Abstract: A thermoplastic composite comprising a thermoplastic polymer matrix comprising an amorphous polyester containing 1,4: 3,6-dianhydrohexitol units, an alicyclic diol and terephthalic acid, wherein diol component comprises 1,4:3,6-dianhydrohexitol and alicyclic diol in ratio from 0.32 to 0.75; and thermoplastic fibers comprising a semi-crystalline polyester containing 1,4: 3,6-dianhydrohexitol units, an alicyclic diol and terephthalic acid, wherein diol component comprises 1,4:3,6-dianhydrohexitol and alicyclic diol in ratio from 0.05 to 0.30 are disclosed. Methods for producing the polymer composite are also disclosed.

Abstract: Packaging material for food products with antimicrobial and antifungal properties including: a) a core layer of polymeric material including at least one active substance having antimicrobial and/or antifungal activity dispersed in the polymer matrix, b) a coating applied to a side of the core layer obtained from a lacquer or a polymeric paint including nano-fillers of a phyllosilicate or hydrotalcite, c) a coating for the release of an active antimicrobial or antifungal agent comprising encapsulated ethanol and a polymeric component selected from chitosan grafted with polyethylene glycol or cyclodextrin, a mixture of chitosan and polyethylene glycol and a polymer or mixture of polymers for printable paint applied to other side of the base layer; optionally the material further comprises: d) a coating with oxygen scavenger activity applied to the coating layer c) and/or a further coating e) including active substances of type b).

Abstract: A polyester resin composition comprising a crystalline wholly aromatic polyester which is a polycondensate of an aromatic dicarboxylic acid and an aromatic diol, and a filler, wherein a structural unit derived from the aromatic dicarboxylic acid comprises a structural unit represented by chemical formula (1): and a structural unit derived from the aromatic diol comprises chemical formula (4): wherein content of a residue of 4,4?-dicarboxy diphenyl ether (corresponding to the structural units represented by chemical formula (1)) and a residue of 4,4?-dihydroxy benzophenone (corresponding to the structural units represented by chemical formula (4)) is at least 80 mol % in the entire structural units of the crystalline wholly aromatic polyester.

Abstract: An environmentally friendly, formaldehyde-free, aqueous binder composition that includes a carbohydrate, a crosslinking agent, and a pre-reacted product of an alcohol or polyol and monomeric or polymeric polycarboxylic acid or polyglycerol is provided. The pre-reacted product may include glycerol and esters of citric acid such a monoglyceryl citrate, diglyceryl citrate, and triglyceryl citrate as well as other higher molecular weight citric acid-based esters. The inclusion of the pre-reacted product in the binder composition helps to speed the crosslinking reaction, induces faster water evaporation, decreases the viscosity of the binder, helps to reduce the amount of water needed for application of the binder, decreases tackiness, and helps to achieve a maximum vertical expansion of the insulation pack in the transfer zone. The binder composition may be used in the formation of insulation materials and non-woven chopped strand mats.

Abstract: Methods for edging optical articles comprising two main faces, at least one of which being coated with an outermost layer comprising fixing the optical article to a chuck with a holding pad that adheres to both the optical article and the chuck, wherein the surface of the holding pad contacting the optical comprises an adhesive material; and edging the optical article with an edging device; wherein prior to fixing the optical article to the chuck, at least one temporary layer of an organic material is formed onto said outermost layer of the optical article, the organic material of the temporary layer comprising at least one organic compound having a fluorinated functional moiety and at least one linking functional moiety capable of establishing at least one intermolecular bond or interaction with the adhesive material of the holding pad. Optical articles obtained via these methods.

Abstract: A catalyst for preparing polyester resins from monobasic or polybasic acids and polyhydric alcohols, comprising a Magnesium compound which has a bonding portion represented by formula —Mg—O—(CR12)a-Q, wherein Q is a Nitrogen or Sulfur and a is an integer from 1 to 4, is disclosed. Catalyst may further comprise Titanium compounds, for example titanium alkoxide, wherein titanium diisopropoxy bistriethanolaminate is particularly preferable from the viewpoint of reactivity and coloring property. Catalyst is capable of shortening production time for polyester resins.

Abstract: A method for preparing a thermal adhesive copolymerized polyester resin is disclosed. The method includes: a transesterification reaction in a reaction mixture of a diol compound according to Formula 1, for example, 2-Methyl-1,3-propanediol, an isophthalic acid (IPA) or an IPA derivative as an acid component, and polyethylene terephthalate; and a condensation polymerization reaction of the reaction mixture to prepare a copolymerized polyester resin. The copolymerized polyester resin has an intrinsic viscosity (I.V.) of 0.5 dL/g to 0.75 dL/g, a softening point (Ts) of 100° C. to 160° C., and a glass transition temperature (Tg) of 60° C. to 70° C. The copolymerized polyester resin can be effectively used in fields of clothing, automobile parts, as a thermal adhesive fiber. wherein R1 is an alkyl group having 1 to 4 carbon atoms, a and b are each independently an integer ranging from 0 to 3, and each solid line represents a single bond when a and b is 0.

Abstract: Filament comprising a polymeric material that includes a diacid component comprising from about 40 to 60 mole % of units derived from terephthalic acid and from about 40 to 60 mole % of units derived from a diacid chosen from isophthalic acid, a cyclohexanedicarboxylic acid, a naphthalenedicarboxylic acid, a stilbenedicarboxylic acid, or a combination thereof; a glycol component comprising at least 75 mole % of units derived from cyclohexanedimethanol; wherein the polymeric material has an inherent viscosity loss of 3% or less after being extruded; and method of using this filament in production of different articles by 3D printing are disclosed.

Abstract: A polyethylene terephthalate (PET) polymer having diacid units derived from diacid compounds, said diacid units comprising: a) from 92.50 mol % to 97.75 mol % of terephthalic units derived from terephthalic acid (TA) or an ester thereof, and b) from 2.25 mol % to 7.50 mol % of 2,5-FDCA units derived from 2,5- furandicarboxylic acid (2,5-FDCA) or an ester thereof, and-diol units derived from diol compound(s), the diol units having monoethylene glycol units derived from monoethylene glycol (MEG), as well as to a method to prepare a PET polymer. The use of a 2,5-FDCA compound selected from 2,5- furandicarboxylic acid (2,5-FDCA) and esters thereof as an anti-crystallization comonomer in a PET polymer and a bio-based PET polymer in which the anti-crystallisation comonomer is bio-based.

Abstract: Optical films comprising a polyester resin comprising a structural unit (A) of the following formula (1) wherein the content of the structural unit (A) based on the total structural units of the polyester resin is 76 mol % or greater: wherein R1 is a hydrogen atom, CH3, or C2H5; R2 and R3 is each independently a hydrogen atom or CH3; and n is 1, for example, Decahydro-1,4:5,8-dimethanonaphthalene-2-methoxycarbonyl-6(7)-methanol. Retardation films and circularly or elliptically polarizing plates comprising the optical films are also provided.

Abstract: A polyester resin composition includes: (A) polycyclohexylenedimethylene terephthalate (PCT) resin which is a polymer of terephthalic acid and cyclohexanedimethanol, wherein the cyclohexanedimethanol has a trans/cis isomer ratio of about 2.3 or more; (B) a white pigment, wherein the white pigment is titanium dioxide; and (C) inorganic fillers, wherein the inorganic fillers are glass fibers. A molded article formed from the polyester resin composition can exhibit improved mechanical properties and moldability, and thus can be suitable for light emitting diode (LED) reflectors.

Abstract: A catalyst composition for a polyester manufacturing process, comprising a titanium catalyst and/or an antimony catalyst as main catalyst, and either (i) at least one co-catalyst A, or (ii) at least one co-catalyst B and at least one co-catalyst C, or (iii) a combination thereof, and wherein co-catalyst A is selected from the group consisting of a metal salt of an alkyl or an aryl phosphinic acid, or a metal salt of an alkyl or aryl diphosphinic acid, or a combination thereof, and co-catalyst B is selected from the group consisting of an alkyl or aryl phosphinic acid, an alkyl or aryl diphosphinic acid a combination thereof, and co-catalyst C selected from the group of a metal salt, a metal hydroxide or a metal organyl compound.

Abstract: An object is to provide an optical polyester film and a transparent conductive film that are superior in transparency, heat resistance, optical properties, and adhesion. The optical polyester film includes: a base material containing a polyester resin containing a unit (A) of the following formula (1); and at least one functional layer disposed on at least one surface of the base material, wherein the at least one functional layer is selected from the group consisting of a hard coat layer, a transparent conductive layer, an anti-reflection layer, a gas barrier layer, and an adhesive layer.

Abstract: A polymer composition comprising at least two polyesters having improved mechanical properties including a good balance between ultimate tensile strength, elastic modulus and elongation on failure. In particular, the composition comprises from 1 to 99% by weight of at least one aromatic polyester (AP) comprising units from a diol component and units from an acid component, the units from the acid component comprising from 70 to 100 mol % of repeating units from at least one heterocyclic polyfunctional aromatic acid of renewable origin and from 99 to 1% by weight of at least a second aliphatic-aromatic polyester (AAPE). This composition is suitable for producing articles such as films, moulded objects, thermoformed objects or expanded articles. The heterocyclic aromatic acid is 2,5-furandicarboxylic acid and the aliphatic-aromatic polyester is biodegradable and is a copolyester comprising repeating units from aromatic acid of the phthalic acid type, aliphatic diacids, and aliphatic diols.

Abstract: A robust hydrogel-solid hybrid formed of a substrate material having a nonporous and non-topographically patterned surface and a tough hydrogel bonded to the surface, the tough hydrogel having over 90 wt % water, and the hydrogel being bonded to provide interfacial toughness over 300 Jm?2, and even over 1000 Jm?2. The hydrogel is formed of polyacrylamide or polyethylene glycol diacrylate, which provide long-chain polymer networks, and chitosan, hyaluronan, or alginate, which provide mechanically dissipative components. An anchor, which can be a silane, a sulfide, or an amine, is disposed between the surface and the hydrogel to provide chemical bonding between the surface and the long-chain networks of the hydrogel.

Abstract: An object is to provide an optical lens having low water-absorbing capacity and superior in heat resistance, transparency, and optical characteristics (refractive index, Abbe's number, and photoelastic coefficient). The optical lens includes a polyester resin containing a unit (A) of the following formula (1).

Abstract: A device for making polybutylene terephthalate includes (1) a slurry paste vessel; (2) a tower reactor to which a mixture of 1,4-butane diol and terephthalic acid from vessel (1) is supplied, the tower reactor having a plurality of reactor zones wherein the lower third of the tower reactor is in the form of a hydrocyclone with attached heat exchanger, and the hydrocyclone has a supply line from vessel (1), the hydrocyclone being connected to the top side of the tower reactor; (3) a first continuously stirred tank reactor to which the product from tower reactor (2) is supplied; (4) an optional second continuously stirred tank reactor to which the product from (3) is supplied; (5) a dual shaft ring reactor to which the product from stirred tank reactor (3) or (4), is supplied; and (6) a pelletizer where the product from dual shaft ring reactor (5) is continuously fed and pelletized.

Abstract: A process of forming a functionalized polyhydroxyalkanoate (PHA) material includes forming a saturated PHA material via a bacterial fermentation process. The process further includes performing an oxide elimination reaction on the saturated PHA material to form an unsaturated PHA material having a carbon-carbon double bond in a polymer backbone. The process also includes utilizing the unsaturated PHA material to form an epoxidized PHA material. The process further includes utilizing the epoxidized PHA material to form a functionalized PHA material. The functionalized PHA material has one or more cross-linkable functional groups bonded to a polymer backbone of the functionalized PHA material.

Abstract: Photoresponsive polymers that comprise a unit derived from an amide functional diol compound that includes a coumarin group are provided. Advantageously, the photoresponsive groups of the photoresponsive polymers may be used to control the viscosity of the photoresponsive polymer. The photoresponsize polymers may also include units derived from amide functional diol compounds with include a fatty acid chain or a polyethylene glycol chain. The photoresponsive polymers may be used for 3d printing. When an adhesive group is added to a photoresponsive polymer they may be used as an adhesive. Adhesive groups include catechol groups.

Abstract: A polyester resin having a diol constitutional unit and a dicarboxylic acid constitutional unit, wherein 20 to 100 mol % of the diol constitutional unit is a constitutional unit derived from a diol having a dinorbornane ring; a glass transition temperature of the polyester resin is 90° C. or higher; an amount of heat of a crystallization exothermic peak in temperature drop of the polyester resin is 5 J/g or less; and a yellow index (YI) value as measured by a reflection method according to JIS K 7103 is 10 or less.