Abstract: A resin powder material comprising copolymerized polybutylene terephthalate resin powder and an inorganic substance, for example, fumed silica, having an average primary particle diameter of 100 nm or less in an amount up to 1.0 wt %. The polybutylene terephthalate resin comprises from 5 mol % to 15 mol % of Isophthalic acid and has powder with average particles diameter of 79 ?m and a maximum particles diameter of 106 ?m. Powder is obtained by grinding pellets of the copolymerized polybutylene terephthalate resin having a viscosity of 0.85 to 1.0 dl/g. Powder composition used for production of molded articles by powder laminate molding process.

Abstract: A method of preparing self-adhesive polyester elastomer composite membrane includes the following steps: mix methyl formate or ethyl acetate with thermoplastic polyester elastomer (TPEE) powder or granules; add a modifier, a photo initiator or a thermal initiator; continue mixing to prepare uniformed mixture; after drying uniformed mixture prepare a polyester elastomer membrane through an injection laminating process and apply pressure sensitive adhesive on one side of the polyester elastomer membrane. Prepared membrane poses good bonding characteristics to textile materials and can be used in production of clothing.

Abstract: A polymer composition for the production of shaped objects via selective sintering includes ?70.0 wt % of poly(ethylene terephthalate), wherein ?25.0 wt % and ?90.0 wt % of the poly(ethylene terephthalate has resulted from a selective sintering process as unsintered material. The polymer composition is a powder having a D10 of ?10 and ?40 ?m, a D50 of ?75 and ?100 ?m, and a D90 of ?160 and ?200 ?m. The polymer composition allows for the production of an article having a continuous use temperature of ?100° C., and results in a low change of molecular weight during exposure to selective sintering powder processing temperatures. Further, the polymer composition allows for a significant reduction of the waste material generated during selective sintering as the unsintered material does not have to be disposed of as waste but may be used again.

Abstract: A polyester copolymer, having a number average molecular weight of equal to or more than 4000 gram/mole and having a glass transition temperature of less than 140° C., containing: (a) in the range from equal to or more than 45 mole % to equal to or less than 50 mole % of one or more bicyclic diol monomer units derived from the group consisting of isosorbide, isoidide, isomannide, 2,3:4,5-di-O-methylenegalactitol and 2,4:3,5-di-O-methylene-D-mannitol; (b) in the range from equal to or more than 25 mole % to equal to or less than 49.9 mole %, of an oxalate monomer unit; (c) in the range from equal to or more than 0.1 mole % to equal to or less than 25 mole % of one or more linear C3-C12 dicarboxylate monomer units; and (d) optionally equal to or more than 0 mole % to equal to or less than 5 mole % of one or more additional monomer units, the percentages based on the total amount of moles of monomer units within the polyester copolymer.

Abstract: Compositions of high molecular weight poly(hydroxy acid) polymer having good thermal stability and a weight average molecular weight of >100,000 by GPC. The compositions include one or more chain-terminator compounds/impurities which may be incorporated into the polymer and rendered harmless by the presence of appropriate amounts of bi-functional and multi-functional polymerization initiators. A process including first mixing glycolic acid and/or lactic acid (with chain-terminators), and a diol or di-acid initiator, and at least one multifunctional initiator to form a liquid monomer mixture in an agitated polycondensation reactor. Next, polycondensing to form a liquid reaction mixture comprising a pre-polymer having a weight average molecular weight of >10,000 by GPC, and greater than 80% by mole hydroxyl or carboxyl end-group termination, then crystallizing to form a first solid reaction mixture.

Abstract: A method includes applying a composition for forming a resist underlayer film to a substrate having a recess in a surface, and baking the composition for forming a resist underlayer film to form a resist underlayer film for filling at least the recess. The composition for forming a resist underlayer film has a copolymer having a structural unit of following formula (1), a cross-linkable compound, a cross-linking catalyst, and a solvent: wherein R1 and R2 are each independently a C1-3 alkylene group or a single bond, Z is an —O— group, a —S— group, or a —S—S— group, and Ar is an arylene group.

Abstract: A method for preparing a polycarbonate ester includes feeding a monomer mixture containing (i) at least one compound selected from the group consisting of compounds of the following Formulae 1 and 3; (ii) a compound of the following Formula 2; and (iii) a 1,4:3,6-dianhydrohexitol to a polycondensation reactor and allowing the monomers and the 1,4:3,6-dianhydrohexitol to react to prepare the polycarbontate ester.

Abstract: A method for preparing a biogenic guanidine complex, the method including: mixing dimethyl sulfoxide (DMSO) with water in a volume ratio thereof of 1:1 to yield a solvent DMSO-H2O; adding organic guanidine (G) and a compound MX2 in a molar ratio G/MX2=1:1 or 2:1 to the solvent DMSO-H2O, where the organic guanidine (G) is selected from arginine (Arg), guanidinoacetic acid (Gaa), creatine (Cra), creatinine (Cran), guanine (Gua), and agmatine (Agm); M represents Fe2+, Mg2+, or Zn2+; and X represents Cl?, CH3COO?, or CH3CH(OH)COO?; stirring the solvent DMSO-H2O containing the organic guanidine and the compound MX2; recycling the solvent DMSO-H2O through vacuum distillation and obtaining a solid; transferring the solid to a Buchner funnel, and washing the solid with deionized water and ethanol consecutively; and removing the deionized water and ethanol through vacuum filtration, and drying the solid.

Abstract: A polyester resin that exhibits heat resistance and transparency by including at least dispiro[5.1.5.1]tetradecane-7,14-diol as a diol component, and a preparation method of this polyester resin are disclosed. The polyester resin is obtained by copolymerization of two or more glycols in addition to dispiro[5.1.5.1]tetradecane-7,14-diol and dicarboxylic acid component, which may include terephthalic acid. The diol component may include 1,4-cyclohexanedimethanol in a range from 30 to 50 mol % based on 100 mol % of the dicarboxylic acid and dispiro[5.1.5.1]tetradecane-7,14-diol in a range from 5 to 60 mol % based on 100 mol % of the dicarboxylic acid moiety and ethylene glycol.

Abstract: Polymers and methods of making the same are described whereby the polymers generically include one or more units each of which necessarily has a 1,2,4-substituted cyclohexane group or a 1,1,2,4-substituted cyclohexane group. According to specific disclosures herein, polymers and methods of making the same are described whereby the polymers have one or more S1 units represented by the formula: wherein n is an integer equal to or higher than 1, m is 0 or 1, A is H or CH3, and wherein each of X and Y is a specifically defined group.

Abstract: An end and monomer functionalized poly(propylene fumarate) polymer and methods for preparing this polymer, comprising isomerized residue of a maleic anhydride monomer and a functionalized propylene oxide monomer according to the formula: where n is an integer from more than 1 to 100; R is the residue of an initiating alcohol having a propargyl, norbornene, ketone or benzyl functional group; and R? is a second functional group selected from the group consisting of propargyl groups, 2-nitrophenyl groups, and combinations thereof are disclosed. The end and monomer functional groups allow for post-polymerization modification with bioactive materials using “click” chemistries and use of the polymer for a variety of applications in medical fields, including, for example, 3-D printed polymer scaffold.

Abstract: Provided are integrated processes for the conversion of ethylene oxide to polypropiolactone. System for the production of polypropiolactone are also provided.

Abstract: Processes for making a fluid conduits and fluid conduits made thereby are disclosed. The fluid conduits include a mono-layer formed of at least 80 wt %, based on total weight of the mono-layer, of a thermoplastic elastomer in an amount of at least 80 wt % with respect to the total weight of the mono-layer. The thermoplastic elastomer is preferably a block copolymer elastomer formed of hard segments (e.g., polyesters, polyamides and/or polyurethanes) and soft segments (e.g., aliphatic polyethers, aliphatic polyesters and/or aliphatic polycarbonates) and exhibits a melt flow rate measured at 230° C. under a load of 10 kg (MFR 230° C./10 kg), according to ISO1133 (2011) of at most 40 g/10 min and having a heat resistance of at least 250 hours at 175° C. at which the elongation at break remains at least 100% as measured according to ISO 527 with a test speed of 50 mm/min.

Abstract: A medical material comprising film obtained from a polyester wherein the polyester has a weight average molecular weight of 1,250,000 or greater determined by gel permeation chromatography calibrated with polystyrene standards. The polyester comprises a 3-hydroxybutyrate unit and a 4-hydroxybutyrate unit as polymerization units, and proportion of the 4-hydroxybutyrate unit relative to all monomer units is from 14 mol % to 40 mol %. The polyester film is useful for medical apparatus, packaging material for food, plastic sheet for agriculture, flowerpots for seedings, and sheets for construction and engineering.

Abstract: A process for polymerizing ?-butyrolactone that includes contacting racemic ?-butyrolactone or an enantiomer thereof with a catalyst/initiator system which includes a rare earth metal, a chiral ligand, at least one nucleophilic ligand, optionally at least one solvent ligand, and optionally an alkali based co-catalyst. The chiral ligand is an enantiomer of a unit of formula I Each Rz independently is substituted or unsubstituted linear C1-C20 alkyl, or substituted or unsubstituted branched, or cyclic C3-C20 alkyl, substituted or unsubstituted C6-C20 aryl, substituted or unsubstituted C5-C20 heteroaryl, or halogen. Each Ra independently is H, Me+, (MeZ)+, wherein Z is a charge equalizing anion, or wherein two Ra together are alkaline earth metal, wherein Me+ is alkali metal or alkaline earth metal.

Abstract: Polycarbonate block copolymers are provided, which have: (A) a polyester block of chemical formula 1; and (B) a polycarbonate block derived from a dihydric phenol of chemical formula 3 compound and phosgene. The copolymers may be prepared by (1) polymerizing ester oligomers to form a compound of chemical formula 1; and (2) copolymerizing the ester oligomer obtained in (1) with a polycarbonate oligomer prepared from a dihydric phenol compound of chemical formula 3 and phosgene, in the presence of a polymerization catalyst. The block copolymer may have a viscosity average molecular weight (Mv) of 10,000 to 200,000.

Abstract: Calendered films or sheets obtained from a composition comprising at least one polyester which has the L* color value of greater than 90 and comprises terephthalic acid residues, optional aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; glycol component comprising 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues and ethylene glycol residues; a catalyst/stabilizer component which comprises titanium atoms, manganese atoms, phosphorous atoms; fillers; release additives and does not comprises tin atoms. Calendered films or sheets can be used in a wide range of applications including packaging, pool liners, graphic arts, transaction cards, security cards and others.

Abstract: Aqueous compositions can be thickened without increasing stringiness, by using polymers of polyacrylic acid, poly(2-acryamide-2-methylpropanesulfonate), or salts thereof, having a weight average molecular weights of 500,000 to 8,000,000 as thickeners. The polymers contain no more than 10 mass % of polymers having a molecular weight of 10,000,00 or more, and/or contain no more than 10 mass % of polymers having more than three times the weight average molecular weight. Aqueous solutions of these polymers exhibit a low degree of stringiness, and are particularly useful as thickeners for cosmetics.

Abstract: A method of manufacturing a molded article by a low shear manufacturing process that includes: placing a solid polyester in a mold having mold surfaces; heating said polyester until it becomes molten; dispersing said molten polyester over said mold surfaces; solidifying said molten polyester to form a solid molded article; and removing said molded article from said mold; where the polyester is obtained by polymerization of dimethylcyclohexane dicarboxylic acid, cyclohexane dimethanol, polytetramethylene ether glycol and branching agent and has a steep melting curve evidenced by a puddling curve slope of ?2 to ?10.

Abstract: A heat-resistant, bio-based polycarbonate ester prepared by melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate, 1,4-cyclohexanedicarboxylate, or a terephthalate is disclosed. The heat-resistant, bio-based polycarbonate ester includes a repeat unit 1 of Formula 1, a repeat unit 2 of Formula 2, and a repeat unit 3 of Formula 3: The polycarbonate ester has excellent heat resistance, transparency, and processability. A method of producing the polycarbonate includes a step of melt polycondensation of 1,4:3,6-dianhydrohexitol and a carbonate, 1,4-cyclohexanedicarboxylate, or a terephthalate.