Patents Assigned to Toshiba Silicone Co., Ltd.
  • Patent number: 5789359
    Abstract: The detergent of this invention, directed to the cleaning of an object having a gap portion at least in part thereof, contains at least one of components of the detergent having a solubility parameter difference of not more than 3 from and a contact angle within 15.degree. with at least one of components of a smear on the object. The detergent provides an ideal cleaning for the object because it easily permeates into and dissolves the machining oil filling the gaps between closely cohering thin metallic strips. The method of cleaning according to the invention has first cleaning the object with a polar detergent and then rinsing and drying the cleaned object with a detergent having low polarity or no polarity. In the precision cleaning of such objects as electronic parts, therefore, it manifests satisfactory cleaning and drying properties.
    Type: Grant
    Filed: April 2, 1996
    Date of Patent: August 4, 1998
    Assignees: Kabushiki Kaisha Toshiba, Toshiba Silicone Co., Ltd.
    Inventors: Hiroshi Shimozawa, Masaru Kumagai, Fumihiko Tsuchitani, Mayumi Koga, Tadayuki Nakamura, Nobuhiro Saitoh, Shigeo Yamafuji
  • Patent number: 5789517
    Abstract: A continuous production method of polyorganosiloxane particles by press-introducing an organoalkoxysilane into an aqueous phase such as water through a porous membrane to form a monodisperse O/W type emulsion and adding a catalyst to the emulsion to condensation polymerize the organoalkoxysilane. Non-porous polyorganosiloxane particles having a uniform particle size can be stably and continuously produced with a high efficiency.
    Type: Grant
    Filed: September 26, 1996
    Date of Patent: August 4, 1998
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Tetsunori Ochiai, Makoto Nishida, Mitsunori Iwasaki
  • Patent number: 5783609
    Abstract: A process which comprises reacting a high molecular weight polyorganosiloxane or a composition containing the same with an alkoxysilane and/or a partially hydrolyzed condensate thereof at a temperature of lower than 300.degree. C. in the presence of an alcoholate compound and recovering the resulting organoalkoxysilane and, in addition thereto, at least one of a distillable polyorganosiloxane low molecular weight compound, a non-volatile liquid polyorganosiloxane and a silica; and a process which comprises reacting a high molecular weight polyorganosiloxane or a composition containing the same with an alcoholate compound at a temperature of 50.degree. to 150.degree. C. in an anhydrous state and recovering the resulting distillable polyorganosiloxane low molecular weight compound and, in addition thereto, at least one of an organoalkoxysilane and a non-volatile liquid polyorganosiloxane.
    Type: Grant
    Filed: June 27, 1996
    Date of Patent: July 21, 1998
    Assignees: Tama Chemicals Co., Ltd., Toshiba Silicone Co., Ltd.
    Inventors: Tsurahide Cho, Yoshiro Ohta, Toshitsura Cho, Tohru Yamashita, Nobuaki Ohkawa, Makoto Nishida
  • Patent number: 5782983
    Abstract: A part still wet with water or an aqueous type detergent adhering to the surface thereof is drain washed in a washing tank using a hydrophobic dewatering cleaning agent. In this operation of dewatering cleaning, the hydrophobic dewatering cleaning agent stored in the washing tank is circulated between the washing tank and a reserve tank to deprive the hydrophobic dewatering cleaning agent of water entrained thereby by means of a concentration type filter inserted in a path laid for the circulation. A hydrophobic filter is mainly used as the concentration type filter. The dewatering cleaning is continued and meanwhile the consequently isolated hydrophobic dewatering cleaning agent is exclusively returned to the washing tank. As a result, the water concentration in the hydrophobic dewatering cleaning agent stored in the washing tank can be constantly kept below a prescribed level.
    Type: Grant
    Filed: April 19, 1994
    Date of Patent: July 21, 1998
    Assignees: Kabushiki Kaisha Toshiba, Toshiba Silicone Co., Ltd.
    Inventors: Minoru Inada, Yasutaka Imajo, Kimiaki Kabuki, Nobuhiro Saitoh
  • Patent number: 5759638
    Abstract: The present invention relates to a process for forming an electronic circuit, which comprises coating a polyorganosilane on at least one surface of a substrate for forming an electronic circuit, followed by drying to form a solid state polysilane thin film, masking a portion for forming a circuit of said thin film and oxidizing a remaining portion to form an insulating portion, and then doping an oxidizing substance to the portion subjected to masking to form a conductive portion, and in order to oxidize a partial portion of the thin film, said thin film is irradiated with UV light in the presence of oxygen, preferably, in the oxidizing step, by carrying out partial oxidation while controlling an oxidation degree, the remaining portion is converted into three or more kinds of portions having different volume resistivities.
    Type: Grant
    Filed: March 4, 1997
    Date of Patent: June 2, 1998
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Takafumi Imai, Keiji Kabeta, Kiyoaki Syuto, Shigeru Wakamatsu
  • Patent number: 5717009
    Abstract: An adhesive composition which comprises:(A) 100 parts by weight of a polyorganosiloxane represented by the formula (I): ##STR1## (wherein R.sup.1 s may be the same or different from each other and each represent a monovalent hydrocarbon group or a halogen-substituted hydrocarbon group; and n is a positive integer);(B) 0.5 to 10 parts by weight of a tetraalkoxysilane represented by the following formula:R.sup.2.sub.a Si(OR.sup.3).sub.4-a (II)(wherein R.sup.2 represents an alkyl group having 1 to 3 carbon atoms, a phenyl group or a vinyl group; R.sup.3 represents an alkyl group having 1 to 4 carbon atoms or an alkoxy-substituted alkyl group having 3 to 6 carbon atoms; and a is 0 or 1),or a partially hydrolyzed condensate thereof; and(C) 0.1 to 15 parts by weight of a trialkoxysilane represented by the formula (III):R.sup.4 (R.sup.5).sub.b Si(OR.sup.6).sub.3-b (III)(wherein R.sup.4 represents a substituted or unsubstituted aminoalkyl group; R.sup.
    Type: Grant
    Filed: July 17, 1996
    Date of Patent: February 10, 1998
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Shigeki Matsushita, Fumihiko Kobayashi
  • Patent number: 5716443
    Abstract: A surface treating agent for coating vehicles comprises an amino group-containing polyorganosiloxane represented by the general formula (1) below, an organic acid, polydimethylsiloxane having a viscosity at 25.degree. C. of 5 to 300 cSt and an aqueous medium: ##STR1## wherein R is a monovalent hydrocarbyl group having a carbon number of 1 to 20, R.sup.1 is any of a monovalent hydrocarbyl group having a carbon number of 1 to 20, an alkoxy group having a carbon number of 1 to 6 or hydroxyl group, m is an integer of 10 to 1,000, n is an integer of 1 to 20, R each may be identical with or different from the other, and R.sup.1 each may also be identical with or different from the other, R.sup.2 is a substituent represented by the general formula (2) of: ##STR2## wherein R.sup.3 and R.sup.5 are a divalent hydrocarbyl group having a carbon number of 1 to 6, R.sup.4, R.sup.6 and R.sup.7 are hydrogen atom or a monovalent hydrocarbyl group having a carbon number of 1 to 20, r is an integer of 0 to 3, R.sup.3 and R.sup.
    Type: Grant
    Filed: September 5, 1996
    Date of Patent: February 10, 1998
    Assignees: Taiho Industries, Co., Ltd., Toshiba Silicone Co., Ltd.
    Inventors: Tetsuo Kijima, Makoto Miyazaki, Sachiko Yusa
  • Patent number: 5688840
    Abstract: A process for preparing a room temperature-curable organopolysiloxane composition comprising (A) (A-1) a specific organopolysiloxane or a mixture of (A-1) and (A-2) a specific silicone compound or a partial hydrolysis product thereof, (B) silica powder having a specific surface area of 20 to 800 m.sup.2 /g, (C) a curing catalyst, and (D) a silane coupling agent or an organopolysiloxane having a specific substituent, which comprises adding component (D) to component (A) prior to kneading or at the time of kneading components (A) and (B). The composition exhibits excellent physical characteristics, excellent workability in terms of flowability, adhesion, and extrudability, undergoes no change in viscosity with time and, in particular, suffers no impairment of these characteristics when stored for a long period of time.
    Type: Grant
    Filed: October 4, 1995
    Date of Patent: November 18, 1997
    Assignee: Toshiba Silicone Co., Ltd.
    Inventor: Kazuhisa Ono
  • Patent number: 5676938
    Abstract: A cosmetic composition comprising a silicone resin comprising from 50 to 99 mol % of R.sup.1 Si(O).sub.1.5 units wherein R.sup.1 represents a substituted or unsubstituted monovalent hydrocarbon group and from 1 to 50 mol % of (R.sup.2).sub.3 Si(O).sub.0.5 units wherein R.sup.2 represents a substituted or unsubstituted monovalent hydrocarbon group, sum of the R.sup.1 Si(O).sub.0.5 units and the (R.sup.2).sub.3 Si(O).sub.0.5 units being 100 mol %.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: October 14, 1997
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Hiroshi Kimura, Yutaka Horie, Yoshiyuki Sato
  • Patent number: 5641832
    Abstract: A room temperature-curable organopolysiloxane composition is disclosed, comprising (A) 100 parts by weight of an organopolysiloxane terminated with a silanol group or an alkoxy group, (B) from 0.1 to 30 parts by weight of an organosilicon compound containing more than 2, in average, of hydrolyzable groups bonded to the silicon atom per molecule, (C) from 1 to 650 parts by weight of an oil-absorbing filler which has been prepared by impregnating (a) a porous filler with (b) a volatile organic compound which is incompatible or partly compatible to component (A) and compatible with an organic oily substance in an amount of from 1% by weight based on the weight of the porous filler up to a saturation amount and, if desired, (D) a requisite amount of a curing catalyst. The composition exhibits satisfactory adhesion to a substrate in such adhesion operation as an FIPG system without requiring wiping of organic oily contaminants on the substrate, such as hydrocarbon oils, e.g.
    Type: Grant
    Filed: January 11, 1996
    Date of Patent: June 24, 1997
    Assignee: Toshiba Silicone Co. Ltd.
    Inventor: Hisayuki Nagaoka
  • Patent number: 5633312
    Abstract: Disclosed is a process for preparing a polyorganosilane which comprises subjecting a disilane compound having at least two substituted or unsubstituted hydrocarbyloxy groups in one molecule to disproportionation reaction in the presence of a catalyst comprising a reaction product of an organic alkali metal compound represented by the formula (I):RM (I)wherein R represents a substituted or unsubstituted monovalent hydrocarbon group; and M represents an alkali metal,represented by the formula (III):MR.sup.3.sub.p M (III)wherein R.sup.3 represents a saturated or unsaturated chain or cyclic divalent hydrocarbon group or a divalent heterocyclic group, two or more R.sup.3 s may be the same or different and an ether oxygen atom may exist between two or more R.sup.3 s; p represents an integer of 1 or more; and M represents an alkali metal atom,and at least one of a disilane compound and a silane compound both of which have a substituted or unsubstituted hydrocarbyloxy group(s).
    Type: Grant
    Filed: April 1, 1996
    Date of Patent: May 27, 1997
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Keiji Kabeta, Sigeru Wakamatsu, Takafumi Imai
  • Patent number: 5607992
    Abstract: An addition reaction type silicone rubber composition for injection molding compounded with an azo compound, carbon black, and at least one of cerium hydroxide and cerium oxide is disclosed. Silicone rubber moldings having a small compression set and an excellent flame retardance are obtained without need of carrying out a postcure after primary molding. Further, integral molding of the silicone rubber and a thermoplastic resin can be carried out.
    Type: Grant
    Filed: February 23, 1996
    Date of Patent: March 4, 1997
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Shuji Chiba, Takeshi Matsumoto
  • Patent number: 5591783
    Abstract: An ultraviolet-curable silicone composition involving:(A) 100 parts by weight of a polyorganosiloxane comprising structural units represented by the general formula R.sup.1.sub.m R.sup.2.sub.n SiO.sub.(4-m-n)/2 ;(B) from 0.1 to 10 parts by weight of a polyorganosiloxane which is blocked by (OH)R.sup.3.sub.2 Si.sub. 1/2 at both ends or (b) an alcohol-modified polyorganosiloxane containing two or more alcoholic OH groups per molecule; and(C) a catalytically effective amount of an onium salt as a photoinitiator.
    Type: Grant
    Filed: February 9, 1995
    Date of Patent: January 7, 1997
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Keiji Kobayashi, Roy M. Griswold
  • Patent number: 5584917
    Abstract: The water repellent for window panes of automobiles of this invention comprises an amino group-containing polyorganosiloxane having the specific structure, an organic acid, a surfactant and an aqueous solvent, which is usable regardless of whether it is fine or rains, and can provide a uniform film having a good water repellency held for a long period.
    Type: Grant
    Filed: July 5, 1995
    Date of Patent: December 17, 1996
    Assignees: Taiho Industries Co., Ltd., Toshiba Silicone Co., Ltd.
    Inventors: Tetsuo Kijima, Seigo Shinohara, Sachiko Yusa
  • Patent number: 5536537
    Abstract: A process of producing a surface-modified weather strip for automobiles is disclosed. The process comprises coating a silicone emulsion composition formed by mixing and dispersing the components (A) to (D) as defined hereinabove on the surface of a weather strip for automobiles, and heat curing the coating at a temperature of from 50.degree. to 250.degree. C. The weather strip thus produced has excellent durability, soundproof property, weather resistance, non-sticking property, antifreezing property, slipping property, abrasion resistance, etc.
    Type: Grant
    Filed: March 17, 1995
    Date of Patent: July 16, 1996
    Assignees: Toshiba Silicone Co., Ltd, Toyoda Gosei Co., Ltd.
    Inventors: Takashi Mizushima, Hiroyoshi Shimotsu
  • Patent number: 5489662
    Abstract: A process for the preparation of an organosilicon polymer, which comprises reacting one equivalent of a bis(alkoxysilyl) compound represented by the following general formula:R.sup.1 R.sup.2 R.sup.3 Si--(A).sub.p --SiR.sup.1 R.sup.2 R.sup.3wherein R.sup.1, R.sup.2 and R.sup.3 each represents the same or different substituted or unsubstituted monovalent hydrocarbon group or an alkoxy group, with the proviso that at least one of R.sup.1, R.sup.2 and R.sup.3 is an alkoxy group; A represents a divalent aromatic group, a divalent conjugated or nonconjugated unsaturated aliphatic group, or a divalent saturated aliphatic group; and p represents an integer of 1 or more, with one or more equivalents of an alkoxydisilane represented by the following general formula:(OR.sup.4).sub.6-n Si.sub.2 (R.sup.5).sub.nwherein R.sup.4 and R.sup.
    Type: Grant
    Filed: August 31, 1994
    Date of Patent: February 6, 1996
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Shigeru Wakamatsu, Keiji Kabeta, Takafumi Imai
  • Patent number: 5457167
    Abstract: A polyorganosiloxane-type thermoplastic resin having excellent slidability, abrasion resistance, weatherability, impact strength, fatigue resistance and chemical resistance is disclosed. The thermoplastic resin comprises a graft copolymer (IV) obtained by graft-polymerizing at least one vinyl monomer (v) onto a modified polyorganosiloxane obtained by polymerizing 80 to 99.8% by weight of an organosiloxane (I) having the structural unit described thereinabove, 0.1 to 10% by weight of at least one graft crosslinking agent (II) containing an alkoxysilyl group, selected from the group consisting of a vinyl-type graft crosslinking agent, a mercapto-type graft crosslinking agent, an acryloyl-type crosslinking agent and a vinylphenyl-type crosslinking agent, and 0.1 to 10% by weight of a compound (III) having two alkoxysilyl groups, provided that (I)+(II)+(III)=100% by weight.
    Type: Grant
    Filed: November 15, 1994
    Date of Patent: October 10, 1995
    Assignees: Japan Synthetic Rubber Co., Ltd., Toshiba Silicone Co., Ltd.
    Inventors: Keigo Higaki, Kouichi Sakurai, Nobuo Kawahashi, Yoichi Kamoshida, Makoto Matsumoto, Kazuto Shinohara, Kouji Kanuma
  • Patent number: 5424352
    Abstract: A heat-conductive silicone rubber composition compounded with magnesium oxide obtained by a dead burning method, wherein the magnesium oxide comprises magnesium oxide having specific properties and/or which is obtained from a water-soluble magnesium salt and an alkaline material in a specific method. The silicone rubber composition has excellent heat conductivity and workability.
    Type: Grant
    Filed: March 22, 1994
    Date of Patent: June 13, 1995
    Assignee: Toshiba Silicone Co., Ltd.
    Inventor: Satoshi Watanabe
  • Patent number: 5415912
    Abstract: A pressure-sensitive adhesive composition comprising (A) a pressure-sensitive adhesive and (B) a polyorganosilsesquioxane fine powder is disclosed. The composition shows excellent adhesion tackiness, and enables smooth rewinding during production of pressure-sensitive tapes.
    Type: Grant
    Filed: September 20, 1993
    Date of Patent: May 16, 1995
    Assignee: Toshiba Silicone Co., Ltd.
    Inventors: Yoshitaka Ushizaka, Shinya Watanabe
  • Patent number: 5378406
    Abstract: A fungiresistant polyorganosiloxane composition comprising(A) 100 parts by weight of a polyorganosiloxane having a viscosity at 25.degree. C. of from 100 to 500,000 cSt, each of both the terminals of which being blocked with a silanol group or an alkoxy group,(B) from 0.1 to 20 parts by weight of an organisilicon compound having on the average more than 2 hydrolyzable groups each bonded to a silicon atom in the molecule,(C) from 0.001 to 25 parts by weight of a benzimidazolylcarbamate compound represented by the formula ##STR1## wherein R.sup.1 represents a hydrogen atom, an alkyl group having from 1 to 4 carbon atoms, a halogen atom, or a nitro group; R.sup.2 represents an alkyl group having from 1 to 4 carbon atoms or an alkoxyalkyl group having from 2 to 4 carbon atoms: and R.sup.3 represents a hydrogen atom, an N-substituted or unsubstituted carbamoyl group or an N-substituted or unsubstituted carbamoyloxy group, and(D) from 0.
    Type: Grant
    Filed: July 12, 1993
    Date of Patent: January 3, 1995
    Assignee: Toshiba Silicone Co., Ltd.
    Inventor: Hisayuki Nagaoka