Abstract: Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein functional aliphatic and/or aromatic amine compounds or derivatives are used as electrolyte additives to reduce gas generation in Li-ion batteries.

Abstract: Systems and methods for silosilazanes, silosiloxanes, and siloxanes as additives for silicon-dominant anodes in a battery that may include a cathode, an electrolyte, and an anode active material. The active material may comprise 50% or more silicon as well as an additive including one or more of: silosilazane, polysilosilazane, silicon oxycarbides, and polyorganosiloxane. The active material may comprise a film with a thickness between 10 and 80 microns. The film may have a conductivity of 1 S/cm or more. The active material may comprise between 50% and 95% silicon. The active material may be held together by a pyrolyzed carbon film. The anode may comprise lithium, sodium, potassium, silicon, and/or mixtures and combinations thereof. The battery may comprise a lithium ion battery. The electrolyte may comprise a liquid, solid, or gel.

Abstract: Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein the anode is a Si-dominant anode that utilizes water-soluble maleic anhydride- and/or maleic acid-containing polymers/co-polymers, derivatives, and/or combinations (with or without additives) as binders.

Abstract: Systems and methods for collocated gasoline pumps and electric vehicle charging stations for ultra-high speed charging may include a fuel station having fuel pumps, electric vehicle supply equipment, and a charge buffer. The charge buffer may receive electric current from an electricity supply grid and supply current to the electric vehicle supply equipment. The electric vehicle supply equipment may charge batteries at a rate greater than 4 C, 5.6 C, or 10 C. The electric vehicle supply equipment may be configured to charge batteries with silicon-dominant anodes including active material of 50% or more silicon. The charge buffer may be located in an underground former fuel tank. The electric vehicle supply equipment may supply greater than 120 kW. The charge buffer may include an array of capacitors and/or an array of batteries. The electric vehicle supply equipment may be configured to apply a voltage to batteries above their battery voltage limit when charging.

Abstract: A method for periodic deep discharge to extract lithium in silicon-dominant anodes may include providing a cell comprising a cathode, a separator, and a silicon-dominant anode; charging and discharging the cell through a plurality of cycles; and, following the plurality of cycles, performing one or more deep discharge cycles, where each of the one or more deep discharge cycles comprises a cutoff voltage below a normal operating voltage range of the cell. The one or more deep discharge cycles may comprise a C/10 or lower or C/20 or lower discharge current. The one or more deep discharge cycles may include a cutoff voltage of 3.2 V or less, a cutoff voltage of 2.5 V or less, a cutoff voltage of 1.5 V or less, or a cutoff voltage of 1 V or less. The cell may be configured at a higher temperature during the one or more deep discharge cycles.

Abstract: Systems and methods for water soluble weak acidic resins as carbon precursors for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and pyrolyzed water-soluble acidic polyamide imide as a primary resin carbon precursor. The electrode coating layer may include a pyrolyzed water-based acidic polymer solution additive. The polymer solution additive may include one or more of: polyacrylic acid (PAA) solution, poly (maleic acid, methyl methacrylate/methacrylic acid, butadiene/maleic acid) solutions, and water soluble polyacrylic acid. The electrode coating layer may include conductive additives. The current collector may include a metal foil, where the metal current collector includes one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer may be more than 70% silicon.

Abstract: Systems and methods for sulfur-containing chemicals as cathode additives for silicon-based lithium ion batteries may include a silicon-based anode, an electrolyte, and a cathode. The cathode may include an active material and a sulfur-containing additive. The cathode active material may include one or more of nickel cobalt aluminum oxide (NCA), nickel cobalt manganese oxide (NCM), lithium iron phosphate (LFP), lithium cobalt oxide (LCO), and lithium manganese oxide (LMO). The sulfur-containing additive may include elemental sulfur and/or Li2S. The sulfur-containing additive may include one or more of lithium polysulfides (Li2Sn, where n=2-8), polysulfides, and organic polysulfides. The sulfur-containing additive may include one or more of metal sulfides, transition metal polysulfide complexes, S-containing organic polymers or copolymer, polymeric sulfur, and transition metal sulfides.

Abstract: Systems and methods for batteries comprising a cathode, an electrolyte, and an anode, wherein functional aliphatic and/or aromatic amine compounds or derivatives are used as electrolyte additives to reduce gas generation in Li-ion batteries.

Abstract: Systems and methods are provided for synthesizing solid-state polymer electrolyte and/or using solid-state polymer electrolyte in production of all-solid-state alkali-ion batteries.

Abstract: A method and system for carbon-coated silicon in a pyrolyzed carbon binder electrode on copper current collectors may include providing a metal current collector; forming a non-porous carbon coating on the metal current collector; coating silicon particles with carbon; forming an active material layer on the metal current collector, where the active material layer comprises at least 50% silicon particles by weight and a carbon source; and pyrolyzing the active material layer on the metal current collector, with no silicon particles in contact with metal from the metal current collector. The metal current collector may include copper. The battery anode may include no copper-silicon eutectic. The silicon particles may range in size from 2 to 50 ?m. The active material layer may include aluminum carbide. A source for the pyrolyzed carbon may include polyimide and/or polyamide-imide. The current collector may be coated with the non-porous carbon coating using physical vapor deposition.

Abstract: Systems and methods for all-conductive battery electrodes may include an electrode coating layer on a current collector, where the electrode coating layer comprises more than 50% silicon, and where each material in the electrode has a resistivity of less than 100 ?-cm. The silicon may have a resistivity of less than 10 ?-cm, less than 1 ?-cm, or less than 1 m?-cm. The electrode coating layer may comprise pyrolyzed carbon and/or conductive additives. The current collector comprises a metal foil. The metal current collector may comprise one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer comprises more than 70% silicon. The electrode may be in electrical and physical contact with an electrolyte. The electrolyte may comprise a liquid, solid, or gel. The battery electrode may be in a lithium ion battery.

Abstract: Systems and methods are provided for high volume roll-to-roll direct coating of electrodes for silicon-dominant anode cells. A system for continuous roll-to-roll electrode processing may include one or more components configured for receiving a plurality of precursor composite rolls, with each precursor composite roll including a precursor composite film coated on a current collector, and a heat treatment oven configured for applying heat treatment concurrently to the plurality of precursor composite rolls, to convert the precursor composite film in each precursor composite roll into a pyrolyzed composite film on the current collector. The system is configured for processing the plurality of precursor composite rolls in a continuous manner.

Abstract: A method of managing battery performance may include obtaining, via a measurement device, measurements of one or more parameters relating to one or more cells; generating or updating, based on the measurements, a machine learning model; and generating, using the machine learning model, cell performance prediction data for use in managing at least one cell. Each cell includes a cathode, a separator, and a silicon-dominant anode. The measurements of the one or more parameters correspond to a plurality of different types of data. The measurements include one or more of: measurements of cells or cell components before formation or cycling, measurements from formation cycles for one or more cells, measurements from a number of cycles after formation for one or more cells, and measurements of characteristics of cell components prior to cell assembly.

Abstract: Systems and methods for silicon dominant lithium-ion cells with controlled lithiation of silicon may include a cathode, an electrolyte, and an anode. The anode may include silicon lithiated at a level after discharge that is configured to be above a minimum threshold level, where the minimum threshold lithiation is 3% silicon lithiation. The lithiation level of the silicon after charging the battery may range between 30% and 95% silicon lithiation, between 30% and 75% silicon lithiation, between 30% and 65% silicon lithiation, or between 30% and 50% silicon lithiation. The lithiation level of the silicon after discharging the battery may range between 3% and 50% silicon lithiation, between 3% and 30% silicon lithiation, or between 3% and 10% silicon lithiation. The minimum threshold level may be a lithiation level below which a cycle life of the battery degrades. The electrolyte may include a liquid, solid, or gel.

Abstract: Systems and methods for all-conductive battery electrodes may include an electrode coating layer on a current collector, where the electrode coating layer comprises more than 50% silicon, and where each material in the electrode has a resistivity of less than 100 ?-cm. The silicon may have a resistivity of less than 10 ?-cm, less than 1 ?-cm, or less than 1 m?-cm. The electrode coating layer may comprise pyrolyzed carbon and/or conductive additives. The current collector comprises a metal foil. The metal current collector may comprise one or more of a copper, tungsten, stainless steel, and nickel foil in electrical contact with the electrode coating layer. The electrode coating layer comprises more than 70% silicon. The electrode may be in electrical and physical contact with an electrolyte. The electrolyte may comprise a liquid, solid, or gel. The battery electrode may be in a lithium ion battery.

Abstract: Systems and methods for water soluble weak acidic resins as carbon precursors for silicon-dominant anodes may include an electrode coating layer on a current collector, where the electrode coating layer is formed from silicon and a primary resin carbon precursor; wherein the primary resin carbon precursor comprises a water-soluble acidic polyamide imide functionalized with acidic groups and one or more polymeric stabilizing additives. The electrode coating layer may also include a base and/or a surfactant. The electrode coating layer may be more than 70% silicon.

Abstract: Systems and methods are provided for forming of batteries using carbon compositions as conductive additives for dense and conductive cathodes. An example battery may include an anode, an electrolyte, and a cathode including an active material, with the active material including 0D conductive carbon particles with nanoscale structure in three dimensions, and 1D conductive carbon particles with nanoscale structure in two dimensions. A ratio of the 1D conductive carbon particles to the 0D conductive carbon particles in the active material may be between 0.5 and 2. For example, the ratio of the 1D conductive carbon particles to the 0D conductive carbon particles may be approximately 1. The 1D carbon particles have a diameter of less than 120 nm, a surface area of 30 m2/g, and/or a dispersive surface energy of more than 180 mJ/m2. The 0D and 1D particles may comprise between 1% and 10% of the active material.

Abstract: Systems and methods are provided for control of furnace atmosphere for improving capacity retention of silicon-dominant anode cells. Furnace atmosphere may be controlled during processing of a silicon-dominated electrode in a furnace, with the processing including pyrolysis of the silicon-dominated electrode, and the controlling including setting or adjusting one or more of pressure of the furnace atmosphere, and composition of the furnace atmosphere. The controlling of the furnace atmosphere may be configured based on at least one environment condition. The at least one environment condition may be an oxygen-free environment.

Abstract: Systems and methods for high speed formation of cells for configuring anisotropic expansion of silicon-dominant anodes may include a cathode, an electrolyte, and an anode, where the anode may include a current collector and an active material on the current collector. An expansion of the anode may be configured by a charge rate during formation of the battery. The expansion of the anode may be less than 1.5% in lateral dimensions of the anode for higher charge rates during formation with the active material being more than 50% silicon, where the higher charge rate may be 1 C or higher, and perpendicular expansion may be higher for charge rates below 1 C during formation. The expansion of the anode may be lower in lateral dimensions for thicker current collectors, which may be 10 ?m or thicker, and may be lower in lateral dimensions for more rigid materials for the current collector.

Abstract: Systems and methods for use of perforated anodes in silicon-dominant anode cells may include a cathode, an electrolyte, and an anode, where the cathode and anode each comprise an active material on a current collector. Both of the current collector and active material may be perforated. For example, the current collector may be perforated and/or both the current collector and active material may be perforated. The battery may comprise a stack of anodes and cathodes. Each cathode of the stack may be perforated and/or each anode of the stack may be perforated. Each cathode of the stack may comprise two layers of active material on each side of the cathode where a first of the two layers of active material may be for prelithiation of anodes of the battery. A second of the two layers may be for lithium cycling of the battery.