Abstract: A catalytic method for treating an H2S/SO2 mixture for producing liquid sulphur including the following steps: a) at least one step of heating the mixture containing H2S/SO2 to a temperature Tc; b) at least one step of catalytically reacting the heated mixture obtained in a) in the presence of at least one catalyst and at least one step of recovering the exiting mixture containing gaseous sulphur; and c) at least one step of converting the gaseous sulphur contained in the exiting mixture obtained at step b) into liquid sulphur, wherein between step b) and step c), the temperature Ts of said exiting mixture and the dew point Tr of the gaseous sulphur contained in said exiting mixture are measured and in that the heating temperature Tc of step a) is adjusted so that the temperature Ts is 5° C. to 30° C. above the dew point Tr.
Abstract: The invention relates to a method of determining the rate of dilution of the lubricating oil by the fuel in an internal combustion engine. The invention is characterized in that it comprises the following steps consisting in: marking either the lubricating oil or the fuel with a radioactive tracer, measuring the radioactivity of an oil sample using a detector that is sensitive to the radioactive radiation emitted by the radioactive tracer, and transmitting the results of the aforementioned measurements to a computer which uses said results in order to calculate the rate of dilution of the lubricating oil by the fuel. The invention also relates to a device which is used to implement said method, in particular a test bench for engines.
Type:
Grant
Filed:
December 17, 2004
Date of Patent:
August 24, 2010
Assignees:
Total Raffinage Marketing, Delta Services Industriels S.P.R.L.
Abstract: A method is proposed for heating a hydrocarbons reservoir, comprising the provision of an installation comprising: a first wellbore equipped with an injection string fitted with an adjustable choke and an extraction string fitted with an adjustable choke, a set of sensors, intended to measure physical variables, an automatic device making it possible to control and monitor the operation of the installation; the circulation of steam from one string to the other; the control of the steam injection flow rate in function of a target value; the keeping of a set of physical variables within a predetermined range of values by continuous action of the automatic device on the choke of the injection string, and on the choke of the extraction string.
Type:
Application
Filed:
December 22, 2009
Publication date:
August 12, 2010
Applicant:
TOTAL S.A.
Inventors:
Dominique Mauduit, Bruno Marty, Pierre Lemetayer, Emmanuel Toguem Nguete
Abstract: A flow device intended for a two-phase flow processing enclosure of the natural counter-flow type, in which an ascending gaseous flow and a descending liquid flow circulate. The device is formed by an appreciably horizontal tray having openings for the passage of the ascending gaseous flow, and a channel for recovering the descending liquid flow, the channel discharging into a flow orifice. The flow device includes a single guide device extending beneath the tray and connected to the flow orifice in such a way that the liquid flows on its outer wall. Also, a processing enclosure, particularly for processing a hydrocarbonated or aqueous type liquid flow, containing the flow device.
Abstract: The present invention relates to a process for the production of a high melt flow propylene homopolymer or random copolymer with low odor and low volatiles content, which is suitable for thin-walled injection molding applications, said process comprising the step of polymerizing propylene and one or more optional comonomers in presence of a Ziegler-Natta catalyst comprising a titanium compound having at least one titanium-halogen bond, and a diether compound as internal electron donor, both supported on a magnesium halide in active form, an organoaluminium compound and an optional external donor.
Abstract: A device for discharging, through a central rotating chimney, fluids from a fluidized bed driven in a rotational movement in the same direction by the rotation of the outer circular wall of a reaction chamber and/or by injection of part of these fluids along the circular wall of a fixed or rotating chamber, and methods for catalytic polymerization, drying, or other treatments of solid particles in suspension in a rotating fluidized bed or for cracking or other catalytic conversions of fluids using this device.
Abstract: The disclosure relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The disclosure also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The disclosure further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
Type:
Application
Filed:
July 17, 2008
Publication date:
August 5, 2010
Applicants:
TOTAL REFFINAGE MARKETING, CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS
Inventors:
Pierre Chaverot, Charlotte Godivier, Ludwik Leibler, Ilias Iliopoulos, Amanda Kathryn Leach
Abstract: The invention relates to a bituminous composition that comprises a major portion of at least one bitumen and a minor portion of at least one chemical additive, said additive being an organogelling agent that generates a network of hydrogen bonds between the organogelling molecules constituting the same, and trapping the bitumen phase up to a maximum temperature TR of between 40 and 120° C. The invention also relates to the use of these bitumen compositions in the field of road applications, particularly in the production of road binders, as well as in industrial applications. The invention also relates to a method for preparing these bituminous compositions.
Type:
Application
Filed:
January 18, 2008
Publication date:
August 5, 2010
Applicant:
TOTAL RAFFINAGE MARKETING
Inventors:
Laurence Lapalu, Régis Vincent, Laurent Bouteille, Benjamin Isare
Abstract: Provided is a method for preparing a support for olefin polymerization catalysts used in polyolefin preparation processes. Particularly, provided is a novel method for preparing a support for olefin polymerization catalysts comprising the reaction of metal magnesium with an alcohol in the presence of an additive for initiating the reaction, characterized in that halogenated nitrogen compound is used as the additive for initiating the reaction, resulting in a spherical dialkoxy magnesium support.
Type:
Grant
Filed:
December 21, 2006
Date of Patent:
August 3, 2010
Assignee:
Samsung Total Petrochemicals Co., Ltd.
Inventors:
Eun-Il Kim, Young-Joo Lee, Hoe-Chul Jung, Joon-Ryeo Park
Abstract: The disclosure relates to a bitumen/polymer composition comprising at least one bitumen and at least one graft polymer, the grafts enabling the bitumen/polymer compositions to be thermoreversibly cross-linked. The disclosure also relates to the use of said bitumen/polymer compositions in fields of application relating to roads, especially in the production of asphalt binders, and in industrial fields of application. The disclosure further relates to the method for producing said thermoreversibly cross-linked bitumen/polymer compositions.
Type:
Application
Filed:
July 18, 2008
Publication date:
July 29, 2010
Applicants:
TOTAL RAFFINAGE MARKETING, CENTRE NATIONAL DE RECHERCHE SCIENTIFIQUE (CNRS)
Inventors:
Pierre Chaverot, Charlotte Godivier, Ludwik Leibler, Ilias Iliopoulos, Amanda Kathryn Leach
Abstract: The invention relates to a method of determining the consumption of oil from an oil separation system (2) in the blow by gas recycling circuit of an internal combustion engine.
Type:
Grant
Filed:
March 11, 2005
Date of Patent:
July 27, 2010
Assignees:
Total Raffinage Marketing, Delta Services Industriels S.P.R.L.
Abstract: A method, program and computer system for conciliating hydrocarbon reservoir model data are provided. This method, implemented by means of a computer, comprises the steps of: providing (S10) a set of local permeability values kHi of the reservoir and (S12) a value of an apparent permeability KH of the reservoir; and numerically calculating (S22) a value of a power ?H, from: a mean power formula, of the type K H ? H = 1 N × ? i = 1 i = N ? k H i ? H , relating the apparent permeability KH to the local permeabilities via the power ?H; and the set of local permeability values kHi and the value of the apparent permeability KH; comparing (S30) the calculated power ?H with a reference value; and depending on this comparison, modifying (S20) the set of local permeability data kHi.
Abstract: The present invention relates to a process to make light olefins from an oxygen-containing, halogenide-containing or sulphur-containing organic feedstock comprising: contacting said oxygen-containing, halogenide-containing or sulphur-containing organic feedstock in a primary reactor with a catalyst made of a metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology at conditions effective to convert at least a portion of the feedstock to form a first reactor effluent comprising light olefins and a heavy hydrocarbon fraction; separating said light olefins from said heavy hydrocarbon fraction; contacting said heavy hydrocarbon fraction in a second reactor at conditions effective to convert at least a portion of said heavy hydrocarbon fraction to light olefins; wherein said MeAPO has an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula HxMeyAlzPkO2 in which, y+z+k=1 x<=y y has a value ranging from 0.0008 to 0.
Abstract: The present invention concerns a monovinylaromatic polymer composition comprising a bio-sourced polymer dispersed phase and optionally a rubber dispersed phase wherein said bio-courced polymer dispersed phase is predominantly made of particles having a size of less than 10 ?m. The present invention also relates to a process (hereunder referred as the first process) to make said monovinylaromatic polymer composition, said process comprising admixing: a monovinylaromatic monomer, at least one bio-sourced polymer, optionally a rubber, at conditions effective to polymerize at least a part of the monovinylaromatic monomer and generate a compatibilizer of the bio-sourced polymer and monovinylaromatic polymer.
Abstract: The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerisation of olefins comprising the steps of: I) providing a support prepared consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalising the support with a solution containing a fluorinated functionalising agent; IV) heating the functionalised and fluorinated support of step c) under an inert gas and then under oxygen; V) retrieving an active fluorinated support. That activating support is used to activate a metallocene catalyst component for the polymerisation of olefins.
Type:
Grant
Filed:
July 21, 2006
Date of Patent:
July 20, 2010
Assignee:
Total Petrochemicals Research Feluy
Inventors:
Floran Prades, Christophe Boisson, Roger Spitz, Abbas Razavi
Abstract: Provided is a preparation method of a catalyst for ethylene (co)polymerization, comprising the following steps: (1) preparing a magnesium compound solution by contact-reacting a halogenated magnesium compound with a mixed solvent of cyclic ether and at least one alcohol; (2) reacting the resulted magnesium compound solution from the above step (1) with a silicon compound having at least one alkoxy group; (3) preparing a support by adding a titanium compound to the resulted product from the step (2); and (4) reacting thus obtained support with a titanium compound and optionally a monoester compound, resulting in a catalyst. Catalysts prepared according to the present invention have a regulated particle shape, and their particle size can be easily adjusted. Therefore, with such catalyst, it is possible to produce polymers having high bulk density at high production yield.
Type:
Grant
Filed:
November 19, 2008
Date of Patent:
July 20, 2010
Assignee:
Samsung Total Petrochemicals Co., Ltd.
Inventors:
Jin-Kyu Ahn, Joon-Ryeo Park, Chun-Byung Yang, Jong-Sik Kim
Abstract: Production brines are used to scrub a horizontal stack receiving exhaust from an energy source, controlling, reducing, or both noxious chemicals. Mutual remediation of flows from petroleous production cool and scrub exhausts from flares burning waste hydrocarbons, heaters lowering viscosity of crude oil, engines driving oil pumps or natural gas compressors, and the like. Resulting evaporation of production brines results in distilled water, more concentrated brines to reduce hauling, or, optionally, dehydrated dry waste minerals from the brines. Year-round operation of brine evaporation ponds is facilitated, and may be another source of process pre-heating.
Type:
Application
Filed:
January 14, 2010
Publication date:
July 15, 2010
Applicant:
Total Water Management LLC
Inventors:
J. Clair Batty, Craig E. Cox, David A. Bell
Abstract: Petroleous production is associated with effluents well known to foul lines, nozzles, and containers while consuming substantial energy to assist in both production and remediation. A heat exchanger and manifold system maximizes flows, minimizes changes in flow cross-section, and maximizes heat transfer area, while recycling both water and heat between processes. Dirty regions and clean regions result from scrubbing horizontal exhaust stacks and evaporation of production water in concert to remediate one another, while recycling a significant portion of the energy consumed by each. The heat exchanger relies on a manifold having many layered conduits, each connected to a single layer level of one or more cylindrical conduits in the exchanger. The cylinders of the exchanger themselves are arranged in multiple layers, each layer of a heat exchanger element being connected to a single layer of the manifold.
Type:
Application
Filed:
January 14, 2010
Publication date:
July 15, 2010
Applicant:
Total Water Management, LLC
Inventors:
J. Clair Batty, David A. Bell, Craig E. Cox
Abstract: The present invention discloses an active supported catalyst system comprising: a) an iron-based non-metallocene catalyst component; b) an alkylating agent; c) an activating functionalised and fluorinated support. It also discloses a method for preparing said active supported catalyst system and its use in the polymerisation of olefins.
Type:
Application
Filed:
July 26, 2006
Publication date:
July 15, 2010
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Floran Prades, Roger Spitz, Christophe Boisson, Sabine Sirol, Abbas Razavi
Abstract: The present invention relates to metalloaluminophosphate (MeAPO) molecular sieve with lamellar crystal morphology having an empirical chemical composition on an anhydrous basis, after synthesis and calcination, expressed by the formula HxMeyAlzPkO2 wherein, y+z+k=1 x<=y said molecular sieve having predominantly a plate crystal morphology in which the width (W) and the thickness (T) are such as: W/T is >=10 and advantageously ranges from 10 to 100. In a preferred embodiment T is <=0.15 ?m, more desirably <=0.10 ?m, more desirably <=0.08 ?m, advantageously ranges from 0.01 to 0.07 ?m and preferably from 0.04 to 0.07 ?m.
Type:
Application
Filed:
March 10, 2008
Publication date:
July 15, 2010
Applicants:
Total Petrochemcials Research Feluy, Centre National De La Recherche Scientifique (CNRS)
Inventors:
Walter Vermeiren, Nikolai Nesterenko, Carolina Petitto, Francesco Di Renzo, Francois Fajula