Abstract: This invention pertains to novel copolyesters consisting essentially of units (I), (II), (III), and (IV). ##STR1##and blends of these polymers and articles made from both. Units (I), (II), (III), and (IV) are present in specified proportions as defined in the "Description of the Invention."The instant copolyesters display orientation in the molten state, good fiber ratings and high strength. Advantageously, the polymers of the present invention display a significant improvement in viscosity and moldability of the neat polymer. The polymers have excellent mechanical and surface properties including blister resistance, strength, toughness, and ability to vapor phase solder, and form strong fibers while still maintaining a high heat distortion temperature. They have melting points in the range of from about 250.degree. to about 360.degree. C. and are melt-processible. Advantageously, these compositions filled with about 30 weight percent of glass fibers display heat distortion temperatures of up to 240.degree.

Abstract: Process for continuous production of polyesters by esterification of terephthalic acid with 1,4-bis(hydroxymethyl)cyclohexane with a split feed in the presence of a titanium catalyst at 265.degree. to 305.degree. C. and 0.8 to 1.5 bar up to a conversion of 98.0% to 99.0%, then performing precondensation at 290.degree. to 305.degree. C. and 0.01 to 1.5 bar up to a conversion of 99.4% to 99.7% and finally performing polycondensation at 295.degree. to 310.degree. C. and less than 1.5 mbar up to a conversion corresponding to 50% to 95% of the maximum possible viscosity after adding more titanium catalyst.

Abstract: An improved method for producing multiply-branched polyester comprising condensing a reactant having the general formula Z.sup.1 --Ar--(Z.sup.2).sub.j, wherein j is 2 or 3, Ar is an aryl or heteroaryl group having from 1 to 3, solitary or linked or fused, five or six membered rings, and one of Z.sup.1 and Z.sup.2 is a carboxyl group and the other is a group having the general formula ##STR1## wherein R is an alkyl group having from 1 to 3 carbon atoms, X is selected from the group consisting of fluoro and chloro and g is an integer from 0 to about 7.

Abstract: Process for discontinuous production of polyesters by esterification of terephthalic acid with a definite excess of 1,4-bis(hydroxymethyl)cyclohexane in the presence of a titanium catalyst at 180.degree. to 300.degree. C. and 0.8 to 1.5 bar up to a conversion of 98.0% to 99.6%, then precondensation with the addition of more titanium catalyst at 270.degree. to 300.degree. C. and 500 to 5 mbar up to a conversion of 99.5% to 99.9% and polycondensation at 295.degree. to 310.degree. C. and less than 1.5 mbar up to a conversion corresponding to 40% to 95% of the maximum possible viscosity.

Abstract: Melt processable copolyesters having improved thermal stability are prepared from 1,4-butanediol, minor amounts of trans-4,4'-stilbenedicarboxylic acid and a dicarboxylic acid selected from terephthalic acid, isophthalic acid, and mixtures thereof.

Abstract: A single reactor process for formation of block copolymers comprising aromatic ester mesogenic units containing flexible alkane spacers and polyester flexible coil units in the main chain thereof which comprises:(a) reacting an .alpha., .omega.-bis(hydroxybenzoyloxy) alkane monomer with an aromatic acid chloride in a reactor to form a functionalized liquid crystal oligomer containing such mesoenic units; and(b) thereafter reacting the oligomer from (a) in the same reactor with either (i) a polyester oligomer; or (ii) the reagents for synthesizing the polyester oligomer (i).

Abstract: A polyester is provided that comprises as main monomer components thereof a dicarboxylic acid and a diol, including a p-quaterphenyl derivative of specific formula. The use of appropriate kinds of dicarboxylic acid for the polyester makes it possible to obtain a thermoplastic elastomer or an engineering plastic material (i.e., liquid-crystal polymer).

Abstract: A wet strength resin composition is comprised of an aminopolyamide-epichlorohydrin acid salt resin having a total organic chlorine of up to about 0.1% by weight of the resin. The amount of total organic chlorine present is controlled by the process parameters.

Abstract: An aromatic polyesteramide possessing thermotropic liquid crystalline polymer characteristics, which are easily workable in the molten state and have the mesogenic group in the main chain, are obtained by condensing possible substituted aminophenols and hydroquinone derivatives with aromatic dicarboxylic acids.

Abstract: An improved easily processable wholly aromatic polyester exhibiting melt anisotropy and excellent thermal stability is provided which consists essentially of the structural units (i) to (iii) wherein: ##STR1## and wherein Ar.sub.1 is 1,4-phenylene, Ar.sub.2 is 2,6-naphthalene and 2,7-naphthalene, and Ar.sub.3 is 1,4-phenylene and/or 4,4'-biphenylene.

Abstract: Moldable polyester resins having high melt-phase stability and which form substantially no thermal decomposition products during melt-phase processing have a carboxyl end group concentration of no greater than 40 milliequivalent/kg, and are the reaction product of (a) an aromatic dicarboxylic acid or its ester-forming derivative, (b) an aliphatic dihydroxy compound having 2 to 8 carbon atoms, and (c) an ester-forming comonomer having the general formula (I):HO--R--O--A--O--R--OH (I)wherein A represents a divalent organic radical having at least one aromatic ring, R represents a divalent organic radical selected from the group consisting of aliphatic hydrocarbon groups and polyoxyalkylene groups each having 2 to 8 carbon atoms. The ester-forming comonomer is incorporated into the polyester resin chain in an amount between 0.01 to 7 molar %, based on the aromatic dicarboxylic acid.

Abstract: An improved polyester exhibiting melt anisotropy and excellent thermal stability is provided which consists essentially of the structural units (I) to (III) wherein: ##STR1## wherein Ar.sub.1 is 1,4-phenylene, Ar.sub.2 is a mixed system of 2,6-naphthalene and 2,7-naphthalene, and Ar.sub.3 is an aromatic ring containing 6 or more carbon atoms, the unit (I) accounting for 15 to 90 mole percent and the unit (II) for 20 to 70 mole percent of the total amount of the structural units, and the percentage of 2,7-naphthalene to the total amount of Ar.sub.2 in the unit (II) being between 10 and 90 mole percent.

Abstract: Substantially amorphous, high molecular weight polyaniline which is processable into shaped articles such as fibers is disclosed. Polyaniline base made by standard procedures is subjected to extraction to remove impurities and lower molecular weight fractions. The resulting high molecular weight base, which is partially crystalline and insoluble in NMP and concentrated H.sub.2 SO.sub.4, is converted to an amorphous material soluble in NMP and concentrated H.sub.2 SO.sub.4, by a two step process involving conversion to a salt, and reconversion to a base. Fibers prepared from the high molecular weight material exhibit conductivities in the range of about 50 to 100 S/cm.

Abstract: Aromatic sulfides including diarylsulfides and poly(arylene sulfides) are produced in a novel synthesis in high yield under moderate conditions by heating an aromatic disulfide in the presence of aromatic halide, in which the halide is chloride, bromide or iodide; the diaryl sulfides are useful precursors and starting materials for a range of compounds and the poly(arylene sulfides) are important high temperature engineering thermoplastics.

Abstract: A process for the manufacture of a partially cured polysulphide composition is provided, the curing of which is completed upon exposure of the composition to atmospheric moisture. The process comprises mixing a prepolymer with a water activatable curing agent and subjecting the composition to a partial cure with water. The reaction is then stopped by rapid dehydration after the initial induction stage of the reaction prior to the rapid increase in the viscosity of the composition. Curing of the composition is then completed by exposing the composition to atmospheric moisture.

Abstract: The invention relates to a binder (A) which contains hydroxyl groups and carboxyl groups, the latter optionally in neutralized form, wherein the binder (A) is essentially composed of a mixture of polyalkylidenepolyphenols (B) having average degrees of condensation of 2.3 to 8.0 and average molecular weights M.sub.n of 250 to 1,000, these polyalkylidenepolyphenols (B) containing phenolic OH groups and carboxyl groups, and polyaddition products (C) containing structural units (d) which are derived from epoxide compounds (D) which on average contain at least two (1,2-)epoxide groups per molecule, the structural units (d) having an average molecular weight M.sub.n of 600 to 10,000, and containing structural units (b) which are derived from the polyalkylidenephenols (B), and these polyaddition products (C) have average molecular weights M.sub.n of at least 1,100.

Abstract: Tough, high strength fibers of copolyesters from hydroquinone, isophthalic acid and 4,4'-oxydibenzoic acid in defined proportions.

Abstract: The invention relates to thermotropic liquid crystalline polymer compositions of the general formula:--(CO--C.sub.6 H.sub.4 O).sub.m --(CO--C.sub.6 H.sub.4 --CO).sub.n--(O--C.sub.6 H.sub.4 --X).sub.p --(O--C.sub.6 H.sub.4 --C(CH.sub.3).sub.2 --C.sub.6 H.sub.4 --O).sub.q --(O--C.sub.6 H.sub.4 --S--C.sub.6 H.sub.4 --O).sub.t --where substantially all aromatic substituents are para to one another, where--X-- can be either --O-- or --NH--, andm, n, p, q and t are mole fractions totaling 1.0,wherem is 0 to 0.75,m plus 2p is 0.5 to 0.75,n is 0.125 to 0.5,p is 0 to 0.375,q is 0.125 to 0.25,n equals p plus q plus t, andt is greater than 0.0125, but equal to no greater than 90% of q plus t.Preferably X is --O--, m is from 0.5 to 0.75 and p is less than 0.05. Alternatively, m is less than 0.1 and p is from 0.25 to 0.375.

Abstract: The present invention discloses a wholly aromatic, melt processable polyester which is comprised of recurring moieties derived from the following compounds: 2,6-naphthalenedicarboxylic acid, 4-hydroxybenzoic acid, an aromatic dihydroxy compound, and 6-hydroxy-2-naphthoic acid. The resulting wholly aromatic polyester is capable of forming a thermotropic melt phase at temperatures below approximately 350.degree. C. and most preferably at temperatures below approximately 290.degree. C.

Abstract: In an improved process condensation polymers having terminal arylcyclobutene moieties are prepared. Such polymers are prepared by adding to a condensation polymerization process one or more arylcyclobutene chain terminating compounds along with the multi-hydric compounds and condensation polymer precursors that are typically employed in such a process. Desirably the condensation polymers have an average degree of polymerization of at least about 2, preferably at least about 3 based on multi-hydric compound. This process can be used to prepare a range of condensation polymers including polycarbonates, polyesters and polyester-carbonates. The resulting products can be easily processed and shaped into various forms and structures according to the known techniques. During or subsequent to the processing, the polymers can be crosslinked, by exposure to heat or radiation, for example, to provide crosslinked polymer compositions.