Patents Examined by Mark Sweet
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Patent number: 5185392Abstract: A polyarylene sulfide resin composition useful for molded parts comprises (A) 100 parts by weight of a polyarylene sulfide, (B) 0.01 to 10 parts by weight of an organic bisphosphite of the formula: ##STR1## in which R.sub.1 and R.sub.2 are each an alkyl, an alkyl having at least one substituent, an aryl, an aryl having at least one substituent or an alkoxy, (C) 0 to 400 parts by weight of an inorganic filler and (D) 0.01 to 5 parts by weight of at least one alkoxy silane.Type: GrantFiled: December 26, 1990Date of Patent: February 9, 1993Assignee: Polyplastics Co., Inc.Inventors: Toshifumi Nonaka, Toshikatsu Nitoh, Andrew Auerbach
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Patent number: 5185397Abstract: A polymeric emulsion comprising a (i) polymer, (ii) water, and (iii) a surfactant is useful as a binder for a water-based varnish that is resistant to water, 50% ethanol, and alkali. The polymer comprises about 20 to about 40 weight percent of a soft monomer whose homopolymer has a T.sub.g of less than about -20.degree. C. and about 60 to about 80 weight percent of a mixture of hard monomers each of whose homopolymer has a T.sub.g of greater than about 30.degree. C. As part of the hard monomer comonent of the polymer, the polymer comprises about 5 to about 25 weight percent acrylonitrile and about 1 to about 5 weight percent of an olefinic carboxylic acid. Typically, the polymer comprises less than about 1 weight percent surfactant and has a calculated T.sub.g of about 25.degree. to about 60.degree. C., an actual T.sub.g of about 30.degree. to about 70.degree. C., and an average particle size of less than about 250 nm.Type: GrantFiled: August 21, 1989Date of Patent: February 9, 1993Assignee: Rohm and Haas CompanyInventor: John Biale
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Patent number: 5183844Abstract: A composition comprises poly(arylene sulfide), fiberglass, an additive containing an element selected from among the group consisting of alkaline earth metals, magnesium and beryllium; and silica present in an amount sufficient to increase the shear sensitivity of the composition so that the composition does not drool during molding. A method for providing a composition having reduced drool during molding comprises admixing with a composition containing poly(arylene sulfide) and fiberglass an amount of silica sufficient to increase shear sensitivity of the composition so that the composition has reduced drool during molding.Type: GrantFiled: July 2, 1990Date of Patent: February 2, 1993Assignee: Phillips Petroleum CompanyInventor: Van C. Vives
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Patent number: 5180769Abstract: An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95% by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts byw eight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.Type: GrantFiled: March 19, 1992Date of Patent: January 19, 1993Assignee: Sumitomo Chemical Company LimitedInventors: Tadashi Hikasa, Koichiro Ibuki, Tatsuo Hamanaka, Motoo Mizumori
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Patent number: 5179137Abstract: A heat-resistant, high-impact polystyrene composition is disclosed, comprising:(A) 100 parts by weight of high-impact polystyrene,(B) from 1.5 to 5 parts by weight of glass fibers,(C) from 2.5 to 10 parts by weight of a styrene-butadiene-styrene copolymer, and(D) from 0.05 to 5 parts by weight of a metal salt of a higher fatty acid,the high-impact polystyrene (A) having a polybutadiene content of from 4.5 to 8.0% by weight and an average rubber particle diameter of from 0.5 to 2.0 .mu.m and containing no plasticizer;the glass fibers (B) having an average fiber length of from 0.5 to 2 mm and an average aspect ratio of 20 or more and having undergone surface treatment with a silane coupling agent; andthe styrene-butadiene-styrene copolymer (C) having a butadiene unit content of from 40 to 80% by weight.Type: GrantFiled: December 7, 1990Date of Patent: January 12, 1993Assignee: Sumitomo Chemical Co., Ltd.Inventors: Yasushi Okamoto, Tetsuo Uno
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Patent number: 5179145Abstract: The present invention relates to glass filled poly(arylene sulfide) molding compositions which upon being molded result in products having improved mechanical properties. Methods of preparing the compositions, methods of using the compositions to form molded products and the molded products so produced are also provided. The compositions are comprised of poly(arylene sulfide) resin, glass reinforcement material, an epoxysilane and an organic phosphite.Type: GrantFiled: September 27, 1990Date of Patent: January 12, 1993Assignee: Phillips Petroleum CompanyInventor: Roy F. Wright
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Patent number: 5177163Abstract: A tackifier resin is prepared by polymerizing a monomer mixture of 10-70% piperylene concentrate and 30-90% of a vinyl aromatic monomer in the presence of a boron trifluoride catalyst and an inert diluent. The resin is water white in color, has a Gardner number of less than one, a softening point of 60.degree. to 120.degree. C. and a polydispersity of 1 to 5. The tackifier is used in formulations based on EVA, block copolymers and polyolefins for hot melt and pressure sensitive adhesive applications.Type: GrantFiled: June 7, 1991Date of Patent: January 5, 1993Assignee: Hercules IncorporatedInventors: Sung G. Chu, Norman E. Daughenbaugh, Jr., Mark J. Rosner
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Patent number: 5173522Abstract: A rubber composition comprising a naturally occurring and/or synthetic rubber and a selected amount of a hydrogen donor material having a hydrogen transfer (hydrogen atom/mol anthracene) of at least 0.1. The composition is highly stable during molding and in use under severe temperature and shearing conditions and substantially immune to deterioration by heat or radiation and ultraviolet rays.Type: GrantFiled: November 13, 1990Date of Patent: December 22, 1992Assignee: Nippon Oil Co, Ltd.Inventor: Junichi Kubo
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Patent number: 5173523Abstract: Aqueous polymer emulsions whose polymer component essentially consists ofA) from 15 to 50% by weight of copolymer A ofI from 25 to 98.5% by weight of a C.sub.1 -C.sub.20 -alkyl acrylate or methacrylate or a mixture of these esters,II from 0 to 60% by weight of a monomer I or a vinylaromatic,III from 1.Type: GrantFiled: February 20, 1990Date of Patent: December 22, 1992Assignee: BASF AktiengesellschaftInventors: Gerhard Auchter, Gerhard Neubert, Rolf Osterloh
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Patent number: 5169900Abstract: Polyolefin coatings and films that may be used as release sheets, processes for the manufacture thereof and the related compositions are disclosed. The release sheets are formed from a composition of polyolefin, a dimethyl polysiloxane having functional end-groups, a vinyl silane, an agent for grafting the vinyl silane onto the polyolefin and a moisture curing agent. The composition is fed to an extruder and formed into sheet, especially by feeding a mixture having two components, one having an excess of vinyl silane and the other having less than an excess of vinyl silane, based on the amount of dimethyl polysiloxane in each component. The release sheets may be used, for instance, as the backing sheet for labels.Type: GrantFiled: November 9, 1990Date of Patent: December 8, 1992Assignee: Du Pont Canada Inc.Inventor: Paul V. Gudelis
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Patent number: 5166227Abstract: High amounts of silicon dioxide are readily incorporated into an emulsion polymerized elastomer by mixing an aqueous dispersion of silicon dioxide with a latex of the emulsion polymer and subsequently spray drying the mixture. Free flowing, fine-size (e.g., less than 500 micrometers) particles are produced with generally complete incorporation of silicon dioxide. The presence of the silicon dioxide permits rubbers with low gel and/or low Mooney viscosity to be spray dried whereas previously this could not be accomplished. Compared to conventional means of adding a silica to a bale rubber, the above powdered masterbatch gives shorter mixing times with lower power consumption with improved physical properties, such as tensile strength.Type: GrantFiled: November 29, 1990Date of Patent: November 24, 1992Assignee: Zeon Chemicals USA, Inc.Inventors: Charles C. Raines, Philip H. Starmer
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Patent number: 5162392Abstract: An injection moldable biodegradable plastic formed of corn starch and low-density polyethylene. Ethylene acrylic acid co-polymer can be included in proportions ranging from 0-10%, by weight, and sodium hydroxide can be utilized to neutralize the acidic portions of the ethylene acrylic acid co-polymer. When no ethylene acrylic acid co-polymer is utilized, glycerol is added. To improve injection molding characteristics, the ethylene acrylic acid co-polymer and polyethylene are premixed before the addition of corn starch.Type: GrantFiled: November 13, 1990Date of Patent: November 10, 1992Assignee: Agri-Tech Industries, Inc.Inventors: Richard P. Wool, David C. Schiltz, Dale Steiner
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Patent number: 5155151Abstract: A thermoplastic resin composition having improved heat stability which comprises a thermoplastic resin which contains at least 5% by weight of an .alpha.-alkyl-substituted aromatic copolymer comprising .alpha.-alkyl-substituted aromatic vinyl compound and at least one other comonomer copolymerizable therewith, wherein the composition contains a metal-deactivating agent which has a molecular weight of not more than 2,000 and at least one group of the formula: ##STR1## or an organometallic colorant containing free metal in an amount of not more than 2,000 ppm, from which a molded article having no or less silver streaks can be produced.Type: GrantFiled: February 21, 1992Date of Patent: October 13, 1992Assignee: Sumitomo Naugatuck Co., Ltd.Inventors: Kenji Hashimoto, Syuzi Takahashi, Hiroyuki Minematsu
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Patent number: 5155161Abstract: A styrene resin composition comprising [I] a polymer component which is a mixture of (A) 1 to 50% by weight of a resinous styrene polymer in which a functional group represented by formula>C.dbd.N.sup.+ <is bound to a polymer chain either directly or via the other atomic group and (B) 99 to 50% by weight of the other styrene resin than the above, and [II] a particulate or granular additive [II].Type: GrantFiled: September 6, 1990Date of Patent: October 13, 1992Assignee: Nippon Zeon Co., Ltd.Inventors: Hidenori Onishi, Kohokichi Noguchi, Hiroyuki Watanabe
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Patent number: 5153249Abstract: A polypropylene resin composition comprising 100 parts by weight of a polypropylene resin, 0.01 to 1.0 part by weight of 1.3, 2.4-di-benzylidene sorbitol and 0.005 to 1.0 part by weight of talc. The components of the polypropylene resin composition are not guided and do not escape from the composition even when it is immersed in hot water. The composition is excellent in transparency and products obtained by blow molding of the composition are also excellent in transparency.Type: GrantFiled: May 7, 1990Date of Patent: October 6, 1992Assignee: Mitsui Toatsu Chemicals, Inc.Inventors: Sachio Yokote, Yoichi Kawai, Masaki Misumi
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Patent number: 5147903Abstract: Dental materials contain a filler which consists of polymeric crosslinked (meth)-acrylates having a particle size in the range from 0.001 to 100 .mu.m, a degree of swelling of 50 to 2,000% by weight and a degree of crosslinking of 1 to 100% by weight, (meth)-acrylic acid esters which form crosslinkages and no crosslinkages, and additives.Type: GrantFiled: April 8, 1991Date of Patent: September 15, 1992Assignee: Bayer AktiengesellschaftInventors: Wolfgang Podszun, Fritjof Bley
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Patent number: 5143963Abstract: A composition of matter formed by melt-blending a thermoplastic polymer and from 0.01% to <1% of a fluorocarbon additive, the additive having a lower surface energy than that of the polymer; the blending resulting in a cooled admixture having a concentration of fluorocarbon additive through a cross-section of the solid composition lower in the interior thereof and higher at the surfaces thereof.Type: GrantFiled: January 9, 1991Date of Patent: September 1, 1992Assignee: RES Development Corp.Inventors: Robert E. Sterling, Eugene P. Goldberg
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Patent number: 5137955Abstract: A propylene polymer film is described which is composed of a composition comprising 100 parts by weight of a propylene polymer, 0.01 to 0.5 part by weight of a fine spherical silica particle and 0.3 to 5.0 parts by weight of hydroxy-fatty acid glyceride. A laminate film including a layer comprised of the above composition is also described. The film has an excellent transparency, gloss, slipperiness and adhesiveness, as well as a good adaptability to vacuum deposition.Type: GrantFiled: March 16, 1990Date of Patent: August 11, 1992Assignee: Toray Industries, Inc.Inventors: Katsuhiro Tsuchiya, Kenji Takuwa, Katsuya Ogawa
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Patent number: 5135967Abstract: The present invention relates to an underseal composition for motor vehicles, comprising a finely divided vinyl chloride homopolymer, copolymer, terpolymer or graft polymer, a plasticizer, a stabilizer, and a filler comprising calcium carbonate particles, wherein at least a part of said filler is provided with a surface coating formed by a surface treatment agent which comprises at least one saturated or unsaturated carboxylic acid, fatty acid or substituted fatty acid, said carboxylic acid or fatty acid having from 2 to 32 carbon atoms and containing at least one polar group in addition to at least one --COOH group, or a salt of said carboxylic acid or fatty acid. The underseal composition has improved rheological properties.Type: GrantFiled: October 4, 1990Date of Patent: August 4, 1992Assignee: Deutsche Solvay-werke GmbHInventors: Gerd Aumann, Gerd Klatte, Hans-Juergen Korte
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Patent number: 5118753Abstract: An olefinic thermoplastic elastomer composition which is excellent in mechanical properties and is substitutable for vulcanized rubbers is provided, which comprises a mixture comprising (A) 40-95 % by weight of an oil-extended olefinic copolymer rubber comprising 100 parts by weight of an olefinic copolymer rubber having a Mooney viscosity (ML.sub.1+4 100.degree. C.) of 150-350 and 20-150 parts by weight of a mineral oil and (B) 5-60% by weight of an olefinic plastic, said mixture being partially crosslinked by dynamic heat treatment in the presence of an organic peroxide. This composition gives superior molded articles free from bleeding of oil on the surface.Type: GrantFiled: July 5, 1990Date of Patent: June 2, 1992Assignee: Sumitomo Chemical Company, LimitedInventors: Tadashi Hikasa, Koichiro Ibuki, Tatsuo Hamanaka, Motoo Mizumori