Abstract: A process for preparing an emulsion or a dispersion comprising crystalline particles of at least one active principal that comprises contacting a solution of at least one solute in a solvent or mixture of solvents in a first flowing stream with a non-solvent in a second flowing stream wherein the non-solvent and solvent are not miscible with each other, so as to form an emulsion or a dispersion. Super saturation is brought about by suitable means, and the emulsion or dispersion is subjected to ultrasonic irradiation to mediate crystal nucleation.

Abstract: Methods of dissociating and recovering methane from solid hydrate deposits are provided. A method for recovering methane from a methane hydrate includes at least applying electromagnetic radiation to the methane hydrate to dissociate the methane-water bond. Further provided is an apparatus for dissociating methane from a methane hydrate. The apparatus includes at least: an electromagnetic spectrum power source; a probe connected to the electromagnetic spectrum power source; an antenna connected to the distal end of the probe is capable of focusing a radiated beam into a target area of a methane hydrate; and a control system in communication with and capable of controlling the electromagnetic spectrum power source, the probe, and the antenna.

Abstract: The invention is directed to a method of forming, producing or manufacturing functionalized nanomaterials, and, specifically, soluble functionalized nanomaterials. The presently described invention also relates to nanomaterial-based composites consisting of a target material, which can include ceramic, polymer, or metallic matrices incorporated into or grown on nanomaterials, as well as a method or synthesis technique for the formation, production, or manufacture of nanomaterial-based composites through microwave-induced reaction.

Abstract: An instrument and method for high pressure microwave assisted chemistry are disclosed. The method includes the steps of applying microwave radiation to a sample in a sealed vessel while measuring the temperature of the sample and measuring the pressure generated inside the vessel and until the measured pressure reaches a designated set point, opening the vessel to release gases until the pressure inside the vessel reaches a lower designated set point, closing the vessel, and repeating the steps of opening the vessel at designated pressure set points and closing the vessel at designated pressure set points to the sample until the sample reaction reaches a designated high temperature. The designated set points can controllably differ from one another as the reaction proceeds. Microwave energy can be applied continuously or intermittently during the opening and closing steps.

Abstract: The invention relates to the synthesis of silicon-containing nanoparticles by laser pyrolysis. For this purpose: a precursor (SIH4) containing the element silicon is conveyed, by a transport fluid (He), into a pyrolysis reactor (REAC); laser radiation (LAS) is applied, in the reactor, to a mixture that the transport fluid and the precursor form; and silicon-containing nanoparticles (nP) are recovered at the exit of the reactor. In particular, the power of the laser radiation is controlled. Furthermore, the effective pulse duration is controlled within a laser firing period. Typically, for a power greater than 500 watts and a pulse duration greater than 40% of a laser firing period, nanoparticles having a crystalline structure with a size of less than or of the order of one nanometer are obtained at a rate greater than or of the order of 80 milligrams per hour. Under optimum conditions, a record rate of greater than 740 milligrams per hour was able to be obtained.

Abstract: A method produces a cycloalkanone oxime by photonitrosation using light emitting diodes as the light source for the next generation that replaces an electric discharge lamp with, for example, mercury or sodium sealed therein. The method produces the cycloalkanone oxime by a photochemical reaction of a cycloalkane with a photo nitrosating agent in a liquid by light irradiation. The method uses a light source satisfying conditions that, in an emission energy distribution with respect to wavelength of the light source, a wavelength at which emission energy has a maximum value is in a range of 550 nm to 700 nm and a wavelength range outputting energy of or over 5% strength of the peak strength is equal to or less than 150 nm. An irradiation distance in the liquid is equal to or greater than 200 mm, and concentration of the photo nitrosating agent in the liquid is 0.1 mol % to 0.5 mol %.

Abstract: This invention relates to a system and a method for achieving efficient production of hydrogen in a hydrogen generator, comprising at least a hydrogen generator, a liquid in said hydrogen generator to produce hydrogen from, and a ceramic that emits infrared at wavelengths covering at least a portion of 3-20 micrometers range so that said liquid can be excited with infrared at said wavelengths before or during the production of hydrogen for improved hydrogen production efficiency. The use of infrared-excited electrolyte solution in a hydrogen generator helps reduce the energy consumption, lower operating voltage, and thus reduce the cost of the production of hydrogen.

Abstract: A process for preparing crystalline particles of an active principal in the presence of ultrasonic irradiation that comprises contacting a solution of a solute in a solvent in a first flowing stream with an anti-solvent in a second flowing stream causing the mixing thereof, wherein the flow rate ratio of the anti-solvent: solvent is higher than 20:1, and collecting crystals that are generated.

Abstract: Disclosed is a method for producing an alcohol using a device for reducing carbon dioxide by light energy. In this device, a cathode electrode includes copper or a copper compound, and an anode electrode includes a region including a nitride semiconductor layer in which an AlxGa1-xN layer (0<x?1) and a GaN layer are laminated. A first electrolytic solution consisting of an aqueous potassium chloride solution (aqueous KCl solution) is contained in a cathode chamber in which the cathode electrode is placed. A second electrolytic solution including an aqueous sodium hydroxide solution (aqueous NaOH solution) is contained in an anode chamber in which the anode electrode is placed.

Abstract: A photocatalyst comprising silver orthophosphate (Ag3PO4) is used for selective and exhaustive conversion of alcohols into their corresponding carbonyl compounds; namely, benzyl alcohol, 4-methoxy benzyl alcohol and/or cinnamyl alcohol with >99% yield. The reactions were carried out in double distilled water at room temperature and pressure under sunlight-type excitation. Oxidation of alcohols is selective and Ag3PO4 may be active for a variety of other essential oxidation reactions.

Abstract: A method is followed to prepare a powder that includes carbon, silicon and boron, the silicon being in silicon carbide form and the boron being in boron carbide and/or free boron form. The method includes contacting a carbon-based precursor, a silicon-based precursor and a boron-based precursor BX3, X being a halogen atom, to obtain a mixture of these three precursors. The resulting mixture is subjected to laser pyrolysis. The boron-based precursor BX3 is heated, prior to the contacting step and/or simultaneously with the contacting step, to a temperature higher than the condensation temperature of the precursor.

Abstract: The invention describes a high-pressure vessel for holding samples which are to be heated, the high-pressure vessel having: a lower part (5, 104) and a lid part (6, 105) which can be locked together and when closed surround on all sides a reaction chamber for initiating and/or promoting chemical and/or physical high-pressure reactions, it being possible for the lower part (5, 104) and the lid part (6, 105) to be moved relative to each other in an automated fashion between an open access position and a closed microwave processing position, a sample holder (101) and/or a vessel insert (9) being connected to the lid part (6, 105).

Abstract: A process and apparatus for removing NOx from exhaust gases produced by combustion-based energy sources. An array of high voltage pulsed electron beams are repetitively generated and transported through a thin foil into the exhaust gas containing NOx. The electron beam deposits its energy into the gas and produces reactive radicals N2+, N+, e, N2 from the NOx in the gas. These radicals recombine through chemical reactions to produce benign by-products nitrogen N2 and oxygen O2 which are output into the atmosphere.

Abstract: Methods for labeling a substrate using a hetero-Diels-Alder reaction are disclosed. The hetero-Diels-Alder reaction includes the reaction of an o-quinone methide (e.g., an o-naphthoquinone methide) with a polarized olefin to form a hetero-Diels-Alder adduct. The o-quinone methide or the polarized olefin can be attached to a surface of a substrate, and the other of the o-quinone methide or the polarized olefin can include a detectable label. The o-quinone methide can conveniently be generated by irradiation of a precursor compound, preferably in an aqueous solution, suspension, or dispersion.

Abstract: A method for generating hydrogen is disclosed. The method includes substantially submersing nanowires having metallic nanoparticles into water, exposing the water submerged nanowires to light, and collecting hydrogen gas produced by photolysis from the exposure to light.

Abstract: A method to fabricate boron nitride nanotubes incorporating magnesium diboride in their structure. In a first embodiment, magnesium wire is introduced into a reaction feed bundle during a BNNT fabrication process. In a second embodiment, magnesium in powder form is mixed into a nitrogen gas flow during the BNNT fabrication process. MgB2 yarn may be used for superconducting applications and, in that capacity, has considerably less susceptibility to stress and has considerably better thermal conductivity than these conventional materials when compared to both conventional low and high temperature superconducting materials.

Abstract: In a method of operating a microwave plasma abatement apparatus comprising a microwave generator, and a gas chamber for receiving microwave energy from the microwave generator and within which a plasma is generated using the microwave energy, the amount of microwave energy that is not absorbed within the gas chamber is monitored, and the power of the microwave energy generated by the microwave generator is adjusted in dependence on the monitored microwave energy.

Abstract: The invention relates to a method for producing alkaline amides or imides of ethylenically unsaturated C3 to C6 carboxylic acids by reacting amines that contain at least one primary and/or secondary amino group and at least one tertiary amino group with ethylenically unsaturated C3 to C6 carboxlic acids to form an ammonium salt and said ammonium salt is subsequently converted into the alkaline amide or imide by means of microwave radiation, with the proviso that the primary and/or secondary amino group is devoid of alkoxy groups.

Abstract: The present invention is directed to a method for making an enantiomeric organic compound having a high amount of enantiomer excesses including the steps of a) providing an aqueous solution including an initial reactant and a catalyst; and b) subjecting said aqueous solution simultaneously to a magnetic field and photolysis radiation such that said photolysis radiation produces light rays that run substantially parallel or anti-parallel to the magnetic field passing through said aqueous solution, wherein said catalyst reacts with said initial reactant to form the enantiomeric organic compound having a high amount of enantiomer excesses.

Abstract: The invention relates to a method for the photoelectrochemical production of hydrogen and oxygen and for the simultaneously or separately conducted photoelectrical/photovoltaic production of electricity, characterized in that water is brought into contact with silicides, while applying light at the same time, or the contact with water can be foregone if electricity is produced exclusively. The invention enables the production of hydrogen and oxygen in a simple way directly from water, wherein the use of UV light and cost-intensive catalysts can be foregone.