Abstract: The invention relates to a method for producing formaldehyde from methanol by non-oxidative dehydrogenation, in a reactor, in the presence of a catalyst at a temperature between 300 and 1000° C. Said method is characterized in that the generation of the catalyst takes place spatially separate from the reactor and at a temperature greater than the dehydrogenation.

Abstract: Rotatable plastic rollers are produced by either injecting between a roller shaft and an outer running roller layer a thermoplastic material which, during cooling down, shrinks toward the roller shaft and away from the outer running roller layer on account of a contraction in volume or, in the multi-component injection-molding process, by first injecting the outer running roller layer and then injecting between the latter and the roller shaft a thermoplastic material which then likewise shrinks toward the roller shaft and away from the outer running roller layer. The process produces plastic rollers comprising an inner running roller layer (2), which is bonded solidly with the roller shaft (1), and an outer running roller layer (3), which can rotate freely with respect to said inner layer by means of a sliding gap (6). The roller shaft may optionally also be sheathed with a thermoplastic elastomer. This may take place in the same process during the multi-component injection molding.

Abstract: A process for the continuous preparation of a thermoplastic molding composition with narrow scatter of the melt flow index, which comprises mixing two or more chemically identical starting materials of different melt flow index in a pelletizing extruder fitted with an on-line melt flow index meter and adjustable metering systems.

Abstract: Process for the removal of trioxane from a liquid mixture comprising trioxane, formaldehyde, alcohol, hemiformals formed from the form-aldehyde and the alcohol, usual secondary components arising in the preparation of trioxane, and, in addition or as an alternative to the alcohol and the hemiformals, water, in which the trioxane is transferred into the gas phase by vaporization or evaporation and subsequently converted into a liquid state by condensation and obtained as condensate or converted into a solid state by desublimation and obtained as desublimate. Through the process, an increase in the concentration of the trioxane by 2.5 times or more is achieved.

Abstract: A process for the production of electrically conductive layers on the surface of plastics in which the surface of a plastic filled with electrically conductive constituents is irradiated with laser energy in such a way that the plastic is evaporated down to a predetermined depth at the point of incidence by the laser energy, leaving behind the electrically conductive constituents, which increase in concentration and thus form an electrically conductive layer. With the aid of the process, plastic moldings with integrated electrically conductive layers or tracks on the surface can be produced, for example components used in the electrical and electronics industries or other large or small plastic parts of any desired shape which are provided with conductive elements in certain places. The molding can also be a constituent of a composite article with other materials.

Abstract: A plastic molding which on one side has on its surface electrical conductor tracks into which contact pins are inserted, part of these contact pins protruding from the surface with the electrical conductor tracks and part of the contact pins penetrating through the layer of plastic and protruding out on the other, opposite side as well as a subassembly comprising a housing of at least one thermoplastic material or plastic blend, which has at a selected location on its inner side on the surface electrical conductor tracks, into which contact pins are inserted, part of these contact pins protruding from the surface with the electrical conductor tracks and part of the contact pins penetrating through the layer of plastic of the housing and protruding out exclusively or additionally on the opposite outer side, as well as at least one electrical or electronic device.

Abstract: Aluminum salts of phosphinic acid or diphosphinic acids having alkyl and/or aryl substitutes, obtainable by heating an ester of the corresponding phosphinic acids or diphosphinic acids with aluminum hydroxide at a temperature of more than 150° C. under pressure in the presence of water, are distinguished by a particular crystal structure and are suitable as flameproofing agents for plastics.

Abstract: A process for the post-purification in particular of pyrolysis gases for preparing pure formaldehyde, hemiformal being pyrolyzed in an evaporator, the resulting formaldehyde vapor being passed through a condensed liquid component collected in the bottom area of the evaporator, the condensed liquid component being passed out as a falling film situated on the inner wall through a cooled outlet tube disposed in the bottom area of the evaporator and the formaldehyde vapor being passed through the cooled outlet tube in cocurrent and the liquid component and the formaldehyde being taken off separately at the outlet tube end remote from the evaporator.

Abstract: Processes for making trioxane, polyoxymethylene and polyoxymethylene copolymers from formaldehyde, made by the dehydrogenation of methanol in the presence of a catalytic active species set free from a sodium compound, at a temperature in the range of 300° C. to 1000° C., wherein a carrier gas stream which has a temperature above the dehydrogenation temperature is fed to the reactor.

Abstract: The present invention relates to an absorbent comprising at least one cycloolefin copolymer which contains polymerized units which are derived from at least one cyclic and at least one acyclic olefin.

Abstract: The invention relates to a process for using nitric acid to oxidize polyarylene sulfide to polyarylene sulfoxide, oxidizing at least 98% of the sulfide groups of the polyarylene sulfide to sulfoxide groups. According to the invention polyarylene sulfide is treated with nitric acid at a concentration of from 60 to 80% with heating. The polyarylene sulfoxide prepared by the novel process can be used as an excellent chemical blowing agent for foaming thermoplastics.

Abstract: The invention relates to a process for the production of spherical, polyester particles, wherein the particle size can be exactly adjusted in the range of 1 to 200 &mgr;m and a particle size distribution with a span (=d90−d10/d50)≦1.5, as well as the use of the produced particles for toner compositions in electrophotographic and direct printing systems and powder coatings.

Abstract: Powders of oxidized polyarylene sulfide and powders comprising from 1 to 99% by weight of oxidized polyarylene sulfide and from 1 to 99% by weight of a metal, carbide, ceramic or high temperature polyimide, polyamide imide, polyester imide and aromatic polyester plastic, or a mixture thereof are very suitable for use in thermal spraying and thereby form coatings having a strong chemical and mechanical resistance and high dimensional stability when exposed to high and low temperatures. Such coatings are advantageous for use as abradable seal clearance control coating in the compressor section of gas turbine engines, motor vehicle turbochargers and superchargers, and for use as a coating of reaction vessels, kitchen ware, sealings or bearings.

Abstract: The invention relates to a method for producing a cycloolefin copolymer by polymerization of 0.1-99.9 wt. %, with respect to the total amount of monomers, of at least one polycyclic olefin, 0-99.9 wt. %, with respect to the total amount of monomers, of at least one monocyclic olefin, 0.1-99.9 wt. %, with respect to the total amount of monomers, of at least one acyclic 1-olefin, in the presence of a catalyst system consisting of at least one cocatalyst and at least one metal coordination complex with taut geometry.

Abstract: In a process for preparing formaldehyde from methanol by dehydrogenation in a reactor in the presence of a catalyst at a temperature in the range from 300 to 1000° C., a circulating gas stream comprising by-products of the dehydrogenation is passed through the reactor.

Abstract: The process for preparing sulfur-containing polymers, in particular polyarylene sulfides, from at least one sulfide and at least one aromatic dihalogen compound, in a solvent, is carried out in the steps: a) a mixture of aromatic dihalogen compound and sulfide is polymerized, b) aromatic dihalogen compound and sulfide are added to the polymerized mixture and c) the reaction mixture is polymerized further. The sulfur-containing polymers prepared by the process are distinguished by high purity and good mechanical properties.

Abstract: Cycloolefin resin pellets of the present invention comprises a cycloolefin resin pellet and a powdery coating material and/or a liquid coating material, the melting point or the glass transition point of the coating material being 200° C. or lower, and the coating material being adhered onto the surface of the cycloolefin resin pellets, so that the molded product thereof is excellent in transparency.

Abstract: In a process for preparing formaldehyde from methanol by dehydrogenation in a reactor in the presence of a catalyst at a temperature in the range from 300 to 1000° C., a carrier gas stream which has a temperature above the dehydrogenation temperature is fed to the reactor.

Abstract: In a process for preparing formaldehyde from methanol by dehydrogenation in a reactor in the presence of a catalyst at a temperature in the range from 300 to 1000° C., a carrier gas stream which has a temperature above the dehydrogenation temperature is fed to the reactor.

Abstract: The present invention relates to a thermoformable composite film comprising at least one film which comprises cycloolefin copolymer and comprising, laminated to at least one side of this film, a thermoplastic film. The thermoformable film is obtainable by using a solvent-free single-component adhesive to apply the thermoplastic film laminated to the film which comprises cycloolefin copolymer. The film which is laminated is a PVDC-containing thermoplastic film. The thickness of the entire film is from 100 to 500 &mgr;m, the thickness of PVDC film is from 5 to 150 &mgr;m and the thickness of the COC film is from 50 to 400 &mgr;m. The thermoformable composite film is used to produce blister packs.