Abstract: The invention relates to a method for the catalytic hydrotreatment of a load based on a diesel fuel oil and a biological load based on plant oils and/or animal fats in a hydrotreatment unit. The invention is characterized in that the hydrotreatment unit comprises at least one hydrotreatment reactor operating on a countercurrent. The invention also relates to a hydrotreatment unit for implementing said method, and a corresponding hydrorefining unit.
Abstract: Lubricant compositions include: (a) one or more polyalkylene glycol base oils obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms, include at least one butylene oxide and (b) at least one detergent chosen from salicylates or phenates. The present disclosure also relates to: 1) use of a lubricant composition as engine oil, preferably as oil for the engines of petrol or diesel motor vehicles; 2) use of a group of additives for an engine lubricant comprising polyalkylene glycol bases obtained by polymerization or copolymerization of alkylene oxides comprising from 3 to 8 carbon atoms; and 3) use of at least one additive chosen from salicylates, phenates, dithiocarbamates, amine-based or phenol-based antioxidants, preferably from salicylates or phenates, for reducing the Noack volatility of the base oils of polyalkylene glycol type, obtained from alkylene oxides comprising from 3 to 8 carbon atoms.
Type:
Application
Filed:
November 24, 2011
Publication date:
September 19, 2013
Applicants:
DOW GLOBAL TECHNOLOGIES LLC, TOTAL RAFFINAGE MARKETING
Inventors:
Nicholas Obrecht, Julien Guerin, Nadjet Khelidj
Abstract: The present invention relates to a process for the production of propylene in which in a first step isobutanol is subjected to a simultaneous dehydration and skeletal isomerisation to make substantially corresponding olefins, having the same number of carbons and consisting essentially of a mixture of n-butenes and iso-butene and in a second step n-butenes are subjected to methathesis, said process comprising: a) introducing in a reactor a stream (A) comprising isobutanol, optionally water, optionally an inert component, b) contacting said stream with a catalyst in said reactor at conditions effective to dehydrate and skeletal isomerase at least a portion of the isobutanol to make a mixture of n-butenes and iso-butene, c) recovering from said reactor a stream (B), removing water, the inert component if any and unconverted isobutanol if any to get a mixture of n-butenes and iso-butene, d) fractionating said mixture to produce a n-butenes stream (N) and to remove the essential part of isobutene optionally recy
Type:
Application
Filed:
March 15, 2011
Publication date:
September 19, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Walter Vermeiren, Cindy Adam, Delphine Minoux
Abstract: A method is proposed for heating a hydrocarbons reservoir, comprising the provision of an installation comprising: a first wellbore equipped with an injection string fitted with an adjustable choke and an extraction string fitted with an adjustable choke, a set of sensors, intended to measure physical variables, an automatic device making it possible to control and monitor the operation of the installation; the circulation of steam from one string to the other; the control of the steam injection flow rate in function of a target value; the keeping of a set of physical variables within a predetermined range of values by continuous action of the automatic device on the choke of the injection string, and on the choke of the extraction string.
Type:
Grant
Filed:
December 22, 2009
Date of Patent:
September 17, 2013
Assignee:
Total S.A.
Inventors:
Pierre Lemetayer, Emmanuel Toguem Nguete, Bruno Marty
Abstract: The present invention relates to a process for the production of fibres and filaments with polypropylene having a broad polydispersity index. The present invention also relates to high elongation nonwoven prepared from such fibres and filaments. It further relates to films and laminates prepared from high elongation nonwoven.
Abstract: The invention relates to a hydroconversion catalyst, which comprises a refractory oxide support, at least one metal selected from group VIII and at least one metal selected from group VIB and which is characterized in that it has at least one organic compound containing at least one oxime group of formula (I)>C?NOR1, in which R1 is selected among hydrogen and alkyl, allyl, aryl, alkylene or cycloaliphatic groups, and combinations thereof, these groups being able to be substituted by at least one electron donor group.
Abstract: A process for preparing dimethyl ether or a mixture of dimethyl ether and methanol including passing a raw gas containing carbon monoxide and hydrogen through a catalyst slurry containing a mixture including (a) a medium oil having as a main component, a branched, saturated aliphatic hydrocarbon having 16 to 50 carbon atoms, 1 to 7 tertiary carbon atoms, 0 quaternary carbon atoms, and 1 to 16 carbon atoms in the branched chains bonded to the tertiary carbon atom; and at least one of the tertiary carbon atoms is bonded to hydrocarbon chains with a chain length having 4 or more of carbon atoms in three directions, (b) a methanol synthesis catalyst; (c) a methanol dehydration catalyst; and (d) a methanol shift catalyst or a methanol dehydration/shift catalyst.
Type:
Grant
Filed:
February 9, 2012
Date of Patent:
September 17, 2013
Assignees:
Inpex Corporation, Japan Petroleum Exploration Co., Ltd., Total Gas & Power Ventures, Toyota Tsusho Corporation
Abstract: A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock, the feedstock containing at least one C1 to C6 aliphatic hetero compound selected from alcohols, ethers, carbonyl compounds and mixtures thereof and steam in an amount whereby the feedstock contains up to 80 weight % steam, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene, the crystalline silicate having been subjected to de-alumination by a steaming step and being selected from at least one of an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of from 250 to 500 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio or from 150 to 800.
Abstract: The present invention is a method of reducing the formation of fouling deposits occurring in a caustic scrubber used to remove acid gases comprising: a) providing a caustic scrubber fed with an alkaline aqueous solution comprising essentially one or more of NaOH, KOH or LiOH, b) providing an olefin-containing hydrocarbon stream, contaminated with oxygenated compounds and acid gases, and said oxygenated compounds are capable to make polymeric fouling deposits in the presence of the alkaline solution of the scrubber, c) sending the above hydrocarbon stream to the caustic scrubber to recover an olefin-containing hydrocarbon stream essentially free of acid gases, wherein, d) an efficient amount of a solvent capable to reduce the formation of fouling deposits is introduced in the caustic scrubber and/or in the alkaline solution fed to the scrubber, e) the liquid outlet of the scrubber is sent to means to separate the solvent from the alkaline solution, f) optionally an additive capable to reduce the conversion of
Abstract: The present invention discloses a catalyst system based on a metallocene catalyst component and a new single site catalyst component for the production in a single reactor of improved polyolefins having a bimodal molecular weight distribution.
Abstract: A graft polymer PG includes a polymer backbone P and at least one side graft G linked to the polymer backbone, the graft G having the general formula (1): in which R1 and R2 represent, separately from one another, straight or branched, unsaturated or saturated hydrocarbon groups, such that the total number of carbon atoms in groups R1 and R2 is between 2 and 110; X represents an amide, amino-acid, urea or urethane function, the graft G being linked to the polymer backbone P via the sulphur atom. The graft polymer PG is a polymer that allows thermoreversible cross-linking and can be used in many fields such as coatings, paints, thermoplastics, adhesives, lubricants, fuels, inks, cements, construction materials, rubbers and bitumens. The graft polymer PG can be used in particular for thermoreversibly cross-linking bitumen/polymer compositions and thus for reducing coating, spreading and/or compaction temperatures during the production of bituminous coated materials.
Type:
Application
Filed:
November 8, 2011
Publication date:
September 12, 2013
Applicants:
Centre National De La Recherche Scientifique (CNRS ), Total Raffinage Marketing
Inventors:
Sylvia Harders, Ludwik Leibler, Ilias Iliopoulos, Julie Prevost
Abstract: This invention is related to the preparation of polyethylene pipe resins suitable for transporting hot and cold water containing chlorine dioxide.
Abstract: A method of tracking the rate of corrosion of a metal conduit traversed by a corrosive fluid, in which is provided a device arranged so as to form, when said device is installed on a wall of the metal conduit, a chamber able to receive gaseous hydrogen issuing by permeation across said wall of said conduit, the method comprising: (i) a step of treatment to eliminate a metallic species from the chamber, (ii) a step of measuring a quantity of hydrogen received in the chamber, with a view to estimating the rate of corrosion of the metal conduit.
Abstract: This invention relates to the synthesis of polycarbonates prepared from carbonate monomers derived from the biomass in the presence of a system comprising an organometallic transfer agent and alcohol. It also relates to the polymers resulting from these cyclic compounds.
Type:
Application
Filed:
April 26, 2013
Publication date:
September 12, 2013
Applicants:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE (CNRS), TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Jean-Francois Carpentier, Sophie Guillaume, Marion Helou, Yann Sarazin, Olivier Miserque
Abstract: Provided are a solid catalyst for propylene polymerization and a method for preparing the same, specifically a solid catalyst for propylene polymerization which does not contain any environmentally harmful material and can produce a polypropylene having excellent stereoregularity with a high production yield, and a method for preparing the catalyst.
Type:
Application
Filed:
September 2, 2011
Publication date:
September 12, 2013
Applicant:
SAMSUNG TOTAL PETROCHEMICALS CO., LTD.
Inventors:
Sang Yull Kim, Jin Woo Lee, Eun Il Kim, Joon Ryeo Park
Abstract: The present invention relates to a process for the production of fibres and filaments with polypropylene having a broad polydispersity index. The present invention also relates to high elongation nonwoven prepared from such fibres and filaments. It further relates to films and laminates prepared from high elongation nonwoven.
Abstract: The present invention discloses metallic complexes based on hydroxyl-carbonyl fulvene ligands, their method of preparation and their use in the oligomerization or polymerization of ethylene and alpha-olefins.
Abstract: The present invention discloses a slurry loop reactor comprising at least two loop reactors connected in series and wherein the line connecting the two loops is subject to a dynamic pressure difference.
Type:
Application
Filed:
April 24, 2013
Publication date:
September 5, 2013
Applicant:
TOTAL RESEARCH & TECHNOLOGY FELUY
Inventors:
Daan Dewachter, Louis Fouarge, Alain Brusselle
Abstract: The present invention relates to a process for preparing an activating support for metallocene complexes in the polymerization of olefins comprising the steps of: I) providing a support consisting in particles formed from at least one porous mineral oxide; II) optionally fixing the rate of silanols on the surface of the support; III) functionalizing the support with a solution containing a metallic salt; IV) heating the functionalized support of step c) under an inert gas or hydrogen; V) oxidizing the support of step IV by treatment under N2O and then under oxygen; VI) retrieving an active support having a controlled number of OH groups. That activating support is used to activate a metallocene catalyst component for the polymerization of olefins.
Type:
Grant
Filed:
April 29, 2010
Date of Patent:
September 3, 2013
Assignee:
Total Research & Technology Feluy
Inventors:
Gaëlle Pannier, Christophe Boisson, Roger Spitz