Abstract: A mixture of hydrocarbons consisting of gas oil and residual oil is catalytically cracked in the presence of a fluidized zeolite catalyst. The mixture of hydrocarbons is classified by boiling range as a 550.degree.-1000.degree. F. gas oil and a 1000+.degree. F. vacuum residuum. The gas oil is selectively cracked using a freshly regenerated fluid zeolite catalyst having less than 0.1 wt % residual carbon to give a high yield of desirable liquid hydrocarbon boiling from about 60.degree.-670.degree. F. The vacuum residuum is injected into the riser reactor at a point near the riser outlet to quench the cracking reactions in the gas oil. The vacuum residuum undergoes a small amount of reaction removing undesirable materials and yielding a liquid hydrocarbon boiling up to about 1000.degree. F. The amount of vacuum residuum cracking and overall yield of liquid hydrocarbons are controlled by downstream injection of vacuum residuum into the riser.

Abstract: Disclosed is a catalyst, a method for its preparation, and a process for its use in the production of high octane gasoline and/or other valuable liquid hydrocarbon products from carbo-metallic oils contaminated with heavy metals and coke precursors. The catalyst is prepared from a shapable composition containing reticulated carbon black particles which are subsequently removed by burning, as in a catalyst regenerator, to provide large feeder pores in a shaped catalyst structure. The catalyst and process conditions for its use facilitate conversion of the contaminated oils to lighter products at catalytic sites within the catalyst structure which may contain zeolitic materials.

Abstract: A process for reducing the molecular weight of hydrocarbons using NaAlCl.sub.4 is provided wherein the hydrogen to carbon ratio of the liquid product slate is approximately the same as the feed material. The process comprises contacting the feed material with a molten salt of NaAlCl.sub.4 having substantially no excess aluminum chloride or sodium chloride, preferably at a temperature of at least 660.degree. F., and at a pressure above atmospheric, preferably from about 50 psia to about 2000 psia, depending upon the product slate desired. According to the present invention, heavy hydrocarbons are converted to a liquid product slate wherein the product slate has an average molecular weight substantially lower than the average molecular weight of the hydrocarbon feedstock.

Abstract: Disclosed is a method and apparatus for fluid catalytic cracking (FCC). The output of a riser conversion zone is fed to a riser cyclone separator, a primary cyclone separator, and secondary cyclone separator, connected in series within a single reactor vessel. The riser cyclone separator is connected to the primary cyclone separator by a conduit which prevents random post-riser thermal cracking of the hydrocarbons after they exit the riser cyclone. Means are also provided to blend stripping gas with the cracked hydrocarbons as they travel from the riser conversion zone to said primary cyclone separator. The stripping gas blends with the cracked hydrocarbons to improve the separation of hydrocarbons from catalyst. Steam may also be directly injected into the riser cyclone separator to aid in separation of hydrocarbons from catalyst.

Abstract: This invention concerns a process for the preparation of a gasoline boiling hydrocarbon from a mixture of hydrocarbons specifically defined. The hydrocarbon feedstock is a mixture of two hydrocarbon oils with the first hydrocarbon oil having a Conradson carbon test value C.sub.1 and % w such that the quotient of C.sub.1 /R is higher than 0.8 and a second hydrocarbon oil having a Conradson carbon test number C.sub.2 such that the quotient C.sub.2 /R is lower than 0.2 wherein R is equal to the reactor carbon requirement for the particular catalytic cracking unit and is between 3 and 8 percent by weight.

Abstract: Low-molecular weight olefins from heavy hydrocarbons are obtained with a hydrogenating pretreatment and a subsequent thermal cracking of at least a portion of the hydrogenated product. In the first stage, the polyaromatic content of a first hydrocarbon fraction high in polyaromatic compounds, e.g., a vacuum gas oil, is selectively degraded with a zeolitic hydrotreating catalyst, and in a second stage the resultant hydrocarbons are refined with a non-zeolitic hydrotreating catalyst in admixture with a second heavy hydrocarbon fraction low in polyaromatic compounds, e.g., and atmospheric gas oil. This two-stage process permits the utilization of lower operating pressures as compared to the separate treatment of the heavy hydrocarbon fractions.

Abstract: A process for hydrocracking a hydrocarbon feedstock having a propensity to form polynuclear aromatic hydrocarbon compounds to suppress fouling the processing unit. The hydrocracking method includes contacting the hydrocarbon feedstock with a crystalline zeolite hydrocracking catalyst, contacting at least a portion of the resulting unconverted hydrocarbon oil containing polynuclear aromatic compounds with an iron catalyst in the presence of hydrogen to hydrogenate and hydrocrack the polynuclear aromatic hydrocarbon compounds, and recycling unconverted hydrocarbon oil having a reduced concentration of polynuclear aromatic compounds to the hydrocracking zone.

Abstract: A process for converting cellulose-containing refuse into a fuel comprising forming a suspension of said cellulosic material in a polycyclic hydrogen donor substance and hydrogenating the suspension at elevated temperature and pressure in the presence of a catalyst to produce a mixture of gaseous, liquid and solid hydrocarbons having a low oxygen content and correspondingly high calorific value.

Abstract: A process for preparing silica-alumina compositions suitable as catalyst material comprises mixing a first aqueous solution containing an aluminum salt (preferably KAl(SO.sub.4).sub.2) and an ammonium salt (preferably (NH.sub.4).sub.2 SO.sub.4) with a second solution containing an alkali metal silicate (preferably Na.sub.2 SiO.sub.3), wherein the concentration of the ammonium salt is chosen so as to afford coprecipitation of silica-alumina hydrogel (preferably at a pH of about 3-6). The silica-alumina hydrogel is then separated, optionally dried, and calcined. Calcined silica-alumina can be employed as cracking catalysts or as supports for hydrofining/hydrocracking catalysts.

Abstract: A novel catalyst composite is disclosed as well as a novel method of preparing the composite and a novel use for the composite. The novel composite comprises a nonacidic zeolite, catalytically effective amounts of a Group VIII metal component, and a silica support matrix derived by a high pH gelation of an alkali metal silicate sol. This novel composition has particular utility as a dehydrocyclization catalyst for the conversion of paraffins to aromatic compounds.

Abstract: This invention relates to an apparatus and a method for pyrolytic decomposition of polymeric materials into lower molecular weight products involving the heat treatment of raw polymeric material within reactive conduits submerged in a fluidized bed furnace operated at pyrolizing temperatures.

Abstract: A natural active stable catalyst for use in the hydrodemetallization (HDM) and the hydroconversion (HC) of heavy crudes and residues and, in particular, a method for the preparation of the catalyst from natural clay and a process for the treatment of heavy crudes and residues with the catalyst. The catalyst is free of hydrogenating metals of Groups VIB and VIII of the Periodic Table and comprises primarily iron, silica and alumina derived from the composition of the natural clay. The catalyst possesses a surface area of between 20 to 100 m.sup.2 /g, a total pore volume of between 0.20 to 0.90 cc/g, where 50 to 100% of the total pore volume contains pores of diameter greater than 400 .ANG.. The catalyst has a ratio I(Fe)/I(Si+Al) of between 0.2 to 0.9 as determined by XPS.

Abstract: A two-stage process for hydrotreating asphaltenes and metallic contaminants-containing heavy hydrocarbon oils which comprises a demetallization step using a catalyst composition which is smaller in pore size and less in active metal amount than the conventional demetallization catalysts, and a hydrotreating step using a catalyst composition which is larger in pore size and more in active metal amount than the conventional hydrodesulfurization catalysts or hydrocracking catalysts, said hydrotreating step being located downstream of said demetallization step.

Abstract: At least one decomposable molybdenum dithiocarbamate compound is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum dithiocarbamate compound is then contacted in a hydrofining process with a catalyst composition comprising a support selected from the group consisting of alumina, silica and silica-alumina and a promoter comprising at least one metal selected from Group VIB, Group VIIB and Group VIII of the Periodic Table. The introduction of the decomposable molybdenum dithiocarbamate compound may be commenced when the catalyst is new, partially deactivated or spent with a beneficial result occurring in each case.

Abstract: The invention concerns a process for converting heavy petroleum residues to hydrogen and to gaseous and distillable hydrocarbons, comprising the association of a step of hydropyrolysis (inside tube 3) with a step of catalytic steam-gasification of the formed coke (outside tube 3), characterized in that the hydropyrolysis step is performed in the presence of a solid supporting a carbon gasification catalyst circulating between the hydropyrolysis zone and the coke steam-gasification zone, said steam-gasification being performed in the absence of oxygen.The petroleum residue, hydrogen and steam are introduced respectively through lines 5, 6 and 7.The products are withdrawn through line 10. Heat may be supplied by the radiating tube 4.

Abstract: A process wherein a feed comprising an admixture of liquid hydrocarbon compounds which includes a polynuclear aromatic hydrocarbon compound, or compounds (PNA's) is contacted in the presence of hydrogen over an iron catalyst at temperature sufficient to selectively hydrogenate and hydrocrack, or destroy the PNA's of the admixture without excessively hydrogenating and hydrocracking the non-PNA's of said feed. The process is particularly applicable for the removal of PNA's from reformates, processed naphthas, and other hydroprocessed streams or the like to achieve a lower and more favorable distribution of PNA's in a motor gasoline pool, and further to remove PNA's from prime fuels and heavier hydrocarbon mixtures.

Abstract: At least one decomposable molybdenum additive selected from the group consisting of a mixture of a molybdenum dithiophosphate and a molybdenum carboxylate and a mixture of a molybdenum dithiocarbamate and a molybdenum carboxylate is mixed with a hydrocarbon-containing feed stream. The hydrocarbon-containing feed stream containing such decomposable molybdenum additive is then contacted in a hydrovisbreaking process with hydrogen under suitable hydrovisbreaking conditions.

Abstract: A combination endotracheal tube and stethoscope is provided so as to allow simultaneous patient ventilation and monitoring of vital sounds by a single instrument. The tracheal tube includes an inflation cuff adjacent the distal end and a longitudinal pressure conduit to inflate the cuff so as to peripherally seal the assembly against the trachea wall. An audio cuff extends at least partially coextensive and concentrically with the inflation cuff and has sufficient resiliency to vibrate in response to the patient's vital sounds. The inflation cuff comprises a highly flexible bulb in direct contact with the trachea wall and the audio cuff is a sleeve inside the bulb and spaced peripherally from the tube to allow vibration. The sleeve is sufficiently stable to maintain the spacing even upon inflation of the bulb. Preferably, the sleeve is positioned wholly within the inflation bulb. The pressure conduit extends longitudinally along the tube and opens into communication with the inflation cuff.

Abstract: The present invention provides novel catalyst products for promoting the combustion of carbon monoxide, particularly in catalytic cracking units, especially FCC units. The improved products of the invention comprise one or more catalytically active metals selected from the group consisting of palladium or mixtures of palladium and at least one other precious metal on a porous silica-alumina support obtained by leaching sufficient silica from shaped particles of calcined clay with caustic solution to impart porosity to the particles. The calcined clay from which silica is leached to impart porosity is preferably kaolin clay that has been calcined at a temperature and for a time sufficient to substantially convert the clay into mullite and silica, whereby the support particles consist essentially of mullite crystals.

Abstract: High yields of desired distillate oil are obtained by subjecting heavy oil to catalytic conversion with hydrogen at superatmospheric pressure in a temperature staged process, wherein the oil-catalyst slurry is subjected in the initial stage to a temperature in the range of 780.degree.-825.degree. F. (415.degree.-440.degree. C.) and in a subsequent stage to a temperature which is at least 20.degree. F. higher than that employed in the previous stage, preferably in the range of 800.degree.-860.degree. F. (.about.425.degree.-460.degree. C.).