Abstract: Provided is a process for polymerization and copolymerization of ethylene, specifically comprising carrying out polymerization or copolymerization ethylene in the presence of (a) a solid complex titanium catalyst which is produced by the process comprising: (i) preparing a magnesium compound solution by contacting a halogenated magnesium compound and an alcohol for allowing a reaction; (ii) reacting the resulted magnesium compound solution with an ester compound having at least one hydroxyl group and a silicon compound having at least one alkoxy group; (iii) reacting the resulted solution with a mixture of a titanium compound and a silicon compound to obtain a solid titanium catalyst component; (iv) washing the resulted solid titanium catalyst component with a halogenated saturated hydrocarbon compound; and (v) further reacting the washed solid titanium catalyst component with a titanium compound to obtain a solid complex titanium catalyst, and (b) an organometallic compound from Group II or III of Periodic t
Type:
Grant
Filed:
December 28, 2006
Date of Patent:
July 13, 2010
Assignee:
Samsung Total Petrochemicals Co., Ltd.
Inventors:
Sang Yull Kim, Ho Sik Chang, Chun Byung Yang
Abstract: The present invention relates to the field of single site catalyst systems based on phosphino-iminophenol complexes that are suitable for oligomerising or polymerising ethylene and alpha-olefins.
Abstract: Provided is a method of preparation of a spherical support for an olefin polymerization catalyst. Specifically, provided is a method of preparation of a support which can be used in preparation of an olefin polymerization catalyst, wherein, MgX(I) (X=halogen atom) is prepared by reacting a reaction initiator, nitrogen halide, and magnesium metal, and then magnesium metal and alcohol are reacted in the presence of the MgX, thereby resulting a smooth-surfaced spherical dialkoxy magnesium support having a uniform particle size distribution.
Type:
Application
Filed:
September 11, 2008
Publication date:
July 8, 2010
Applicant:
SAMSUNG TOTAL PETROCHEMICALS CO., LTD.
Inventors:
Eun-Il Kim, Young-Joo Lee, Hoe-Chul Jung, Joon-Ryeo Park
Abstract: Provided is a method of preparation of dialkoxy magnesium that is used as a support for an olefin polymerization catalyst for polyolefin preparation. Specifically, provided is a method of preparation of a support for an olefin polymerization catalyst, which comprises preparation of dialkoxy magnesium by reacting magnesium metal with alcohol in the presence of a reaction initiator, wherein bromine is used as the reaction initiator so as to obtain spherical dialkoxy magnesium.
Type:
Application
Filed:
September 11, 2008
Publication date:
July 8, 2010
Applicant:
SAMSUNG TOTAL PETROCHEMICALS CO., LTD.
Inventors:
Eun-Il Kim, Young-Joo Lee, Hoe-Chul Jung, Joon-Ryeo Park
Abstract: The present invention for a two-stroke marine engine, which can be used with both high-sulphur content fuel oils and low-sulphur content fuel oils. It relates to a cylinder lubricant having a BN determined according to the standard ASTM D-2896 greater than or equal to 40 milligrams of potash per gram of lubricant, comprising a lubricant base stock for marine engines and at least one overbased detergent based on alkali metals or alkaline-earth metals, characterized in that it also contains a quantity of 0.01% to 10% preferably 0.1% to 2% by weight relative to the total weight of the lubricant, of one or more (A) compounds chosen from the primary, secondary or tertiary monoalcohols the alkyl or alkylene chain of which is saturated or unsaturated, linear or branched and comprises at least 12 carbon atoms.
Type:
Application
Filed:
October 5, 2007
Publication date:
July 1, 2010
Applicant:
TOTAL RAFFINAGE MARKETING
Inventors:
Valérie Doyen, Denis Lancon, Jean-Marie Bourmaud, Florence Bredon
Abstract: The present invention relates to a process to monitor unwanted formation of a polymer having internal mechanical strain wherein acoustic emission generated by said polymer formation is detected by one or more acoustic sensors attached to a piece of equipment. In a preferred embodiment the device to carry-out the process comprises: a resonant piezo-electric transducer attached to a piece of equipment, optionally a conditioner unit, connected to the previous transducer, said conditioner unit comprising means for filtering and an operational preamplifier, optionally a unit, connected to said conditioner unit, in which there is at least one adjustable threshold level (unless the conditioner unit comprises said adjustable threshold level), optionally a pulse counter connected to the conditioner unit comprising at least one adjustable threshold level. The invention is particularly useful for monitoring the unwanted popcorn polymers made from butadiene or isoprene.
Type:
Application
Filed:
January 8, 2008
Publication date:
July 1, 2010
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Jean-Pierre Thoret Bauchet, Gustav Alcuri
Abstract: The present invention discloses the use of a chromium-based catalyst system in two serially connected loop reactors for copolymerising ethylene and a comonomer, at reduced productivity, the final polyethylene having a reduced amount of gel.
Type:
Grant
Filed:
February 8, 2005
Date of Patent:
June 29, 2010
Assignee:
Total Petrochemicals Research Feluy
Inventors:
Philippe Bodart, Philippe Marechal, Eric Damme
Abstract: A mine transport vehicle is disclosed having two main bodies, one a power and control section and the other a payload section, the two sections being connected by an articulating joint. The power and control section has seating for an operator and a passenger. The payload section has seating for four passengers as well as capacity for at least approximately 2000 pounds of equipment. The weight distribution of each section is such that the stress on the frame and articulating joint is minimized thus providing improved life of the joint.
Type:
Grant
Filed:
April 25, 2007
Date of Patent:
June 29, 2010
Assignee:
Listerhill Total Maintenance Center LLC
Inventors:
Donald B. Flournoy, Jr., Floyd T. Patterson, Michael J. Stumpe, John F. Bryerton, Hilard R. Cantrell, Jr., Timothy A. Ellett
Abstract: A process is provided for recovering polymer solids from a polymerisation reactor effluent. The process comprises extracting the polymerisation effluent from a polymerisation reactor; passing the effluent, or a part thereof, to a flash vessel for flashing liquid in the effluent to vapour, and removing said vapour from said flash vessel; passing the polymer solids from the flash vessel to a transfer apparatus which comprises a transfer vessel; passing the polymer solids from the transfer vessel to a purging means for removing residual liquid from the polymer solids; wherein the polymer solids are passed from the flash vessel to the purging means in a continuous flow such that a quantity of polymer solids is maintained in the transfer vessel. An apparatus for performing the process is also provided.
Abstract: The present invention discloses a slurry loop reactor having at least two loops (1, 2) and comprising a by-pass line (11) connecting two points (12, 13) of the same loop reactor by an alternate route having a different transit time than that of the main route, said by-pass line also collecting the growing polymer of a first loop reactor (1) and sending said growing polymer to an entry point (13) in a second reactor (2).
Abstract: The present invention relates to the field of single site catalyst systems based on pyridine-iminophenol, pyridine-iminoalcohol or pyridine-iminoamine complexes and suitable for oligomerising or homo- or co-polymerising ethylene and alpha-olefins.
Abstract: The present invention relates to a bituminous mastic, in other words a mixture comprising on the one hand at least one bitumen-based hydrocarbon binder, More particularly a blown bitumen, and on the other hand fines, including an ultrafines fraction. The invention also relates to poured asphalts and bituminous coatings comprising a bituminous mastic. A method of producing such bituminuous materials is described, as are the road-building and industrial applications of these materials.
Type:
Application
Filed:
February 13, 2007
Publication date:
June 24, 2010
Applicant:
TOTAL FRANCE
Inventors:
Pierre Chaverot, Gilles Gauthier, Herve Di Benedetto, Brice Delaporte
Abstract: The invention relates to a hydrocarbon hydroconversion catalyst comprising a carrier based on refractory oxide, a metal of the group VIII, and a metal of the group VIB. Said catalyst is characterised in that it also comprises at least one organic compound selected from the alkene diols of formula (I) wherein R1 represents a C2-10 alkenylene group, preferably C2-4 alkenylene, a C6-18 arylene group, or a C7-18 alkylene-arylene group, and each R2 independently represents a hydrogen atom or a C1-18 alkyl group, a C1-18 alkenyl group, a C6-18 aryl group, a C3-8 cycloalkyl group, or a C7-20 alkylaryl or arylalkyl group, or the two groups R2 together form a divalent C2-18 group, the carbonated chain of the R2 groups containing or carrying at least one heteroatom selected from S, N and O. The invention also relates to a method for preparing one such catalyst, and to the use of said catalyst for hydrotreatment or hydroconversion.
Type:
Grant
Filed:
January 19, 2006
Date of Patent:
June 22, 2010
Assignees:
Total Raffinage Marketing, IFP
Inventors:
Thierry Cholley, Jean-Pierre Dath, Claude Brun, Georges Fremy, Francis Humblot
Abstract: Circulating completion, workover and drilling fluids used in hydrocarbon recovery are filtered after monitoring for viscosity, which frequently causes plugging of filters. A viscometer generates a signal representative of viscosity in the fluid; the signal is used by a programmable controller to divert viscous fluid from the filter, or to take other action to prevent damage to the filter. The viscometer can be used in various positions in the system. Fluids deemed too viscous for the filter can be sent to a viscosity-reducing device, which may be a heating, shear-thinning, or cavitation device, to reduce its viscosity, enabling the fluid to pass through a filter without fouling. After filtering and a return to a lower temperature, the fluid may be treated if necessary to become viscous again for a useful purpose.
Type:
Grant
Filed:
May 21, 2007
Date of Patent:
June 15, 2010
Assignee:
Total Separation Solutions, LLC
Inventors:
Robert L. Sloan, Kevin W. Smith, Harry D. Smith, Jr.
Abstract: A cavitation device is used to heat and facilitation the separation of mixtures and emulsions of oil and water. Waste heat from the power source for the cavitation device may be utilized to elevate the temperature of incoming mixtures or emulsions. The heated mixture of emulsion is sent to a separation vessel where vapor may be removed and/or recovered, and where oil is removed as it separates into an identifiable layer. The separation vessel may be a flash tank.
Type:
Grant
Filed:
February 6, 2007
Date of Patent:
June 15, 2010
Assignee:
Total Separation Solutions, LLC
Inventors:
Kevin W. Smith, Robert L. Sloan, Harry D. Smith, Jr.
Abstract: Disclosed is a method for separating aromatic compounds using a simulated moving bed adsorptive chromatography, comprising a sulfolan process that is a non-aromatic compound removing process, a benzene/toluene fractionation process, an aromatic compound fractionation process, a selective toluene disproportionation process, a transalkylation process, a simulated moving bed para-xylene separation process and a xylene isomerization process, wherein the method is characterized by further comprising a simulated moving bed xylene mixture pre-treatment process and an additional xylene isomerization process. The separation method of aromatic compounds according to the present invention can make significant improvement in para-xylene and benzene production in the overall process, as compared to the conventional aromatic compound separation process.
Abstract: The present invention relates to a process for the selective production of olefins from light hydrocarbons comprising: a) fractionating a butane fraction in a de-isobutanizer to obtain an enriched iso-butane fraction and an enriched normal-butane fraction, b) cracking said normal-butane fraction and optionally an ethane fraction, optionally a propane fraction, in a non-catalytic cracking zone to produce an olefin rich stream, preferably the ethane fraction, if any, the propane fraction, if any, and normal-butane fractions are cracked in separate non-catalytic cracking zones, c) treating said olefin rich stream in a separating section comprising: removing hydrogen and methane, recovering an ethylene stream, recovering an ethane stream and recycling said stream to the cracking zone, recovering a propylene stream, recovering a propane stream, optionally recycling said stream to the cracking zone, recovering a C4 stream, removing the heavies, d) selectively hydrogenating the dienes and alkynes in the C4 strea
Type:
Application
Filed:
May 16, 2007
Publication date:
June 10, 2010
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Francois Bouvart, Walter Vermeiren, Wolfgang Garcia, Alain Chepda
Abstract: This invention relates to the fluorinated dialkoxy-diimine metal complexes and their use in catalyst system for the polymerisation or oligomerisation of ethylene and alpha-olefins.
Type:
Application
Filed:
September 14, 2007
Publication date:
June 10, 2010
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Jean-Francois Carpentier, Evgueni Kirillov, Thomas Christophe, Abbas Razavi