Abstract: Used oils, especially used lubricating oils which are normally considered waste and are discarded or burned, are reclaimed for reuse by a re-refining procedure involving the steps of:(a) heat soaking the used oil;(b) distilling the heat soaked oil;(c) passing the distillate through a guard bed of activated material;(d) hydrotreating the guard bed treated distillate under standard hydrotreating conditions.If the used oil to be re-refined contains a quantity of water and/or fuel fraction which the practioner considers sufficiently large to be detrimental, the used oil may be subjected to a dewatering/defueling step prior to being heat soaked.
Type:
Grant
Filed:
February 16, 1983
Date of Patent:
April 23, 1985
Assignee:
Exxon Research and Engineering Co.
Inventors:
Lloyd E. Reid, Keith C. Yao, Douglas G. Ryan
Abstract: This invention provides a process for the recovery of bitumen from mined tar sands that comprises admixing mined tar sands with a hydrocarbon liquid such as light crude oil or a mixture of light crude oils from a nearby reservoir thereby obtaining a bitumen-hydrocarbon mixture mixed with sand, separating the bulk of said bitumen-hydrocarbon mixture from the sand as a liquid, and recovering the remainder of the bitumen-hydrocarbon mixture using chemical waterflooding techniques.
Type:
Grant
Filed:
February 16, 1984
Date of Patent:
April 23, 1985
Assignee:
Mobil Oil Corporation
Inventors:
Harold S. Chung, Joseph J. Dickert, Jr.
Abstract: The process for increasing the production of petrochemical conversion processes in the presence of a carbon-hydrogen fragmentation compound in the presence of a non-zeolitic molecular sieve.
Type:
Grant
Filed:
May 2, 1983
Date of Patent:
April 23, 1985
Assignee:
Union Carbide Corporation
Inventors:
Gary N. Long, Regis J. Pellet, Jule A. Rabo
Abstract: In an atmospheric distillation tower of a coal liquefaction process, tower materials corrosion is reduced or eliminated by introduction of boiling point differentiated streams to boiling point differentiated tower regions.
Type:
Grant
Filed:
March 21, 1984
Date of Patent:
April 16, 1985
Assignee:
International Coal Refining Company
Inventors:
Kenneth L. Baumert, Alberto A. Sagues, Burtron H. Davis
Abstract: A continuous process for producing an optically anisotropic pitch. A reaction tank is used to treat a starting material. An upper section is utilized for thermal decomposition polycondensation zone. A lower portion of the tank is used as a settling zone.
Abstract: A process is disclosed for producing alkylbenzenes by the alkylation of aromatic hydrocarbons with olefins. High reactivity and selectivity are afforded by the use of a catalyst comprising sodium and/or sodium amide deposited on a carrier represented by the formula K.sub.2 O. x Al.sub.2 O.sub.3 where x is 0.5.ltoreq.x.ltoreq.11.
Abstract: Vinylidene olefins are selectively removed from a mixture of olefins containing vinylidene olefins by reacting the mixture with either hydrogen sulfide or a hydrocarbyl mercaptan and then distilling the resultant mixture to obtain a substantially vinylidene olefin-free product.
Abstract: A process for conversion of an asphaltenes-containing heavy oil or heavy oil fraction to lighter fractions comprises 3 steps of: catalytic hydrodemetallation, hydrovisbreaking and catalytic hydrodesulfuration.
Abstract: A catalyst for reforming CH.sub.3 OH to H.sub.2 and CO, which is high in activity, selectivity and durability. The catalyst uses a granular or monolithic carrier which is made of active alumina at least in its surface regions, and compound oxide(s) of perovskite structure MAlO.sub.3, where M is a metal selected from the rare earth elements, e.g. La or Ce, or from the titanium family elements, e.g. Ti or Zr, and catalytic metal(s) of the platinum group, e.g. Pt, Pd and/or Rh, are deposited on the carrier. Preferably the amount of the metal(s) M in the compound oxide(s) is 0.1-10.0 Wt % of the carrier, and the content of the metal(s) of the platinum group in the catalyst is 0.1 to 1.0 Wt %.
Abstract: A catalyst containing tungsten, potassium, and bismuth on a support, preferably silica gel, is disclosed which is useful in reverse disproportionation of stilbene and ethylene to produce styrene.
Abstract: In the conversion of light olefins to heavier hydrocarbons, an improved recovery technique is provided for selectively removing unreacted light olefins from a catalytic reactor effluent. This system is useful in converting ethene-rich feedstocks to gasoline and/or distillate products, particularly in oligomerization processes employing shape selective siliceous catalysts such as ZSM-5 type zeolites. By recycling gasoline-range hydrocarbons as a sorbent liquid, unreacted C.sub.2.sup.+ components may be absorbed from reactor effluent vapor and returned for further contact with the catalyst.
Type:
Grant
Filed:
February 1, 1984
Date of Patent:
April 16, 1985
Assignee:
Mobil Oil Corporation
Inventors:
Bernard S. Wright, Chung H. Hsia, Hartley Owen
Abstract: A process is disclosed for the preparation of a more active paraffin hydrocarbon hydroisomerization catalyst from synthetic mica montmorillonite, preferably a nickel synthetic mica montmorillonite catalyst, which may also contain palladium, by treating the catalyst with one or more compounds comprising chlorine which can further release one or more protons and/or hydrogen chloride, and preferably by treating with hydrochloric acid.
Abstract: Hydrocarbon processing equipment is protected against fouling during the processing of hydrocarbons at elevated temperatures by adding to the equipment small amounts of the N,N'-dimer of phenothiazine and at least one mono- or ditertiary alkyl catechol and/or at least one mono- or ditertiary alkylhydroquinone.
Type:
Grant
Filed:
August 10, 1984
Date of Patent:
April 16, 1985
Assignee:
Atlantic Richfield Company
Inventors:
Richard F. Miller, Michael P. Nicholson
Abstract: Coking of residual oil and devolatization/partial gasification and desulfurization of solid particulate fuel are carried out in a single reactor. The particulate fuel is burned in a combustion zone in the bottom of the reactor. A bed of particulate fuel is fluidized above the combustion zone with gases rising from the combustion zone. The fluidized bed is maintained at a temperature which cokes the residual oil and volatizes the particulate fuel. A high temperature, low velocity zone is maintained between the combustion zone and the fluidized bed for calcination and desulfurization of the solid fuel.
Abstract: A method for dehydrogenating dehydrogenatable hydrocarbons which comprises contacting hydrocarbon with an oxide of Tb having combined therewith an amount of alkali and/or alkaline earth metal which is sufficient to improve the selectivity to dehydrogenated hydrocarbon products. The oxide is reduced by the contact which is carried at about 500.degree. to 1000.degree. C. Reducible oxides of Tb are regenerated by oxidizing the reduced composition with molecular oxygen. Solids prepared from the oxide Tb.sub.4 O.sub.7 are particularly effective in the process.
Abstract: Fractionation apparatus material corrosion in a coal liquefaction system is reduced by addition of compounds having a pK.sub.b <6 to tower feed streams or to the tower itself.
Type:
Grant
Filed:
March 21, 1984
Date of Patent:
April 16, 1985
Assignee:
International Coal Refining Company
Inventors:
Kenneth L. Baumert, Alberto A. Sagues, Burtron H. Davis
Abstract: Amorphous silica-alumina catalysts, having a layer of an aluminum compound chemically bonded onto the surface of a silica xerogel and having protons as the electrical charge balancing species, have been found to give surprising selectivity in the conversion of water/methanol mixtures to toluene.
Type:
Grant
Filed:
November 22, 1983
Date of Patent:
April 16, 1985
Assignee:
Coal Industry Patents Limited
Inventors:
Joseph G. Robinson, Pierce W. F. Riemer
Abstract: A method for preparing synthetic oils characterized by a high viscosity index and prepared from 1-olefin is described. The method comprises polymerizing a 1-olefin or a mixture of 1-olefins in the presence of(a) at least one transition metal halide catalyst,(b) at least one alkyl aluminum compound containing up to about 15 carbon atoms in each alkyl group and up to about 40 carbon atoms per molecule as a co-catalyst, and(c) a saturated alkyl fluoride.The homopolymers and copolymers prepared in accordance with the method of the invention generally are characterized by a high viscosity index such as between about 100 to 300. The homopolymers and copolymers are useful as synthetic lubricants and as additives to synthetic or mineral oil lubricants for modifying the viscosity index characteristics of the lubricants.
Abstract: Hydrocarbon processing equipment is protected against fouling during the processing of hydrocarbons at elevated temperatures by adding to the equipment small amounts of at least one N,N'-dimer of phenothiazine or a substituted phenothiazine and at least one mono- or ditertiary alkylphenol.
Type:
Grant
Filed:
August 10, 1984
Date of Patent:
April 9, 1985
Assignee:
Atlantic Richfield Company
Inventors:
Richard F. Miller, Michael P. Nicholson