Abstract: An electrolyte solution for iron-tungsten plating is prepared by dissolving in an aqueous medium a divalent iron salt (e.g., iron (II) sulfate) and an alkali metal citrate (e.g., sodium citrate, potassium citrate, or other alkali metal citrate) to form a first solution, dissolving in the first solution a tungstate salt (e.g., sodium tungstate, potassium tungstate, or other potassium tungstate) to form a second solution, and dissolving in the second solution a citric acid to form the electrolyte solution. An iron-tungsten coating is formed on a substrate using the electrolyte solution by passing a current between a cathode and an anode through the electrolyte solution to deposit iron and tungsten on the substrate.

Abstract: An electrolytic system and method of manufacturing white phosphorus.

Abstract: The invention relates to a method for making nanopores in thin layers or monolayers of transition metal dichalcogenides that enables accurate and controllable formation of pore within those thin layer(s) with sub-nanometer precision.

Abstract: Aspects included herein include an electrolytic system for electrochemical reduction of carbon dioxide, the system comprising: a cathode comprising: a porous gas-diffusion membrane permeable to CO2; an electrocatalyst layer adjacent to a second side of the gas-diffusion membrane; the electrocatalyst layer comprising: an electrically conductive catalyst; and a selectivity-determining organic material attached to at least a portion of the electrically conductive catalyst; wherein: the organic material is formed of a plurality of oligomers; each oligomer comprises a plurality of covalently bonded base units; each base unit comprises at least one heterocyclic group having at least one nitrogen in its structure; and an anion exchange membrane adjacent to the electrocatalyst layer and positioned between the anode and the cathode; wherein anion exchange membrane is characterized by anion conductivity and the cathode is in ionic communication with the anode via the anion exchange membrane.

Abstract: An electrolyte solution for iron-tungsten plating is prepared by dissolving in an aqueous medium a divalent iron salt (e.g., iron (II) sulfate) and an alkali metal citrate (e.g., sodium citrate, potassium citrate, or other alkali metal citrate) to form a first solution, dissolving in the first solution a tungstate salt (e.g., sodium tungstate, potassium tungstate, or other potassium tungstate) to form a second solution, and dissolving in the second solution a citric acid to form the electrolyte solution. An iron-tungsten coating is formed on a substrate using the electrolyte solution by passing a current between a cathode and an anode through the electrolyte solution to deposit iron and tungsten on the substrate.

Abstract: The present disclosure relates to methods of fabricating a porous structure, such as a porous silicon carbide structure. The methods can include a step of providing a structure to be rendered porous, and a step of providing an etching solution. The methods can also include a step of electrochemically etching the structure to produce pores through at least a region of the structure, resulting in the formation of a porous structure. The morphology of the porous structure can be controlled by one or more parameters of the electrochemical etching process, such as the strength of the etching solution and/or the applied voltage.

Abstract: An electrochemical method includes performing anodic halogenation of Cu foils, performing subsequent oxide-formation in a KHCO3 electrolyte, and performing an electroreduction in neutral KHCO3 to generate a copper catalyst.

Abstract: A method of and system for surface finishing an additive manufactured part. A part having a surface roughness with macroasperities is placed in a chamber with an electrolyte and an electrode. A pulse/pulse reverse power supply is connected to the part rendering it anodic and connected to the electrode rendering it cathodic.

Abstract: Electrochemical analysis method and system for monitoring and controlling the quality of electrochemical deposition and/or plating processes. The method uses a fingerprinting analysis method of an output signal to indicate whether the chemistry and/or process is operating in the normally expected range and utilizes one or more substrates as working electrode(s) and a) whereby the potential between the one or more working electrodes and one or more reference electrodes is analyzed to provide an output signal fingerprint which is represented as potential difference as a function of time or b) the input power of a process power supply to provide input energy in the form of current and/or potential between the working electrode(s) and a counter-electrode whereby the method utilizes the potential between the one or more working electrode(s) and at least one of: one or more reference electrodes; or one or more counter-electrodes; to provide an output signal fingerprint.

Abstract: A crude oil demulsification system includes a vessel. A cyclonic separator is disposed outside the vessel. The cyclonic separator is configured to receive and separate phases of a multi-phase fluid stream into a gaseous stream and a liquid stream that includes a first liquid phase and a second liquid phase by inducing cyclonic flow. A heat exchanger is fluidically connected to the cyclonic separator. The heat exchanger is disposed outside the vessel, and is configured to receive the liquid stream and to heat the liquid stream by exchanging heat with a heating medium flowed through the heat exchanger. An electrostatic coalescer is fluidically connected to the heat exchanger and is disposed inside the vessel. The electrostatic coalescer is configured to receive the liquid stream heated by the heat exchanger and to demulsify the liquid stream by causing coalescence of liquid droplets of one of the first or second liquid phases.

Abstract: The present invention realizes industrially excellent effects such that when electric power having a large output fluctuation, such as renewable energy, is used as a power source, electrolysis performance is unlikely to be deteriorated and excellent catalytic activity is retained stably over a longer period of time, and in addition, the present invention provides a technique that enables forming a catalyst layer of an oxygen generation anode, which gives such excellent effects, with a more versatile materials and by a simple electrolysis method.

Abstract: An object is to provide a methane synthesis device having as a whole a reduced size and a simplified configuration. A methane synthesis device 100 is composed of respective components from an end plate 2 at the leftmost side to an end plate 23 at the rightmost side and is compactly assembled by fastening plural bolts and nuts to bring these individual components into tightly contact with each other. The components may be divided into a Sabatier reaction unit of signs 3 to 9, a water electrolysis unit of signs 13 to 19, and other components. Hydrogen gas generated in the water electrolysis unit is mixed with carbon dioxide gas and supplied to the Sabatier reaction unit, and methane is synthesized in the Sabatier reaction unit. The size of the device is reduced as a whole and configuration is simplified by integrally stacking the water electrolysis unit, the Sabatier reaction unit, a carbon dioxide supplying unit, and a hydrogen gas supplying unit.

Abstract: Herein discussed is a method of producing hydrogen comprising: (a) providing an electrochemical reactor having an anode, a cathode, and a membrane between the anode and the cathode; (b) introducing a first stream to the anode, wherein the first stream comprises ammonia or a product from ammonia cracking; (c) introducing a second stream to the cathode, wherein the second stream comprises water; and wherein hydrogen is generated from water electrochemically without electricity input. Systems for producing hydrogen from ammonia are also discussed.

Abstract: A method of producing hydrogen using a water electrolysis system comprising at least an electrolyzer and a purifier for removing oxygen in a hydrogen gas generated in the electrolyzer. The method includes controlling a concentration of oxygen in a hydrogen gas to be introduced to the purifier to be constantly less than 0.5 volume % when the electrolyzer is operated at least under a current density of 0.5 kA/m2 or greater; and further controlling Ob/Oa to be less than 10.0, where Oa represents the concentration of oxygen in the hydrogen gas to be introduced to the purifier when the electrolyzer is operated under a current density of 2.0 kA/m2, and Ob represents the concentration of oxygen in the hydrogen gas to be introduced to the purifier when the electrolyzer is operated under a current density of 0.2 kA/m2.

Abstract: A fluid-treatment apparatus has a coil structure, a first circuit formed by a rectifier diode and a capacitor in parallel connection, a second circuit formed by a first coil wound on a first section of the coil structure and a second coil wound on a second section of the coil structure, and a third circuit formed by a third coil wound on the second coil and a fourth coil wound on a third section of the coil structure. The first and second coils have a first winding direction, and the third and fourth coils have a second winding direction opposite to the first winding direction. The first and second coils are a first alternate-current (AC) input terminal and the anode of the rectifier diode. The third and fourth coils are connected to a second alternate-current (AC) input terminal and the cathode of the rectifier diode.

Abstract: An alkaline water electrolysis system includes: a plurality of reaction chambers, each including a main electrode and an auxiliary electrode; a piston provided in each reaction chamber to change a volume of the reaction chamber through reciprocating motion; a drive motor; a connecting rod and a crankshaft installed to change rotational motion of the drive motor into reciprocating linear motion of the piston; a plurality of gas valves installed on an upper side of the reaction chamber to discharge hydrogen and oxygen generated in the reaction chamber through different paths, respectively; a pressure sensor installed in the reaction chamber; a controller configured to open and close the gas valves in response to a signal received from the pressure sensor; and an electrolyte supply apparatus provided to supply an electrolyte to the reaction chambers.

Abstract: A metal article comprises two metals, and a first hole and an oxide layer are set correspondingly on the surfaces of the two metals. To avoid the electrolytic corrosion on the interface between the two metals during the formation of the first hole, the disclosure provides a method of manufacturing the metal article. By putting a metal substrate in a first electrolyte including an etching agent and a passivating agent and applying electricity on the metal substrate, the metal article with the first hole is formed without electrolytic corrosion. The disclosure also provides a metal composite, which is formed by setting a material part in the first hole of the metal article.

Abstract: A hydrogen-oxygen generation system includes an electrolytic cell configured to generate hydrogen and oxygen by electrolyzing water, and discharge the hydrogen and the oxygen as separate generated gasses. An accumulator includes a water storage chamber configured to store the water, and a gas chamber configured to receive a pressurized gas, and the water storage chamber and the gas chamber are separated from each other by an elastic body membrane. The accumulator is configured to transfer the water stored in the water storage chamber toward the electrolytic cell at a transfer pressure in accordance with a pressure of the pressurized gas in the gas chamber. A water supply unit is configured to supply the water to the water storage chamber, and a gas supply unit is configured to supply the pressurized gas to the gas chamber.

Abstract: Electro-coalescer systems herein may include a vessel, a base plate separating a process chamber and an electric enclosure, rod-shaped ceramic insulated electrodes, and a sealing assembly. An end of the electrodes is located within the electric enclosure. The electrodes traverse respective through-holes of the base plate into or through the process chamber, where a second portion is supported by a spacer, configured to maintain a position of the electrodes while allowing fluid passage. The sealing assembly forms a seal between the through-holes and the rod-shaped insulated electrodes, preventing fluid traversing from the process chamber into the electric enclosure. The sealing assembly may include: a metal fitting disposed around the rod-shaped insulated electrode; metal o-rings; metal seats; and a closing nut. The metal fitting has a coefficient of thermal expansion similar to that of the ceramic insulator, thereby preventing breakage of the electrodes during use.

Abstract: The present invention relates to a system for the separation of oil/water emulsions by electrocoalescence having a fluid conduction means or tubing, at least one cathode, at least one electrode, at least one anode, at least one power source and at least one spark gap for a cathode and a spark gap for the anode. Furthermore, the present invention also relates to a method for the separation of oil/water emulsions by electrocoalescence carried out by a system according to the invention.