Abstract: A method for manufacturing a steel plate provided with a layered structure. A method for manufacturing a steel plate includes: i) providing a high carbon steel plate; ii) homogenizing the high carbon steel plate; iii) transforming the high carbon steel plate into an austenitic phase by heating the high carbon steel plate; iv) contacting the high carbon steel plate with an oxidization gas and converting the high carbon steel plate into a steel plate comprising surface layers that are spaced apart from each other and are decarburized to be transformed into a ferritic phase, and a center layer that is located between the surface layers and is not decarburized; and v) cooling the high carbon steel plate and transforming the center layer into a martensitic phase.

Abstract: An acidic chromium-free solution for treating a metal surface containing: a vanadium cation source and/or a vanadyl cation source; an organic acid as an anion source; and at least one oxoacid as another anion source is provided. The oxoacid is selected from oxoacids of nitrogen, sulfur, phosphorus, boron, and chlorine. A metal component composed of, for example, aluminum or magnesium is brought into contact with the chromium-free solution to form a vanadium coating film of a surface of the metal component. A surface treating process using this chromium-free solution is useful for formation of a coating film having low corrosion resistance and low electric resistance.

Abstract: Method for manufacturing a zinc-coated nonferrous metal component for the production of a corrosion-protected vehicle body in a mixed construction includes providing an untreated nonferrous metal component and applying a coating by zinc diffusion onto the nonferrous metal component. A zinc dust mixture is diffused at a temperature of from 300 to 600° C. so as to form a zinc diffusion layer.

Abstract: The invention relates to an aqueous composition and to a method for the anticorrosion conversion treatment of metallic surfaces, particularly metallic materials which are assembled into composite structures, comprising steel or galvanized or alloy-galvanized steel and any combinations thereof, the composite structure being composed at least in part of aluminum or the alloys thereof. The aqueous composition according to the invention is based on a phosphating solution and contains, in addition to water-soluble compounds of zirconium and titanium, a quantity of free fluoride in a ratio that both permits phosphating of the steel and galvanized and/or alloy-galvanized steel surfaces and determines low pickling rates of the aluminum substrate with simultaneous passivation of the aluminum.

Abstract: Disclosed are replenisher compositions and methods of replenishing pretreatment compositions. The methods include adding a replenisher composition to a pretreatment composition wherein the replenisher composition includes: (a) a dissolved complex metal fluoride ion wherein the metal ion comprises a Group IIIA metal, Group IVA metal, Group IVB metal, or combinations thereof; (b) a component comprising an oxide, hydroxide, or carbonate of Group IIIA, Group IVA, Group IVB metals, or combinations thereof; and optionally (c) a dissolved metal ion comprising a Group IB metal, Group IIB metal, Group VIIB metal, Group VIII metal, Lanthanide Series metal, or combinations thereof.

Abstract: A method of ultra-fast boriding of a metal surface. The method includes the step of providing a metal component, providing a molten electrolyte having boron components therein, providing an electrochemical boriding system including an induction furnace, operating the induction furnace to establish a high temperature for the molten electrolyte, and boriding the metal surface to achieve a boride layer on the metal surface.

Abstract: The object of this present invention is to provide novel means for inhibiting elution of hexavalent chromium from a chemical conversion coating. A composition for chemical conversion treatment comprises at least 0.1 g/L of a polyphenol and at least 1.5 g/L in chromium ion equivalent of an aqueous trivalent chromium compound and has a pH of 6 or less. A chemical conversion coating formed on a metallic surface of a member by contacting the surface with the composition for chemical conversion treatment has a hexavalent chromium content of 0.04 ?g/cm2 or less after exposure to an environment having a temperature of 80 degrees C. and a relative humidity of 100% for 120 hours. The content of hexavalent chromium is measured by a method compliant with EN15205. A composition containing at least 0.1 g/L of a polyphenol can be used as a composition for post-coating treatment of a chemical conversion coating obtained by conventional chemical conversion treatment.

Abstract: A metal surface treatment method for a metal base material in order to improve the uniformity of a cathodic electrodeposition coating film, the method including: a surface treatment step for forming a chemical conversion film on a metal base material by contacting the metal base material with a metal surface treatment composition including zirconium and/or titanium ions and an adhesive imparting agent characterized in being at least one selected from the group consisting of (A) silicon-containing compound, (B) adhesive imparting metal ion, and (C) adhesive imparting resin; and a heating/drying step to heat and dry the metal base material, on which the chemical conversion film is formed, at 60° C. to 190° C. for at least 30 seconds.

Abstract: A slurry and slurry coating process for forming a diffusion aluminide coating on a substrate, including internal surfaces within the substrate. The process involves preparing a slurry of a powder containing a metallic aluminum alloy having a melting temperature higher than aluminum, an activator capable of forming a reactive halide vapor with the metallic aluminum, and a binder containing an organic polymer. The slurry is applied to surfaces of the substrate, which is then heated to burn off the binder, vaporize and react the activator with the metallic aluminum to form the halide vapor, react the halide vapor at the substrate surfaces to deposit aluminum on the surfaces, and diffuse the deposited aluminum into the surfaces to form a diffusion aluminide coating. The process can be tailored to selectively produce an inward or outward-type coating. The binder burns off to form an ash residue that can be readily removed.

Abstract: An alloy casting having a protective layer disposed on a surface of the casting is provided. The protective layer is resistant to liquid metal attack, and wherein the protective layer includes an oxide of an element present in the alloy. A method of forming a protective layer on a surface of the alloy casting is also provided. The method includes disposing the alloy in a mold, and oxidizing an element of the alloy to form a protective layer on the surface of the casting.

Abstract: A container for molten metal has at least one opening in which a refractory nozzle brick is mounted. A refractory purge plug or a refractory sleeve defining an outlet opening is inserted in the nozzle brick opening. A defined gap is formed between the nozzle brick opening and the purge plug or the sleeve and is filled with a refractory mass, this mass consisting of a material which can be easily bored or milled out of the mass for the purpose of replacing the purge plug or the sleeve. In this manner, laborious cleaning steps can be avoided and the nozzle brick no longer risks being damaged.

Abstract: A surface treatment method of a magnesium alloy article includes, instead of forming a primer on a magnesium alloy based composite first, directly performing a hairline finish process on the magnesium alloy based composite, to form a hairline structure on a surface of the magnesium alloy based composite, and performing a chemical oxidation process on the magnesium alloy based composite, to form a glossy film covering the hairline structure on the magnesium alloy based composite, thereby forming a magnesium alloy article structure. Alternatively, another chemical oxidation process is performed before the hairline finish process, to form an oxide film on the surface of the magnesium alloy based composite.

Abstract: An improved flue gas cooler 10, or bank of coolers 10, handles flue gas G from aluminum reduction cells in an aluminum smelter plant. Each flue gas cooler 10 has a gas inlet chamber 14, a gas outlet chamber 16, and a matrix of gas cooling tubes 18 extending between the inlet chamber and the outlet chamber. Each cooling tube 18 has a bell-shaped inlet end 19 comprising an aerodynamically curved gas-accelerating profile effective to facilitate streamlined flow of flue gas G into the tube. The improved flue gas cooler makes it possible to connect the flue gas cooler to receive flue gas G direct from the aluminum reduction cells without getting clogged by dust and sublimates present in the flue gas.

Abstract: A method for coating a metal substrate with a white to off-white or gray colored autodeposited coating comprising water, polymeric resin, HF and pigment particles comprising a core of titanium dioxide, an intermediate zirconia and/or alumina layer, and an outer organic layer, optionally the particles are treated with an anionic surfactant.

Abstract: A tinned steel sheet includes an Sn-containing plating layer disposed on at least one surface of a steel sheet and in which mass per unit area of Sn is 0.05 to 20 g/m2; a first chemical conversion coating disposed on the Sn-containing plating layer and contains P and Sn, and in which mass per unit area of P is 0.3 to 10 mg/m2; a second chemical conversion coating disposed on the first chemical conversion coating and contains P and Al, and in which mass per unit area of P is 1.2 to 10 mg/m2 and mass per unit area of Al is 0.24 to 8.7 mg/m2; and a silane coupling agent-treating layer formed with the silane coupling agent disposed on the second chemical conversion coating and has a mass per unit area of Si of 0.10 to 100 mg/m2.

Abstract: The present invention relates to a method for diffusion treatment of a coating on an engineering part resistant to marine climate, comprising: Step 1. pretreating the part; Step 2. preheating the part in a protective atmosphere furnace; Step 3. immersing the pre-heated part in a plating solution in a way that the part is rotated in the submerging process; Step 4. carrying out diffusion treatment, i.e., placing the immersion-plated part into a vacuum furnace, maintaining at 800 to 950° C. for 1 to 3 hours, and then cooling it down prior to discharge, such that atoms at an interface are diffused to form a diffusion layer on a substrate, achieving metallurgical bonding between the coating and the substrate. Treatment by the method of the present invention enables the part to have full resistance to corrosion and scouring erosion under marine climate.

Abstract: The invention relates to a method and coating agents used in the method which provide good adherence to and good corrosion protection of metal substrates; the coating coating agents are cross-linkable via radical polymerization. Adhesion promoting compounds are present in the conversion layer in a quantity of about 0.01 to 40 weight percent and contain, on average, one reactive unsaturated group and at least one H-active group per molecule.

Abstract: One exemplary embodiment includes a process for forming a hard carbide coating onto a low chromium-containing steel article via a chemical deposition process carried out on a particulate mix, in which molybdenum in the form of a compound FeMo or titanium in the form of a compound FeTi, or a mixture of FeMo and FeTi, may be added to the particulate mix used to form the coating.

Abstract: A method of superfinishing a large hollow wheel gear in a vibratory bowl having a center hub comprises at least partially filling the vibratory bowl with an amount of finishing media, laying the gear horizontally into the bowl over the center hub, supplying a quantity of an active chemistry into the bowl and agitating the vibratory bowl at a frequency such that the gear settles into and is fully supported by the media. By controlling the process parameters, the hollow wheel gear may be caused to rotate in the media and can be made to float at a desired level. The method is particularly suitable for hollow wheel gears for large wind turbines.

Abstract: A method of bonding a metal to a substrate involves forming an oxide layer on a surface of the substrate, and in a molten state, over-casting the metal on the substrate surface. The over-casting drives a reaction at an interface between the over-cast metal and the oxide layer to form another oxide. The other oxide binds the metal to the substrate surface upon solidification of the over-cast metal.