Patents by Inventor Miya (Yi-Cheng) Hsieh
Miya (Yi-Cheng) Hsieh has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 4526941Abstract: A process for polymerizing an .alpha.-olefin which comprises contacting the .alpha.-olefin at a temperature of about 10.degree. C. to about 100.degree. C. with a catalyst comprising a slurry component (A) and an organometallic component (B), the component (A) being obtained, without intermediate or final solids separation, by reacting (1) a slurry reaction mixture produced by reacting one mol of (i) a hydrocarbon-soluble organomagnesium component of the general formulaM.alpha.Mg.beta.R.sub.p.sup.1 R.sub.q.sup.2 X.sub.r Y.sub.sor of the reaction product of M.alpha.Mg.beta.R.sub.p.sup.1 R.sub.q.sup.2 X.sub.r Y.sub.s with at least one electron donor selected from the group consisting of ethers, thioethers, ketones, aldehydes, carboxylic acids or derivatives thereof, alcohols, thioalcohols and amines, with 0.1 to 10 mols of (ii) a chlorosilane compound of the formulaH.sub.a SiCl.sub.b R.sub.4-(a+b).sup.10at a temperature of about 20.degree. C. to about 150.degree. C.Type: GrantFiled: September 23, 1983Date of Patent: July 2, 1985Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hisaya Sakurai, Tadashi Ikegami, Masayoshi Miya, Katsuhiko Takaya
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Patent number: 4525027Abstract: In a single mode optical fiber comprising a core made of glass and a cladding surrounding the core and made of glass, when a difference .DELTA. between refractive indices n.sub.1 and n.sub.2 of the core and cladding is expressed by (n.sub.1 -n.sub.2)/(n.sub.1).times.100%, the refractive indices n.sub.1 and n.sub.2 are determined to satisfy a relation 1.0<.DELTA.<3.6 and a diameter of the core is determined according to this value of .DELTA..Type: GrantFiled: September 5, 1984Date of Patent: June 25, 1985Assignee: Nippon Telegraph & Telephone Public Corp.Inventors: Katsunari Okamoto, Takao Edahiro, Akio Kawana, Tetsuo Miya
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Patent number: 4515943Abstract: Novel highly pure and stable crystals of .beta.-nicotinamide-adenine-dinucleotide tetrahydrate (NAD) which is triclinic system and has a space group of P1 or P1 and lattice constants: a=8.861 .ANG., b=11.181 .ANG., c=8.630 .ANG., .alpha.=90.82.degree., .beta.=103.40.degree. and .gamma.=109.71.degree.. The crystalline NAD is prepared by cooling a 20 to 60 w/v % aqueous solution of amorphous NAD, which has preferably been treated with a porous weakly basic anion exchange resin to remove impurities, at a temperature of 0.degree. to 20.degree. C. When the crystalline NAD is added to the aqueous solution as seeds, the desired high pure crystalline NAD is prepared without conducting the treatment of amorphous NAD with the porous weakly basic anion exchange resin. A high pure amorphous NAD is obtained from the crystalline NAD by dissolving the crystalline NAD in water and subjecting the aqueous solution to freeze drying or precipitation with a solvent.Type: GrantFiled: April 19, 1983Date of Patent: May 7, 1985Assignee: Kohjin Co., Ltd.Inventors: Toyofumi Miya, Yukiharu Kobayashi, Masao Yano
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Patent number: 4431568Abstract: A catalyst useful for polymerizing olefins which comprises a solid catalyst component [A] and an organometallic component [B], the solid catalyst component [A] being obtained by reacting (1) a solid inorganic oxide, (2) a hydrocarbon-soluble organomagnesium component of the general formulaM.sub..alpha. M.sub.g.beta. R.sub.p.sup.1 R.sub.q.sup.2 X.sub.r Y.sub.swherein.alpha., p, q, r and s each independently is 0 or a number greater than 0,.beta.is a number greater than 0,p+q+r+s=m.alpha.+2.beta.,m is the valence of M,M is a metal of the 1st to 3rd groups of the Periodic Table,R.sup.1 and R.sup.2 each independently is a hydrocarbon group having 1 to 20 carbon atoms,X and Y each independently is an OR.sup.3, OSiR.sup.4 R.sup.5 R.sup.6, NR.sup.7 R.sup.8 or SR.sup.9 group wherein R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7 and R.sup.8 each independently is a hydrogen atom or a hydrocarbon group having 1 to 20 carbon atoms and R.sup.Type: GrantFiled: December 15, 1981Date of Patent: February 14, 1984Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Masayoshi Miya, Hisaya Sakurai, Tadashi Ikegami
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Patent number: 4431543Abstract: Phosphorus, nitrogen and BOD are removed from organic waste liquid containing the same by mixing the organic waste liquid with activated sludge which is substantially free of oxygen, nitric acid and nitrous acid and subjecting the mixture to the action of the activated sludge under anaerobic conditions which forms a mixture of a liquid rich in soluble phosphorus and an activated sludge low in phosphorus. The sludge and liquid are separated. A portion of the liquid is subjected to solid-liquid separation to form a liquid high in phosphorus and a sludge low in phosphorus. This latter sludge is, along with the other portion of the liquid and the sludge from which the liquid has been initially separated are mixed with oxygen, in the presence of nitric acid or nitrous acid and subjected to aerobic biological oxidation. This results in the formation of a liquid low in phosphorus and an activated sludge.Type: GrantFiled: April 7, 1982Date of Patent: February 14, 1984Assignee: Ebara Infilco Kabushiki KaishaInventors: Yoshitaka Matsuo, Toshihiro Tanaka, Akiko Miya
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Patent number: 4393697Abstract: An air flow rate measuring apparatus having an air flow sensor and a temperature sensor which are disposed in a passage for intake air formed in the vicinity of a main air flow guide chamber in an internal combustion engine. The electric characteristics of the air flow sensor vary with the flow rate of air flowing by the sensors. The air flow sensor and temperature sensor have the same shape and the same construction. The temperature sensor is used to compensate the temperature of the air flow sensor so as to maintain the air flow sensor at a predetermined temperature. These sensors are arranged in the same plane that is at right angles to the direction in which said intake air flows. The sensors are extended parallel to each other in symmetrical relationship with respect to the center line in the above-mentioned plane. Conductor support pins to which the sensors are fixed are also arranged symmetrically with respect to the center line in the mentioned plane.Type: GrantFiled: January 30, 1981Date of Patent: July 19, 1983Assignee: Hitachi, Ltd.Inventors: Kanemasa Sato, Sadayasu Ueno, Kazuhiko Miya
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Patent number: 4381668Abstract: An intake barrel connected to an intake pipe of an internal combustion engine is provided therein with a venturi member. Openings are formed in the wall of the intake barrel at the upstream and downstream sides of the venturi member. A bypass passage forming member provided with a groove of a length greater than the distance between said openings is fixed to the outside of the intake barrel. A bypass passage is formed by these openings and the groove. A spacer is interposed between the intake barrel and the bypass passage forming member. The cross-sectional area of the bypass passage can be varied by varying the thickness of the spacer.Type: GrantFiled: August 15, 1980Date of Patent: May 3, 1983Assignee: Hitachi, Ltd.Inventors: Kanemasa Sato, Sadayasu Ueno, Kazuhiko Miya, Yoshishige Oyama, Yutaka Nishimura
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Patent number: 4372647Abstract: In a single mode optical fiber of the type comprising a core, a cladding surrounding the core and an intermediate layer, the refractive indices n1, n2 and n3 respectively of the core, the cladding and the intermediate layer are selected such that the following relations are satisfied0.5<.DELTA.1<1.5-0.3>.DELTA.2>-1.Type: GrantFiled: October 1, 1980Date of Patent: February 8, 1983Assignee: Nippon Telegraph & Telephone Public CorporationInventors: Katsunari Okamoto, Takao Edahiro, Akio Kawana, Tetsuo Miya
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Patent number: 4369656Abstract: An air flow rate sensor including a resistor the characteristic of which depends on temperature for operation mounted in a suction conduit of an internal combustion engine. The air flow rate sensor includes a tube of inorganic material, a platinum wire wound in convolutions on the surface of the tube, and a glass coating applied at least to the surface of the resistor while allowing a part of the surface to be exposed. The glass coating has a thickness smaller than the diameter of the resistor wire and enables equalization of pulsations of the sensor output to be obtained because of the thermal capacity of the glass coating.Type: GrantFiled: February 2, 1981Date of Patent: January 25, 1983Assignee: Hitachi, Ltd.Inventors: Sadayasu Ueno, Kanemasa Sato, Yoshishige Oyama, Yutaka Nishimura, Kazuhiko Miya
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Patent number: 4366704Abstract: An air intake apparatus for the internal combustion engine is disclosed comprising a heating resistor placed in a bypass for passing the air of an amount in a predetermined ratio to the amount of the air passing through a main air path communicating with the internal combustion engine, the bypass circumventing or detouring the main air path. The bypass body for defining the bypass is made of a synthetic resin material in order to prevent heat conduction to the heating resistor from an external source.Type: GrantFiled: November 26, 1980Date of Patent: January 4, 1983Assignee: Hitachi, Ltd.Inventors: Kanemasa Sato, Sadayasu Ueno, Kazuhiko Miya
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Patent number: 4330650Abstract: Catalysts for polymerization of olefin which comprise a solid catalyst component (A) and an organometallic compound with a heterocyclic carboxylic acid ester (B), wherein the solid catalyst component (A) is obtained by reacting or/and grinding a special magnesium compound (1), a titanium halide (2) and a carboxylic acid ester (3); and the heterocyclic carboxylic acid ester is N-, S- or O-containing heterocyclic compound, and processes for polymerization of olefin employing such a catalyst.Type: GrantFiled: March 28, 1980Date of Patent: May 18, 1982Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hisaya Sakurai, Hideo Morita, Masayoshi Miya, Katsuhiko Takaya, Haruyuki Yoneda
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Patent number: 4312783Abstract: A catalyst comprising (A) a solid catalyst component obtained by reacting a titanium compound having a hydrocarbyloxy group with an organoaluminum compound in the presence of an ether to give a liquid material or to give a solid titanium component (a) which is solubilized by addition of a tetravalent titanium halide with or without an ether without separation or after separation from the reaction mixture, and heat treating the liquid material at a temperature of 70.degree. to 180.degree. C. with or without addition of a tetravalent titanium halide, and (B) an organoaluminum compound is effective for polymerization or copolymerization of olefins with high stereoregularity and has high polymerization activity.Type: GrantFiled: July 16, 1980Date of Patent: January 26, 1982Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hisaya Sakurai, Masayoshi Miya, Katsuhiko Takaya, Haruyuki Yoneda
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Patent number: 4278567Abstract: A process for the preparation of copper-iron-aluminum hydrogenation catalysts comprises the step of: dissolving a cupric salt, a ferrous salt and an aluminum salt in water dissolving urea in the resulting aqueous solution in such an amount that the mole number of urea is at least 0.7 time as large as the sum of equivalents of the metal ions, heating the mixed aqueous solution, further continuing the heating until a pH of the liquid is 4.6 to 7.5, adding an alkali to the reaction liquid to elevate a pH to 9.5 to 11.5, further conducting the reaction and then separating, water-washing, drying and calcining the formed precipitate.Type: GrantFiled: March 10, 1980Date of Patent: July 14, 1981Assignee: Kao Soap Co., Ltd.Inventors: Bunji Miya, deceased, by Fumiaki Miya, heir, by Yukiko Nawashiro, heir
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Patent number: 4255280Abstract: Catalysts for polymerization of olefin which comprise a solid catalyst component (A) and an organometallic compound with a heterocyclic carboxylic acid ester (B), wherein the solid catalyst component (A) is obtained by reacting or/and grinding an organomagnesium compound (1), of the formulaM.sub..alpha. Mg.sub..beta. R.sub.p.sup.1 R.sub.q.sup.2 X.sub.rwherein.alpha., p, q and r each independently .gtoreq.0,.beta.>0,p+q+r=m.alpha.+2.beta.M is Al, Zn, B or Be,m is the valence of M,R.sup.1 and R.sup.2 are the same or different hydrocarbon groups having 1-20 carbon atoms, andX is a halogen atom,or of the reaction product of M.sub..alpha. Mg.sub..beta. R.sub.p.sup.1 R.sub.q.sup.2 X.sub.r with an electron donor, with 0.01 to 100 moles of (ii) a chlorosilane compound containing Si-H bonds and of the formulaH.sub.a SiClR.sub.4-(a+b).sup.3wherein0<a.ltoreq.Type: GrantFiled: March 12, 1979Date of Patent: March 10, 1981Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hisaya Sakurai, Hideo Morita, Masayoshi Miya, Katsuhiko Takaya, Haruyuki Yoneda
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Patent number: 4252689Abstract: A copper-iron-aluminum hydrogenation catalyst is prepared by separately and simultaneously adding dropwise to a bath of water (a) an aqueous solution of cupric, ferrous and aluminum salts and (b) an aqueous solution of alkali metal compound effective to precipitate the copper, iron and aluminum ions, and then agitating the reaction mixture at a temperature of at least 50.degree. C., at a pH of 9.5 to 11.5, for from 10 minutes to 10 hours, then recovering the precipitate and treating it to convert it to an active catalyst.Type: GrantFiled: June 27, 1979Date of Patent: February 24, 1981Assignee: Kao Soap Co., Ltd.Inventor: Bunji Miya
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Patent number: 4214101Abstract: A process for preparing ether carboxylates which comprises contacting an ethoxylated alcohol or alkylphenol or an ethylene oxide/propylene oxide block copolymer, with oxygen, in the presence of a palladium catalyst, at a pH of from 8 to 13 and at a temperature of 50.degree. to 95.degree. C.Type: GrantFiled: April 13, 1978Date of Patent: July 22, 1980Assignee: Kao Soap Co., Ltd.Inventors: Bunji Miya, Akio Kimura
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Patent number: 4191905Abstract: A housing for a subminiature piezoelectric quartz crystal vibrator element, in which a glass substrate has a recess formed in an upper surface thereof, the subminiature quartz crystal vibrator element being supported such as to be positioned within a periphery of the recess in the upper surface and separated by fixed distances from surfaces of the recess, a cover is disposed upon the glass substrate to hermetically seal the quartz crystal vibrator element between the cover and the glass substrate.Type: GrantFiled: May 19, 1978Date of Patent: March 4, 1980Assignee: Citizen Watch Company LimitedInventors: Yuh Yasuda, Sigeru Kizaki, Yukio Miya
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Patent number: 4183629Abstract: An electronic optical display device comprising two substrates and an electronic optical substance sealed in a gap formed between said substrates and displaying when an electric voltage is applied thereto is disclosed. The device comprises two upper and lower substrates which are the same in plane configuration and a lead electrode extending along the side surface of said substrates and is most suitable for use in a thin type digital watch.Type: GrantFiled: July 14, 1977Date of Patent: January 15, 1980Assignee: Citizen Watch Co. Ltd.Inventors: Katsuo Nishimura, Hisao Wakabayashi, Takatoshi Osaka, Kazunari Kume, Yasuhiro Ogura, Yukio Miya
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Patent number: 4159963Abstract: Novel highly active catalysts useful for highly stereospecific polymerization of olefin which enables to produce polymer of good grain size having a high stereoregularity can be obtained by a combination of [A] a solid catalyst component obtained by reacting a specified organomagnesium component (i) with a specified chlorosilane compound containing Si--H (ii) to obtain a solid (1) and reacting said solid (1) with a titanium compound containing at least one halogen atom (2) and a carboxylic acid or a derivative thereof (3) and [B] a component consisting of an organometallic compound and a carboxylic acid or a derivative thereof.The organomagnesium component is of the formulaM.sub..alpha. Mg.sub..beta. R.sub.p.sup.1 R.sub.q.sup.2 X.sub.r Y.sub.swherein .alpha. is a number of 0 or greater than 0; .beta.> 0; p, q, r and s are each a number of 0 or greater; p+q+r+s=m.alpha.+2.beta. wherein m is the valency of M; M is a metal element of the 1st to the 3rd group of the Periodical Table; R.sup.1 and R.sup.Type: GrantFiled: January 30, 1978Date of Patent: July 3, 1979Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hisaya Sakurai, Hideo Morita, Tadashi Ikegami, Masayoshi Miya
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Patent number: 4159256Abstract: Novel high active catalysts useful for highly stereospecific polymerization of olefin which enables to produce polymer of low content of catalyst residue, and of good grain size having a high stereoregularity can be obtained by a combination of [A] a solid catalyst component obtained by reacting and/or grinding a specified organomagnesium component (i) with a specified chlorosilane compound containing Si-H (ii) to obtain a solid (1) and reacting said solid (1) with a titanium compound containing at least one halogen atom (2) and a carboxylic acid or a derivative thereof (3) and [B] a component consisting of an organometallic compound and a carboxylic acid or a derivative thereof. The organomagnesium component is of the formulaM.sub..alpha. Mg.sub..beta. R.sub.p.sup.1 R.sub.q.sup.2 X.sub.r Y.sub.swherein .alpha. is a number of 0 or greater than 0; .beta.>0, p, q, r, and s are each a number of 0 or greater; p+q+r+s=m.alpha.+2.beta.Type: GrantFiled: February 10, 1978Date of Patent: June 26, 1979Assignee: Asahi Kasei Kogyo Kabushiki KaishaInventors: Hisaya Sakurai, Hideo Morita, Tadashi Ikegami, Masayoshi Miya, Katsuhiko Takaya