Patents Examined by Irving Vaughn
  • Alkylbenzene sulfonic acid modified mannich reaction products from oxidized polymers
    Patent number: 4131553
    Abstract: This invention provides a process for and products of the Mannich condensation reaction of oxidized olefinic polymers. The Mannich reaction is carried out in the presence of about 0.01 to 40.0% by weight of an oil soluble sulfonic acid based on the neat polymer. The sulfonic acid improves the properties of the oxidized oil soluble Mannich reaction product and catalyzes the Mannich condensation reaction.
    Type: Grant
    Filed: February 15, 1978
    Date of Patent: December 26, 1978
    Assignee: Standard Oil Company (Indiana)
    Inventor: C. Thomas West
  • Railway lubricating oil
    Patent number: 4131551
    Abstract: An improved lubricant composition comprises (A) a lubricant mineral oil base, (B) a Mannich condensation reaction product comprising the reaction product of an alkyl phenol, a polyamine and formaldehyde, (C) an alkaline earth metal salt of a Mannich condensation reaction product comprising the reaction product of alkyl phenol, formaldehyde and a polyamine, (D) an alkylbenzene alkaline earth metal sulfonate of low total base number, and (E) the alkaline earth metal salts of a bis-alkylphenol sulfide, (F) chlorinated paraffin, and (G) dimethyl siloxane polymer.
    Type: Grant
    Filed: August 15, 1977
    Date of Patent: December 26, 1978
    Assignee: Standard Oil Company
    Inventors: Jerry L. Thompson, Sigmund S. Deluga, James W. Harnach, Eliahu Shamah
  • MXY.sub.3 solid lubricants
    Patent number: 4130492
    Abstract: Materials of the general formula MXY.sub.3 wherein M is selected from the group consisting of Mg, V, Mn, Fe, Co, Ni, Zn, Cd, Sn, Pb and mixtures thereof; X is a pnictide selected from the group consisting of phosphorus, arsenic, antimony, and mixtures thereof, and Y is a chalcogenide selected from the group consisting of sulfur, selenium and mixtures thereof, have been discovered to be superior lubricants exhibiting resistance to oxidation and thermal degradation, low friction, excellent antiwear activity and long effective life. Metal surfaces coated with such materials resist gauling and damage due to adhesive or corrosive wear. These materials can be used as dry solid lubricants or as additives to oils and greases.
    Type: Grant
    Filed: March 30, 1978
    Date of Patent: December 19, 1978
    Assignee: Exxon Research & Engineering Co.
    Inventors: John M. Longo, John J. Steger
  • Machining fluid
    Patent number: 4130493
    Abstract: A machining fluid includes a basic component in the form of an aqueous solution and an aliphatic acid organic compound which is produced by a fermentation process comprising cultivating a microorganism in a culture medium containing a saccharide, nitrogen source and an inorganic salt and accumulated in a culture broth and separated and recovered from the culture broth.
    Type: Grant
    Filed: July 19, 1977
    Date of Patent: December 19, 1978
    Assignee: Inoue-Japax Research Incorporated
    Inventor: Kiyoshi Inoue
  • Synthetic lubricant composition
    Patent number: 4130494
    Abstract: Synthetic lubricating oil compositions comprising a unique combination of additives. A variety of esters known in the prior art to be useful in synthetic lubricating compositions for aircraft engines may be used in the compositions of this invention. Esters derived from neopentyl polyols are, however, preferred and best results are obtained when the esters are derived from a mixture of such polyols. The additive combination comprises, essentially, an oil-soluble organic amine salt of a phosphate ester and a neutral oil-soluble organosulfonic acid ammonium salt. The additive combination is particularly effective in increasing the load carrying ability of lubricating oils, which especially is critical in applications such as turbine engines.
    Type: Grant
    Filed: February 6, 1978
    Date of Patent: December 19, 1978
    Assignee: Exxon Research & Engineering Co.
    Inventors: Harold Shaub, Stephen J. Metro
  • Demulsifier additive compositions for lubricants and fuels and concentrates containing the same
    Patent number: 4129508
    Abstract: Lubricant and fuel compositions characterized by improved demulsifying properties are disclosed, which properties are contributed substantially by an additive comprising a mixture of:(A) One or more reaction products of a hydrocarbon-substituted succinic acid or anhydride with one or more polyalkylene glycols or monoethers thereof,(B) One or more organic basic metal salts, and(C) one or more alkoxylated amines.
    Type: Grant
    Filed: April 24, 1978
    Date of Patent: December 12, 1978
    Assignee: The Lubrizol Corporation
    Inventor: Edward J. Friihauf
  • Lubricating greases
    Patent number: 4129512
    Abstract: The polyurea thickener of a polyurea grease is prepared from:(a) a mixture of aliphatic and aromatic monoamines(b) one or more aromatic di-isocyanates(c) a diamine which is 4,17-dioxaeicosandiamine-1,20 and which has the formulaH.sub.2 N--(CH.sub.2).sub.3 --O--(CH.sub.2).sub.12 --O--(CH.sub.2).sub.3 --NH.sub.
    Type: Grant
    Filed: February 8, 1978
    Date of Patent: December 12, 1978
    Assignee: The British Petroleum Company Limited
    Inventors: Alexander W. Kisselow, Peter K. Wulk
  • Overbased phenoxide-halo carboxylic acid condensate additives for lubricants
    Patent number: 4128488
    Abstract: Compositions made by reacting (I) a metal phenoxide substituted with at least one hydrocarbon-based group of at least about 30 carbon atoms with (II) a carboxylic acid reagent containing from one to three carboxyl-based groups and a halogen-substituted hydrocarbon-based aliphatic or alicyclic group containing a halogen atom are useful as additives for lubricants and normally liquid fuels. Analogous thiophenoxide-based compositions are similarly useful. These compositions are also useful as intermediates for the preparation of other useful additive compositions through their reaction with alcohols, amino compounds, reactive small ring heterocycles and basically reacting metal compounds.
    Type: Grant
    Filed: December 5, 1977
    Date of Patent: December 5, 1978
    Assignee: The Lubrizol Corporation
    Inventor: Thoams F. Steckel
  • Lubricant for high temperature nuclear service
    Patent number: 4128486
    Abstract: Finely divided B.sup.11 N particles dispersed in a carrier form as anti-gall, anti-seize lubricants in high temperature situations where neutron radiation is present.Suitable carrier materials comprise volatile solvents, B.sup.11 carborane polysiloxanes, polyphenyl siloxanes, polyphenyl ethers and dimethyl polyalkylene ether copolymers of methylphenyl siloxanes.
    Type: Grant
    Filed: January 27, 1977
    Date of Patent: December 5, 1978
    Assignee: Combustion Engineering, Inc.
    Inventors: David N. Palmer, John E. Davison
  • Stabilization of sodium/potassium silicate-containing coating bath
    Patent number: 4128487
    Abstract: A coating bath containing sodium and/or potassium silicate is stabilized and its useful life prolonged by the additions of sodium or potassium hydroxide in amounts at least substantially equal to that required to compensate for the amounts of CO.sub.2 or CO.sub.3 anions introduced into the bath which, in reacting with the hydroxide formed by the hydrolysis of the silicate to form carbonates, upsets the hydrolysis equilibrium leading to further hydrolysis of the silicate. Similarly, a quantity of hydroxide is added to compensate substantially for other reactive species which significantly affect the hydrolysis equilibrium of the silicate.
    Type: Grant
    Filed: January 9, 1978
    Date of Patent: December 5, 1978
    Assignee: Carpenter Technology Corporation
    Inventor: William L. Karpen
  • Lubricant compositions
    Patent number: 4125472
    Abstract: Lubricant compositions are provided which contain: oleaginous media, and an antiwear improving amount of a product formed by reacting (a) a compound having the formula: ##STR1## where R' is a substantially unbranched paraffinic alkyl group containing from about 10 to about 36 carbon atoms, and R is a hydrocarbyl group containing from 1 to about 4 carbon atoms with at least one hydrogen atom present on the carbon atom which is bonded to the oxygen; with (b) a substituted imidazoline of the formula: ##STR2## where one of the R.sup.2 and R.sup.3 substituents must be a substantially unbranched paraffinic or olefinic hydrocarbyl group containing from about 12 to about 35 carbon atoms; and the other R.sup.2 or R.sup.
    Type: Grant
    Filed: December 12, 1977
    Date of Patent: November 14, 1978
    Assignee: Mobil Oil Corporation
    Inventor: Milton Braid
  • Sulfurized oil
    Patent number: 4125471
    Abstract: A stable free sulfur containing mineral oil is produced in a two-step process. The first step of the process comprises producing a sulfurized solubilizing oil by reacting a lubricant oil with elemental sulfur until the uncombined sulfur content is less than about 0.5%. The second step comprising dissolving in the oil a quantity of sulfur such that the final concentration of uncombined sulfur is less than 2.0%.
    Type: Grant
    Filed: August 3, 1977
    Date of Patent: November 14, 1978
    Assignee: Standard Oil Company a corporation of Indiana
    Inventors: Paul C. Vienna, Marvin J. Den Herder, Alex Zletz
  • Process for preparing over-based sulfurized alkaline earth metal phenates
    Patent number: 4123371
    Abstract: A process for producing over-based sulfurized alkaline earth metal phenates useful as lubricating oil or fuel oil additives comprising reacting a phenol, sulfur, a dihydric alcohol and an alkaline earth metal oxide or hydroxide with about 0.99 to about 0.001 gram equivalents per phenolic hydroxyl group, and reacting the reaction product with carbon dioxide at a temperature of about 50.degree. to about 230.degree. C.
    Type: Grant
    Filed: December 21, 1977
    Date of Patent: October 31, 1978
    Assignee: Maruzen Oil Co., Ltd.
    Inventors: Takashi Hori, Suetou Hayashida
  • Lubricating oil composition
    Patent number: 4123369
    Abstract: An extended service crankcase lubricating oil composition comprising a base oil and an additive package including a combination of alkaline earth metal sulfonate and alkaline earth metal phosphonate-phenate sulfide. This combination provides enhanced rust inhibition.
    Type: Grant
    Filed: December 1, 1976
    Date of Patent: October 31, 1978
    Assignee: Continental Oil Company
    Inventors: Edsel L. Miller, Robert A. Krenowicz
  • Preparation and use of basic metal salt compositions of phosphorus-containing acids
    Patent number: 4123370
    Abstract: Reaction mixtures comprising components (A) Group II metal salts of phosphorus-containing acids, (B) basically reacting alkali metal compounds, and (C) optionally, di- or trivalent metal-containing salts are suitable for the preparation of basic metal salt compositions of phosphorus-containing acids, with the proviso that components (A), (B), and (C) are not the same. The basic metal salt compositions are useful in the preparation of lubricants.
    Type: Grant
    Filed: March 20, 1978
    Date of Patent: October 31, 1978
    Assignee: The Lubrizol Corporation
    Inventor: Norman A. Meinhardt
  • Alkaline earth metal salt dispersions in acrylic polymers
    Patent number: 4123368
    Abstract: This invention relates to colloidal dispersions of an alkaline earth metal salt in an oil-soluble acrylic polymer which is polymerized from a monomer system of at least one alkyl or hetero-substituted alkyl ester of an acrylic monomer selected from the group consisting of methacrylates and acrylates represented by the formula: ##STR1## wherein R.sup.1 is a --CH.sub.3 or --H radical, and R.sup.2 is selected from the group consisting of C.sub.1-30 alkyl and hetero-substituted alkyl radicals. This invention also relates to colloidal dispersions as described hereinabove wherein the monomer system further includes at least one non-acrylic polymerizable ethylenically unsaturated nitrogen-containing compound. Preferred polymerizable ethylenically unsaturated nitrogen-containing compounds are those selected from the group consisting of 2- and 4-vinylpyridines and N-vinyl-2-pyrrolidinones.
    Type: Grant
    Filed: March 24, 1977
    Date of Patent: October 31, 1978
    Assignee: Rohm and Haas Company
    Inventors: Norman A. Leister, Andrew Neuman
  • Method for preparing clay-based grease compositions
    Patent number: 4122022
    Abstract: An improved method for preparing clay-based grease compositions is described whereby a clay containing pre-grease is prepared and a water phase separated from the clay-bearing pre-grease prior to the addition of an epoxide which is cured, e.g., simultaneously with the dehydration of the pre-grease. The grease compositions prepared in this manner show improved water resistance over those wherein the epoxide is added prior to separation of the water phase and the grease is also more responsive to the addition of conventional grease additives such as extreme pressure additives, anti-corrosion additives and anti-oxidants.
    Type: Grant
    Filed: July 14, 1977
    Date of Patent: October 24, 1978
    Assignee: Shell Internationale Research Maatschap IIJ B.V.
    Inventors: Kenneth A. MacKenzie, Abraham Verhoeff
  • Antioxidant stabilized lubricating oils
    Patent number: 4122021
    Abstract: This invention is directed to a synergistic antioxidant system for use in oils comprising a phenylated naphthylamine, a sulfoxide compound, and, optionally, an oligodynamic amount of copper.
    Type: Grant
    Filed: May 16, 1977
    Date of Patent: October 24, 1978
    Assignee: Uniroyal, Inc.
    Inventors: Frederick Charles Loveless, Walter Nudenberg
  • Reaction product of nickel thiobis(alkylphenolate) and thiobis(alkylphenol) and organic compositions containing the same
    Patent number: 4119548
    Abstract: Nickel (II) thiobis(alkylphenolate) complex with thiobis(alkylphenol) forms novel complexes having improved antioxidant properties which are useful in a wide range of organic media such as lubricants and plastics. These novel complexes also provide energy quenching characteristics to such organic compositions.
    Type: Grant
    Filed: October 28, 1977
    Date of Patent: October 10, 1978
    Assignee: Mobil Oil Corporation
    Inventor: Milton Braid
  • Sulfurized compositions
    Patent number: 4119549
    Abstract: Sulfurized compositions are prepared by the reaction of unsaturated compounds and a mixture of sulfur and hydrogen sulfide under superatmospheric pressure and in the presence of a catalyst, followed by removal of low boiling materials. They are useful as lubricant additives.
    Type: Grant
    Filed: July 11, 1977
    Date of Patent: October 10, 1978
    Assignee: The Lubrizol Corporation
    Inventor: Kirk Emerson Davis