Abstract: There is a need for polymers which are utilized in automotive interiors which offer good color stability as well as a high level of heat and ultraviolet light resistance. It is particularly critical for polymers which are utilized in making skin compounds for automotive instrument and door panels to have excellent color stability as well as excellent heat and ultraviolet light resistance.
Type:
Grant
Filed:
January 27, 1998
Date of Patent:
November 10, 1998
Assignee:
The Goodyear Tire & Rubber Company
Inventors:
Jaclyn Beth Laurich, Gary Lee Burroway, James Walter Horvath
Abstract: A process for producing a microporous oil sorbent polymer comprising the steps of:dissolving a polyunsaturated monomer in a silicone organic solvent to provide a monomer mixture containing more than 90% by weight polyunsaturated monomer;polymerizing said monomers by precipitation polymerization, under an inert atmosphere to precipitate microporous, micro-particles in the form of micro-particles, agglomerates and aggregates having a bulk density of about 0.02 gm/cm.sup.3 to about 0.01 gm/cm.sup.3 and capable of adsorbing at least about 20% by weight organic materials based on the total weight of polymer plus adsorbed organic material.
Abstract: (1) A perfluoroalkyl diester of maleic acid or fumaric acid,(2) a copolymer obtained by polymerizing the perfluoroalkyl ester, a lower alkyl (meth)acrylate and, if necessary, styrene, and(3) a stainproofing agent comprising the copolymergive excellent water repellency, oil repellency and stainproof properties which have never been heretofore obtained.
Abstract: A polymer is formed from a mixture of between about 85 and about 96 wt % .alpha.-.beta.-unsaturated monomers and between about 4 and about 15 wt % unsaturated fatty acids having between 10 and 30 carbons.
Type:
Grant
Filed:
June 23, 1997
Date of Patent:
November 3, 1998
Assignee:
Morton International, Inc.
Inventors:
Stephen L. Walker, Gary A. Deeter, George G. Stuart, II
Abstract: The present invention is directed to a porous polymer micro-particle, in the form of broken spheres, open to a porous oleophilic interior surface area, having a high oil and water absorbency and an apparent bulk density of about 0.02 to about 0.1 grams/cc.
Abstract: The present invention provides a multi-phase polymerization process for making a water insoluble polymer. The process includes (1) providing a mixture comprising carbon dioxide and an aqueous phase, and containing a monomer and a polymerization initiator, and (2) polymerizing the monomer in the reaction mixture. The monomer may be a hydrocarbon or a fluorinated monomer. The polymerization initiator may be soluble in the aqueous phase, soluble in carbon dioxide, or insoluble in both the aqueous phase and carbon dioxide, such that the initiator forms a separate phase. The present invention also provides multi-phase polymerization reaction mixtures useful in the process of making water insoluble polymers.
Type:
Grant
Filed:
September 26, 1997
Date of Patent:
October 20, 1998
Assignee:
University of North Carolina--Chapel Hill
Abstract: The claimed invention is directed to stabilizers, polymers, and emulsifiers useful in preparing molecularly imprinted materials having recognition capabilities corresponding to the imprint molecule.
Abstract: Novel terpolymers are disclosed which comprise the reaction product of a high molecular weight olefin, such as polybutene or polypropylene, with an unsaturated acid reactant, such as maleic anhydride and a di-or polyunsaturated reactant. The terpolymers are useful as dispersants in lubricating oils and fuels and are also used to prepared polysuccinimides and other post-treated additives useful in lubricating oils and fuels.
Abstract: (i) A method for emulsion polymerization of tetrafluoroethylene, which comprises emulsion-polymerizing tetrafluoroethylene in the presence of a polymerization initiator, a paraffin wax containing not larger than 100 ppm of a reducing substance and an emulsifier, and (ii) a method for preventing irregular polymerization of tetrafluoroethylene, which comprises using the above method for emulsion polymerization give a constant polymerization time, and polytetrafluoroethylene having values of physical properties which meet the desired standard requirements.
Type:
Grant
Filed:
August 6, 1997
Date of Patent:
September 29, 1998
Assignee:
Daikin Industries, Ltd.
Inventors:
Takuo Kawamura, Shigeru Ichiba, Tomizo Sota
Abstract: A composition and method is described for providing conformal protective or decorative polymer coatings on metals such as aluminum, copper, iron, steel, zinc, and their by dip autopolymerization. In accordance with the present invention, an acidic solution of organic monomer undergoes autopolymerization upon contact with a metal substrate, thereby forming a polymeric coating on the substrate. The method comprises providing the acidic monomer solution, dipping the metal substrate to be coated for a prescribed period of time depending on the thickness of the coating desired, and then removing the substrate from the solution. Importantly, the polymerization requires no application of external driving force, such as thermal or electrical energy. The coatings thus formed are up to 50 microns thick, and conform to the shape of the substrate. These coatings further have uniform thickness, and excellent thermal stability and protective properties.
Abstract: To provide an aqueous dispersion of a vinylidene fluoride (VdF) copolymer which can be prepared by emulsion-polymerizing VdF monomer with a reactive emulsifying agent and is excellent in stability against sedimentation because an average particle size of the copolymer is as small as not more than 200 nm and a solid content is as high as from 30 to 60% by weight; an aqueous dispersion of a VdF seed polymer which can be prepared by seed-polymerizing an ethylenically unsaturated monomer in the presence of particles obtained by emulsion-polymerizing VdF monomer with a reactive emulsifying agent and is excellent in stability against sedimentation because an average particle size of the seed polymer is as small as not more than 250 nm and a solid content is as high as from 30 to 60% by weight; and processes for preparation thereof.
Abstract: An acrylic polymer of polymerized monomers of about 55-80% by weight of an alkyl methacrylate having 1-12 carbon atoms in the alkyl group, and alkyl acrylate having 1-12 carbon atoms in the alkyl group, substituted or unsubstituted aryl methacrylate or acrylate, substituted or unsubstituted alicyclic methacrylate or acrylate, substituted or unsubstituted cyclic methacrylate or acrylate, a polymerizable vinyl aromatic monomer, vinyl pyrrolidone or any mixtures of the above monomers, and contains about 5-40% by weight of acetoacetoxy ethyl methacrylate and about 5-15% by weight of ethylenically unsaturated acid and the acrylic polymer has a weight average molecular weight of about 10,000-3,000,000 and a glass transition temperature of about -20.degree. to 50.degree. C.
Type:
Grant
Filed:
August 13, 1997
Date of Patent:
August 25, 1998
Assignee:
E. I. du Pont de Nemours and Company
Inventors:
Waifong Liew Anton, Harry Joseph Spinelli, Anjali Abhimanyu Patil
Abstract: A compound of the formula C.sub.6 F.sub.12 --CH.sub.2 CH.sub.2 --SO.sub.3 M, wherein M is a cation having a valence of 1 is used as a dispersing agent in the aqueous dispersion polymerization of tetrafluoroethylene with at least one other perfluorinated copolymerizable monomer.
Abstract: A process for preparing low molecular weight polytetrafluoroethylene having a melting point of 250.degree. C. to 325.degree. C. comprising polymerizing tetrafluoroethylene in at least one polymerization solvent selected from the group consisting of hydrochlorofluorocarbons, hydrofluorocarbons and perfluorocarbons which have boiling points in the range between -10.degree. C. and 70.degree. C. under constant pressure by the supplement of tetrafluoroethylene. According to this process, the low molecular weight polytetrafluoroethylene which is useful as an additive to various materials is produced in the solvent which has a low ozone destruction factor or does not destroy the ozone, under economically advantageous low pressure which can be controlled safely.
Abstract: The object of the invention is to provide a novel process for epoxidation of perfluoro-olefins.This invention relates to a process for epoxidizing a perfluoro-olefin, characterized by employing a tertiary amine N-oxide represented by the general formula (I): ##STR1## (wherein R.sup.1, R.sup.2 and R.sup.3 each is a straight-chain or branched alkyl group having 1 to 10 carbon atoms, a lower alkyl group having 1 to 3 carbon atoms, or an aromatic group which may have a nitro group or a cyano group as a substituent; provided that all of R.sup.1, R.sup.2 and R.sup.3 are selected from the above alkyl groups, R.sup.1, R.sup.2 and R.sup.3 may combine with one another directly or through oxygen atoms or nitrogen atoms to form a cyclic compound of 5-7 membered ring), or iodosobenzene.According to the present invention, perfluoro-olefins can be converted to corresponding perfluoroepoxides cheaply and in high yields.
Type:
Grant
Filed:
September 12, 1996
Date of Patent:
August 4, 1998
Assignee:
Japan as represented by Director General of Agency of Industrial Science and Technology
Abstract: A polymer useful as an inorganic pigment dispersant is provided. The polymer is derived from monomers consisting essentially of an ethylenically unsaturated aromatic monomer, an ethylenically unsaturated acid monomer, and an ethylenically unsaturated amide monomer. The amount of said ethylenically unsaturated acid monomer is sufficient to permit said polymer to associate with an inorganic pigment in an aqueous medium in a manner which disperses said inorganic pigment in said aqueous medium to form a stable aqueous dispersion of said inorganic pigment, and the amount of said ethylenically unsaturated aromatic monomer is sufficient to reduce the water sensitivity of a dried coating of a latex paint comprised of said stable aqueous dispersion of said inorganic pigment. A process of preparing a polymer useful as an inorganic pigment dispersant and a method of preparing an inorganic pigment dispersion useful in the preparation of latex paints are also provided.
Type:
Grant
Filed:
July 11, 1997
Date of Patent:
July 28, 1998
Assignee:
Henkel Corporation
Inventors:
Stephen A. Fischer, Michael S. Wiggins, Bruce Matta
Abstract: The compositions of the present invention relate to improved personal cleansing compositions comprising a surfactant system comprising at least one surfactant selected from the group consisting alkyl glyceryl ether sulphonate surfactants, from above about 0.1% of a nonionic or anionic water soluble polymer, a phase separation initiator and water. These compositions provide improved lathering and conditioning benefits.
Abstract: A polymerization process produces polymers that are insoluble in a reaction mixture that was homogeneous before the polymer began to form. A dispersing agent in the polymerizing system (i.e., the reaction mixture plus the dispersing agent) allows a kinetically stable dispersion of the polymer to be formed in this polymerizing system. The polymerization process is performed in a fluid held under superatmospheric conditions such that the fluid is a liquid or a supercritical fluid; the fluid being carbon dioxide, a hydroflurocarbon, a perfluorocarbon, or a mixture of any of the foregoing.
Type:
Grant
Filed:
November 28, 1995
Date of Patent:
July 14, 1998
Assignee:
Minnesota Mining and Manufacturing Company
Inventors:
Robert S. Clough, Cheryl L. Senger, John E. Gozum