Abstract: A surface of a semiconductor-containing dielectric material/oxynitride/nitride is treated with a basic solution in order to provide hydroxyl group termination of the surface. A dielectric metal oxide is subsequently deposited by atomic layer deposition. The hydroxyl group termination provides a uniform surface condition that facilitates nucleation and deposition of the dielectric metal oxide, and reduces interfacial defects between the oxide and the dielectric metal oxide. Further, treatment with the basic solution removes more oxide from a surface of a silicon germanium alloy with a greater atomic concentration of germanium, thereby reducing a differential in the total thickness of the combination of the oxide and the dielectric metal oxide across surfaces with different germanium concentrations.

Abstract: A method of forming a gate structure for a semiconductor device that includes forming a non-stoichiometric high-k gate dielectric layer on a semiconductor substrate, wherein an oxide containing interfacial layer can be present between the non-stoichiometric high-k gate dielectric layer and the semiconductor substrate. At least one gate conductor layer may be formed on the non-stoichiometric high-k gate dielectric layer. The at least one gate conductor layer comprises a boron semiconductor alloy layer. An anneal process is applied, wherein during the anneal process the non-stoichiometric high-k gate dielectric layer removes oxide material from the oxide containing interfacial layer. The oxide containing interfacial layer is thinned by removing the oxide material during the anneal process.

Abstract: A semiconductor structure includes a high mobility semiconductor, an interfacial oxide layer, a high dielectric constant (high-k) layer, a stack, a gate electrode, and a gate dielectric. The stack comprises a lower metal layer, a scavenging metal layer comprising a scavenging metal, and an upper metal layer formed on the scavenging metal layer. A Gibbs free energy change of a chemical reaction, in which an atom constituting the high mobility semiconductor layer that directly contacts the interfacial oxide layer combines with a metal oxide material comprising the scavenging metal and oxygen to form the scavenging metal in elemental form and oxide of the atom constituting the high mobility semiconductor layer that directly contacts the interfacial oxide layer, is positive.

Abstract: A method of forming a gate structure for a semiconductor device that includes forming a non-stoichiometric high-k gate dielectric layer on a semiconductor substrate, wherein an oxide containing interfacial layer can be present between the non-stoichiometric high-k gate dielectric layer and the semiconductor substrate. At least one gate conductor layer may be formed on the non-stoichiometric high-k gate dielectric layer. The at least one gate conductor layer comprises a boron semiconductor alloy layer. An anneal process is applied, wherein during the anneal process the non-stoichiometric high-k gate dielectric layer removes oxide material from the oxide containing interfacial layer. The oxide containing interfacial layer is thinned by removing the oxide material during the anneal process.

Abstract: A method of forming a gate structure for a semiconductor device that includes forming a non-stoichiometric high-k gate dielectric layer on a semiconductor substrate, wherein an oxide containing interfacial layer can be present between the non-stoichiometric high-k gate dielectric layer and the semiconductor substrate. At least one gate conductor layer may be formed on the non-stoichiometric high-k gate dielectric layer. The at least one gate conductor layer comprises a boron semiconductor alloy layer. An anneal process is applied, wherein during the anneal process the non-stoichiometric high-k gate dielectric layer removes oxide material from the oxide containing interfacial layer. The oxide containing interfacial layer is thinned by removing the oxide material during the anneal process.

Abstract: A semiconductor device including a gate structure present on a channel portion of a semiconductor substrate and at least one gate sidewall spacer adjacent to the gate structure. In one embodiment, the gate structure includes a work function metal layer present on a gate dielectric layer, a metal semiconductor alloy layer present on a work function metal layer, and a dielectric capping layer present on the metal semiconductor alloy layer. The at least one gate sidewall spacer and the dielectric capping layer may encapsulate the metal semiconductor alloy layer within the gate structure.

Abstract: A limited number of cycles of atomic layer deposition (ALD) of Hi-K material followed by deposition of an interlayer dielectric and application of further Hi-K material and optional but preferred annealing provides increased Hi-K material content and increased breakdown voltage for input/output (I/O) transistors compared with logic transistors formed on the same chip or wafer while providing scalability of the inversion layer of the I/O and logic transistors without significantly compromising performance or bias temperature instability (BTI) parameters.

Abstract: A method of forming a semiconductor device that includes forming a high-k gate dielectric layer on a semiconductor substrate, wherein an oxide containing interfacial layer can be present between the high-k gate dielectric layer and the semiconductor substrate. A scavenging metal stack may be formed on the high-k gate dielectric layer. An annealing process may be applied to the scavenging metal stack during which the scavenging metal stack removes oxide material from the oxide containing interfacial layer, wherein the oxide containing interfacial layer is thinned by removing of the oxide material. A gate conductor layer is formed on the high-k gate dielectric layer. The gate conductor layer and the high-k gate dielectric layer are then patterned to provide a gate structure. A source region and a drain region are then formed on opposing sides of the gate structure.

Abstract: A method of forming a semiconductor device that includes forming a high-k gate dielectric layer on a semiconductor substrate, wherein an oxide containing interfacial layer can be present between the high-k gate dielectric layer and the semiconductor substrate. A scavenging metal stack may be formed on the high-k gate dielectric layer. An annealing process may be applied to the scavenging metal stack during which the scavenging metal stack removes oxide material from the oxide containing interfacial layer, wherein the oxide containing interfacial layer is thinned by removing of the oxide material. A gate conductor layer is formed on the high-k gate dielectric layer. The gate conductor layer and the high-k gate dielectric layer are then patterned to provide a gate structure. A source region and a drain region are then formed on opposing sides of the gate structure.

Abstract: Ion implantation to change an effective work function for dual work function metal gate integration is presented. One method may include forming a high dielectric constant (high-k) layer over a first-type field effect transistor (FET) region and a second-type FET region; forming a metal layer having a first effective work function compatible for a first-type FET over the first-type FET region and the second-type FET region; and changing the first effective work function to a second, different effective work function over the second-type FET region by implanting a species into the metal layer over the second-type FET region.

Abstract: A gate dielectric as formed includes a first interfacial dielectric layer and a high dielectric constant (high-k) dielectric layer containing a dielectric metal oxide. A polycrystalline semiconductor material layer is deposited on the high-k dielectric layer, and a second interfacial dielectric layer is formed at an interface between the polycrystalline semiconductor material layer and the high-k dielectric layer. A scavenging-metal-containing layer including a scavenging metal in an elemental form or in a metallic non-metal-element-containing compound is formed over the polycrystalline semiconductor material layer. A metallic compound such as a metallic nitride and a metallic carbide may be present above and/or over the scavenging-metal-containing layer. After formation of a gate stack by patterning, an anneal is performed, during which the oxygen in the interfacial dielectric layers diffuses into the scavenging-metal containing layer so that the thicknesses of the interfacial layers are reduced.

Abstract: Ferroelectric semiconductor switching devices are provided, including field effect transistor (FET) devices having gate stack structures formed with a ferroelectric layer disposed between a gate contact and a thin conductive layer (“quantum conductive layer”). The gate contact and ferroelectric layer serve to modulate an effective work function of the thin conductive layer. The thin conductive layer with the modulated work function is coupled to a semiconductor channel layer to modulate current flow through the semiconductor and achieve a steep sub-threshold slope.

Abstract: A gate dielectric as formed includes a first interfacial dielectric layer and a high dielectric constant (high-k) dielectric layer containing a dielectric metal oxide. A polycrystalline semiconductor material layer is deposited on the high-k dielectric layer, and a second interfacial dielectric layer is formed at an interface between the polycrystalline semiconductor material layer and the high-k dielectric layer. A scavenging-metal-containing layer including a scavenging metal in an elemental form or in a metallic non-metal-element-containing compound is formed over the polycrystalline semiconductor material layer. A metallic compound such as a metallic nitride and a metallic carbide may be present above and/or over the scavenging-metal-containing layer. After formation of a gate stack by patterning, an anneal is performed, during which the oxygen in the interfacial dielectric layers diffuses into the scavenging-metal containing layer so that the thicknesses of the interfacial layers are reduced.

Abstract: Ion implantation to change an effective work function for dual work function metal gate integration is presented. One method may include forming a high dielectric constant (high-k) layer over a first-type field effect transistor (FET) region and a second-type FET region; forming a metal layer having a first effective work function compatible for a first-type FET over the first-type FET region and the second-type FET region; and changing the first effective work function to a second, different effective work function over the second-type FET region by implanting a species into the metal layer over the second-type FET region.

Abstract: A method for fabricating a field effect transistor device includes patterning a fin on substrate, patterning a gate stack over a portion of the fin and a portion of an insulator layer arranged on the substrate, forming a protective barrier over the gate stack, a portion of the fin and a portion of the insulator layer, the protective barrier enveloping the gate stack, depositing a second insulator layer over portions of the fin and the protective barrier, performing a first etching process to selectively remove portions of the second insulator layer to define cavities that expose portions of source and drain regions of the fin without appreciably removing the protective barrier, and depositing a conductive material in the cavities.

Abstract: A semiconductor device includes a first field effect transistor (FET) and a second FET located on a substrate, the first FET comprising a first interfacial oxide layer, and the second FET comprising a second interfacial oxide layer, wherein the second interfacial oxide layer of the second FET is thicker than the first interfacial oxide layer of the first FET; and a recess located in the substrate adjacent to the second FET.

Abstract: A semiconductor device including a gate structure present on a channel portion of a semiconductor substrate and at least one gate sidewall spacer adjacent to the gate structure. In one embodiment, the gate structure includes a work function metal layer present on a gate dielectric layer, a metal semiconductor alloy layer present on a work function metal layer, and a dielectric capping layer present on the metal semiconductor alloy layer. The at least one gate sidewall spacer and the dielectric capping layer may encapsulate the metal semiconductor alloy layer within the gate structure.

Abstract: A semiconductor device including a gate structure present on a channel portion of a semiconductor substrate and at least one gate sidewall spacer adjacent to the gate structure. In one embodiment, the gate structure includes a work function metal layer present on a gate dielectric layer, a metal semiconductor alloy layer present on a work function metal layer, and a dielectric capping layer present on the metal semiconductor alloy layer. The at least one gate sidewall spacer and the dielectric capping layer may encapsulate the metal semiconductor alloy layer within the gate structure.

Abstract: Techniques for combining transistors having different threshold voltage requirements from one another are provided. In one aspect, a semiconductor device comprises a substrate having a first and a second nFET region, and a first and a second pFET region; a logic nFET on the substrate over the first nFET region; a logic pFET on the substrate over the first pFET region; a SRAM nFET on the substrate over the second nFET region; and a SRAM pFET on the substrate over the second pFET region, each comprising a gate stack having a metal layer over a high-K layer. The logic nFET gate stack further comprises a capping layer separating the metal layer from the high-K layer, wherein the capping layer is further configured to shift a threshold voltage of the logic nFET relative to a threshold voltage of one or more of the logic pFET, SRAM nFET and SRAM pFET.

Abstract: An apparatus includes a wafer annealing tool and a plurality of electrodes coupled to the wafer annealing tool, wherein the electrodes are configured to be in physical contact with a wafer so that, when the wafer is annealed, a negative electrical bias is formed across one or more gate stacks of the wafer.