Abstract: The invention provides a lubricant formulation comprising: (a) a base oil selected from API Group I to V oils and mixtures thereof; (b) 0.01 to 10 wt % on the basis of the total weight of the lubricant formulation of a friction modifier additive; and (c) other lubricant formulation additives. The friction modifier additive has a hydroxyl value in the range from 10 to 300 mg KOH/g and is the reaction product of reactants comprising: i) a dimer fatty acid; ii) a polyol; iii) optionally, a C2 to C12 dicarboxylic acid or diol; and iv) optionally, a C1 to C10 mono-carboxylic acid or mono-alcohol. The invention also provides a method of lubricating an internal combustion engine comprising a crankcase and a wet clutch and the use of a friction modifier additive.
Type:
Grant
Filed:
November 2, 2018
Date of Patent:
September 7, 2021
Assignee:
Croda International PLC
Inventors:
David Anthony James Gillespie, John Eastwood, Gareth Moody, Aitziber Viadas Cienfuegos
Abstract: The invention provides a lubricating oil composition for automatic transmissions is made such that it comprises proportionately as its main constituents: 60 to 98 mass % as low viscosity base oils being base oils belonging to Groups 2 to 4 of the API (American Petroleum Institute) base oil categories wherein the kinematic viscosity at 100° C. is 2 to 5 mm2/s (Fischer-Tropsch synthetic oil comprising at least 45 to 80 mass %); 1 to 20 mass % as high-viscosity base oils being metallocene/poly-?-olefins with a kinematic viscosity at 100° C. of 100 to 600 mm2/s; and 1 to 20 mass % being a polymethacrylate with a weight-average molecular weight of 10,000 to 50,000. The viscosity index of this composition is not less than 190, the Brookfield viscosity at ?40° C. is not more than 5000 mPa·s, the 100° C. kinematic viscosity is 5 to 7 mm2/s, and the rate of reduction of the 100° C. kinematic viscosity after a KRL shear stability test (60° C., 20 hr) is not more than 3%.
Abstract: Provided is a method of lubricating a sliding part by applying a lubricating base oil containing an ester compound to the sliding part. The ester compound contains a mixture of one or more compounds represented by a general formula (1) wherein R1 and R2 independently represent a hydrogen, a methyl, a benzoyloxy, a naphthoyloxy, or general formula (2) (—O—C(?O)—R5), R3 and R4 independently represent a benzoyloxy group, a naphthoyloxy group, or general formula (2), and R5 represents a linear C5-21 alkyl group, a branched chain C9-21 alkyl group, or a C5-21 cycloalkyl group that may also be substituted with an alkyl chain. The mixture contains a compound in which at least one among R1 to R4 is general formula (2), and the proportion, in the mixture, of a compound in which at least one among R1 to R4 is a benzoyloxy group or a naphthoyloxy group is 5-100 mole %.
Abstract: A lubricating composition comprises an amide and at least one additive. The amide is the reaction product of a secondary, branched amine and a carboxylic acid. The carboxylic acid may be a monocarboxylic acid or a dicarboxylic acid, including dimer acid. The amide is hydrolytically stable, and may be used to increase the hydrolytic stability of the lubricant composition. Alternatively, the amide may be used to increase the additive solubility or detergency of the lubricant composition.
Abstract: A viscosity index improver comprising a reaction product of (i) an acylated copolymer obtainable by acylating a copolymer of ethylene and one or more C3-C10 alpha-olefins having an Mn of 3,000 to 250,000 g/mol; and (ii) a compound of the formulae (I)-(V): wherein R1, R6, R8, R9, R10, R12 and R15 are independently selected from a hydrogen and an optionally substituted linear or branched alkyl or alkenyl group, and R2, R3, R4, and R5 R7, R11, R13, R14, R16, and R17 are independent selected from an optionally substituted linear or branched alkyl or alkenyl group, and a sum of the number of carbon atoms in each compound of the formulae (I)-(V) is from 6 to 31.
Abstract: The invention concerns an agent for mixing into a service fluid for a technical layout, a concentrate for mixing into a service fluid for a technical layout, and a service fluid. An agent according to the invention contains at least one ingredient A chosen from the group of three-layer silicates, at least one ingredient B chosen from the group consisting of bentonites, pyrogenic silicic acids, and talc, and graphite.
Abstract: Novel uses of copolymers for removing and/or reducing the level of deposits in the fuel system and/or injection system of direct injection diesel and/or gasoline engines are provided. What is provided is the use of particular copolymers as fuel additive or lubricant additive; to processes for preparation of such additives, and fuels and lubricants added therewith, such as, more particularly, as a detergent additive; to use of these copolymers for reducing the level of or preventing deposits in the fuel systems and especially the injection systems of direct injection diesel engines, especially in common rail injection systems, for reducing the fuel consumption of direct injection diesel engines, especially of diesel engines with common rail injection systems, and for minimizing power loss in direct injection diesel engines, especially in diesel engines with common rail injection systems; and as an additive for gasoline fuels, especially for operation of DISI engines.
Type:
Grant
Filed:
July 12, 2016
Date of Patent:
August 10, 2021
Assignee:
BASF SE
Inventors:
Ivette Garcia Castro, Maxim Peretolchin, Jochen Mezger, Klaus Muehlbach
Abstract: The invention provides a lubricant composition comprising an oil of lubricating viscosity and a protic acid salt of an N-hydrocarbyl-substituted gamma-(?-) or delta-amino(thio)ester. The invention further relates to a method of lubricating a mechanical device with the lubricant composition.
Type:
Grant
Filed:
November 4, 2016
Date of Patent:
July 27, 2021
Assignee:
Lubrizol Corporation
Inventors:
Daniel J. Saccomando, William R. S. Barton, Ewan E. Delbridge, Patrick E. Mosier
Abstract: An overbased calcium sulfonate grease composition comprising a reduced amount of overbased calcium sulfonate, calcium hydroxyapatite, base oil, one or more converting agents, and one or more complexing acids if a complex grease is desired. The calcium sulfonate grease composition improves thickener yield and expected high temperature utility as demonstrated by dropping point. A method of making the composition comprising the steps of mixing the calcium sulfonate and base oil, adding the calcium carbonate either before or after conversion, adding one or more converting agents, and adding one or more complexing acids. All or a portion of one or more of the complexing acids may be added with or prior to the one or more converting agents.
Abstract: Systems and methods are provided for processing a feed derived from a renewable source to form oligomerized compounds corresponding to waxes, ketone waxes, and/or lubricant boiling range compounds. The oligomerized compounds derived from the renewable source can have various novel properties relative to waxes and/or lubricant boiling range compounds derived from mineral sources or derived from renewable sources in a conventional manner. The oligomerized compounds can be derived from a renewable source including fatty acids and/or fatty acid derivatives, such as glycerides (including triglycerides) and fatty amides. Optionally but preferably, at least a portion of the fatty acids and/or fatty acid derivatives can include olefinic bonds.
Type:
Grant
Filed:
June 19, 2017
Date of Patent:
July 13, 2021
Assignee:
ExxonMobil Research and Engineering Company
Inventors:
Virginia M. Reiner, Michel Daage, Kun Wang, Chunping Wu, Sarvesh K. Agrawal
Abstract: The present invention relates to a lubricant composition containing a base stock and at least 0.01 wt % of a friction reducing additive which is a compound of the Formula (I): R1[(AO)n—R2]m??(I) wherein R1 is the residue of a group having at least 2 active hydrogen atoms; m is at least 2; AO is an alkylene oxide residue; each n is independently from 0 to 100; and each R2 is independently H or R3, where each R3 is independently a residue of a polyhydroxyalkyl or polyhydroxyalkenyl carboxylic acid, a residue of a hydroxyalkyl or hydroxyalkenyl carboxylic acid and/or a residue of an oligomer of the hydroxyalkyl or hydroxyalkenyl carboxylic acid; and on average at least 0.5 of R2 groups are R3. The lubricant composition is suitable for use in an engine oil, a hydraulic oil or fluid, a gear oil and/or a metal-working fluid.
Abstract: Provided is a lubricating oil composition containing a base oil (A) containing a mineral oil (A1) having a complex viscosity ?* at ?35° C. of 150 Pa·s or less as measured with a rotary rheometer under conditions at an angular velocity of 6.3 rad/s and a strain amount of 0.1%; a viscosity index improver (B) containing a comb-shaped polymer (B1); and a molybdenum-based friction modifier (C), wherein the content of the molybdenum-based friction modifier (C) in terms of a molybdenum atom is more than 500 ppm by mass and less than 900 ppm by mass on the basis of the whole amount of the lubricating oil composition, and a NOACK value is 10% by mass or less.
Abstract: Provided is a method of lubricating a sliding part by applying a lubricating base oil containing an ester compound to the sliding part. The ester compound contains a mixture of one or more compounds represented by a general formula (1) wherein R1 and R2 independently represent a hydrogen, a methyl, a benzoyloxy, a naphthoyloxy, or general formula (2) (—O—C(?O)—R5), R3 and R4 independently represent a benzoyloxy group, a naphthoyloxy group, or general formula (2), and R5 represents a linear C5-21 alkyl group, a branched chain C9-21 alkyl group, or a C5-21 cycloalkyl group that may also be substituted with an alkyl chain. The mixture contains a compound in which at least one among R1 to R4 is general formula (2), and the proportion, in the mixture, of a compound in which at least one among R1 to R4 is a benzoyloxy group or a naphthoyloxy group is 5-100 mole %.
Abstract: The invention provides a lubricant composition for an eccentrically oscillating speed reducer of planetary gear type, which is capable of extending the life of the speed reducer under high temperatures and keeping low input torque at low temperatures, and includes (a) a base oil containing a synthetic oil, (b) a hydrocarbon wax, and (c) at least one calcium salt selected from the group consisting of a calcium salt of petroleum sulfonic acid, a calcium salt of alkyl aromatic sulfonic acid, a calcium salt of oxidized wax, an overbasic calcium salt of petroleum sulfonic acid, an overbasic calcium salt of alkyl aromatic sulfonic acid, and an overbasic calcium salt of oxidized wax.
Abstract: The present disclosure relates to a lubricant composition including an anti-wear additive and metal nanoparticles. The lubricant composition according to the disclosure has, simultaneously, good stability as well as good, long-lasting friction properties.
Type:
Grant
Filed:
February 26, 2015
Date of Patent:
May 25, 2021
Assignee:
Total Marketing Services
Inventors:
Benoit Thiebaut, Fabrice Dassenoy, Paula Ussa
Abstract: The invention is directed to a zinc-free lubricating composition for an internal combustion engine containing a phosphorus anti-wear agent, an ashless antioxidant, and a metal-free basic detergent. The lubricating composition provides wear protection, deposit control, and improved acid control with reduced levels of metal-containing additives.
Abstract: A viscosity index improver comprising a copolymer having a unit (a) derived from a maleimide monomer and a unit (b) derived from a macromonomer, wherein viscosity measured by the following method is 8000 mPa·s or less. Viscosity measurement method: A solution composed of 78 mass % of a Group III base oil (viscosity index: 122, kinematic viscosity at 40° C.: 19.6 mm2/s) on the American Petroleum Institute (API) classification and 22 mass % of the copolymer is measured with a viscometer (TVB-10 manufactured by Toki Sangyo Co., Ltd., rotor: SPINDLE No. M3, rotation speed: 6 rpm) at 25° C.
Abstract: The presently claimed invention is directed to poly(meth)acrylate copolymers containing alkyl(meth)acrylate comonomer with branched C17 alkyl group. The invention is further related to lubricating oil compositions comprising poly(meth)acrylate copolymers containing alkyl(meth) acrylate comonomer with branched C17 alkyl group as viscosity index improving component.
Type:
Grant
Filed:
January 4, 2017
Date of Patent:
April 13, 2021
Assignee:
BASF SE
Inventors:
Szilard Csihony, Mary Elizabeth Dery, Philippe Rabbat, Ryan James Fenton
Abstract: A method for producing a medical device, and a medical device are provided, and the production method includes a step of heating a device together with a solution containing a polymer having the following repeating unit (A) and the following repeating unit (B), or a step of bringing a device into contact with a heated product of a solution containing a polymer having the following repeating unit (A) and the following repeating unit (B): (A) a hydrophilic repeating unit; and (B) a repeating unit having a polyoxyalkylene group in a side chain, the terminal of the side chain being composed of an alkyl group having 5 to 30 carbon atoms, an alkanoyl group having 5 to 30 carbon atoms, or an aryl group having 6 to 30 carbon atoms.
Type:
Grant
Filed:
July 26, 2016
Date of Patent:
April 13, 2021
Assignees:
JSR CORPORATION, JSR LIFE SCIENCES CORPORATION
Abstract: A dry lubricant composition in powder form is provided based on a mixture of alkali metal salts of fatty acids and fatty acid glycerides which is useful in the production of aluminium cans in a deep drawing process, wherein the formed aluminium cans are immediately further processed to yield thin inorganic and/or organic protective coatings. The invention also encompasses the use of the lubricating powder for cold forming of aluminium as well as a process for the deep drawing of aluminium cans.