Patents Examined by Lois Zheng
  • Patent number: 8702837
    Abstract: The invention relates to a method of integrating a plurality of blast furnaces with a plurality of air gas separation units, in which the replacement blower available on the blast furnace site is used to feed compressed air into an air gas separation unit making it possible to enrich the blast-furnace blast with oxygen, this unit being stopped when one of the blowers of the blast furnaces has to be replaced with the blower used by the air gas separation unit.
    Type: Grant
    Filed: July 19, 2012
    Date of Patent: April 22, 2014
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventors: Michel Devaux, Richard Dubettier-Grenier
  • Patent number: 8696831
    Abstract: Disclosed herein is a chromate-free conversion film solution and a method of applying the solution to magnesium and magnesium alloys. The solution contains zirconium ions, manganese ions, barium ions and phosphate corrosion inhibitor; and the pH of the said solution is in the range of 1-5; and may further comprise molybdate as accelerant. The method comprises degreasing, acid etching, surface activation, surface adjusting, and film forming steps. The conversion film obtained in accordance with the disclosed method is uniform, smooth, and compact and has high corrosion resistance and good adhesion with paint film. Moreover, the chromate-free conversion film solution is environmentally friendly and possesses fast film growth rates.
    Type: Grant
    Filed: July 8, 2010
    Date of Patent: April 15, 2014
    Assignee: Institute of Metal Research Chinese Academy of Sciences
    Inventors: Dayong Shan, Yingwei Song, Enhou Han, Rongshi Chen, Wei Ke
  • Patent number: 8691028
    Abstract: A method for protecting a surface of an article includes preparing or otherwise providing a reactive solution of a form of polyaniline and an acid, thereafter applying the reactive solution to the surface of the article to form an adherent conversion coating on the surface, thereafter oxidizing the adherent conversion coating to form an oxidized coating, and thereafter contacting a chromate-free, corrosion inhibiting organic compound such as a salt of a dithiocarbamate or a salt of a dimercaptothiadiazole to the oxidized coating to form a fixed conversion coating on the surface of the article. The resulting article has the fixed conversion coating adhered to the surface of the article. The fixed conversion coating has a mixture of a reduced polyaniline salt, and a fixed disulfur-linked dithiocarbamate polymer or dimer.
    Type: Grant
    Filed: May 10, 2006
    Date of Patent: April 8, 2014
    Assignee: The Boeing Company
    Inventors: Martin W. Kendig, Melitta M. Hon, Leslie F. Warren, Jr.
  • Patent number: 8673091
    Abstract: Disclosed are methods for treating metal substrates, including ferrous substrates, such as cold rolled steel and electrogalvanized steel. The methods include contacting the substrate with a pretreatment composition that includes: (a) a group IIIB and/or IVB metal; (b) free fluorine; (c) a metal fluoride salt formed from a metal which forms a fluoride salt having a pKsp of at least 11; and (d) water.
    Type: Grant
    Filed: August 3, 2007
    Date of Patent: March 18, 2014
    Assignee: PPG Industries Ohio, Inc
    Inventors: Mark W. McMillen, Edward F. Rakiewicz
  • Patent number: 8652270
    Abstract: Disclosed are methods for treating and coating a ferrous metal substrate, such as cold rolled steel, hot rolled steel, and electrogalvanized steel. These methods include contacting the ferrous metal substrate with an aqueous pretreatment composition comprising: (a) a Group IIIB and/or IVB metal compound; (b) phosphate ions; and (c) water.
    Type: Grant
    Filed: December 7, 2011
    Date of Patent: February 18, 2014
    Assignee: PPG Industries Ohio, Inc.
    Inventors: Randall J. Brent, Nicephoros A. Fotinos, John F. McIntyre, David A. Raney, Richard M. Vargas
  • Patent number: 8652271
    Abstract: A bath containing nickel ions and formic acid is injected into a film-forming aqueous solution flowing in a circulation pipe connected to feed water pipe made of carbon steel in a BWR plant. This film-forming aqueous solution is supplied into the feed water pipe through the circulation pipe, and then, a nickel metal film is formed on an inner surface of the feed water pipe. After the nickel metal film is formed, a film-forming aqueous solution containing iron (II) ions, formic acid, nickel ions, hydrogen peroxide, and hydrazine is supplied to the feed water pipe. A nickel ferrite film is formed on the surface of the nickel metal film in the feed water pipe. Then, the nickel ferrite film is come into contact with water containing dissolved-oxygen at 150° C. or above to transform the nickel metal film into a nickel ferrite film. A thick nickel ferrite film is formed on the inner surface of the feed water pipe. Corrosion of the carbon steel member composing the plant can further reduce.
    Type: Grant
    Filed: August 3, 2010
    Date of Patent: February 18, 2014
    Assignee: Hitachi-GE Nuclear Energy, Ltd.
    Inventors: Tsuyoshi Ito, Hideyuki Hosokawa, Yukio Hirama, Motoaki Sakashita, Makoto Nagase
  • Patent number: 8652272
    Abstract: A bath containing nickel ions and formic acid is injected into a film-forming aqueous solution flowing in a circulation pipe connected to a feed water pipe made of carbon steel in a BWR plant. This solution is supplied into the pipe through the circulation pipe, and a nickel metal film is formed on an inner surface of the pipe. After the film is formed, a film-forming aqueous solution containing iron (II) ions, formic acid, nickel ions, hydrogen peroxide, and hydrazine is supplied to the pipe. A nickel ferrite film is formed on the surface of the nickel metal film in the pipe. The nickel ferrite film comes into contact with water containing dissolved oxygen at or above 150° C. to transform the nickel metal film into a nickel ferrite film. A thick nickel ferrite film is formed on the inner surface of the feed water pipe.
    Type: Grant
    Filed: January 22, 2013
    Date of Patent: February 18, 2014
    Assignee: Hitachi-GE Nuclear Energy, Ltd.
    Inventors: Tsuyoshi Ito, Hideyuki Hosokawa, Yukio Hirama, Motoaki Sakashita, Makoto Nagase
  • Patent number: 8641833
    Abstract: An object of the present invention is to provide an R—Fe—B based sintered magnet having on a surface thereof a chemical conversion film with higher corrosion resistance than a conventional chemical conversion film such as a phosphate film, and a method for producing the same. The corrosion-resistant magnet of the present invention as a means for achieving the object is characterized by comprising a chemical conversion film containing at least Zr, Nd, fluorine, and oxygen as constituent elements and not containing phosphorus directly on a surface of an R—Fe—B based sintered magnet, wherein R is a rare-earth element including at least Nd.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: February 4, 2014
    Assignee: Hitachi Metals, Ltd.
    Inventors: Toshinobu Niinae, Koshi Yoshimura, Koji Kamiyama
  • Patent number: 8623153
    Abstract: The present application discloses a method for producing a stable ultra thin metal film that comprises the following steps: a) deposition, on a substrate, of an ultra thin metal film, such as an ultra thin film of nickel, chromium, aluminum, or titanium; b) thermal treatment of the ultra thin metal film, optionally in combination with an O2 treatment; and c) obtaining a protective oxide layer on top of the ultra thin metal film.
    Type: Grant
    Filed: June 10, 2009
    Date of Patent: January 7, 2014
    Assignee: Fundacio Institut de Ciencies Fotoniques
    Inventors: Valerio Pruneri, Luis Martinez Montblanch, Stefano Giurgola, Paolo Vergani
  • Patent number: 8617322
    Abstract: A laminated structure by internal oxidation includes an alloy coating layer structured as columnar grains. The alloy coating layer includes a first metal element and a second metal element, wherein the first metal element is oxidized more easily than the second metal element. The surface layer portion of the alloy coating layer has a plurality of oxide layers and a plurality of metal layers stacked alternately with each other. The material of the oxide layers includes the oxide of the first metal element and the material of the metal layers includes the second metal element.
    Type: Grant
    Filed: November 24, 2010
    Date of Patent: December 31, 2013
    Assignee: National Taiwan Ocean University
    Inventors: Yung-I Chen, Rong-Tan Huang, Bing-Nan Tsai
  • Patent number: 8617321
    Abstract: The present invention provides a surface treatment method for an aluminum alloy and a surface treatment method for a magnesium alloy, which enable providing the surface of an aluminum alloy containing magnesium or the surface of a magnesium alloy with sufficient corrosion resistance to corrosive gases, while preventing the surface from scattering magnesium therefrom even when used in a vacuum at a temperature of not less than 300° C. In this method, a carbon fluoride compound is applied over the surface of the aluminum alloy containing magnesium or the surface of the magnesium alloy, followed by heating in an oxygen atmosphere, thereby forming a fluoride passivation film.
    Type: Grant
    Filed: October 2, 2007
    Date of Patent: December 31, 2013
    Assignees: Ulvac, Inc., Ulvac Techno, Ltd.
    Inventors: Shunji Misawa, Sakae Inayoshi, Hiroshi Sato
  • Patent number: 8608869
    Abstract: A method is disclosed for improving the corrosion behavior of cast magnesium alloy articles in which the magnesium alloy comprises an average composition of more than about 5 per cent by weight of aluminum. A microstructure with regions of varying aluminum content is developed during solidification. The microstructure comprises magnesium-rich grains generally surrounded by an aluminum-enriched phase on the boundaries between adjacent grains. The magnesium-rich grain interiors are then selectively chemically or electrochemically attacked to leave a more corrosion resistant aluminum-enriched surface on the articles. The corrosion resistance of the articles may be further enhanced by one or more of anodizing, aluminizing or painting the corrosion-resistant aluminum-enriched surface.
    Type: Grant
    Filed: December 16, 2010
    Date of Patent: December 17, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Deepika Sachdeva, Arun M. Kumar, Guangling Song
  • Patent number: 8597443
    Abstract: A method of forming an article from an ?-? titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the ?-? titanium alloy.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: December 3, 2013
    Assignee: ATI Properties, Inc.
    Inventors: John J. Hebda, Randall W. Hickman, Ronald A. Graham
  • Patent number: 8597442
    Abstract: A method of forming an article from an ??? titanium including, in weight percentages, from about 2.9 to about 5.0 aluminum, from about 2.0 to about 3.0 vanadium, from about 0.4 to about 2.0 iron, from about 0.2 to about 0.3 oxygen, from about 0.005 to about 0.3 carbon, from about 0.001 to about 0.02 nitrogen, and less than about 0.5 of other elements. The method comprises cold working the ??? titanium alloy.
    Type: Grant
    Filed: September 12, 2011
    Date of Patent: December 3, 2013
    Assignee: ATI Properties, Inc.
    Inventors: John J. Hebda, Randall W. Hickman, Ronald A. Graham
  • Patent number: 8591670
    Abstract: An acidic, aqueous composition contains a trivalent chromium compound, an organo-functional silane, and a compound of a group IV-B element. The composition protects metal surfaces, preferably aluminum and aluminum alloys, against corrosion and improves their paint adhesion. The trivalent chromium compound may comprise chromium fluoride and optionally others, such as chromium nitrate. The organo-functional silane is preferably an aminopropyltriethoxy silane, and the compound of a group IV-B element is preferably fluorozirconic acid. The composition can either be dried-in-place or rinsed before a further coating layer is applied. The composition may also include at least one polymer having a plurality of both carboxylic functional groups, alone or with hydroxyl groups.
    Type: Grant
    Filed: May 7, 2008
    Date of Patent: November 26, 2013
    Assignee: Bulk Chemicals, Inc.
    Inventor: Richard J. Church
  • Patent number: 8591638
    Abstract: A tin or tin alloy plating film surface treatment aqueous solution that can reduce whiskers on the surface of a tin or tin alloy plating film, and can provide a favorable tin or tin alloy plating film using a simple method for tin or tin alloy plating films that are used on electronic components.
    Type: Grant
    Filed: September 22, 2009
    Date of Patent: November 26, 2013
    Assignee: Rohm and Haas Electronic Materials LLC
    Inventor: Yutaka Morii
  • Patent number: 8568522
    Abstract: Process for passivating metallic surfaces, and a preparation suitable for implementing the process, comprising at least water, an acid, and a copolymer of functionalized (meth)acrylic esters, monomers containing phosphoric and/or phosphonic acid groups, monomers having COOH groups, and, if appropriate, further monomers. Copolymer which comprises said monomers.
    Type: Grant
    Filed: July 18, 2007
    Date of Patent: October 29, 2013
    Assignee: BASF SE
    Inventors: Frank Klippel, Alexander Göthlich, Gunnar Schornick, Dietrich Fehringer, Thomas Heidenfelder, Helmut Witteler, Walter Bertkau
  • Patent number: 8544703
    Abstract: The injection chamber (CI) includes a tubular body formed by a supply portion, having a radial supply window to receive a charge of molten metal (MF) and in which is incorporated an injection portion provided with an outlet end opened to the interior of a molding cavity. A piston is provided to be displaced in the interior of the tubular body to inject the molten metal (MF) in the molding cavity. The supply portion has its inner region, which receives the pouring impact of the charge of molten metal (MF), lined by an insert formed in a high melting point material and presenting an inner contour in the form of a circle arc coinciding with that of the supply and injection portions.
    Type: Grant
    Filed: July 14, 2010
    Date of Patent: October 1, 2013
    Assignee: W. Fischer Tecnica Ltda.
    Inventor: Wilmar Fischer
  • Patent number: 8540826
    Abstract: A process for surface treatment of aluminium foils includes steps of applying an etching solution to chemically etch at least one surface of the foil to form an etched surface, and forming an aluminium oxidized coating on the etched surface. The etching solution comprises an aqueous solution which includes hydrogen peroxide as an oxidant and sulfuric, orthophosphoric or nitric acid.
    Type: Grant
    Filed: October 4, 2010
    Date of Patent: September 24, 2013
    Assignee: University of Windsor
    Inventors: Srimanta Ray, Jerald A. D. Lalman
  • Patent number: 8535456
    Abstract: A chemical conversion treatment solution for a steel material is provided. The solution is an acidic aqueous solution of pH 3 to 5 containing 50 to 500 ppm by weight of zirconium fluoride complex in terms of Zr, 5 to 50 ppm by weight of free fluorine, and 5 to 30% by weight in relation to Zr of polyethyleneimine having a weight average molecular weight of 300 to 10,000, a molar ratio of the primary amino group of at least 30%, and a molar ratio of the tertiary amino group of at least 15% in relation to the total amino group content. A method for chemical conversion treatment is also provided. This invention realizes excellent coating adhesion and corrosion resistance after the coating, as well as improved throwing power in the coating, and in particular, in the electrodeposition coating of a steel material.
    Type: Grant
    Filed: January 11, 2011
    Date of Patent: September 17, 2013
    Assignee: Henkel AG & Co. KGaA
    Inventors: Hitoshi Ishii, Yasuhiko Nagashima