Abstract: A biodegradable plastic composition, which may be in the form of a molded dy, includes gelatinized starch and a biodegradable, aliphatic polyester resin having a melting point of 45.degree.-130 .degree. C. The plastic is produced by kneading a blend containing a starchy substance selected from non-gelatinized, granular starch and gelatinized starch and the aliphatic polyester resin at a temperature higher than the melting point of the aliphatic polyester in the presence of water in an amount of 1-45 % based on the weight of the starchy substance.
Type:
Grant
Filed:
October 1, 1992
Date of Patent:
October 26, 1993
Assignees:
Director-General of Agency of Industrial Science, Technology Research Institute of Innovative Technology for the Earth, Chuo Kagaku Co., Ltd.
Abstract: A pharmaceutical composition comprising a therapeutic agent, together with a polymeric delivery vehicle, the vehicle being made of poly(phosphoesters).
Type:
Grant
Filed:
March 24, 1992
Date of Patent:
October 26, 1993
Assignee:
The Johns Hopkins University School of Medicine
Abstract: A method of making controlled sequence condensation copolymers from mer systems capable of forming at least two unique recurring units is disclosed and claimed. Sequenced polyesters containing the residue of hydroxyacids are specifically exemplified.
Type:
Grant
Filed:
May 15, 1992
Date of Patent:
October 26, 1993
Assignee:
Hoechst Celanese Corp.
Inventors:
Michael J. Jaffe, Marie Borzo, Edward C. Chenevey, Eui W. Choe, M. Ishaq Haider, Subhash Makhija
Abstract: The invention relates to a flame retardant plastics composition and based on a polyamide, a polyolefin, and magnesium hydroxide of the following composition:(1) 5 to 52 wt. % of a polyamide (PA),(2) 8 to 55 wt. % of a polyolefin (PO) composition comprising polypropylene at least partially functionalized with a compound containing an ethylenically unsaturated group and/or a propylene group and a carboxylic acid group, acid anhydride group, acid amide group, imido group, carboxylic ester group, amino group, or hydroxyl group, and(3) 40 to 70 wt. % of magnesium hydroxide particles in platelet form having a specific surface area of not more than 18 m.sup.2 /g.A major portion of the compositions according to the invention satisfies the Underwriters Laboratories Inc. V.sub.0 rating and the compositions also stand out through favorable rheological behavior and the fact that articles made from them by injection moulding have an exceptionally smooth surface.
Abstract: Production of alkali metal or alkaline-earth metal terephthalate by reaction of an alkali metal or alkaline-earth metal hydroxide with a polyol polyterephthalate, and optional conversion of the terephthalate into terephthalic acid.The reaction is performed without addition of water or in the presence of an amount of water representing at most, by weight, the amount of polyterephthalate.The invention is useful for the treatment of polyol polyterephthalate waste.
Abstract: A method for compensation for the proximity effect in electron beam lithography on an e-beam resist material. The exposed surface of the resist material is subdivided into non-overlapping pixels of approximately equal area, with a first set of pixels representing a selected pattern for e-beam lithography and a second set of pixels including all other pixels. The cumulative exposure for each pixel in the first set is computed by adding to the direct beam exposure of that pixel the contributions of spillover (backscattering) exposure arising from exposure of nearby pixels in the second set. The cumulative exposure for each pixel in the second set is computed by adding to the reduced beam exposure of that pixel the contributions of spillover exposure arising from exposure of nearby pixels in the second set. The resist material is then irradiated, pixel-by-pixel with a fixed electron beam radius, with the exposure at each pixel being equal to the cumulative exposure computed for that pixel.
Abstract: A biodegradable composition comprising a polymer matrix having distributed substantially uniformly therethrough hollow sphere-like inclusions or microcapsules, said polymer matrix consisting essentially of a water-soluble polymer/polymer-compatible salt complex with said salt present in an amount sufficient to render said polymer insoluble in water and products made by shaping such composition.
Type:
Grant
Filed:
December 9, 1991
Date of Patent:
October 19, 1993
Assignee:
Southwest Research Institute
Inventors:
Herman W. Schlameus, Mary C. Marshall, Stephen T. Wellinghoff, Donald J. Mangold, James R. Scott
Abstract: Provided is an improved process for the synthesis of 1-cyano-3H-dibenz[f,ij] isoquinoline-2,7-dione compounds, and process exhibiting improvements in quality of products, safety, fewer environmental concerns and economics when compared to presently known processes. The compounds are useful as colorants for polyesters, and selected compounds and when combined with small quantities of certain red colorants are particularly efficacious as blue toners for polyesters.
Type:
Grant
Filed:
May 15, 1992
Date of Patent:
October 12, 1993
Assignee:
Eastman Kodak Company
Inventors:
Kim S. Chamberlin, Wayne P. Pruett, Max A. Weaver, Samuel D. Hilbert, Donna R. Quillen, Preston K. Salyer
Abstract: This invention provides a novel graft polyaniline derivative soluble or gelatinizable in general organic solvents, which forms elastic self-standing films or fibers, and also their production process. The graft polyaniline derivative is represented by the following formula (I) which consists of a quinodiimine unit structure, an imino-1,4-phenylene unit structure and a N-polyether chain substituted imino-1,4-phenylene unit structure bonding at random, ##STR1## wherein k is an integer of at least 1, m and n each is zero or an integer of at least 1, k+m+n=10 to 5,000, m/(n+m)=0 to 1, Alk represents a polyether chain having a number average molecular weight of 100 to 100,000 and having oxygen atoms at the both terminals, A represents a specific linking group.
Abstract: This invention relates to thermotropic liquid crystalline polyester compositions containing recurring units derived from hydroquinone, 4,4'-dihydroxybiphenyl, terephthalic acid, 2,6-naphthalenedicarboxylic acid, 4,4'-bibenzoic acid, and 4-hydroxybenzoic acid which are characterized as having melting points less than 365.degree. C., breaking elongations greater than or equal to 1.5%, and heat distortion temperatures greater than 200.degree. C.This invention further relates to the same compositions containing 20 to 40 weight percent of at least one glass reinforcing/filling agent and which are characterized as having melting points less than 365.degree. C., breaking elongations greater than or equal to 1.8%, and heat distortion temperatures greater than 230.degree. C.The compositions are useful as films, fibers, and shaped or molded articles.
Type:
Grant
Filed:
May 4, 1992
Date of Patent:
October 5, 1993
Assignee:
E. I. Du Pont de Nemours and Company
Inventors:
Gregory R. Alms, Michael R. Samuels, Marion G. Waggoner
Abstract: Polyarylene thioether is easily prepared by oxidative polymerizing an aromatic compound of the formula: ##STR1## wherein R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are independently a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group, and Y is a hydrogen atom or a group of the formula: ##STR2## wherein R.sup.5, R.sup.6, R.sup.7 and R.sup.8 are independently a hydrogen atom, a halogen atom, a lower alkyl group or a lower alkoxy group and X is --O--, --S--, a methylene group or an ethylene group with a sulfidizing agent in the presence of an acid and an oxidizing agent, or in the presence of an acid, a catalyst for oxidative polymerization and oxygen, or in the presence of a Friedel-Crafts catalyst.
Abstract: A workable high-strength heat insulating material containing no asbestos is provided. The high-strength heat insulating material includes fibers of aromatic polyether amide dispersed in the form of filaments, 1-5% by weight, and fibrous wollastonite, 20-70% by weight. The material has a matrix made of a calcium silicate hydrate, and has a density between 1.3-1.9 g/cm.sup.3.
Abstract: A thermotropic copolyesteramide, with a nematic structure of the liquid crystalline phase within a desired temperature range of the mesophase, contains a unit derived from: (a) a saturated .alpha., .omega.-dicarboxylic acid; (b) 4,4'-dihydroxydiphenyl; (c) p-aminobenzoic acid; (d) 2,6-dihydroxyriaphthoic acid.A copolyesteramide of this type exhibits improved characteristics, especially in regard to its elastic modulus and tensile strength, when used as a self-reinforced material or as a reinforcement material for traditional thermoplastic polymers.
Type:
Grant
Filed:
November 13, 1990
Date of Patent:
September 28, 1993
Assignee:
Eniricerche S.p.A.
Inventors:
Ugo Pedretti, Arnaldo Roggero, Francesco P. La Mantia, Enrico Montani, Pierluigi Magagnini
Abstract: A semiconductive developer roll is disclosed having a conductive shaft and a single outer member of polyester urethane in which copper (II) chloride is dissolved. Performance is enhanced by the addition of some silicone oil.
Type:
Grant
Filed:
May 7, 1992
Date of Patent:
September 28, 1993
Assignee:
Lexmark International, Inc.
Inventors:
Ronald W. Baker, Bradley L. Beach, Ronald L. Roe, Donald W. Stafford
Abstract: A halogenated copolycarbonate, including a poly(ester/carbonate), which contains reduced levels of phenolic end groups and end groups which result from side reactions of process chemicals with the copolycarbonate chain, has improved resistance to the degradation-inducing effects of such end groups and has improved washability.
Abstract: A fine-grained polyether-ketone powder, having a particle size with a d.sub.50 value smaller than or equal to 40 .mu.m and a grain size distribution range smaller than or equal to 55 .mu.m, is obtained by cold-grinding of coarse-grained polyether-ketone in a fluid-bed opposed-jets mill, which is provided with a grinding chamber (2) subjected to gas jets, a grinding material-charging device, a screening device (5) for separating coarse material (11) and fine material (10), and a bottom (3) underneath the grinding chamber for added material to be ground and coarse material flowing back from the screening device, the material to be ground and the coarse material flowing back from the screening device being cooled by means of a cryogenic refrigerant.The powders obtained in this way are used for producing surface coatings or composites.
Abstract: Polymeric hydrocarbons having reactive borane groups at chain ends or in the polymer chain are described. These types of polymers can be used as intermediate materials for preparing a broad range of polymers which have functional groups located at both ends of the polymer chain (telechelic polymers). The process of preparing the borane-containing polymers involves metathesis degradation of the polymer at the double bond locations in the backbone and simultaneous functionalization of the broken chain ends by borane monomers. Depending on the nature of the borane monomer, the location of boron atoms can be controlled to be at either the chain ends (telechelic) or in the polymer backbone. The concentration of boron in the resulting polymer is related to the reaction time and the mole ratio between borane monomer and the double bonds in the starting hydrocarbon polymer. In turn, the borane groups are interconvertible to various functional groups, such as OH, NH.sub.2, and halides, under mild reaction conditions.
Abstract: A thermotropic copolyesteramide, with a nematic structure of the liquid crystalline phase within a desired temperature range of the mesophase, contains metered amounts of units derived from: (a) a saturated aliphatic -dicarboxylic acid; (b) 4,4'-dihydroxydiphenyl; (c) 4-hydroxybenzoic acid and (d) 4-aminobenzoic acid or (d') 4-aminophenol.This thermotropic copolyesteramide, produced by the copolymerization of monomers in the molten state, is a material with self-reinforcing characteristics capable of yielding, by normal injection or extrusion processes, remarkable molecular orientations which impart a high rigidity to the manufactured products.The copolyesteramide may be used as a reinforcement material for traditional thermoplastic polymers, by usual techniques.
Type:
Grant
Filed:
November 13, 1990
Date of Patent:
September 7, 1993
Assignee:
Eniricerche, S.p.A.
Inventors:
Ugo Pedretti, Cesarina Bonfanti, Enrico Montani, Arnaldo Roggero, Francesco P. La Mantia
Abstract: Nadimide-terminated polyarylate prepolymers having the formula (I) ##STR1## wherein n is an integer not less than 1, and cured polyarylate resins produced by thermal curing the prepolymers, and processes for producing them are disclosed.The cured polyarylate resins according to the present invention have excellent chemical resistance and high-temperature resistance as well as good mechanical properties and processability.
Type:
Grant
Filed:
July 6, 1992
Date of Patent:
August 31, 1993
Assignee:
Korea Research Institute of Chemical Technology