patents Assigned to Ticona GmbH
  • Patent number: 6017616
    Abstract: The invention relates to a film having more than one layer and made from cycloolefin polymers and having a base layer and at least one outer layer, the base layer being built up essentially from a cycloolefin polymer COP having a glass transition temperature Tg and the outer layer being built up essentially from a mixture of cycloolefin polymers, wherein the mixture of cycloolefin polymers comprises at least two cycloolefin polymers COP.sub.1 and COP.sub.2 whose glass transition temperatures Tg.sub.1 and Tg.sub.2 differ by at least 5.degree. C., where Tg.sub.2 -Tg.sub.1 .gtoreq.5.degree. C. and at the same time the condition Tg.sub.2 -Tg.gtoreq.5.degree. C. is fulfilled.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: January 25, 2000
    Assignees: Ticona GmbH, Mitsui
    Inventors: Karl-Heinz Kochem, Wolfgang Rasp, Herbert Peiffer, Wilfried Hatke
  • Patent number: 6013707
    Abstract: Polyesters such as polyethylene terephthalate or polybutylene terephthalate are provided with a flame-retardant finish by addition of calcium salts or aluminum salts of phosphinic or diphosphinic acids.
    Type: Grant
    Filed: June 9, 1998
    Date of Patent: January 11, 2000
    Assignee: Ticona GmbH
    Inventors: Hans-Jerg Kleiner, Winfried Budzinsky, Gunther Kirsch
  • Patent number: 6013761
    Abstract: A process for the preparation of polyarylene sulfoxides, in which polyarylene sulfide, suspends in a concentrated acid of formula R--SO.sub.3 H, in which R is a halogen atom Ian OH group, an aliphatic radical having 1 to 6 C atoms or an aromatic radcal having 6 to 18 C atoms, or of the formula R.sup.1 --CR.sup.2 R.sup.3 --COOH, in which R.sup.1 is a halogen atom and R.sup.2 and R.sup.3, independently of one another are each a halogen atom, an aliphatic radical having 1 to 50 atoms or a halogenated aliphatic radical having 1 to 5 C atoms, is oxidized by metering in a 30 to 85% strength hydrogen peroxide solution with thorough mixing and at a temperature of from -20 to +45.degree. C. According to this process, the sulfide units of the polyarylene sulfide are converted virtually selectively and completely into sulfoxide units.
    Type: Grant
    Filed: November 19, 1998
    Date of Patent: January 11, 2000
    Assignee: Ticona GmbH
    Inventors: Dirk Zierer, Helmut Scheckenbach
  • Patent number: 5994416
    Abstract: The present invention relates to a process for obtaining polyarylene sulfide from polyarylene sulfide-containing material. For this purpose, the polyarylene sulfide-containing material is treated with a solvent in which it dissolves, and is subsequently reprecipitated. The invention also relates to the purification of polyarylene sulfide-containing material by separating off extraneous substances, to polyphenylene sulfide particles having a specific surface area of at least 80 m.sup.2 /g and to their use as filter material.
    Type: Grant
    Filed: May 19, 1997
    Date of Patent: November 30, 1999
    Assignee: Ticona GmbH
    Inventors: Martin Bruck, Andreas Schleicher
  • Patent number: 5994483
    Abstract: The invention relates to a process for preparing blends of high-performance polymers. The particular features are that at least two single-type polymers are treated with a solvent or a solvent mixture in which the polymers used are soluble, the polymers are thereby dissolved, and are then precipitated in a liquid medium, and recycled material is used for each of the polymeric constituents.
    Type: Grant
    Filed: August 12, 1998
    Date of Patent: November 30, 1999
    Assignee: Ticona GmbH
    Inventors: Martin Bruck, Stefan Disch, Klaus Kohlhepp
  • Patent number: 5990337
    Abstract: The invention relates to a process for the preparation of phosphorus-containing compounds of the formula (I) ##STR1## where R.sup.1 and R.sup.2 are identical or different and are a straight-chain or branched alkyl radical having 1 to 8 carbon atoms, a cyclohexyl-, cyclopentyl-, aryl-, halogen-, (C.sub.1 -C.sub.6)-alkyl- or (C.sub.1 -C.sub.6)-alkoxy-substituted aryl radical, where R.sup.1 and R.sup.2, together with the phosphorus atom and the oxygen atom, can also form a ring, in particular an oxaphosphorin ring, which comprises metering acrylonitrile at elevated temperature into a compound of the formula (II) ##STR2## where R.sup.1 and R.sup.2 are as defined above.
    Type: Grant
    Filed: August 26, 1997
    Date of Patent: November 23, 1999
    Assignee: Ticona GmbH
    Inventor: Hanss-Jerg Kleiner
  • Patent number: 5962623
    Abstract: A continuous process for the preparation of polyacetal copolymers from 1,3,5-trioxane and the comonomers known for this purpose using strong protic acids as an initiator, in which the initiator is added in an amount of 0.01 to 0.6 ppm, based on the total amount of monomers, in finely divided form to the monomer mixture, after the polymerization step the crude polymer is transferred from the polymerization reactor to a mixing unit without further intermediate steps, excess monomer is removed from the crude polymer in the mixing unit or between polymerization reactor and mixing unit by applying reduced pressure and, if desired, generally customary stabilizers, assistants, fillers, reinforcing materials and/or colorants are incorporated into the polymer in the mixing unit.
    Type: Grant
    Filed: September 8, 1998
    Date of Patent: October 5, 1999
    Assignee: Ticona GmbH
    Inventors: Peter Eckardt, Michael Hoffmockel, Karl-Friedrich Muck, Gerhard Reuschel, Satyajit Verma, Michael G. Yearwood
  • Patent number: 5958787
    Abstract: A sensor for oxidizing agents contains an oxidizable aromatic polymer. The sensor comprises a piezoelectric crystal coated with a porous or non-porous layer that contains the oxidizable aromatic polymer.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: September 28, 1999
    Assignee: Ticona GmbH
    Inventors: Axel Schonfeld, Gernot Feucht, Andreas Schleicher, Georg Frank, Heinz Rieger
  • Patent number: 5948830
    Abstract: The novel blend comprises:(A) from 1 to 99% by weight of at least one thermotropic-liquid-crystalline polyester and/or polyesteramide and(B) from 1 to 99% by weight of at least one sulfoxide group-containing polymer,in each case based on the total weight .SIGMA.?(A)+(B)!. Component (B) is a linear and/or branched polymer having a mean molecular weight M.sub.w in the range from 4,000 to 200,000 comprising recurring units of the formula ?--F--S).sub.c --(F--SO).sub.d --!, where F, independently of one another, are simple or para-, meta- or ortho-linked arylene systems having 6 to 18 carbon atoms, preferably phenylene, naphthylene or biphenylene, where the sum c+d is 1, with the proviso that d is always .gtoreq.0.70. Component (A) is a thermotropic liquid-crystalline polymer having a mean molecular weight M.sub.w in the range from 10,000 to 200,000 g/mol and a transition temperature of >250.degree. C., and/or an amorphous thermotropic liquid-crystalline polymer having a mean molecular weight M.sub.
    Type: Grant
    Filed: May 2, 1997
    Date of Patent: September 7, 1999
    Assignee: Ticona GmbH
    Inventors: Helmut Scheckenbach, Dirk Raudies, Andreas Schleicher, Georg Frank
  • Patent number: 5891226
    Abstract: Salts of phosphonous acids are useful as flame retardants in plastics. Preferred salts are calcium or aluminum salts of phenylphosphonous acid and of methanephosphonous acid. Plastic molding materials rendered flame-retardant in this way are useful for manufacturing molded parts, especially electrical components, mechanical components, plugs, mounts, housings, coverings, sheathings and overcoatings.
    Type: Grant
    Filed: March 3, 1997
    Date of Patent: April 6, 1999
    Assignee: Ticona GmbH
    Inventors: Hans-Jerg Kleiner, Winfried Budzinsky, Gunther Kirsch
  • Patent number: 5891988
    Abstract: The process for the preparation of polyarylene sulfones by oxidation of polyarylene sulfides with an oxidizing agent in the presence of a liquid is carried out under reduced pressure so that the liquid boils. The reaction temperature can easily be kept constant in the process.
    Type: Grant
    Filed: September 9, 1997
    Date of Patent: April 6, 1999
    Assignee: Ticona GmbH
    Inventors: Helmut Scheckenbach, Klaus Delpy, Stefan Disch
  • Patent number: 5889102
    Abstract: Molding compositions comprising a thermoplastic, at least one lubricant and at least one fibrous material have high abrasion resistance and high rigidity. The molding compositions comprise, for example, polyoxymethylene, ultrahigh-molecular-weight polyethylene as lubricant and glass fibers. The molding compositions are used for the production of gearwheels, toothed racks, bearings and chains.
    Type: Grant
    Filed: February 24, 1997
    Date of Patent: March 30, 1999
    Assignee: Ticona GmbH
    Inventors: Ulrich Haack, Klaus Kurz, Oskar Schleith
  • Patent number: 5885704
    Abstract: The disclosed oriented polyolefin film contains at least one voided layer. The voided layer contains an amorphous void-initiating polymer which, after orienting, is present as a separate particle inside the void. In the process for producing the polyolefin film, a molten blend comprising an olefin polymer and the amorphous polymer is extruded through a die at an extrusion temperature above the glass temperature or Vicat softening point of the amorphous polymer, the resulting film is drawn off on one or more rollers, and is then subjected to stretch orientation, followed optionally by thermofixing and a surface treatment.
    Type: Grant
    Filed: August 2, 1996
    Date of Patent: March 23, 1999
    Assignee: Ticona GmbH
    Inventors: Herbert Peiffer, Ursula Murschall, Gunter Schloegl, Frank Osan, Thomas Dries
  • Patent number: 5869722
    Abstract: Process for producing aluminum phosphinatesThe invention relates to a process for producing aluminum phosphinates of the formula (I) ##STR1## where R.sup.1 and R.sup.2, independently of each other, are linear or branched (C.sub.1 -C.sub.6)-alkyl or phenyl, which comprises reacting phosphinates of the formula (II) ##STR2## where R.sup.1 and R.sup.2 are as previously stated and R.sup.3 is C.sub.1 -C.sub.6 -alkyl, with aluminum chloride in a molar ratio of from 2.5:1 to 4:1.
    Type: Grant
    Filed: April 22, 1997
    Date of Patent: February 9, 1999
    Assignee: Ticona GmbH
    Inventor: Hans-Jerg Kleiner
  • Patent number: 5869586
    Abstract: The present invention relates to a process for preparing a cycloolefin copolymer by polymerization of at least one cyclic olefin and at least one acyclic olefin in the presence of a catalyst comprising at least one metallocene compound of the formula I, ##STR1## where L is a .pi.-ligand, L' is a .pi.-ligand, T is a bridge between L and L', M is a tetravalent transition metal, m is 1 or 2 and R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are, independently of one another, identical or different and are each a hydrogen atom or a C.sub.1 -C.sub.20 -hydrocarbon radical.
    Type: Grant
    Filed: December 13, 1996
    Date of Patent: February 9, 1999
    Assignees: Ticona GmbH, Mitsui Petrochemical Industries, Ltd.
    Inventors: Michael Riedel, Thomas Weller, Alexandra Jacobs
  • Patent number: 5866246
    Abstract: An oriented film composed of thermoplastic polymers is described which comprises at least one vacuole-containing layer. The vacuole-containing layer comprises particulate hollow bodies which are essentially composed of a polymer which is incompatible with the thermoplastic polymer. A process for producing the film is also described.
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: February 2, 1999
    Assignee: Ticona GmbH
    Inventors: Michael Schreck, Michael Ahlers, Frank Osan
  • Patent number: 5864095
    Abstract: An abrasion-resistant fluoropolymer mixture comprising(A) from 75 to 99% by weight of a fluorocarbon polymer(B) from 1 to 25% by weight of an oxidized polyarylene sulfide and, based on the sum (A)+(B),(C) from 0 to 15% by weight of a filler,is used for the production of feed pipes for Bowden cables which are pressure-resistant and abrasion-resistant.
    Type: Grant
    Filed: December 11, 1997
    Date of Patent: January 26, 1999
    Assignee: Ticona GmbH
    Inventors: Helmut Scheckenbach, Andreas Schleicher, Jurgen Kulpe, Wolfgang Neumann, Bernd Jansen
  • Patent number: 5863986
    Abstract: Polymer alloy comprising a) one or more cycloolefin copolymers and b) one or more types of core-shell particles and c) one or more block copolymers.
    Type: Grant
    Filed: January 23, 1997
    Date of Patent: January 26, 1999
    Assignees: Ticona GmbH, Mitsui Petrochemical Industries, Ltd
    Inventors: Otto Herrmann-Schonherr, Frank Osan
  • Patent number: 5853457
    Abstract: The invention relates to a filter material and to a process for removing ozone from gases and liquids, in which a gas stream or a liquid is brought into contact with a filter material made of an unsaturated cycloolefin polymer or cycloolefin copolymer. The filter material can be used with all ozone-containing gas streams and liquids. Thus, for example, it is used in the removal of the ozone used in sterilization or formed by a copier machine, in addition for removing and detoxifying ozone in liquids.
    Type: Grant
    Filed: May 5, 1997
    Date of Patent: December 29, 1998
    Assignee: Ticona GmbH
    Inventors: Jorg Eysmondt, Frank Osan, Andreas Schleicher
  • Patent number: 5852139
    Abstract: Polymer mixtures which comprise at least one thermoplastic and at least one oxidized polyarylene sulfide show particularly good tribological behaviour. The thermoplastics of the mixture are, for example, polyacetal, polyester, liquid-crystalline polymer, polyaryl ether ketone, polysulfone, polyether sulfone, polyphenylene sulfide or polyether imide. The oxidized polyarylene sulfide is preferably polyphenylene sulfone. The polymer mixtures are used for producing gear wheels, gear racks, bearings, chains, pulleys, rollers, wheels or gasket materials.
    Type: Grant
    Filed: April 8, 1997
    Date of Patent: December 22, 1998
    Assignee: Ticona GmbH
    Inventor: Di Helmut Scheckenbach