Patents by Inventor Rüdiger Sens

Rüdiger Sens has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6727318
    Abstract: The present invention relates to a process for preparing dye-comprising aqueous polymer dispersions by free-radical aqueous emulsion polymerization of ethylenically unsaturated monomers in the presence of free-radical initiators, in which at least some of the monomers are employed in the form of an oil-in-water emulsion E1 whose disperse phase comprises at least one oil-soluble dye, wherein the disperse phase of E1 is formed essentially of dye-comprising monomer droplets having a diameter <500 nm. The present invention also relates to perylene dyes of the formula III as set forth in claim 35. The present invention relates in addition to dye-comprising formulations which comprise the dye-comprising polymers of the invention and to pigmented formulations which comprise a polymer of the invention comprising optical brightener.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: April 27, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Klemens Mathauer, Arno Böhm, Walter Mächtle, Peter Rossmanith, Sabine Kielhorn-Bayer, Klaus Müllen, Ulrike Rohr, Friedrich-Wilhelm Raulfs, Ulrike Schlösser, Wolfgang Schrof, Harutyun Hanciogullari, Karl Siemensmeyer, Paul Delavier, Rüdiger Sens, Torsten Freund, Takahiro Ikeda, Takanori Wakebe
  • Patent number: 6680355
    Abstract: Disclosed is a dispersant obtainable by reacting (i) a di- or polyfunctional isocyanate with (ii) an HX-terminated polymeric compound, where X is COO, O, S or NR1 and R1 is H or C1-C6-alkyl; and either (iii) an HY-terminated homopolymer of a monomer selected from the group consisting of N-vinylamides, N-vinyllactams and vinyl- or allyl-substituted nitrogenous heterocycles or copolymer of one or more of the monomers mentioned and optionally further monomers, where Y is COO, O, S or NR2 and R2 is H or C1-C6-alkyl; or (iv) an HY-functional organic phosphonic ester, where Y is as defined above. The dispersant is especially useful for dispersing pigments and for preparing inkjet inks.
    Type: Grant
    Filed: April 24, 2001
    Date of Patent: January 20, 2004
    Assignee: BASF Aktiengesellschaft
    Inventors: Franz Weingart, Roman Benedikt Raether, Stephan Bauer, Ulrike Hees, Manfred Mielke, Ulrike Schlösser, Rüdiger Sens
  • Patent number: 6669740
    Abstract: Dye preparations comprising, based in each case on the weight of the preparation, from 0.1 to 30% by weight of one or more dyes from the class of the mono- or polyazo dyes containing no acidic groups, from 0.1 to 20% by weight of a dispersant based on an arylsulfonic acid-formaldehyde condensate or from 0.1 to 20% by weight of a water-soluble dispersant based on alkoxylated phenols with or without water, and their use as inks in the inkjet process and for textile sublimation transfer printing.
    Type: Grant
    Filed: November 6, 2002
    Date of Patent: December 30, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Siemensmeyer, Bernd Siegel, Volker Bach, Manfred Herrmann, Günther König, Rüdiger Sens
  • Patent number: 6537331
    Abstract: Dye preparations comprising, based in each case on the weight of the preparation, from 0.1 to 30% by weight of one or more dyes from the class of the mono- or polyazo dyes containing no acidic groups, from 0.1 to 20% by weight of a dispersant based on an arylsulfonic acid-formaldehyde condensate or from 0.1 to 20% by weight of a water-soluble dispersant based on alkoxylated phenols with or without water, and their use as inks in the inkjet process and for textile sublimation transfer printing.
    Type: Grant
    Filed: June 5, 2000
    Date of Patent: March 25, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Siemensmeyer, Bernd Siegel, Volker Bach, Manfred Herrmann, Günther König, Rüdiger Sens
  • Patent number: 6332943
    Abstract: Pigment preparation for the ink-jet process which comprises A) at least one finely divided, organic or inorganic pigment, B) a dispersant based on arylsulfonic acid/formaldehyde condensation products or an alkoxylated phenols, and C) water, as essential constituents. It provides for prints of high light fastness, wash fastness and rub fastness.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: December 25, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Herrmann, Günther König, Rüdiger Sens, Bernd Siegel, Karl Siemensmeyer
  • Patent number: 6302924
    Abstract: Dye mixtures comprising one or more thienyl- and/or thiazole-azo dyes with a coupling component of the aminothiazole, aniline or tetrahydroquinoline series, one or more dyes of the class of the monoazo or disazo dyes, methine dyes, azamethine dyes, anthraquinone dyes, nitro dyes or quinophthalone dyes which have their respective absorption maximum at a wavelength of from 410 to 520 nm and optionally one or more dyes of the class of the monoazo or disazo dyes, methine dyes, azamethine dyes, anthraquinone dyes, nitro dyes or quinophthalone dyes which have their respective absorption maximum at a wavelength of from 600 to 700 nm, the FWHM value of the absorption maximum being at least 2000 cm−1, are useful for thermal transfer and for dyeing or printing synthetic materials.
    Type: Grant
    Filed: September 22, 1998
    Date of Patent: October 16, 2001
    Assignee: Basf Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Rüdiger Sens, Claudia Kräh, Frank Wüthner
  • Patent number: 6294592
    Abstract: The invention provides for pigment preparations containing, as main components, A) at least a finely divided organic or inorganic pigment, B) a dispersing agent composed of formaldehyde-arylsulfonic acid or oxalkylated phenols condensates, C) a radiation curable binder, D) optionally a photoinitiator, and E) water. The invention also provides for the use of said preparations as inks for said ink jet printing method.
    Type: Grant
    Filed: December 30, 1999
    Date of Patent: September 25, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Manfred Herrmann, Gert Motzkus, Wolfgang Reich, Rüdiger Sens, Bernd Siegel, Karl Siemensmeyer
  • Patent number: 6221114
    Abstract: Dye salts which are free from fiber-reactive radicals and have the formula where Chr is an (m+n)-valent radical of a chromophore from the series of the metal-free or metal-containing phthalocyanines, of the quinacridones, of the mono-, dis- or polyazo dyes, of the anthraquinones or copper formazans, Ar is phenyl or naphthyl each of which is unsubstituted or substituted, x⊕ is a metal cation or ammonium ion, y⊕ is a proton, metal cation or ammonium ion, m is 1 to 6 and n is 1 to 6, the sum of m and n being not more than 7, are used in methods of dyeing or printing polymeric material and in dye preparations.
    Type: Grant
    Filed: September 17, 1999
    Date of Patent: April 24, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Frank Würthner, Rüdiger Sens, Günther Seybold, Karl-Heinz Etzbach
  • Patent number: 5738806
    Abstract: Use of azo dyes having a diazo component derived from an aminothienothiophene and a coupling component of the aniline series in nonlinear optics, polymers derived from these azo dyes, the use thereof in nonlinear optics, and novel phenylthienothienylazoanilines.
    Type: Grant
    Filed: May 8, 1996
    Date of Patent: April 14, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Ruediger Sens
  • Patent number: 5719288
    Abstract: Pyridone dyes of the formula ##STR1## where X is nitrogen or C--CN,R.sup.1 and R.sup.2 are each substituted or unsubstituted C.sub.1 -C.sub.10 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, C.sub.3 -C.sub.4 -alkenyl or substituted or unsubstituted phenyl, or R.sup.1 and R.sup.2 together with the nitrogen atom joining them together are a heterocyclic radical,R.sup.3 is hydrogen, C.sub.1 -C.sub.10 -alkyl, C.sub.4 -C.sub.7 -cylcoalkyl, benzyl, substituted or unsubstituted phenyl, substituted or unsubstituted furanyl or substituted or unsubstituted thienyl,R.sup.4 is hydrogen, C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl,R.sup.5 is cyano, carbamoyl, mono- or di(C.sub.1 -C.sub.8 -alkyl)carbamoyl, carboxyl, C.sub.1 -C.sub.8 -alkoxycarbonyl or benzimidazolyl, andR.sup.6 is substituted or unsubstituted C.sub.1 -C.sub.10 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or substituted or unsubstituted phenyl,are useful for dyeing or printing textile materials.
    Type: Grant
    Filed: June 14, 1996
    Date of Patent: February 17, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Ruediger Sens, Karl-Heinz Etzbach, Volker Bach
  • Patent number: 5696243
    Abstract: Diphenylamines of the formula ##STR1## where the ring A can be benzo-fused, andD is aryl or a five-membered aromatic heterocyclyl which contains one to three hetero atoms selected from the group consisting of nitrogen, oxygen and sulfur, in the heterocyclic ring and can be fused to a benzene, thiophene, pyridine or pyrimidine ring,X is N.dbd.N or, if D is aryl, is alternatively CH.dbd.CH, or D--X together is 1,2,2-tricyanovinyl,R.sup.1, R.sup.2, R.sup.3 and R.sup.4 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy or halogen,R.sup.5 is prop-1-en-3-yl, acryloyl or methacryloyl,R.sup.6 and R.sup.7 are each hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.1 -C.sub.6 -alkoxy, halogen, prop-1-en-3-yl, acryloyl, methacryloyl or oxiranylmethoxy, andY is C.sub.1 -C.sub.20 -alkylene,polymers derived from the compounds, and their use in non-linear optics.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: December 9, 1997
    Assignee: GASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Ruediger Sens
  • Patent number: 5654122
    Abstract: Pyridone dyes useful for thermal transfer have the formula ##STR1## where R.sup.1 is hydrogen or C.sub.1 -C.sub.4 - alkyl,R.sup.2 and R.sup.3 are identical or different and each is, independently of the other, hydrogen, substituted or unsubstituted C.sub.1 -C.sub.12 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl, substituted or unsubstituted phenyl, substituted or unsubstituted pyridyl, substituted or unsubstituted C.sub.1 -C.sub.12 -alkanoyl, C.sub.1 -C.sub.12 -alkoxycarbonyl, substituted or unsubstituted C.sub.1 -C.sub.12 -alkylsulfonyl, C.sub.5 -C.sub.7 -cycloalkylsulfonyl, substituted or unsubstituted phenylsulfonyl, substituted or unsubstituted pyridylsulfonyl, substituted or unsubstituted benzoyl, pyridylcarbonyl or thienylcarbonyl or are together with the nitrogen atom to which they are bonded unsubstituted or C.sub.1 -C.sub.4 - alkyl-substituted succinimido, unsubstituted or C.sub.1 -C.sub.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 5, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Ernst Schefczik, Ruediger Sens, Matthias Wiesenfeldt
  • Patent number: 5612465
    Abstract: Azo dyestuffs of the formula ##STR1## where R.sup.1 is unsubstituted or substituted C.sub.1 -C.sub.20 -alkyl, unsubstituted or substituted phenyl, or unsubstituted or substituted mercapto,R.sup.2 is hydroxyl or mercapto andD is the radical of a diazo component which is selected from the group consisting of the radicals of the formulae ##STR2## where L.sup.1 is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted amino, one of the two radicals L.sup.2 and L.sup.3 is hydrogen and the other is C.sub.1 -C.sub.4 -alkyl, unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or unsubstituted or substituted amino, L.sup.4 is hydrogen or C.sub.1 -C.sub.4 -alkyl, L.sup.5 is unsubstituted or substituted C.sub.1 -C.sub.4 -alkoxy or C.sub.1 -C.sub.4 -alkylthio and L.sup.6 is unsubstituted or substituted C.sub.8 -C.sub.13 -alkyl or phenoxy,their use for dyeing or printing textile materials and novel mercaptotriazolopyridines are described.
    Type: Grant
    Filed: February 12, 1996
    Date of Patent: March 18, 1997
    Assignee: BASF Aktiengesellschaft
    Inventors: Ernst Schefczik, Ruediger Sens, Karl-Heinz Etzbach, Helmut Reichelt, Clemens Grund
  • Patent number: 5580980
    Abstract: Pyridone dyes useful for thermal transfer have the formula ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, Y, X and Z are defined in the specification.
    Type: Grant
    Filed: November 1, 1993
    Date of Patent: December 3, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Ernst Schefczik, Ruediger Sens, Matthias Wiesenfeldt
  • Patent number: 5549853
    Abstract: Azo dyes of the formulaW(--X--Y--Chr).sub.n,wheren is 2 to 6,y is C.sub.1 -C.sub.6 -alkylene,Chr is the radical of a mono- or polyazo dye,X is a radical of the formula CO--O or O--CO andW is an n-valent radical which is derived from an unsubstituted or substituted C.sub.2 -C.sub.20 -alkane, an unsubstituted or substituted C.sub.4 -C.sub.7 -cycloalkane, an unsubstituted or substituted benzene or an unsubstituted or substituted naphthalene, or, if n is 4, is also silicon,and their use in nonlinear optics or for dyeing or printing textile materials are described.
    Type: Grant
    Filed: June 6, 1994
    Date of Patent: August 27, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Stefan Beckmann, Karl-Heinz Etzbach, Karl Siemensmeyer, Ruediger Sens
  • Patent number: 5489312
    Abstract: Process for transferring dyes from a transfer to a plastic-coated paper wherein on the transfer there is a cyan thermal transfer dye mixture comprising at least one anthraquinone dye whose absorption maximum is at a wavelength of from 600 to 750 nm and also at least one triazolopyridine, pyridone, 1-amidopyrid-2,6-dione, heterocyclic pyridone and/or halogenated quinolone dye.
    Type: Grant
    Filed: January 23, 1995
    Date of Patent: February 6, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Thomas Werner, Ruediger Sens
  • Patent number: 5461131
    Abstract: Azo dye polymers useful in nonlinear optics contain as characteristic monomer units radicals of the formulae I, II, III and IV ##STR1## where D is the radical of a heterocyclic diazo component,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, and R.sup.2 may also be C.sub.1 -C.sub.4 -alkanoylamino,R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.4 is hydrogen, deuterium, methyl, trideuterated methyl or chlorine,R.sup.5 is hydrogen or deuterium,Y.sup.1 and Y.sup.2 are each substituted or unsubstituted C.sub.2 -C.sub.10 -alkylene,W is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, andX is hydroxyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, phenoxy, amino or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino,and have an average molecular weight of from 1,000 to 100,000.
    Type: Grant
    Filed: February 24, 1995
    Date of Patent: October 24, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Wiesenfeldt, Sabine Gruettner-Merten, Ruediger Sens, Karl-Heinz Etzbach, Heike Kilburg
  • Patent number: 5436306
    Abstract: Methine or azamethine dye polymers useful in nonlinear optics contain as characteristic monomer units radicals of the formulae I, II, III and IV ##STR1## where G is a divalent organic radical,Z is nitrogen or CH,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy,R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.4 is hydrogen, deuterium, methyl, trideuterated methyl or chlorine,R.sup.5 is hydrogen or deuterium,Y.sup.1 and Y.sup.2 are each C.sub.2 -C.sub.10 -alkylene,E is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, andX is hydroxyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, phenoxy, amino or C.sub.1 -C.sub.4 -mono- or -dialkylamino, andthe ring A can be benzofused, and have an average molecular weight of from 1,000 to 100,000.
    Type: Grant
    Filed: June 29, 1994
    Date of Patent: July 25, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Etzbach, Ruediger Sens, Heike Kilburg
  • Patent number: 5434231
    Abstract: Azo dye polymers useful in nonlinear optics contain as characteristic monomer units radicals of the formulae I, II, III and IV ##STR1## where D is the radical of a heterocyclic diazo component,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, and R.sup.2 may also be C.sub.1 -C.sub.4 -alkanoylamino,R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.4 is hydrogen, deuterium, methyl, trideuterated methyl or chlorine,R.sup.5 is hydrogen or deuterium,Y.sup.1 and Y.sup.2 are each substituted or unsubstituted C.sub.2 -C.sub.10 -alkylene,W is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, andX is hydroxyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, phenoxy, amino or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino,and have an average molecular weight of from 1,000 to 100,000.
    Type: Grant
    Filed: June 24, 1993
    Date of Patent: July 18, 1995
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Wiesenfeldt, Sabine Gruettner-Merten, Ruediger Sens, Karl-Heinz Etzbach, Heike Kilburg
  • Patent number: RE35407
    Abstract: Azo dye polymers useful in nonlinear optics contain as characteristic monomer units radicals of the formulae I, II, III and IV ##STR1## where D is the radical of a heterocyclic diazo component,R.sup.1 and R.sup.2 are each hydrogen, C.sub.1 -C.sub.6 -alkyl or substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, and R.sup.2 may also be C.sub.1 -C.sub.4 -alkanoylamino,R.sup.3 is hydrogen, C.sub.1 -C.sub.6 -alkyl, C.sub.5 -C.sub.7 -cycloalkyl or C.sub.3 -C.sub.4 -alkenyl,R.sup.4 is hydrogen, deuterium, methyl, trideuterated methyl or chlorine,R.sup.5 is hydrogen or deuterium,Y.sup.1 and Y.sup.2 are each substituted or unsubstituted C.sub.2 -C.sub.10 -alkylene,W is oxygen, imino or C.sub.1 -C.sub.4 -alkylimino, andX is hydroxyl, substituted or unsubstituted C.sub.1 -C.sub.6 -alkoxy, phenoxy, amino or mono- or di(C.sub.1 -C.sub.4 -alkyl)amino,and have an average molecular weight of from 1,000 to 100,000.
    Type: Grant
    Filed: April 6, 1994
    Date of Patent: December 17, 1996
    Assignee: BASF Aktiengesellschaft
    Inventors: Matthias Wiesenfeldt, Sabine Gruettner-Merten, Ruediger Sens, Karl-Heinz Etzbach, Heike Kilburg