Patents Examined by W. J. Shine
  • Patent number: 5225100
    Abstract: A tablet of compacted detergent powder comprises an anionic detergent-active compound, a detergency builder, and optionally other detergent ingredients. The tablet is the compaction product of a particulate mixture of:(a) from 2 to 40 wt % of a first particulate component comprising from 20 to 100 wt % of anionic detergent-active compound,(b) from 60 to 98 wt % of other ingredients, comprising from 0 to 3 wt % of anionic detergent-active compound.
    Type: Grant
    Filed: July 12, 1991
    Date of Patent: July 6, 1993
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventors: Alan J. Fry, Michael J. Garvey, Geoffrey Newbold, Jonathon Osler, John M. Robb, Douglas Wraige
  • Patent number: 5225390
    Abstract: A Catalyst for reducing the nitrogen oxides in flue gases by a reducing agent and a catalytically active composition are described. The catalyst increases resistance to catalyst poisons such as arsenic trioxide. The composition contains 60-90% by weight of titanium, 10-30% by weight of molybdenum, and 0.2-10% by weight of vanadium, as their respective oxides. A very pure titanium dioxide having less than 500 ppm of calcium and less than 100 ppm of iron, being 60% in the anastase modification. It has a mean particle size of 10 to 100 nm, a mean pore radius of 10 to 30 nm and a BET surface of 10 to 80 m.sup.2 per gram. The catalyst is prepared by wet-grinding a suspension of the titanium dioxide with the vanadium pentoxide and molybdenum trioxide in stated proportions. The suspension is then dried and precalcined for several hours at 450.degree. to 550.degree. C. The precalcined material is comminuted to diameters smaller than 180 .mu.m.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: July 6, 1993
    Assignee: Siemens Aktiengesellschaft
    Inventors: Doris Vogel, Norbert Landgraf, Josef Sprehe, Wolfgang Gajewski, Dietmar Hein, Helmut Schmelz
  • Patent number: 5225096
    Abstract: An automatic dishwasher detergent composition having improved chlorine stability is formulated as a linear viscoelastic, pseudoplastic, gel-like aqueous product of exceptionally good physical stability, low bottle residue, low cup leakage, and improved cleaning performance, Linear viscoelasticity and pseudoplastic behavior is attributed by incorporation of cross-linked high molecular weight polyacrylic acid type thickener. Potassium to sodium weight ratios of at least 1/1 minimize amount of undissolved solid particles to further contribute to stability and pourability. Control of incorporated air bubbles functions to provide the product with a bulk density of about 1.32 to 1.40 g/cc which roughly corresponds to the density of the liquid phase. Stearic acid or other fatty acid or salt further improve physical stability.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: July 6, 1993
    Assignee: Colgate Palmolive Company
    Inventors: Fagim U. Ahmed, Makarand Shevade
  • Patent number: 5223471
    Abstract: A contact material of a fluorine-containing compound of at least one of Sr, Ba, Sc, Y or La, as well as such contact material compositions themselves, is provided.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: June 29, 1993
    Assignee: Amoco Corporation
    Inventor: Don M. Washecheck
  • Patent number: 5223472
    Abstract: A catalyst useful for hydroprocessing a hydrocarbon-containing oil contains at least one hydrogenation component on an amorphous, porous refractory oxide containing delta alumina. The catalyst is prepared by impregnating support particles having a narrow pore size distribution and a median pore diameter greater than about 185 angstroms with a solution containing a precursor of the hydrogenation components, followed by drying and calcining. The catalyst is useful for promoting a number of hydrocarbon hydroprocessing reactions, particularly hydrogenative desulfurization, demetallation and denitrogenation, and most particularly, hydrodemetallation of residuum-containing oils.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: June 29, 1993
    Assignee: Union Oil Company of California
    Inventors: Howard D. Simpson, Milan Skripek
  • Patent number: 5223469
    Abstract: The present invention relates to a fluidized-bed catalyst for propylene ammoxidation to produce acrylonitrile, which consists of silica support and a composite of the formulaA.sub.a B.sub.b C.sub.c Ni.sub.d Co.sub.e Na.sub.f Fe.sub.g Bi.sub.h M.sub.i Mo.sub.j O.sub.xwherein A is potassium, rubidium, cesium samarium, thallium, or mixture thereof; B is manganese, magnesium, strontium, calcium, barium, lanthanum, rare earth, or mixture thereof; C is phosphorus, arsenic, boron, antimony, chromium, or mixture thereof; M is tungsten, vanadium, or mixture thereof. The catalyst of the present invention is highly active and selective for preparing acrylonitrile, more specifically, is suitable for catalyzing the reaction between air and propylene at a rather low ratio hence to greatly enlarge the processing capacity of the reactor. By using the catalyst of the present invention, the processing capacity of the reactor increases by 10-15 percent compared with that using conventional catalysts.
    Type: Grant
    Filed: October 31, 1991
    Date of Patent: June 29, 1993
    Assignee: China Petro-Chemical Corporation
    Inventors: Xin Chen, Lianghua Wu
  • Patent number: 5223470
    Abstract: The invention relates to a nickel on alumina catalyst which has been promoted with sulfur, having an atomic S/Ni ratio of between 0.06 and 0.10, an atomic Ni/Al ratio of between 2 and 10, and a particle size distribution, defined as (d.sub.90-10)/d.sub.50, of between 0.4 and 1.5, d.sub.50 ranging from 4 to 20 .mu.m.
    Type: Grant
    Filed: July 8, 1991
    Date of Patent: June 29, 1993
    Assignee: Engelhard De Meern B.V.
    Inventors: Hermanus J. Bouwman, Pieter J. W. Blom
  • Patent number: 5221652
    Abstract: The present invention relates to a novel route for the synthesis of methanol, and more specifically to the production of methanol by contacting synthesis gas under relatively mild conditions in a slurry phase with a catalyst combination comprising reduced copper chromite and basic alkali salts or alkaline earth salts. The present invention allows the synthesis of methanol to occur in the temperature range of approximately 100.degree.-160.degree. C. and the pressure range of 40-65 atm. The process produces methanol with up to 90% syngas conversion per pass and up to 95% methanol selectivity. The only major by-product is a small amount of easily separated methyl formate. Very small amounts of water, carbon dioxide and dimethyl ether are also produced. The present catalyst combination also is capable of tolerating fluctuations in the H.sub.2 /CO ratio without major deleterious effect on the reaction rate. Furthermore, carbon dioxide and water are also tolerated without substantial catalyst deactivation.
    Type: Grant
    Filed: March 26, 1991
    Date of Patent: June 22, 1993
    Assignee: The University of Pittsburgh
    Inventors: John W. Tierney, Irving Wender, Vishwesh M. Palekar
  • Patent number: 5221657
    Abstract: A process for producing the precursor of a precipitated catalyst for the sub.3 synthesis, based on Fe, Al, Co and K oxides, which comprises the steps of:(A) preparing an aqueous solution of water-soluble compounds of Fe, Al and Co--adding iron as a water-soluble ferrous salt of an organic acid--and causing, by addition of an alkaline precipitating solution, the co-precipitation of the corresponding (Fe, Al and Co) hydroxides, which still contain iron in the ferrous form;(B) oxidizing the hydroxide suspension prepared according to point (A) until divalent iron and trivalent iron are in a ratio to each other which ranges from 0.20 to 0.50;(C) operating an alkaline doping with a potassium compound and heating in an inert atmosphere up to above 850.degree. C.
    Type: Grant
    Filed: May 29, 1991
    Date of Patent: June 22, 1993
    Assignee: Ministero dell'Universita' e della Ricerca Scientifica e Tecnologica
    Inventors: Franco Montino, Luigi Balducci, Francesco Ferrero, Nicola Pernicone
  • Patent number: 5221653
    Abstract: Coated catalyst particulates, well adopted for the oxidation of olefins into .alpha.,.beta.-unsaturated aldehydes, e.g., for the oxidation of propylene into acrolein, and the coating layer of which comprising a catalytically active phase including a catalytically effective amount of bismuth and iron molybdate and dopant amounts of phosphorus and potassium, are prepared by providing a calcined and ground catalytically active intermediate composition devoid of phosphorus and potassium values, coating this intermediate composition onto a particulate support substrate comprising rough-surfaced inert and solid spheres, also coating phosphorus and potassium values onto the particulate support substrate, and then calcining the support particulates thus coated.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: June 22, 1993
    Assignee: Rhone-Poulenc Chimie
    Inventors: Philippe Jaeger, Olivier Legendre
  • Patent number: 5221656
    Abstract: A hydroprocessing catalyst and process of using such catalyst wherein such catalyst has at least one hydrogenation metal deposited on an inorganic oxide support and is further characterized by a surface area of greater than about 220 m.sup.2 /g, a pore volume of about 0.23-0.30 cc/g in pores greater than about 600 Angstroms radius, an average pore radius of about 30-70 Angstroms in pores less than 600 Angstroms, and an incremental pore volume curve with a maximum at about 25-50 Angstroms radius.
    Type: Grant
    Filed: March 25, 1992
    Date of Patent: June 22, 1993
    Assignee: Amoco Corporation
    Inventors: Frederick T. Clark, Albert L. Hensley, Jr., Simon G. Kukes, David C. Arters
  • Patent number: 5219816
    Abstract: A supported catalyst and a method of making a supported catalyst useful in the dehydrogenation of light paraffins. This catalyst comprises 0.3 to 5 wt. % Ga and 0.1 to 5 wt. % Pt on a spinel type support material characterized by the formula Mg.sub.x Al.sub.2 O.sub.3+x where x is a number from about 0.1 to 1.1. The improvement comprises the incorporation of a water soluble Mg salt into said support prior to the impregnation of Pt and Ga.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: June 15, 1993
    Assignee: Exxon Research & Engineering Company
    Inventors: Ying Zhou, Stephen M. Davis
  • Patent number: 5219818
    Abstract: Peanut hulls are processed into dust free granules suitable for use as chemical carriers and moisture absorbent materials by being pulverized to a powder. This is done by milling the hulls through a screen having interstices no larger than 3/32 inch. The powder is then compacted into compact masses that are divided into granules and screened.
    Type: Grant
    Filed: June 22, 1992
    Date of Patent: June 15, 1993
    Assignee: Bio-Plus, Inc.
    Inventor: Stephen L. Ivie
  • Patent number: 5219486
    Abstract: Automatic dishwasher detergent composition is formulated as a linear viscoelastic, pseudoplastic, gel-like aqueous product of exceptionally good physical stability, low bottle residue, low cup leakage, and improved cleaning performance, Linear viscoelasticity and pseudoplastic behavior is attributed by incorporation of cross-linked high molecular weight polyacrylic acid type thickener. Potassium to sodium weight ratios of at least 1/1 minimize amount of undissolved solid particles to further contribute to stability and pourability. Control of incorporated air bubbles functions to provide the product with a bulk density of about 1.26 to 1.40 g/cc which roughly corresponds to the density of the liquid phase. Stearic acid or other fatty acid or salt further improve physical stability.
    Type: Grant
    Filed: November 8, 1991
    Date of Patent: June 15, 1993
    Assignee: Colgate Palmolive Company
    Inventors: Fahim U. Ahmed, Makarand Shevade
  • Patent number: 5219495
    Abstract: A liquid detergent composition containing anionic detergent, nonionic detergent, excess caustic and high amounts of water is disclosed, together with processes for its preparation and use.
    Type: Grant
    Filed: December 16, 1991
    Date of Patent: June 15, 1993
    Assignee: Lever Brothers Company, Division of Conopco, Inc.
    Inventor: Feng-Lung G. Hsu
  • Patent number: 5219815
    Abstract: This invention relates to electroless nickel plating of metals which are normally noncatalytic for electroless nickel initiation. It is especially useful in the electronics industry, such as for production of electroless nickel/electroless gold tabs or surface mount pads on printed circuit boards, and for use in electroless nickel plating over copper for radiofrequency interference shielding. More particularly, it comprises ammonium halide salt solutions of a palladium salt with another Group VIII precious metal salt and acid and optionally an alkali halide salt for effectively and completely catalyzing the initiation of electroless nickel plating on copper substrates.
    Type: Grant
    Filed: September 23, 1991
    Date of Patent: June 15, 1993
    Assignee: Applied Electroless Concepts Inc.
    Inventors: Gerald A. Krulik, Nenad V. Mandich
  • Patent number: 5217937
    Abstract: An SiO.sub.2 -containing copper oxide-chromium oxide catalyst is obtained through heat treatment of copper oxide and chromium oxide, or of a precursor compound convertible into copper oxide or chromium oxide in the presence of an SiO.sub.2 component; it is characterized by the fact that, after the heat treatment,(a) the intensity ratio between the X-ray diffraction lines (XRD reflexes) of the copper oxide with d=0.232 nm and of the CuCr.sub.2 O.sub.4 spinel with d=0.240 nm formed through heat treatment, determined as the ratio of the reflex amplitudes, is 0.7 to 4.0:1, and(b) the copper mass, which is dissolved by stirring 10 g of the catalyst in 100 ml of 10 weight percent acetic acid at 20.degree. C. for 2 minutes, amounts to a maximum of 200 mg.
    Type: Grant
    Filed: November 21, 1991
    Date of Patent: June 8, 1993
    Assignee: Sud-Chemie Aktiengesellschaft
    Inventors: Michael Schneider, Gerd Maletz, Karl Kochloefl
  • Patent number: 5217940
    Abstract: High-strength alumina substrates and catalysts with predetermined pore structures having a sulfonated polyamine product incorporated therein, raw batch mixes and a process for making the same are disclosed.
    Type: Grant
    Filed: September 19, 1989
    Date of Patent: June 8, 1993
    Inventors: Ma'mum A. Halabi, Anthony Stanislaus, Huda Al-Zaid
  • Patent number: 5217938
    Abstract: A zirconia-based catalyst is prepared by mulling a mixture of a zirconia source and a solvent, which mixture has a solids content of from 20% by weight to 60% by weight, and extruding the mixture.
    Type: Grant
    Filed: April 21, 1992
    Date of Patent: June 8, 1993
    Assignee: Shell Oil Company
    Inventors: Donald Reinalda, Paul Blankenstein
  • Patent number: 5217939
    Abstract: Reticulated ceramic or metal substrate coated with Cobalt compounds, noble metals or mixtures thereof are superior catalysts for the oxidation of ammonia to produce nitric oxide.
    Type: Grant
    Filed: May 11, 1992
    Date of Patent: June 8, 1993
    Assignee: Scientific Design Company, Inc.
    Inventor: Larry E. Campbell