Abstract: A catalyst system for attaining high conversions of NO, HC, and CO in a fuel-lean emission flow (i.e., containing SO.sub.2, H.sub.2 O, H.sub.2, and considerable excess oxygen), the system comprising: (a) a first stage reducing catalyst for treating the nitric oxide emissions, the catalyst containing highly acidic gamma alumina (i.e., with a pH.sub.pzc of less than 3); (b) means for injecting gaseous or liquid reductants into the emission stream prior to entering said first stage catalyst, said first stage catalyst temperature being selected to be in the range of 550.degree.-650.degree. C.; and (c) an oxidation catalyst effective for treating the effluent from the first stage catalyst.Another aspect of this invention is a method of treating the exhaust gas from a fuel-lean emission flow from a fossil-fueled internal combustion engine having a redox ratio of 0.02-0.

Abstract: There is provided a Diesel engine exhaust gas-purifying catalyst which comprises (1) a catalytic component comprising titania having dispersed and deposited thereon at least one noble metal selected from palladium, platinum and rhodium, and (2) a refractory three dimensional structure as a carrier. This catalyst is excellent in the performance of removal by combustion at low temperature of harmful components such as uncalcined hydrocarbons and carbon monoxide in addition to carbonic fine particles, and moreover has only low ability to oxide sulfur dioxide, whereby formation of sulfates can be inhibited.

Abstract: Alkylene oxide adducts of organic compounds having active hydrogen atoms are prepared by a process which comprises contacting and reacting an alkylene oxide reactant comprising one or more vicinal alkylene oxides with an active hydrogen containing reactant comprising one or more compounds having active hydrogen atoms in the presence of a catalytically effective amount of a xerogel comprising one or more compounds comprising a rare earth element and phosphorus. The product alkoxylates are known to be useful, for instance, as nonionic surfactants, wetting and emulsifying agents, solvents, and chemical intermediates.

Abstract: Acid-resistant copper oxide-chromium oxide catalysts for hydrogenation of fatty acids or fatty acid mixtures and/or the esters thereof are obtained through heat treatment of copper oxide and chromium oxide or of precursor compounds that are convertible into copper oxide or chromium oxide and which contain aluminum zirconium, cerium and/or lanthanum oxide as an additional metal component. The acid resistance is defined by the fact that the amount of copper which is dissolved by stirring 10 g of the catalyst for 2 minutes in 100 ml of 10 weight percent acetic acid at 20.degree. C., is a maximum of 200 mg.

Abstract: A catalyst for the production of a substituted benzaldehyde by catalytic vapor-phase oxidation of a substituted toluene, which catalyst has as a catalytically active substance being composed of an oxide represented by the general formula III:V.sub.a Mo.sub.b X.sub.c Y.sub.d O.sub.e (III)wherein V, Mo, and O are respectively for vanadium, molybdenum, and oxygen, X is at least one element selected from the group consisting of sodium, potassium, rubidium, cesium, and thallium, Y is at least one element selected from the group consisting of niobium, tantalum, phosphorus, antimony, bismuth, tellurium, tin, lead, boron, copper, and silver, and a, b, c, d, and e indicate the atomic ratios of relevant elements such that where a+b=1, then b=0.05 to 0.4, c=0.1 to 1, d=0 to 1, and e=the value determined by the state of oxidation of other elements.

Abstract: The present invention features a process, and a product formed by the process, wherein a catalyst device is fabricated in situ. Metal powders, metal alloy powders and mixtures thereof are introduced to a substrate, by means of a washcoat suspension. After the suspension is applied, the metals are transformed into active catalyst and catalyst support materials. The process comprises the steps of: (a) introducing to a substrate, metal powders, metal alloy powders and mixtures thereof, having particles in average diameter sizes of approximately between 5 and 50 microns; and (b) transforming in situ the particles of the metals and metal alloys and mixtures thereof, whereby the metals, metal alloys and mixtures thereof are converted into active catalyst and catalyst support materials having sub-micron average diameter sizes.

Abstract: An anionically stabilized lithium catalyst wherein the anion is sulfate, phosphate, aluminate, silicate and mixtures thereof. The anionically stabilized lithium catalyst may be supported on a metal oxide support of magnesium oxide, titanium oxide, zinc oxide, calcium oxide, barium oxide, strontium oxide, zirconium oxide, hafnium oxide, yttrium oxide, lanthanum oxide, samarium oxide, and mixtures thereof or when aluminate or silicate is used as the anion the aluminate or silicate may act as the support. The catalyst may be used to promote reactions at temperatures higher than prior lithium catalysts, particularly higher than about 600.degree. C., such as oxidative coupling of aliphatic and alicyclic hydrocarbons to produce higher molecular weight compounds and oxydehydrogenation of aliphatic and alicyclic hydrocarbons to produce unsaturated hydrocarbons or to change the functional group of the hydrocarbon.

Abstract: A catalyst for neutralizing vapors and aerosols of organic compounds, carbon monoxide, and a variety of other oxidizable materials from an exhaust which contains oxygen. The catalyst has a carrier made either from titanium dioxide and aluminum oxide or from magnesium-aluminum spinel modified with titanium dioxide. The catalyst has a surface film of active components which include copper oxide and copper chromite (or their nickel or cobalt analog) chemically integrated into the carrier surface by Cu-o-Ti and Cr-O-Ti chains (or their nickel or cobalt analog). The catalyst should comprise from about 0.1% to about 15% by weight of copper oxide (CuO), chromium oxide (Cr.sub.2 O.sub.3), or mixtures of those compounds; from about 5% to about 25% by weight of copper chromite (CuCr.sub.2 O.sub.4); from about 3% to about 25% by weight titanium dioxide (TiO.sub.2); and from about 60% to about 90% by weight of aluminum oxide (Al.sub.2 O.sub.3), magnesium/aluminum spinel (MgAl.sub.2 O.sub.

Abstract: A catalyst composition comprising a refractory support having deposited thereon an active layer containing a platinum group metal component comprising an alumina component having the platinum group metals rhodium and palladium dispersed thereon, a cerium compound, a strontium compound, and a zirconium compound.

Abstract: An aqueous alkaline cleaner and a process are described for reducing the discoloration of aluminum surfaces treated with are aqueous alkaline cleaner compositions. The process comprises including in the aqueous cleaner composition, an effective amount of at least one heterocyclic compound. Enhanced mobility of the aluminum surfaces also can be obtained when the heterocyclic compound is a solid particulate compound which is mixed with an oil prior to addition to the aqueous alkaline cleaner. In a preferred embodiment, the heterocyclic compounds are soluble pyrroles, imidazoles, pyrazoles, thiazoles or triazoles.

Abstract: Method for the production of catalytically active mixed phases in powder form from precursors which contain the elements of the mixed phase and are treated thermally and mechanically.The precursor or precursors contained in a solution or suspension are applied to heated surfaces of moving heat carrying bodies and precipitated and dissociated on them with evaporation of the solvent or of the liquid component of the suspension. The mixed phase formed on the heat carrying bodies is removed from the heat carrying bodies and then, to prepare it for further use, it is crushed.

Abstract: This invention relates to a purifying-catalyst for exhaust gas emitted from internal combustion engines such as automobiles, and the object is to provide a catalyst which exhibits excellent exhaust gas purification performance at lower temperature compared to usual catalysts, even after high temperature aging, and a process for preparation thereof.

Abstract: A catalyst composition and process for using said catalyst is disclosed wherein the catalyst comprises 0.24 to 0.26 weight percent platinum and 0.48 to 0.52 weight percent rhenium disposed on an alumina spheroidal carrier.

Abstract: A catalyst for the selective reduction of nitrous oxide with ammonia contains, in addition to titanium oxide as component (A), at least one oxide of W, Si, B, Al, P, Zr, Ba, Y, La, Ce and at least one oxide of V, Nb, Mo, Fe, Cu as component (B), whereby the atomic ratio between the elements of components (A) and (B) amounts to 1:0.001 up to 1. The catalyst can be obtained by kneading reactive titanium oxide with a high specific surface of predominantly anatase with the substances of component (B) or their preliminary stages, adding processing agents, winding up with a homogeneous kneaded mass, extruding the latter, drying the extrudate and calcining in air at 300.degree.-800.degree. C.

Abstract: Dry-blended detergent formulations are prepared by absorbing liquid surfactant on absorptive soda ash derived from the dehydration of sodium carbonate decahydrate.

Abstract: A catalyst for the removal or elimination of hydrogen from an atmosphere containing hydrogen, oxygen and steam. The catalyst consists of a metal or a corresponding alloy which influences the oxidation of the hydrogen, and which is applied onto a substrate material as a catalyst layer. The catalyst layer is applied onto the substrate which is formed from plate or sheet metal, fabric, mesh or granulate and consists of a support material which will regard to its expansion under a temperature change is compatible with the catalyst layer and is corrosion-resistance of the substrate material prevents the oxidation thereof in the presence of steam.

Abstract: To recover the antimony contained in a solution of use antimony-containing catalyst, emananting from units for the fluorination or chlorofluorination of halogenated hydrocarbons comprising at least two carbon atoms, the solution is concentrated to the limit of distillation of antimony trichloride, an excess of chlorine is then added to convert SbCl.sub.3 to SbCl.sub.5, and SbCl.sub.5 is distilled under reduced pressure without exceeding 120.degree. C.The recoverd antimony pentachloride is sufficiently pure to be able to be recycled directly to the fluorination reactor.

Abstract: H.sub.2 S formation by three-way catalyst is suppressed by incorporating nickel, manganese or iron oxides into an undercoat layer disposed on a substrate, such as a monolith substrate. A topcoat overlying the undercoat is comprised of a three-way catalyst material which includes one or more of platinum, rhodium and palladium as catalytic metals.

Abstract: A process is provided for the alkylation of aromatic substrates with a C.sub.2 -C.sub.4 alkylating agent over an alkylation catalyst comprising zeolite omega at moderate temperature and pressure conditions to provide liquid phase conditions.The liquid phase alkylation process is carried out using a plurality of series connected reaction stages operated at an average temperature of no more than 300.degree. C. with the interstage injection of the C.sub.2 -C.sub.4 alkylating agent in a manner to maintain at least 2 mole percent of alkylating agent solubilized in the aromatic substrate.The reaction stages of a multistage system are operated at a pressure above the vapor pressure of the aromatic substrate and below the vapor pressure of the alkylating agent at the alkylation reaction conditions. The aromatic substrate and the alkylating agent are supplied to a first of the reaction stages in relative amouns to provide a first mole ratio of aromatic substrate to alkylating agent.

Abstract: An improved non-viscous aqueous dust control solution which includes a polyvinyl alcohol and boric acid. The improved solution may be spray applied or applied as a foam. The solution may include cross-linking agents, extenders, plasticizers or surfactants.