Abstract: A polyester resin, including: (a) a constitutional unit derived from at least one tetravalent carboxylic acid selected from Compounds (A) and (B); a constitutional unit derived from a bisphenol A-alkylene oxide adduct; and a constitutional unit derived from an aliphatic alcohol having a boiling point of lower than or equal to 290° C.

Abstract: A copolymerized saturated polyester resin is formed by polycondensation of an acid component and an alcohol component. The acid component contains (a-1) 90 to 99% by mole of an aromatic dicarboxylic acid or a C1-2 alkyl ester thereof and (a-2) 0.5 to 2% by mole of a trifunctional or higher functional carboxylic acid or an anhydride thereof. The alcohol component contains (b-1) 45 to 80% by mole of an alicyclic polyhydric alcohol and (b-2) 20 to 55% by mole of an aliphatic polyhydric alcohol having a C1-3 alkyl side chain. A coating composition containing the copolymerized saturated polyester resin shows excellent corrosion resistance and chemical resistance. A coating film formed from the coating composition shows excellent processability and resin solubility, and is useful for coating a can and pre-coated metal.

Abstract: A polyester resin and a coating composition containing the polyester resin are disclosed. The polyester resin includes a repeating unit obtained by copolymerizing (a) a divalent acid component and (b) a diol component containing (b-1) an isosorbide and (b-2) a cycloaliphatic diol, and has excellent heat resistance and solubility in a solvent. The cycloaliphatic diol may be one or more diol derivatives of a tricycle C7-14 alkane. A coating formed from a coating composition containing the polyester shows excellent heat resistance, hardness, chemical resistance, pollution resistance, and hydrolysis resistance.

Abstract: An oriented film or a shrink film comprising a polyester composition which comprises at least one polyester which comprises: a dicarboxylic acid component comprising: about 90 to about 100 mole % of terephthalic acid residues; about 0 to about 10 mole % of aromatic and/or aliphatic dicarboxylic acid residues having up to 20 carbon atoms; and a glycol component comprising: about 10 to about 29 mole % 2,2,4,4-tetramethyl-1,3-cyclobutanediol residues; and about 71 to about 90 mole % ethylene glycol residues; and optionally, diethylene glycol residues; wherein the total mole % of the dicarboxylic acid component is 100 mole %, and wherein the total mole % of the glycol component is 100 mole %; wherein the inherent viscosity of the polyester is from 0.50 to 0.8 dL/g.

Abstract: A reversibly crosslinked polymer and methods for producing and using the obtained polymer are disclosed. In particular, reversibly crosslinked polymers of the invention comprise polyesters formed by the reaction of mercaptosuccinic acid and a diol to form a monomeric unit that includes thiol groups as crosslinking moieties. Oxidation of the thiol groups affords crosslinked polymer comprising a disulfide linkage that, upon reduction of the disulfide linkage, provides a non-crosslinked polymer. In some embodiments, polymers of the invention are degradable and are biocompatible.

Abstract: A liquid crystal polyester fibers containing a liquid crystal polyester, in which the liquid crystal polyester has repeating units represented by Formulae (1), (2) and (3), at least one of the repeating units contains 2,6-naphthylene, a content of the repeating unit containing the 2,6-naphthylene is 40 mol% or greater with respect to a total content of all the repeating units, and an orientation degree of the liquid crystal polyester in a length direction of the fiber is 89% to 95%: —O—Ar1—CO—??(1), —CO—Ar2—CO—??(2), and —X—Ar3—Y—??(3), wherein Ar1 represents phenylene, naphthylene, or biphenylylene, Ar2 and Ar3 each independently represent phenylene, naphthylene, or biphenylylene, and at least one of Ar1, Ar2, and Ar3 contains 2,6-naphthylene, X and Y each independently represent oxygen or —NH—, Ar1, Ar2, or Ar3 may be each independently substituted with halogen, alkyl, or aryl.

Abstract: A thermoplastic resin composition includes: a polyester resin; a white pigment; a core-shell structured impact modifier; and a modified polyolefin resin. Exemplary compositions include polycyclohexylenedimethylene terephthalate (PCT) resin; titanium oxide; a core-shell structured impact modifier obtained by grafting methyl (meth)acrylate to the polydimethylsiloxane rubber core; and an ethylene-methacrylate copolymer. The thermoplastic resin composition is usable for the production of molded article as a reflector or reflector cup for a LED (light-emitting diode) that maintains reflectance at elevated temperature.

Abstract: Disclosed are aliphatic-aromatic biodegradable polyesters obtained from aliphatic dicarboxylic acids comprising azelaic acid, sebacic acid, suberic acid, brassylic acid and their esters; polyfunctional aromatic acids of renewable origin and particularly 2,5-furan dicarboxylic acid, and diols, such as 1,2-ethanediol, 1,2-propanediol, 1,3-propanediol, 1,4-butanediol, 1,5-pentanediol, 1,6-haxanediol, 1,7-heptanediol, 1,8-octanediol, 1,9-nonanediol, 1,10-decanediol, 1,11-undecanediol, 1,12-dodecanediol, 1,13-tridecanediol, 1,4-cyclohexanedimethanol, propylene glycol, neopentyl glycol, 2-methyl-1,3-propanediol, dianhydrosorbitol, dianhydromannitol, dianhydroiditol, cyclohexanediol, cyclohexane-methanediol, aromatic diols such as phenols, and furan diol. Also disclosed are blends of the polyesters with other biodegradable polymers of either natural or synthetic origin.

Abstract: A method for manufacturing a semiconductor substrate having a patterned group-III nitride compound layer without collapsing a formed mask pattern due to reflow or decomposition even when an etching method at a high temperature of 300° C.-700° C. is used, including the steps: forming a patterned mask layer on the substrate's group-III nitride compound layer, and etching the group-III nitride compound layer by dry etching at 300° C. or higher and 700° C. or lower using the mask pattern, to form patterned group-III nitride compound layer, wherein the patterned mask layer contains a polymer containing a unit structure of the following Formula (1): a polymer containing a unit structure of the following Formula (2): O—Ar1??Formula (2) a polymer containing a structural unit of the following Formula (3): O—Ar2—O—Ar3-T-Ar4??Formula (3) a polymer containing a combination of unit structure of Formula (2) and unit structure of Formula (3), or a crosslinked structure of the polymers.

Abstract: Disclosed is a sealant film including at least a layer formed of a polyester as a superficial layer, in which the polyester contains 20 to 50 mol % of a 2,5-furandicarboxylic acid unit, 18 to 49.5 mol % of at least one diol unit selected from the group consisting of an ethylene glycol unit, a 1,3-propanediol unit, and a 1,4-butanediol unit, and 0.5 to 2.5 mol % of a diethylene glycol unit, the sealant film has a crystallinity of less than 14%, and the sealant film is a stretched film that exhibits a shrinkage ratio of 6% or more in a maximum shrinkage direction upon being allowed to stand at 125° C. for 20 seconds. This provides a sealant film superior in mechanical properties, especially tensile elongation, and also superior in heat sealability, non-adsorptivity, and gas barrier properties.

Abstract: A polyester resin having low-temperature (80-240° C.) fluidity, storage stability, and achieving both dispersibility and grindability, where the polyester resin includes, in reacted form: a polyhydric alcohol; a polycarboxylic acid; a sulfonate component, which is a bis(2-hydroxyethyl)isophthalate sulfonic acid salt; and a hetero alicyclic skeleton, which can be a monomer of formula (1) and/or formula (2): where X is O, S, or NH and R1 to R4 are functional groups. Also, a method for producing the polyester resin by polymerizing a mixture containing the polyhydric alcohol, the polycarboxylic acid, the sulfonate component and the hetero alicyclic skeleton component having formula (1) and/or (2).

Abstract: Provided is a heat-shrinkable polyester film which has heat shrinkage properties in a main shrinkage direction in the longitudinal direction, a small variation in shrinkage in the width direction, and less likely generated wrinkles and strains at the time of shrinkage finishing. The polyester film is prepared from a polyester raw material resin comprising 50 mol % or more of an ethylene terephthalate unit in 100 mol % of constituent units of a polyester, diol components selected from aliphatic, alicyclic, and aromatic diols, and an amorphous monomer component that is 2% or more in 100 mol % of either a polyhydric alcohol component or a polybasic carboxylic acid component in the whole polyester resin, wherein the polyester does not contain polybasic carboxylic acids of tribasic or more, and the polyester film is obtained by uniaxial drawing in the longitudinal direction.

Abstract: A polyethylene terephthalate composition (PET), an injection-molded bottle preform made from a PET composition, a refillable PET container blow-molded from the preform, catalyst compositions used for making the PET composition, methods for making the PET composition, methods for injection-molding a PET bottle preform, methods for blow-molding a refillable PET bottle from a preform and methods for improving the rewash stability and recyclability of refillable PET bottles particularly for carbonated soft drinks are disclosed. The polyethylene terephthalate composition includes a polyester resin containing terephthalic acid, isophthalic acid, ethylene glycol and cyclohexane dimethanol and residual amount of catalytic composition comprising Sb and Ti. The polyethylene terephthalate composition is especially useful for large blow moldings and provides a change in the fill point volume after 5 wash cycles of a 2.5 liter blow molded bottle of 14 ml or less.

Abstract: An automobile component including a molded article containing a copolymerized polyester resin synthesized from a hydroxycarboxylic acid monomer, a diol monomer, and a dicarboxylic acid/ester monomer and having a unit (A) of formula (1), a diol unit (B), and a unit (C) derived from a dicarboxylic acid or an ester-forming derivative of the dicarboxylic acid. A content of the unit (A) in the total units of the copolymerized polyester resin is 60 to 90 mol %, The formula (1) is where R1 is a hydrogen atom, CH3, or C2H5, R2 and R3 are each independently a hydrogen atom or CH3, and n is 0 or 1.

Abstract: A composition for forming a heat shrinkable film includes a polyethylene terephthalate (PET) resin having an inherent viscosity of 0.50 to 1.2 dl/g, and a polyester based copolymer including a dicarboxylic acid-derived residue including a residue derived from an aromatic dicarboxylic acid and a diol-derived residue including a residue derived from 4-(hydroxymethyl)cyclohexylmethyl 4?-(hydroxymethyl)cyclohexane carboxylate represented by the following Chemical Formula 1 and a residue derived from 4,4-(oxybis(methylene)bis)cyclohexane methanol represented by the following Chemical Formula 2.

Abstract: There is provided a heat shrinkable film comprising a polyester based copolymer capable of having an excellent shrinkage rate and being heat shrunk at a low temperature. The heat shrinkable film according to an exemplary embodiment of the present invention includes a polyester based copolymer, wherein the polyester based copolymer includes: a dicarboxylic acid-derived residue including a residue derived from an aromatic dicarboxylic acid; and a diol-derived residue including a residue derived from 4-(hydroxymethyl)cyclohexylmethyl 4?-(hydroxymethyl)cyclohexane carboxylate represented by the following Chemical Formula 1 and a residue derived from 4,4-(oxybis(methylene)bis) cyclohexane methanol represented by the following Chemical Formula 2.

Abstract: A coating composition includes: (a) 60 to 90 percent by weight of an active hydrogen-containing polyester having a number average molecular weight of at least 23,000, an acid value below 5 and a hydroxyl value below 10, (b) 0.1 to 10 percent by weight of a polyanhydride, and (c) 5 to 30 percent by weight of a curing agent reactive with the active hydrogens associated with (a) and (b), the percentages being based on weight of resin solids of the coating composition, where the reaction product of the coating composition forms a single coating without including a thermoplastic polymer. The coating composition is useful in coating food and beverage containers, particularly 2-piece cans formed by drawing and redrawing (DRD).

Abstract: A method for preparing a biodegradable polyester elastomer includes a following steps comprising: dissolving a predetermined amount of titanium dioxide in an aqueous mixture of sulphuric acid, DI water, and ethanol to form a first solution; refluxing the first solution in a silicone oil bath and a stirring speed of 300-450 rpm at a temperature of 90-100° C. to form a second solution; preparing a solid superacid catalyst by drying, grinding and calcining sulfated titania and using this catalyst to produce a biodegradable polyester elastomer.

Abstract: A polyester with ultra-high flowability and good stability over time is provided. The polyester can be polybutylene terephthalate (PBT) or another aliphatic polyester, whose intrinsic viscosity (IV) is less than 0.6 dL/g and a carboxylic end group (CEG) content is 15 meq/kg or less, and characterized by having a melt volume rate (MVR) of greater than 400 cm3/10 min at 250° C. A resin composition of this polyester is provided, which can be meltblown into microfibers of a uniform diameter and a concentrated diameter distribution, forming a fabric with a uniform small pore size.

Abstract: A method of making a non-solid state polyester that includes: a) reacting terephthalic acid and ethylene glycol; b) removing the water continuously; c) polymerizing the monomers and oligomers in vacuum conditions at a temperature to form molten polyester having an IV (intrinsic viscosity) of about 0.7 to 0.