Abstract: This invention relates to a process for producing a quality-improved water-absorbent polymer in which the aqueous liquid (I), which is obtained by mixing in an aqueous medium at least one kind of a water-soluble salt (A) selected from a group of halogenated compounds, sulfates, acetates, and nitrates, which are derived from at least one kind of a polyvalent metal selected from a group of aluminum, calcium, and magnesium, with at least one kind of a water-soluble salt (B) selected from a group of monovalent metal salts and ammonium salts, which are derived from at least one kind of an oxyacid selected from a group of sulfurous acid and thiosulfuric acid, is mixed with a water-absorbent polymer (II) in a proportion of that the water-soluble salt of the polyvalent metal (A) is in a range of 0.1.about.10 parts by weight against 100 parts by weight of the water-absorbent polymer (II) and the water-soluble salt of the oxyacid (B) is in a range of 0. 1.about.
Abstract: Weatherable thermoplastic polymeric compositions are formed by blending weatherable grafted rubber composition with an aliphatic diester selected from the group consisting of dialkoxyalkoxyalkyl diesters and dialkoxydialkoxyalkyl diesters of aliphatic dicarboxylic acids containing 4 to 8 carbon atoms.
Abstract: Effective amounts of low molecular weight brominated polystyrenes unexpectedly provide good property retention and yet achieve desired flame retardance, for example, UL-94 VO in high impact polystyrene. In contrast, high molecular weight brominated styrene polymers (degree of polymerization equals 2,000) do not provide good property retention such as impact strength and toughness in high impact polystyrene. The degree of polymerization of the brominated polystyrenes of the present invention is generally from about 3 to about 20 and can have a considerable variation in the amount of halogenation. The high impact polystyrenes blended with the low molecular weight brominated polystyrenes are readily processed by conventional equipment.
Abstract: Effective amounts of low molecular weight brominated polystyrenes unexpectedly provide good property retention and yet achieve desired flame retardance, for example, UL-94 VO in high impact polystyrene. In contrast, high molecular weight brominated styrene polymers (degree of polymerization equals 2,000) do not provide good property retention such as impact strength and toughness in high impact polystyrene. The degree of polymerization of the brominated polystyrenes of the present invention is generally from about 3 to about 20 and can have a considerable variation in the amount of halogenation. The high impact polystyrenes blended with the low molecular weight brominated polystyrenes are readily processed by conventional equipment.
Abstract: Effective amounts of low molecular weight brominated polystyrenes unexpectedly provide good property retention and yet achieve desired flame retardance, for example, UL-94 VO in high impact polystyrene. In contrast, high molecular weight brominated styrene polymers (degree of polymerization equals 2,000) do not provide good property retention such as impact strength and toughness in high impact polystyrene. The degree of polymerization of the brominated polystyrenes of the present invention is generally from about 3 to about 20 and can have a considerable variation in the amount of halogenation. The high impact polystyrenes blended with the low molecular weight brominated polystyrenes are readily processed by conventional equipment.
Abstract: A composition comprises a carboxylic acid compound which contains at least three carbon atoms together with an organic sulphur-containing acid or salt of such an acid. The carboxylic acid may be an aliphatic diacid such as succinic acid. The sulphur-containing acid may be a sulphonic acid or sulphuric acid derivative such as the sodium salt of an alkyl sulphonic acid or of sulpho-succinic acid or of a carboxylic acid ester derivative of sulpho-succinic acid. The composition may be incorporated into an olefin polymer. The composition may be obtained by conventional powder blending or, for a polymer composition, melt blending techniques. Preferred polymer compositions have an increased clarity and a reduced level of haze compared to the polymer alone or the polymer containing only the carboxylic acid.
Abstract: Disclosed herein is a polypropylene molded article characterized in that the content of hexane and/or heptane therein is from 0.1 to 5 ppm and the content of 2,4-dimethyl-heptene-1 therein is from 0.1 to 5 ppm. It has a greatly lowered level of odor and hence is suitable for food packaging.
Abstract: A dispersion of a colored high-molecular weight particulate material is prepared by a) mixing a pigment with an aqueous emulsion of a resin to form a dispersion of the pigment within the emulsion; b) combining the dispersion with particles of polyvinyl chloride containing a plasticizer to form a mixture; and c) adding a metal salt to the mixture to cause the resin to coagulate onto the particles of the polyvinyl chloride. A film comprising the resin and the pigment is formed on the particles of the polyvinyl chloride.
Abstract: A polymeric composition which degrades in the presence of oxygen either photochemically or thermo-oxidatively comprising a blend of polyethylene, e.g. low density polyethylene and cerium (III) stearate.This composition is especially useful in degradable food wrap and packaging and as an agricultural mulch film.
Abstract: A process for preparing polymer non-aqueous dispersions to be formulated together with a binder component in coating compositions, which comprises the steps of: (1) emulsion polymerizing a hydroxy group containing .alpha.,.beta.-ethylenically unsaturated monomer, a polyfunctional .alpha.,.beta.-ethylenically unsaturated monomer and an .alpha.,.beta.-ethylenically unsaturated monomer different therefrom by using a water-soluble polymerization initiator, preferably a persulphate, in a soap free system or in the presence of an ester group containing anionic or cationic surfactant; adding an organic solvent, preferably comprising an amphipathic organic solvent, to a resultant polymer aqueous dispersion; and then adding a basic compound catalyst when the anionic surfactant is used or an acidic compound catalyst when the cationic surfactant is used, to thereby hydrolyze completely said surfactant and water-soluble polymerization initiator at a temperature not exceeding 95.degree. C.
Abstract: The present invention relates to a mononitrone of the formula: ##STR1## The amount of alpha-(2,4-dihydroxy)phenyl N-phenyl nitrone which is used in the modification of a diene containing polymer may range from about 0.1 to about 30 percent by weight of said polymer. The modified polymers exhibit improved tear properties as measured by Strebler adhesion values.
Type:
Grant
Filed:
August 2, 1990
Date of Patent:
February 25, 1992
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Jose Cantillo, Robert W. Strozier, William P. Francik
Abstract: A resin composition for cleaning the inside of molding machines, capable of easily achieving the color exchange and resin exchange of thermoplastic resins in various molding machines, in a small quantity, by a simple operation and in a short time is provided, which resin composition is a cleaning resin composition having (a) 1-10 wt. % of a polystyrene resin, 1-20 wt. % of a neutral salt of an alkylbenzenesulfonic acid, 1-30 wt. % of an inorganic filler and 0.5-10 wt. % of a water-repellent compound blended with a high density polyethylene resin having a melt index of 1.0 or less and a Q value expressing a molecular weight distribution, of 10 or less.
Abstract: A process for the solventless (neat) hydrogenation of 4-acetoxyacetophenone to produce 4-acetoxyphenyl methylcarbinol. The reaction proceeds by heating at 54.degree. C. to 120.degree. C. with an excess of hydrogen in the presence of a Pd/C or activated nickel such as Raney Nickel catalyst in the absence of a solvent. The 4-acetoxyphenyl methylcarbinol may then be dehydrated to 4-acetoxystyrene. The later may be polymerized to poly(4-acetoxystyrene) and hydrolyzed to poly(4-hydroxystyrene).
Abstract: A fibrous magnesium oxysulfate of granular form according to the present invention has an apparent specific gravity of 0.13-0.25, an oil absorption of 250-600 ml/100 g, a fiber diameter of 0.1-2.0 .mu.m and a fiber length of 10-100 .mu.m. The thermoplastic resin composition obtained by incorporating the magnesium oxysulfate into a thermoplastic resin has good properties and good appearance.
Abstract: An aqueous polymeric gel-forming composition capable of selectively plugging highly permeable zones in subterranean oil-bearing formations. The composition comprises an aqueous solution of an anionic acrylamide copolymer of high molecular weight, comprising about 5 to 95 weight percent of 2-acrylamido-2-methylpropanesulfonic acid, about 2 to 95 weight percent of N-vinyl-N-methyl acetamide and about 5 to 93 weight percent of acrylamide, and a crosslinking agent selected from the group consisting of transition metal ions, phenolic resins and amino resins. The compositions of this invention will form stable gels in brines of wide-ranging salinity and are effective at the pH levels encountered in carbon dioxide and water flooding operations. Also provided is a process for selectively plugging regions of higher permeability within an oil-bearing formation to improve sweep efficiency during a fluid flood oil recovery operation.
Abstract: The present invention relates to a process for preparing a rubber containing polymer bound antidegradants. The process comprises the aqueous emulsion polymerization of (a) at least one functionalized monomer that contains an antidegradant moiety and a polymerizable vinyl group; with (b) at least one copolymerizable conjugated diene monomer, wherein the polymerization is conducted in the presence of from about 1 to about 70 parts by weight of an ester based on 100 parts by weight of total monomers. The ester functions as a synergist for the antidegradant, as a cosolvent/dispersing agent for the antidegradant during emulsion polymerization and as a plasticizer for the final polymer product.
Abstract: A composition for closing pores in a formation following a steam-flooding enhanced oil recovery process. The composition comprises an aqueous temperature activated gellable mixture. This mixture is comprised of water, water dispersible polymers, phenolic compounds, and aldehyde producing compounds. Polymers which can be utilized herein include polyvinyl alcohol, polyacrylamide and poly(acrylamide-co-acrylamido-2-methylpropane sulfonate). Phenol is the phenolic compound of choice. At a formation temperature greater than 300.degree. F., trioxane, the preferred aldehyde producing compound decomposes to yield formaldehyde which reacts with phenol to form phenolic resin in situ. The resin gels the polymer and forms a solid gel in a heated zone of the formation.
Abstract: An improved polyolefin composition, film product, and a method of preparation are provided. Fluoropolymers, preferably fluoroelastomers, and metal stearates, are added to polyolefins. The composition has and exhibits improved impact strength and better processability.
Abstract: This invention provides a plasticized hydrogenated nitrile composition. The composition of the present invention must contain a peroxide vulcanization system and a specific type of plasticizer. Vulcanizates according to the invention have superior resistance to hot air ageing in comparison to conventionally plasticized compositions, and most surprisingly, in comparison to non-plasticized compositions. The compositions of the present invention may be used to prepare hoses, seals, gaskets and other rubber goods.
Abstract: In accordance with the invention there is a composition comprising a ABS or ABS type resin in admixture with a mold release effective amount of a fluid hydrogenated oligomer of an alpha-olefin.