Abstract: A lithium ion capacitor includes a positive electrode made of a material capable of reversibly doping and dedoping lithium ions and/or anions; a negative electrode made of a material capable of reversibly doping and dedoping lithium ions; and an electrolytic solution made of an aprotonic organic solvent electrolyte solution of a lithium salt. When the negative electrode and/or positive electrode and a lithium ion supply source are electrochemically brought into contact, lithium ions are doped in a negative electrode and/or positive electrode. A positive electrode potential after the positive electrode and negative electrode are short-circuited is 2.0 V (vs. Li/Li+) or less. The positive electrode and/or negative electrode has a current collector made of a metal foil that has many holes that penetrate through both sides and have an average diameter of inscribed circles of the through-holes of 100 ?m or less.

Abstract: The present invention provides a chemically amplified resist composition comprising: a resin (A) which contains no fluorine atom and a structural unit (a1) having an acid-labile group in a side chain, a resin (B) which contains a structural unit (b2) having a fluorine-containing group in a side chain and at least one structural unit selected from the group consisting of a structural unit (b1) having an acid-labile group, a structural unit (b3) having a hydroxyl group and a structural unit (b4) having a lactone structure in a side chain, and an acid generator, wherein the amount of the resin (B) is 2 parts by weight or less per 100 parts by weight of the resin (A).

Abstract: An ammonium metavanadate is heat-treated to 500° C. or less at a predetermined rate of temperature rise, whereby a microcrystal particle of a vanadium pentoxide can be formed. According to the production method described above, a crystal of a nano-vanadium having a layer length of 100 nm or less can be formed. The nano-vanadium formed by the production method described above can effectively be used for an electrode of an electric storage device such as a battery. The production method according to the present invention can be linked to a conventional production method in which an ammonium metavanadate can be formed in the course of the method, whereby the present invention can smoothly be embodied.

Abstract: The present invention provides a chemically amplified resist composition comprising: a resin (A) which contains no fluorine atom and a structural unit (a1) having an acid-labile group in a side chain, a resin (B) which contains a structural unit (b2) having a fluorine-containing group in a side chain and at least one structural unit selected from the group consisting of a structural unit (b1) having an acid-labile group, a structural unit (b3) having a hydroxyl group and a structural unit (b4) having a lactone structure in a side chain, and an acid generator, wherein the content of the structural unit (b1) based on the total units of the resin (B) is less than 10 mol %.

Abstract: When a layered crystal material of vanadium pentoxide that can be used as a positive electrode active material is manufactured, a sulfur-containing organic material is not used as a raw material in the present invention. Therefore, uncertain adhesion of the sulfur-containing organic material to the layered crystal material is eliminated. The property of the suspension containing a vanadium compound and plural lithium compounds such as lithium sulfide and lithium hydroxide is adjusted by using these lithium compounds. By this adjustment, the pentavalence of the vanadium ions is controlled to be a desired ratio. Consequently, an active material having reproducibility can be manufactured. First discharge energy of a lithium ion secondary battery using the active material can be enhanced.

Abstract: In a current collector laminating step, a current-collector laminate unit 30 composed of current-collector materials 31 and 32 and a film material 33 is formed. Resist layers 34 having a predetermined pattern are formed on both surfaces of the current-collector laminate unit 30. An etching process is performed with the resist layers 34 used as a mask, whereby through-holes 20a and 23a are formed on the respective current-collector materials 31 and 32. The resist layers 34 are removed from the current-collector laminate unit 30. Since the etching process is performed on the plural current-collector materials 31 and 32, productivity of an electrode can be enhanced. During the application of the slurry, the film material 33 prevents the leakage of the electrode slurry. Therefore, the current-collector laminate unit 30 can be conveyed in the horizontal direction, whereby the productivity of the electrode can be enhanced.

Abstract: A resist layer is formed over one surface of a current-collector material, while a resist layer having a predetermined pattern is formed on the other surface of the current-collector material. Through-holes are formed on the current-collector material through an etching process. An electrode slurry is applied onto the current-collector material formed with the through-holes without removing the resist layers. Specifically, since the through-holes are closed by the resist layer, the electrode slurry does not pass through the through-holes to leak out. Therefore, the current-collector material can be conveyed in the horizontal direction, whereby the productivity of an electrode can be enhanced. The resist layers are made of PVdF, and the resist layers are removed in a heating and drying step in which the PVdF is dissolved.

Abstract: A lithium ion capacitor includes, as a lithium ion supply source, a lithium metal foil for batteries or capacitors. A current collector 4 and a separator 3 formed of a paper or resin nonwoven fabric are preliminarily pressure-bonded and integrated to opposite surfaces of a lithium metal foil 1 for batteries or capacitors.

Abstract: A physical property of a suspension into which plural lithium materials, such as a lithium sulfide, lithium hydroxide, etc., and a vanadium material are dissolved is adjusted by using the plural lithium materials. According to the adjustment, the valence of pentavalent vanadium ions is controlled to be a desired ratio. A material having the obtained layered crystal particles and an amorphous part is used as a starting material, and this material is subject to a heat treatment. With this process, the layered crystal particles grow, while the amorphous part is decreased. Consequently, it is confirmed that the rate of capacity deterioration is improved.

Abstract: Mesoporous graphite is used as an active material of a negative electrode constituting a lithium ion secondary battery or a lithium ion capacitor. Specifically, the mesoporous graphite has a specific area within the range of 0.01 m2/g or more and 5 m2/g or less, and the total volume of mesopores within the range of 0.005 mL/g or more and 1.0 mL/g or less, wherein a volume of mesopores each having a pore diameter of 10 nm or more and 40 nm or less is 25% or more and 85% or less of the total volume of mesopores. By this structure, an output characteristic is enhanced.

Abstract: The present invention provides a polyhydric compound represented by the formula (I): wherein R51 to R67 each independently represent a hydrogen atom etc., at least one selected from the group consisting of R1 to R5 is a group represented by the formula (II): wherein Q1 and Q2 each independently represent a fluorine atom etc., U represents a C1-C20 divalent hydrocarbon group etc., and A+ represents an organic counter ion, and the others are hydrogen atoms or groups represented by the formula (III): wherein X1 to X4 each independently represent a hydrogen atom etc., n represents an integer of 0 to 3, W represents any one of the following groups: Z1 represents a C1-C6 alkyl group etc., and ring Y represents a C3-C20 alicyclic hydrocarbon group, and a chemically amplified resist composition containing the same.

Abstract: A mixture layer for an electrode is formed on a punched current collector. For example, the mixture layer is made of an active material, conductive assistant, binder, and the like. The mixture layer having the structure described above is formed into a slurry, for example, and applied onto the current collector. The applied mixture layer is dried to fabricate an electrode. The thus formed electrode is used to assemble an electric storage device. Upon the assembly, lithium ions are pre-doped into a negative electrode. The pre-doping time is determined according to air permeability of the electrodes.

Abstract: An electric storage device 10 has a positive electrode 13, a negative electrode 14 and a separator 15 provided between the positive electrode 13 and the negative electrode 14. The negative electrode surface 14b is formed to be larger than the positive electrode surface 13b in such a manner that a positive electrode outer edge 13c and a negative electrode outer edge 14c are apart from each other by 2 mm or more. By this configuration, an ion restricting section 15b is formed at the outer peripheral portion of the separator 15. Accordingly, the movement of the lithium ions toward the negative electrode end surface 14a can be restricted, when the device is charged with a large current, whereby the deposition of metal lithium on the negative electrode end surface 14a can be prevented.

Abstract: An electric storage device 10 has an electrode laminate unit 12 including positive electrodes 14, negative electrodes 15 and a lithium electrode 16 provided at the outermost part of the electrode laminate unit 12. The lithium electrode 16 has a lithium-electrode current collector 26 welded to a negative-electrode current collector 22 and a lithium unit 27 sandwiched between the lithium-electrode current collector 26 and the negative electrode 15. The lithium unit 27 is composed of a lithium holding plate 27a that is in contact with the lithium-electrode current collector 26, and a lithium ion source 27b that is provided to the lithium holding plate 27a. The lithium ion source 27b is not mounted on the lithium-electrode current collector 26, but only the lithium-electrode current collector 26 is laminated and welded, whereby the damage of the lithium ion source 27b is prevented, and the manufacturing operation is simplified.

Abstract: It is to provide a lithium ion capacitor having a high capacity retention at the time of continuous charge at a high temperature and excellent in durability. A lithium ion capacitor comprising a positive electrode, a negative electrode and an aprotic organic solvent electrolyte solution of a lithium salt as an electrolytic solution, characterized in that a positive electrode active material is a material capable of reversibly supporting lithium ions and/or anions, a negative electrode active material is a material capable of reversibly supporting lithium ions, the negative electrode and/or the positive electrode is doped with lithium ions so that the potential of the positive electrode is at most 2.0 V after the positive electrode and the negative electrode are short-circuited, and the electrolytic solution contains vinylene carbonate or its derivative.

Abstract: A lithium ion capacitor includes a positive electrode, a negative electrode, and a non-protonic organic solvent electrolytic solution of a lithium salt. A positive electrode active material is a material capable of reversibly doping a lithium ion and/or an anion. A negative electrode active material is a material capable of reversibly doping a lithium ion. The lithium ion is doped in advance to either one or both of the negative electrode and the positive electrode so that a positive electrode potential after the positive electrode and the negative electrode are short-circuited is 2.0 V (relative to Li/Li+) or less when capacitance per unit weight of the positive electrode is C+(F/g), weight of the positive electrode active material is W+(g), capacitance per unit weight of negative electrode is C?(F/g), and weight of the negative electrode active material is W?(g), a value of (C?×W?)/(C+×W+) is 5 or more.

Abstract: A lithium ion capacitor including a positive electrode, a negative electrode, and an aprotic organic solvent solution of a lithium salt as an electrolytic solution. The positive electrode active material is capable of reversibly supporting lithium ions and/or anions, the negative electrode active material is capable of reversibly supporting lithium ions and anions, and the potentials of the positive electrode and the negative electrode are at most 2.0 V after the positive electrode and the negative electrode are short-circuited. The positive electrode and the negative electrode are alternately laminated with a separator interposed therebetween to constitute an electrode unit, the cell is constituted by at least two such electrode units, lithium metal is disposed between the electrode units, and lithium ions are preliminarily supported by the negative electrode and/or the positive electrode by electrochemical contact of the lithium metal with the negative electrode and/or the positive electrode.

Abstract: An organic electrolyte capacitor is provided with a high energy density, a high power and a high capacitance even at ?20°. The organic electrolyte capacitor has a high discharge capacity even at a temperature as low as ?20° C., while having a high voltage and a high energy density. The structure of the organic electrolyte capacitor includes a positive electrode, a negative electrode, and an electrolyte capable of transporting lithium ions. The positive electrode can reversibly support lithium ions and anions, and the negative electrode can reversibly support the lithium ions by using a mesopored carbon material having a pore volume of 0.10 ml/g or more for a pore diameter of 3 nm or larger.

Abstract: A lithium ion capacitor includes a positive electrode including a positive electrode active material capable of reversibly doping either one or both of a lithium ion and an anion, a negative electrode including a negative electrode active material capable of reversibly doping a lithium ion, and a non-protonic organic solvent electrolytic solution of a lithium salt as an electrolytic solution. The lithium ion is doped to either one or both of the negative electrode and positive electrode so that the positive electrode potential after the positive electrode and negative electrode are short-circuited is 2.0 V or less. A surface of the negative electrode is covered with a polymer.

Abstract: An electric storage device 10 has a first electric storage component 29 and a second electric storage component 30. The first component 29 and the second component 30 are connected in parallel. A positive-electrode mixture layer 22 contains a lithium cobaltate to increase a capacity. A positive-electrode mixture layer 27 contains an activated carbon to increase an output. A current collector 16 having through holes 16a is provided between the layers 22 and 27. A positive electrode terminal 25 is connected to a positive-electrode current collector 21 of the first component 29 through an electricity supply path 24 provided with a resistor 23. By this configuration, the electric current flowing through the first electric storage component 29 can be restricted when the device is charged or discharged with high current.