Abstract: A gas stream comprising LPG and naphtha hydrocarbons is absorbed with a sponge absorbent to recover LPG and naphtha hydrocarbons. The gas stream may comprise stripper off gas and/or PSA tail gas. An absorbent stream may be a stripped stream. The stripper off gas stream and the stripped stream may be obtained from a stripper that is downstream of a hydroprocessing unit.
Abstract: Process scheme configurations are disclosed that enable conversion of crude oil feeds with several processing units in an integrated manner into petrochemicals. The designs utilize minimum capital expenditures to prepare suitable feedstocks for the steam cracker complex. The integrated process for converting crude oil to petrochemical products including olefins and aromatics, and fuel products, includes mixed feed steam cracking, fluid catalytic cracking and conversion of naphtha to chemical rich reformate. Feeds to the mixed feed steam cracker include light products from hydroprocessing zones within the battery limits, recycle streams from the C3 and C4 olefins recovery steps, and raffinate from a pyrolysis gasoline and FCC naphtha aromatics extraction zone within the battery limits. Chemical reformate from straight run naphtha streams is used as an additional feed to the aromatics extraction zone and or the mixed feed steam cracker.
Type:
Grant
Filed:
November 17, 2017
Date of Patent:
December 22, 2020
Assignee:
Saudi Arabian Oil Company
Inventors:
Mohammed Saeed Al-Ghamdi, Bader BaHammam, Naif Al Osaimi, Sami Barnawi
Abstract: Methods for operating a system having two downflow high-severity FCC units for producing products from a hydrocarbon feed includes introducing the hydrocarbon feed to a feed separator and separating it into a lesser boiling point fraction and a greater boiling point fraction. The greater boiling point fraction is passed to the first FCC unit and cracked in the presence of a first catalyst at 500° C. to 700° C. to produce a first cracking reaction product and a spent first catalyst. The lesser boiling point fraction is passed to the second FCC unit and cracked in the presence of a second catalyst at 500° C. to 700° C. to produce a second cracking reaction product and a spent second catalyst. At least a portion of the spent first catalyst or the spent second catalyst is passed back to the first FCC unit, the second FCC unit or both.
Type:
Grant
Filed:
April 4, 2018
Date of Patent:
December 22, 2020
Assignee:
Saudi Arabian Oil Company
Inventors:
Sameer A. Al-Ghamdi, Saad Al-Bogami, Abdennour Bourane
Abstract: A fluid catalytic cracking (FCC) unit for the production of hydrocarbon products includes a fluid injection system coupled to a reactor by a standpipe. The fluid injection system includes a plurality of nozzles for injecting oil feedstock into the standpipe to react with a catalyst flowing therethrough.
Abstract: An improved contactor/separator process is presented where one or more stages of contact and separation is achieved by providing one or more shroud and disengagement device combinations within a vessel, where the disengagement device is connected to the top of the shroud that contains vertically hanging fibers. A liquid admixture of immiscible fluids is directed co-currently upward through the shroud at flooding velocity or greater, where all of the admixture exits the disengagement device through a coalescing material. Tray supports are used to stack additional shroud and disengagement combinations vertically within the vessel. Each tray allows less dense liquids exiting one disengagement device from a lower shroud and disengagement device combination to enter the bottom of a shroud of a shroud and disengagement device combination position vertically above the lower shroud and disengagement device combination.
Type:
Grant
Filed:
March 20, 2020
Date of Patent:
December 8, 2020
Assignee:
MERICHEM COMPANY
Inventors:
James F. McGehee, Jeffrey B. Gomach, Baisheng Zou
Abstract: Optimized, heat-integrated methods and systems are provided to produce multiple, high-value products from oil shale, while minimizing overall energy and water usage. A method for producing multiple products from oil shale comprises: feeding raw oil shale into a heated retorting unit, to convert kerogen into a retorted stream; introducing the retorted stream to a distillation column to generate a high-cetane diesel stream, an ?-olefin-containing chemical stream, an asphalt/asphalt additive stream, and an overhead gas stream, wherein heat contained in the retorted stream is harnessed as distillation energy; separating the overhead gas stream into a fuel gas stream and a purge gas stream; combusting the fuel gas stream to generate hot flue gas; heating the purge gas with hot flue gas; feeding the heated purge gas directly to the heated retorting unit; and recovering the high-cetane diesel stream, the ?-olefin-containing chemical stream, and the asphalt/asphalt additive stream as products.
Abstract: Processes for the production of a gasoline blend. A C7 portion of a naphtha stream is first isomerized to increase the branched, iso-paraffins, and then, the isomerized effluent is passed to a dehydrogenation reaction zone. In the dehydrogenation zone, the C7 saturated hydrocarbons are convert to C7 olefins. The C7 olefins have a higher octane number than the C7 saturated hydrocarbons, and the branched olefins have a higher octane number than the normal olefins. The C7 olefins can be blended in a gasoline pool. C5 and C6 hydrocarbons can be isomerized and dehydrogenated as well, separately or with the C7 components.
Type:
Grant
Filed:
June 27, 2019
Date of Patent:
December 1, 2020
Assignee:
UOP LLC
Inventors:
Mark P. Lapinski, Rajeswar Gattupalli, Bryan K. Glover, Mohamed Shakur, Keith A. Couch, Michael W. Penninger, Soumendra Mohan Banerjee, Deepak Bisht, Gautam Pandey, Amit Sharma, Priyesh Jayendrakumar Jani, Nishesh Garg
Abstract: A method and a device for preparing a vanadium-containing combustible in a de-asphalting device. In this way, a vanadium-containing combustible is supplied to a de-asphalting unit via a supply line in a de-asphalting device, wherein the vanadium-containing combustible supplied into the de-asphalting unit forms a first mass flow and a substantially de-asphalted combustible is discharged from the de-asphalting unit via a discharge line. A bypass line is connected to the supply line, wherein, via the bypass line, a second mass flow of the vanadium-containing combustible is directed past the de-asphalting unit in parallel to the first mass flow and supplied to the discharge line, such that a combined mass flow is formed in the discharge line.
Type:
Grant
Filed:
June 28, 2017
Date of Patent:
November 17, 2020
Assignee:
Siemens Aktiengesellschaft
Inventors:
Markus Kinzl, Ansgar Kursawe, Sebastian Löw
Abstract: A multi-stage process for the production of an ISO8217 compliant Product Heavy Marine Fuel Oil from ISO 8217 compliant Feedstock Heavy Marine Fuel Oil involving a core process under reactive conditions in a Reaction System composed of one or more reaction vessels, wherein one or more of the reaction vessels contains one or more catalysts in the form of a structured catalyst bed and is operated under reactive distillation conditions. The Product Heavy Marine Fuel Oil has a sulfur level has a maximum sulfur content (ISO 14596 or ISO 8754) between the range of 0.05 mass % to 1.0 mass. A process plant for conducting the process for conducting the process is disclosed.
Type:
Grant
Filed:
August 14, 2018
Date of Patent:
November 17, 2020
Assignee:
Magēmā Technology LLC
Inventors:
Michael Joseph Moore, Bertrand Ray Klussmann, Carter James White
Abstract: A system for co-processing crude oil with residuum includes an ebullated bed hydrocracking unit; an atmospheric distillation column fluidly coupled to the ebullated bed hydrocracking unit; a vacuum distillation column fluidly coupled to the atmospheric distillation column and the ebullated bed hydrocracking unit; and a deasphalting unit fluidly coupled to the vacuum distillation column and the ebullated bed hydrocracking unit; and a control system communicably coupled to the ebullated bed hydrocracking unit, the atmospheric distillation column, the vacuum distillation column, and the deasphalting unit. The control system is configured to perform operations including operating the deasphalting unit to produce a first cut that includes deasphalting oil, a second cut that includes resin oil, and a third cut that includes asphaltene.
Type:
Grant
Filed:
June 15, 2018
Date of Patent:
November 17, 2020
Assignee:
Saudi Arabian Oil Company
Inventors:
Mohammed A. Al-Wohaibi, Vinod Ramaseshan, Marcus J. Killingworth, Hisham T. Al-Bassam
Abstract: A process and apparatus for hydrocracking a hydrocarbon stream strips a liquid hydrocracked stream in a reboiled stripping column to provide a stripping overhead stream and a stripped stream and a vaporized stripping overhead stream has LPG hydrocarbons absorbed from it with an absorbent stream comprising the stripped stream. No equipment is needed to remove water from the absorbent stream due to the lack of steam added during stripping with a reboil column.
Abstract: A process and apparatus for hydrocracking a hydrocarbon stream that feeds a cold stripped stream and a hot stripped stream to a prefractionator from which a prefractionated overhead stream and a prefractionated bottoms stream are passed to a product fractionation column. The product fractionation column may produce three products, light naphtha, heavy naphtha and distillate omitting the need for a naphtha splitter column.
Abstract: The present disclosure discloses an integrated device for millisecond-level gas phase catalytic cracking reaction and separation, comprising: a horizontal inertial cyclone separator, a horizontal inertial cyclone separator feed tube, a pyrolysis vapour inlet, a regenerated catalyst inlet, a horizontal inertial cyclone separator central tube, a cracked vapour outlet, a catalyst outlet tube, a spent catalyst silo, a first loop-seal, a riser regenerator, a settling tank, a gas-solid separator, and a second loop-seal.
Type:
Grant
Filed:
November 1, 2019
Date of Patent:
November 3, 2020
Assignee:
CHINA UNIVERSITY OF PETROLEUM (EAST CHINA)
Abstract: A process and apparatus for hydrocracking a hydrocarbon stream that feeds a cold stripped stream and a hot stripped stream to a product fractionation column which may be reboiled. The product fractionation bottoms stream is passed to a heavy fractionation column that may be steam stripped and may be under vacuum.
Type:
Grant
Filed:
June 26, 2018
Date of Patent:
November 3, 2020
Assignee:
UOP LLC
Inventors:
Donald A. Eizenga, Hari S. Bajpai, Richard K. Hoehn
Abstract: A crude oil refinery pre-heat train (PHT) includes a crude oil stream pipeline system that extends through the PHT and is configured to carry a stream of crude oil from an inlet of the PHT to a furnace of the PHT; heat exchangers positioned in the crude oil stream pipeline system; and a control system. The heat exchangers include a first set of heat exchangers positioned in the crude oil stream pipeline system between the inlet of the PHT and one or more de-salters of the PHT; a second set of heat exchangers positioned in the crude oil stream pipeline system between the one or more de-salters of the PHT and one or more pre-flash drums of the PHT; and a third set of heat exchangers positioned between the one or more pre-flash drums of the PHT and the furnace of the PHT.
Abstract: The delayed coking method includes directing a heated secondary feedstock, which contains heated primary feedstock and recirculate, from a reaction furnace to a coking chamber. Vapor-liquid coking products formed in the coking chamber are then directed to a fractionation column, which fractionates hydrocarbon gas, gasoline, light and heavy gas oils, and bottom residues. Heavy gas oil from the fractionation column is directed to a thermal cracking furnace, the products of which are cooled by cooled light gas oil and directed to an evaporator for separation. In the evaporator, gases and light boiling products are removed by evaporation and returned to the fractionation column, and the remaining distillate cracking residue is separated and used as a component of the recirculate, along with bottom residues from the fractionation column. The resulting process produces high quality and high yield needle and anode cokes.
Abstract: This development proposed adding a catalyst to an oxygen stripper. The oxygen stripper would be run at a temperature just below or at coking temp. The oxygen stripper includes a catalyst containing Group VI or VII metals to remove free radicals. Most preferably, the catalyst is a nickel-molybdenum catalyst.
Abstract: A paraffin control unit with staged high voltage temperature controlled electric immersion heaters to maintain the paraffin component of the crude oil in the liquid phase. The paraffin control unit removes large volumes of naturally occurring fine sand from the incoming liquids while also removing the crude oil from the influent fluid stream, the natural gas from the influent fluid stream, salt water from the influent fluid stream, all while maintaining the temperature of the crude oil fraction above the cloud point of its paraffin constituent. The removed sand is collected in sand pans and is automatically removed at timed intervals. The automation assures that the accumulating sand is removed from the sand pans as rapidly as it accumulates, thus preventing an over-accumulation of sand. The process fluids flow through a coalescer and a baffle assembly which purify and separate the component phases suitable for custody transfer.
Abstract: Provided are embodiments that include a hydrocarbon fluid processing system including an ultrasonic hydrocarbon degassing unit including a vapor recovery vessel adapted to direct flow of a hydrocarbon fluid mixture along a flowpath extending through an interior of the vapor recovery vessel, and an ultrasonic transducer system disposed inside the vapor recovery vessel and in the flowpath of the hydrocarbon fluid mixture. The hydrocarbon fluid mixture including a hydrocarbon liquid and a gas entrained in the hydrocarbon liquid, the ultrasonic transducer system adapted to transmit ultrasonic signals into the hydrocarbon fluid mixture along the flowpath, and the ultrasonic signals adapted to separate the gas from the hydrocarbon liquid.
Abstract: A process and apparatus for catalytically cracking fresh heavy hydrocarbon feed to produce cracked products is disclosed. A fraction of the cracked products can be obtained to re-crack it in a downer reactor. The downer reactor may produce high selectivity to light olefins. Spent catalyst from both reactors can be regenerated in the same regenerator.