Abstract: Provided herein are palladium-mediated coupling reactions useful in the preparation of ketone-containing organic molecules. The provided methods can be used for the preparation of natural products and pharmaceutical agents, including Eribulin, halichondrins, and analogs thereof. The present invention also provides novel halichondrin analogs which can be prepared via the palladium-mediated coupling reactions. The novel halichondrin analogs can be used in the prevention and/or treatment of diseases or conditions (e.g., proliferative diseases such as cancer).

Abstract: The present disclosure generally relates to magnetic media devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The recording head includes a main pole, a trailing shield hot seed layer, a spin Hall layer disposed between the main pole and the trailing shield hot seed layer, and a spin-torque layer disposed between the main pole and the trailing shield hot seed layer. Spin-orbit torque (SOT) is generated from the spin Hall layer. The spin-torque layer magnetization switching or precession is induced by the SOT. The SOT based head reduces the switching current and the Vjump due to higher spin polarization ratio, which improves energy efficiency. In addition, the spin Hall layer and the spin-torque layer are easier to form compared to the conventional pseudo spin-valve structure.

Abstract: A curable composition is disclosed. The curable composition comprises: (A) an organopolysiloxane containing at least two silicon-bonded aliphatically unsaturated groups per molecule; (B) an organohydrogensiloxane containing at least two silicon-bonded hydrogen atoms per molecule; (C) a hydrosilylation-reaction catalyst; (D) a hydrosilylation-reaction inhibitor; and (E) a catalyst different from component (C) and capable of deactivating the (D) hydrosilylation-reaction inhibitor at an elevated temperature of from 50 to 120 C such that components (A) and (B) react in the presence of at least component (C) at the elevated temperature. A process of preparing a coated substrate with the curable composition is also disclosed.

Abstract: The present disclosure generally relates to magnetic media devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The recording head includes a main pole, a trailing shield hot seed layer, a spin Hall layer disposed between the main pole and the trailing shield hot seed layer, and a spin-torque layer disposed between the main pole and the trailing shield hot seed layer. Spin-orbit torque (SOT) is generated from the spin Hall layer. The spin-torque layer magnetization switching or precession is induced by the SOT. The SOT based head reduces the switching current and the Vjump due to higher spin polarization ratio, which improves energy efficiency. In addition, the spin Hall layer and the spin-torque layer are easier to form compared to the conventional pseudo spin-valve structure.

Abstract: The present disclosure generally relates to data storage devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The head includes a main pole at a media facing surface (MFS), a trailing shield at the MFS, and a heavy metal layer disposed between the main pole and the trailing shield at the MFS. Spin-orbit torque (SOT) is generated from the heavy metal layer and transferred to a surface of the main pole as a current passes through the heavy metal layer in a cross-track direction. The SOT executes a torque on the surface magnetization of the main pole, which reduces the magnetic flux shunting from the main pole to the trailing shield. With the reduced magnetic flux shunting from the main pole to the trailing shield, write-ability is improved.

Abstract: The present disclosure generally relates to data storage devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The head includes a main pole, a trailing shield, and an oscillator located between the main pole and the trailing shield. The oscillator is disposed at a media facing surface (MFS). The oscillator includes a spin-torque layer sandwiched between two distinct spin Hall layers. The two distinct spin Hall layers generate spin-orbit torque (SOT) that induces in-plane precessions on opposite surfaces of the spin-torque layer, and both in-plane precessions are in the same direction. The same-direction in-plane precessions on opposite surfaces of the spin-torque layer reduce the critical current of the oscillation of the oscillator, leading to high quality recording.

Abstract: Provided herein are palladium-mediated coupling reactions useful in the preparation of ketone-containing organic molecules. The provided methods can be used for the preparation of natural products and pharmaceutical agents, including Eribulin, halichondrins, and analogs thereof. The present invention also provides novel halichondrin analogs which can be prepared via the palladium-mediated coupling reactions. The novel halichondrin analogs can be used in the prevention and/or treatment of diseases or conditions (e.g., proliferative diseases such as cancer).

Abstract: The present invention provides unified synthesis of the CI-CI 9 building blocks of halichondrins and analogs thereof using selective coupling of poly-halogenated nucleophiles in chromium-mediated coupling reactions. The present invention also provides a practical and efficient synthesis of C20-C38 building blocks of halichondrins and analogs thereof. Also provided herein are general methods of selective activation and coupling of poly-halogenated analogs with an aldehyde. The provided coupling reactions are selective for halo-enone and halo-acetylenic ketal over vinyl halide and halide attached to a sp hydridized carbon. The provided efficient selective coupling reactions can allow easy access to the CI-CI 9 building blocks and C20-C38 building blocks of halichondrins and analogs thereof with limited or no purification or separation of the intermediates.

Abstract: The present disclosure generally relates to data storage devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The head includes a main pole, a trailing shield, and an oscillator located between the main pole and the trailing shield. The oscillator is disposed at a media facing surface (MFS). The oscillator includes a spin-torque layer sandwiched between two distinct spin Hall layers. The two distinct spin Hall layers generate spin-orbit torque (SOT) that induces in-plane precessions on opposite surfaces of the spin-torque layer, and both in-plane precessions are in the same direction. The same-direction in-plane precessions on opposite surfaces of the spin-torque layer reduce the critical current of the oscillation of the oscillator, leading to high quality recording.

Abstract: The present disclosure generally relates to data storage devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The head includes a main pole, a trailing shield, and an oscillator located between the main pole and the trailing shield. The oscillator is disposed at a media facing surface (MFS). The oscillator includes a spin-torque layer sandwiched between two distinct spin Hall layers. The two distinct spin Hall layers generate spin-orbit torque (SOT) that induces in-plane precessions on opposite surfaces of the spin-torque layer, and both in-plane precessions are in the same direction. The same-direction in-plane precessions on opposite surfaces of the spin-torque layer reduce the critical current of the oscillation of the oscillator, leading to high quality recording.

Abstract: The present disclosure generally relates to data storage devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The head includes a main pole, a spin Hall structure surrounding at least a portion of the main pole at a location that is recessed from a media facing surface (MFS), and a spin-torque structure surrounding at least a portion of the main pole at the MFS. Spin-orbit torque (SOT) is generated from the spin Hall structure. The spin-torque structure magnetization switching (or precession) is induced by the SOT. The SOT based head with the spin-torque structure increases both track density (tracks per inch) and linear density (bit per inch). The areal density capability (ADC), which is the product of tracks per inch and bit per inch, can be further improved by removing the side shield and the leading shield, when the spin-torque structure is utilized in the SOT based head.

Abstract: The present disclosure generally relates to data storage devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The head includes a main pole, a heavy metal structure surrounding at least a portion of the main pole at a media facing surface (MFS), and two magnetic structures sandwiching the heavy metal structure. Spin-orbit torque (SOT) is generated from the heavy metal structure, inducing magnetization switching (or precession) in the magnetic structures. The SOT reduces the magnetic flux shunting from the main pole to the trailing shield, and the magnetization switching sharpens the write field profile in the cross-track direction. The SOT based head with the magnetic structures sandwiching the heavy metal structure increases both track density (tracks per inch) and linear density (bit per inch), which in turn increases the areal density capability (ADC), which is the product of tracks per inch and bit per inch.

Abstract: A magnetic write apparatus has a media-facing surface (MFS), a pole having leading and trailing surfaces, a trailing shield having a pole-facing surface, a write gap and coil(s). The pole's trailing surface has a portion adjoining the MFS and oriented at a nonzero, acute bevel angle from a direction perpendicular to the MFS. The pole-facing surface includes a first portion adjoining the MFS and oriented at a first angle substantially the same as the bevel angle, a second portion oriented at a second angle greater than the first trailing shield angle, and a third portion oriented at a third angle substantially the same as the first angle. The write gap has first, second and third thicknesses adjacent to the first, second and third portions of the pole-facing surface, respectively. The first thickness is constant. The second thickness varies. The third thickness is constant and greater than the first thickness.

Abstract: The present disclosure generally relates to data storage devices, and more specifically, to a magnetic media drive employing a magnetic recording head. The head includes a main pole, a spin-torque structure surrounding at least a portion of the main pole at a media facing surface (MFS), and a spin Hall structure surrounding the spin-torque structure. Strong spin-orbit torque (SOT) is generated from the spin Hall structure, enforcing in-plane magnetization oscillation in the spin-torque structure. The SOT based head with the spin Hall structure surrounding the spin-torque structure utilizes less current flowed to the spin Hall structure due to the strong SOT generated by the spin Hall structure.

Abstract: A magnetic write apparatus has a media-facing surface (MFS), a pole having leading and trailing surfaces, a trailing shield having a pole-facing surface, a write gap and coil(s). The pole's trailing surface has a portion adjoining the MFS and oriented at a nonzero, acute bevel angle from a direction perpendicular to the MFS. The pole-facing surface includes a first portion adjoining the MFS and oriented at a first angle substantially the same as the bevel angle, a second portion oriented at a second angle greater than the first trailing shield angle, and a third portion oriented at a third angle substantially the same as the first angle. The write gap has first, second and third thicknesses adjacent to the first, second and third portions of the pole-facing surface, respectively. The first thickness is constant. The second thickness varies. The third thickness is constant and greater than the first thickness.

Abstract: A magnetic apparatus has a media-facing surface (MFS), a pole, a top shield, a back gap and coil(s). The pole includes a yoke extension, a yoke between the yoke extension and the MFS, and a pole tip between the yoke and the MFS. The write gap is between the top shield and the pole tip. The back gap is recessed from the ABS and magnetically and physically connects the top shield to the yoke. The coil(s) energize the pole and have multiple turns. Part of a first turn is between the yoke and the top shield. Part of a second turn is recessed from the MFS and aligned with part of the yoke extension. Part of the first turn is between the part of the second turn and the MFS. The back gap is between part of the first turn and part of the second turn.

Abstract: A magnetic writer includes a high magnetic moment write pole layer on a main write pole, the write pole layer including a proximal end recessed from the air bearing surface, and a Wide Area Track Erasure (WATER) reservoir recessed from the proximal end of the write pole layer and transverse to a longitudinal direction of the main write pole. The write pole layer may be conformal in shape to, but have smaller dimensions relative to, the main write pole, such that a distance between their outer surfaces is generally constant in a flare region. The WATER reservoir width, in a cross-track direction, may be greater than or equal to the maximum width of the main write pole.

Abstract: A magnetic write apparatus has a media-facing surface (MFS), a pole having leading and trailing surfaces, a trailing shield having a pole-facing surface, a write gap and coil(s). The pole's trailing surface has a portion adjoining the MFS and oriented at a nonzero, acute bevel angle from a direction perpendicular to the MFS. The pole-facing surface includes a first portion adjoining the MFS and oriented at a first angle substantially the same as the bevel angle, a second portion oriented at a second angle greater than the first trailing shield angle, and a third portion oriented at a third angle substantially the same as the first angle. The write gap has first, second and third thicknesses adjacent to the first, second and third portions of the pole-facing surface, respectively. The first thickness is constant. The second thickness varies. The third thickness is constant and greater than the first thickness.

Abstract: A shingle magnetic write apparatus is described. The shingle magnetic write apparatus includes a pole, a side gap, a write gap, a top shield and side shield(s). The pole has a pole tip region including a top wider than a bottom, and sides. The sides are at a sidewall angle from a down track direction. The write gap is adjacent to the pole top and between the top shield and the pole top. The side shield(s) are magnetically connected with the top shield and extend past the bottom of the pole. The side gap is between the side shield(s) and the pole. The side shield(s) have pole-facing surface(s) not more than a side shield angle from the down track direction. The side shield angle is less than the sidewall angle. The side gap width increases from the top near the gap to the bottom near the bottom of the pole.

Abstract: A shingle magnetic write apparatus is described. The shingle magnetic write apparatus includes a pole, a side gap, a write gap, a top shield and side shield(s). The pole has a pole tip region including a top wider than a bottom, and sides. The sides are at a sidewall angle from a down track direction. The write gap is adjacent to the pole top and between the top shield and the pole top. The side shield(s) are magnetically connected with the top shield and extend past the bottom of the pole. The side gap is between the side shield(s) and the pole. The side shield(s) have pole-facing surface(s) not more than a side shield angle from the down track direction. The side shield angle is less than the sidewall angle. The side gap width increases from the top near the gap to the bottom near the bottom of the pole.