Abstract: The present application relates to extrusion blow-molded articles comprising a polypropylene layer, said polypropylene layer consisting of a polypropylene composition comprising a specific random copolymer of propylene and at least one comonomer. The present application also relates to a process for the production of such extrusion blow-molded articles.
Abstract: A process for preparing a multimodal polyethylene product with at least two different polyethylene resins can include producing a first polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The Ziegler-Natta catalyst used for the production of the first polyethylene resin has an average particle size (D50) of at most 15 ?m. The HLMI of the first polyethylene resin is between 0.01 and 5 g/10 min. The process can include separately producing a second polyethylene resin in the presence of a Ziegler-Natta catalyst in a reactor. The MI2 of the second polyethylene resin is between 1 and 150 g/10 min. The process can include physically blending together the first and second polyethylene resins to produce a multimodal polyethylene product. The physical blending can be performed in a device for continuously melting and blending the first and second polyethylene resins.
Abstract: A process for converting a hydrocarbon feedstock to provide an effluent containing light olefins, the process comprising passing a hydrocarbon feedstock, the feedstock containing at least one C1 to C6 aliphatic hetero compound selected from alcohols, ethers, carbonyl compounds and mixtures thereof and steam in an amount whereby the feedstock contains up to 80 weight % steam, through a reactor containing a crystalline silicate catalyst to produce an effluent including propylene, the crystalline silicate having been subjected to de-alumination by a steaming step and being selected from at least one of an MFI-type crystalline silicate having a silicon/aluminium atomic ratio of from 250 to 500 and an MEL-type crystalline silicate having a silicon/aluminium atomic ratio or from 150 to 800.
Abstract: The present invention discloses an active metallocene catalyst system prepared with a hafnium-based metallocene catalyst system and an activating agent comprising an aluminoxane and a sterically hindered Lewis base.
Type:
Application
Filed:
May 24, 2013
Publication date:
December 19, 2013
Applicant:
TOTAL PETROCHEMICAL RESEARCH FELUY
Inventors:
Vincenzo Busico, Roberta Cipullo, Roberta Pellecchia, Abbas Razavi
Abstract: The present invention relates to a method for optimizing the sequential feeding of at least two ethylene polymerization catalysts to an ethylene polymerization reactor, comprising: transferring to a mixing vessel a first ethylene polymerization catalyst and a first diluent, decreasing the concentration of said first ethylene polymerization catalyst in said mixing vessel, transferring to said mixing vessel a second ethylene polymerization catalyst and a second diluent, progressively replacing said first ethylene polymerization catalyst by said second ethylene polymerization catalyst and said first diluent by said second diluent, increasing the concentration of said second ethylene polymerization catalyst in said mixing vessel, sequentially transferring said first ethylene polymerization catalyst and said second ethylene polymerization catalyst from said mixing vessel to an ethylene polymerization reactor.
Abstract: The invention relates to A process for the polymerization of ethylene to produce a polyethylene resin in at least two slurry loop reactors connected to each other in series, the resin having a bimodal molecular weight distribution, a molecular weight distribution MWD of at least 7.0, an HLMI of from 1 to 100 g/10 min, and a density of from 0.935 to 0.960 g/cm3, wherein in one reactor 30 to 47 wt % based on the total weight of the polyethylene resin of a high molecular weight (HMW) polyethylene fraction is produced having an HL275 of from 0.05 to 1.8 g/10 min (the equivalent of HLMI of from 0.01 to 1.56 g/10 min), a density of from 0.925 to 0.942 g/cm3 and an MWD of at least 5.0, and in the other reactor a low molecular weight (LMW) polyethylene fraction is produced having an HLMI of from 10 to 1500 g/10 min and a density of from 0.960 to 0.975 g/cm3, in the presence of a Ziegler-Natta catalyst system.
Type:
Grant
Filed:
February 7, 2011
Date of Patent:
December 17, 2013
Assignee:
Total Research & Technology Feluy
Inventors:
Aurélien Vantomme, Daniel Siraux, Alain Van Sinoy, Jean-Léon Gielens
Abstract: A method for the estimation of a value for an investigated parameter of a hydrocarbon-producing region, comprising: a) using a design of experiments tool to determine a ruling law for a match parameter as a function of descriptive parameters, b) conducting a set of experiments using a simulation tool wherein, for each experiment, the region is geometrically and physically modelled, c) determining suitable sets of values for descriptive parameters from the ruling law, and d) determining a value for the investigated parameter from most likely sets of values.
Type:
Application
Filed:
February 23, 2011
Publication date:
December 12, 2013
Applicant:
TOTAL SA
Inventors:
Vincent Mongalvy, Lu Lu, Satish Agarwal
Abstract: The invention relates to a method for measuring pressure in an underground formation containing a fluid, comprising the following consecutive steps: establishing fluid communication between a test chamber arranged in a drilling well and the underground formation, via a flowline; moving a piston in the test chamber so as to suction fluid into the test chamber; ensuring fluid isolation of the test chamber relative to the flowline; measuring the pressure in the flowline; and repeating the preceding steps. The invention also relates to a device for measuring pressure in an underground formation containing a fluid adapted for the implementation of said method.
Abstract: Method and plant for converting hydrocarbon feedstock comprising a shale oil, comprising a step of decontaminating, a step of hydroconverting in an ebullating bed, a step of fractionating into a light fraction, a naphtha fraction, a gas-oil fraction and a fraction heavier than the gas-oil fraction, the naphtha and gas-oil fractions being hydrotreated, the fraction heavier than the gas-oil fraction being conveyed to the decontaminating step. The method aims to maximize the yield of fuel bases.
Type:
Application
Filed:
December 16, 2011
Publication date:
December 12, 2013
Applicants:
AXENS, TOTAL RAFFINAGE MARKETING
Inventors:
Christophe Halais, Helene Leroy, Frederic Morel, Cecile Plain
Abstract: Apparatus for use in repairing, and methods of repairing, a door hinge of a vehicle includes use of a substitute hinge bracket and at least one pin configured to be received through at least one opening of a vehicle frame bracket. A locking portion of the at least one pin and a locking surface that defines an opening in the hinge bracket are configured such that the at least one pin is locked in a fixed position relative to the hinge bracket when assembled. Further, another repair apparatus includes a substitute pin having an interference portion for forming an interference fit with one or more surfaces defining an opening of a factory hinge bracket.
Abstract: Method for converting hydrocarbon feedstock comprising a shale oil, comprising a step of hydroconverting in an ebullating bed, a step of fractionating by atmospheric distillation into a light fraction, a naphtha fraction, a gas-oil fraction and a fraction heavier than the gas-oil fraction, a step of liquid/liquid extraction of the fraction heavier than the gas-oil fraction, and a dedicated hydrotreating for each of the naphtha and gas-oil fractions. The method aims to maximize the yield of fuel bases.
Type:
Application
Filed:
December 16, 2011
Publication date:
December 5, 2013
Applicants:
AXENS, TOTAL RAFFINAGE MARKETING
Inventors:
Christophe Halais, Helene Leroy, Frederic Morel, Cecile Plain
Abstract: Receiver lines arranged in an area to be explored are provided with geophones in respective receiver positions for measuring seismic waves from the subsoil. The receiver lines include first parallel lines and second lines parallel to the first lines and located in intermediate positions between the first lines. Seismic waves are emitted from source positions located along the first receiver lines, and seismic data, representing waves measured by the various geophones in response to the emitted waves, are obtained. Said first seismic data are processed by seismic interferometry in order to estimate other seismic data representing responses, in at least some of the receiver positions, to waves emitted from a virtual source located in a receiver position along a second line.
Type:
Application
Filed:
February 20, 2012
Publication date:
December 5, 2013
Applicant:
TOTAL SA
Inventors:
Constantin Gerea, Jean-Marc Mougenot, Francis Clement
Abstract: The present invention relates to caps and closures comprising a specific propylene random copolymer, obtained by polymerization with a metallocene-based polymerization catalyst.
Abstract: Method and plant for converting hydrocarbon feedstock comprising a shale oil, comprising a step of hydroconverting in an ebullating bed, a fractionation into a light fraction, a naphtha fraction, a gas-oil fraction and a fraction heavier than gas-oil, the naphtha and gas oil fraction being hydrotreated, the fraction heavier than gas oil being hydrocracked, the products of the hydrocracking being sent to the step for hydrotreating. The method aims to maximize the yield of fuel bases.
Abstract: The present invention is an expandable vinyl aromatic polymer which comprises: a) a matrix of a vinyl aromatic polymer, b) 1-10% by weight calculated with respect to the polymer (a), of an expanding agent englobed in the polymeric matrix, c) 0.1 to 5% by weight calculated with respect to the polymer (a), of PiB (polyisobutene), homogeneously distributed in the polymeric matrix, d) 0-20% by weight, calculated with respect to the polymer (a), of one or more fillers, other than PiB, homogeneously distributed in the polymeric matrix, Wherein the proportion of PiB is adjusted to increase the Melt Flow Index (MFI) from an initial index to a final index such as the 10% compression strength of the foam made with said expandable vinyl aromatic polymer of the final index is essentially the same or higher than the foam made with said expandable vinyl aromatic polymer of the initial index. The expandable vinyl aromatic polymer of the invention is produced in the form of beads or granules.
Type:
Application
Filed:
October 18, 2011
Publication date:
December 5, 2013
Applicant:
TOTAL RESEARCH & TRCHNOGY FELUY
Inventors:
Stéphane Nowe, Philippe Lodefier, Laetitia Urbanczyk
Abstract: The invention concerns a purge/sampling system for vessels, particularly for high temperature, high pressure vessels such as hydroconversion reactors used in refinery processes and operated in severe conditions. Such purge/sampling system comprises a purge/sampling line (16) equipped with a connector designed to be connected to the vessel (10), a first (18 and a second (20) flow regulation systems mounted in series on the purge/sampling line, wherein at least one injection line (22) is connected to the purge/sampling line between the first and the second flow regulation systems, said injection line comprising connecting means to a source of cleaning fluid (24) and at least one flow regulation device to control the flow of cleaning fluid through injection line and purge/sampling line The invention also concerns a vessel equipped with such a purge/sampling system, as well as a cleaning method using said purge/sampling system.
Type:
Application
Filed:
December 23, 2011
Publication date:
November 28, 2013
Applicant:
TOTAL RAFFINAGE MARKETING
Inventors:
Katell Le Lannic, Xavier Mourain, Maxime Varin
Abstract: A mixture can include 0.01 to 30 weight % of a medium or large pore crystalline silicoaluminate, silicoaluminophosphate materials, or silicoaluminate mesoporous molecular sieves (A), and 99.99 to 70 weight % of a MeAPO molecular sieve. The mixture can be included in a catalyst. An XTO process can include contacting an oxygen-containing, halogenide-containing, or sulphur-containing organic feedstock with the catalyst under conditions effective to convert the organic feedstock to olefin products. A combined XTO and OCP process can include contacting the organic feedstock with the catalyst at conditions effective to convert at least a portion of the organic feedstock to form an XTO reactor effluent including light olefins and a heavy hydrocarbon fraction, separating the light olefins from the heavy hydrocarbon fraction, and contacting the heavy hydrocarbon fraction in an OCP reactor at conditions effective to convert at least a portion of the heavy hydrocarbon fraction to light olefins.
Type:
Application
Filed:
April 22, 2013
Publication date:
November 28, 2013
Applicant:
TOTAL PETROCHEMICALS RESEARCH FELUY
Inventors:
Nikolai Nesterenko, Walter Vermeiren, Sander Van Donk
Abstract: The present disclosure includes liquid compositions that can be used for marking liquid hydrocarbon-based fuels and combustibles; these compositions include at least one marker, one or more solvents and, optionally, one or more functional additives other than the markers. The disclosure also includes a process for qualitative and quantitative detection of these markers present in a liquid hydrocarbon-based composition.
Abstract: The invention relates to a method for preparing a hydroconversion catalyst based on mesoporous silica or silica-alumina, comprising the following steps: (A) deposition of alumina on a mesoporous material having interconnected pores by treatment with at least one aluminium-based reactant, so as to obtain a compound having a Si/Al ratio of between 0.1 and 1000; (B) addition of at least one catalytically active species chosen from the group formed by the metals of group VIII and/or of group VIB; and (C) drying followed by thermal and/or chemical treatment according to the invention. The invention also relates to the catalyst thus obtained as well as a method of hydroconverting (hydrocracking, hydroisomerizing) a hydrocarbon feedstock, which comprises bringing the feedstock to be treated into contact with the hydroconversion catalyst according to the invention.
Type:
Application
Filed:
December 23, 2011
Publication date:
November 14, 2013
Applicants:
CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE, TOTAL RAFFINAGE MARKETING
Inventors:
Metin Bulut, Régine Kenmogne-Gatchuissi, François Fajula, Jean-Pierre Dath, Sander Van Donk, Annie Finiels, Vasile Hulea