Method of manufacturing a semiconductor device and a process of a thin film transistor
To enable radiating an optimum energy beam depending upon the structure of a substrate (whether a metallic film is formed or not) when an amorphous semiconductor film is crystallized and uniformly crystallizing the overall film, first, a photoresist film and the area of an N+ doped amorphous silicon film on the photoresist film are selectively removed by a lift-off method. Hereby, the amorphous silicon film is thicker in an area except an area over a metallic film (a gate electrode) than in the area over the metallic film. In this state, a laser beam is radiated. The N+ doped amorphous silicon film and an amorphous silicon film are melted by radiating a laser beam and afterward, melted areas are crystallized by cooling them to room temperature. As the amorphous silicon film is thicker in the area except the area under which the metallic film (the gate electrode) is formed than in the area under which the metallic film is formed, the maximum temperature of the surface of the film is equal and the overall film can be uniformly crystallized.
Latest Patents:
1. Field of the Invention
The present invention relates to a method of manufacturing a semiconductor device in which a film is formed by crystallizing a semiconductor film by radiating an energy beam on the semiconductor film such as amorphous silicon, particularly relates to a method of manufacturing a semiconductor device provided with structure in which the substrate material of a semiconductor film to be crystallized is not even such as a thin film transistor (TFT) used for a liquid crystal display (LCD) and others.
2. Description of the Related Art
A TFT liquid crystal display uses a thin film transistor (TFT) for a pixel provided with a switching function and this TFT is formed on a glass substrate corresponding to each pixel of the liquid crystal display. There are two types of TFTs of TFT consisting of amorphous silicon films and TFT consisting of polycrystalline silicon films, and high-performance TFT consisting of polycrystalline silicon films of these can be produced on a glass substrate at low temperature by irradiating an amorphous silicon film with an energy beam, particularly an excimer laser beam. The peripheral circuit of a liquid crystal display and a pixel switching device can be produced on the same substrate by using such TFT consisting of polycrystalline silicon films. Recently, TFT provided with bottom gate structure attracts attention of TFTs consisting of polycrystalline silicon films because particularly, stable characteristics can be obtained.
This TFT provided with bottom gate structure is constituted as shown in
This TFT provided with bottom gate structure can be manufactured by the following method: That is, after a molybdenum tantalum (MoTa) film is formed on an overall glass substrate 100, a gate electrode 101 is formed by patterning this molybdenum tantalum film by etching so that the film is in a predetermined shape. Afterward, an oxide film 102 is formed on the surface of the gate electrode 101 by anodizing the gate electrode 101. Next, a silicon nitride film 103, a silicon dioxide film 104 and an amorphous silicon film are sequentially formed on the overall oxide film 102 by plasma enhanced chemical vapor deposition (PECVD).
Next, this amorphous silicon film is once fused by irradiating this amorphous silicon film with a laser beam by an excimer laser for example and afterward, crystallized by cooling the film to room temperature. Hereby, the amorphous silicon film is changed to a polycrystalline silicon film 105. Next, after a silicon dioxide film 106 in the shape corresponding to a channel area is selectively formed on the polycrystalline silicon film 105 of a part to be a channel area, an amorphous silicon film including N-type impurities, for example phosphorus (P) and arsenic (As) is formed and changed to an N+ doped polycrystalline silicon film 107 by irradiating the above amorphous silicon film with a laser beam by an excimer laser again, and the impurities are electrically activated.
Next, after an aluminum (Al) film is formed on the overall film by a sputtering method using argon (Ar) as sputtering gas, this aluminum film and the N+ doped polycrystalline silicon film 107 are respectively patterned by etching so that they are in a predetermined shape, and a source electrode 108 and a drain electrode 109 are respectively formed on a source area 105a and a drain area 105b. Next, dangling bond and others are inactivated by exposing the above silicon dioxide film to hydrogen and hydrogenating a channel area 105c by a hydrogen radical and atomic hydrogen which both pass through the silicon dioxide film 106. TFT provided with bottom gate structure shown in
As described above, in the prior method, an energy beam is radiated onto an amorphous silicon film in a process for crystallizing it, however, at this time, the structure of a substrate under the amorphous silicon film is not even. That is, a metallic film (the gate electrode 101) is applied on the glass substrate 100, the substrate under the amorphous silicon film consists of metal and glass which are different in material and heretofore, an energy beam is simultaneously radiated onto an amorphous silicon film over the respective substrate and film. In this case, the same energy beam as the following energy is also radiated onto an amorphous silicon film over the glass substrate 100 based upon the optimum condition of the crystallizing energy of the amorphous silicon film in a channel area over the metallic film (the gate electrode 101).
However, even if the same amorphous silicon film is used, the optimum value of energy required for crystallization is different depending upon whether a substrate is made of metal or glass because thermal conductivity is different. Therefore, more energy beam is radiated onto the amorphous silicon film on the glass substrate 100 by the prior method according to the optimum condition of the amorphous silicon film on the metallic film (the gate electrode 101) than the optimum condition and therefore, there is a problem that partially a film is broken.
The present invention is made to solve such problems and the object is to provide a method of manufacturing a semiconductor device in which an optimum quantity of energy beams can be radiated depending upon the structure of a substrate when an amorphous semiconductor film is crystallized, an overall film can be uniformly crystallized and a film is never broken.
A method of manufacturing a semiconductor device according to the present invention comprises a process for selectively forming a metallic film on a substrate, a process for forming an amorphous semiconductor film on the substrate and the metallic film so that an area on the substrate is thicker than an area on the metallic film and a process for uniformly polycrystallizing the semiconductor film by radiating an energy beam onto the semiconductor film.
More concretely, a method of manufacturing a semiconductor device according to the present invention comprises a process for forming a metallic film as the gate electrode of a thin film transistor on the surface of a substrate and forming an insulating film on this metallic film and the substrate, a process for forming a first amorphous semiconductor film the thickness of which is uniform on the insulating-film, a process for selectively forming a lift-off film in an area on the first semiconductor film corresponding to the metallic film, a process for forming a second amorphous semiconductor film the thickness of which is uniform including impurities on the lift-off film and the first semiconductor film and a process for polycrystallizing the first and second semiconductor films by radiating an energy beam after the lift-off film and an area on the lift-off film of the second semiconductor film are selectively removed and respectively forming the source area and the drain area of the thin film transistor.
A method of manufacturing a semiconductor device according to the present invention may be also constituted so that it comprises a process for forming a metallic film as the gate electrode of a thin film transistor on the surface of a substrate and forming an insulating film on this metallic film and the substrate, a process for selectively forming a lift-off film in an area on the insulating film corresponding to the metallic film, a process for forming a first amorphous semiconductor film the thickness of which is uniform including impurities on the lift-off film and the insulating film, a process for forming a second amorphous semiconductor film the thickness of which is uniform on the insulating film and the first semiconductor film after the lift-off film and an area on the lift-off film of the first semiconductor film are selectively removed and a process for polycrystallizing the first and second semiconductor films by radiating an energy beam after the second semiconductor film is formed and respectively forming the source area and the drain area of the thin film transistor.
According to a method of manufacturing a semiconductor device according to the present invention, as the thickness of a semiconductor film is different depending upon the state of a substrate (whether a metallic film is formed or not) when an energy beam is radiated to crystallize an amorphous semiconductor film, the overall semiconductor film can be uniformly crystallized by radiating beams with the same energy.
BRIEF DESCRIPTION OF THE DRAWINGS
Referring to drawings, embodiments according to the present invention will be described in detail below.
Prior to the concrete description of the embodiments, first, the basic principle of the present invention will be described. As described above, even if the same amorphous silicon film is used, the optimum value of energy required for crystallization is different depending upon whether a substrate is made by metal or glass. According to the present invention; an overall semiconductor film can be uniformly crystallized by radiating beams with the same energy by changing the thickness of the amorphous silicon film depending upon the structure of a substrate (whether a metallic film is formed or not). The reasons will be described below.
As clear from the result of
If an excimer laser beam is radiated onto the amorphous silicon film 44 in the respective structures shown in
The present invention utilizes such a result for uniformly crystallizing an overall film at the same maximum temperature by changing the thickness of a silicon film depending upon the structure of a substrate (whether a metallic film is formed or not) on the same substrate. An example in which the present invention is applied to a method of manufacturing a thin film transistor will be described below.
First Embodiment
After the amorphous silicon film 13 is formed, a photoresist is applied onto this amorphous silicon film 13 and exposure (back exposure) 15 to this photoresist by gamma rays (wavelength: 436 nm) for example is executed from the rear side of the glass substrate 10. At this time, a photoresist film 14 with the same width as the gate electrode 12 as shown in
Afterward, as shown in
It is desirable for a laser beam 17 that a laser beam the wavelength of which the N+ doped amorphous silicon film 18 can absorb, particularly a pulse laser beam by an excimer laser is used. In detail, a pulse laser beam (wavelength: 308 nm) by XeCl excimer laser, a pulse laser beam (wavelength: 350 nm) by XeF excimer laser and others are used.
Next, as shown in
As described above, according to the method of manufacturing a thin film transistor equivalent to this embodiment, as the thickness of a silicon film is set to a different value depending upon the structure of a substrate (whether a metallic film is formed or not) when a laser beam 17 is radiated for crystallization, the silicon film can be uniformly crystallized over the overall substrate. Therefore, a film is never broken and a process margin can be increased.
Second Embodiment
That is, first as shown in
Afterward, as shown in
Next, as shown in
Next, as shown in
As described above, according to the method of manufacturing a thin film transistor equivalent to this embodiment, as the thickness of a silicon film is set to a different value depending upon the state of a substrate (whether a metallic film is formed or not) when a laser beam 37 is radiated for crystallization, the silicon film can be uniformly crystallized over the overall substrate and a film can be prevented from being broken.
The embodiments according to the present invention are described above, however, the present invention is not limited to the above embodiments and may be variously transformed. For example, in the above embodiments, a metallic film under a silicon film is a nickel film, however, it may be also formed by the other metallic film. In the above embodiments, a silicon film is used for an amorphous semiconductor film, however, the other amorphous film may be also used if only it can be crystallized by radiating an energy beam. Further, in the above embodiments, the present invention is applied to a method of manufacturing a thin film transistor, however, it may be also applied to a process for manufacturing the other semiconductor device. A method of forming amorphous semiconductor films different in thickness depending upon the structure of a substrate is not limited to the methods described in the above embodiments and the other method may be also used.
As described above, according to the methods of manufacturing a semiconductor device according to the present invention, as the thickness of a semiconductor film is set toga different value depending upon the state of a substrate (whether a metallic film is formed or not) when an energy beam is radiated to crystallize the amorphous semiconductor film, the overall semiconductor film can be uniformly crystallized by radiating beams with the same energy. Therefore, there is effect that a film is never broken and a process margin can be increased.
Claims
1-15. (canceled)
16. A method of manufacturing a semiconductor device, comprising:
- forming a gate electrode on a portion of a top side of a substrate, said gate electrode being a metallic film;
- forming an insulating film on said substrate and said gate electrode;
- forming a lift-off film on said insulating film wherein said lift-off film is a photoresist;
- forming an N+ doped amorphous semiconductor film with a uniform thickness on said photoresist and said insulating film wherein said uniform thickness of said N+ doped amorphous semiconductor film is a function of a thickness of said insulating film;
- irradiating said photoresist from a rear side of said substrate;
- removing said photoresist film and said N+ doped amorphous semiconductor film on said photoresist;
- forming an amorphous semiconductor film on said N+ doped amorphous semiconductor film and said insulating film;
- irradiating said amorphous semiconductor film and said N+ doped amorphous semiconductor film with an energy beam with a set optimum value of energy required for crystallization;
- uniformly crystallizing said amorphous semiconductor film and a residual area of said N+ doped amorphous semiconductor film by cooling them to room temperature, wherein a thickness of said amorphous semiconductor film is thicker in an area over said metallic film than in an area not covering said metallic film, and a temperature at a surface of said crystallized amorphous semiconductor film and said N+ doped amorphous semiconductor film is substantially equal; and
- forming source and drain electrodes in predetermined positions on said amorphous semiconductor film and said N+ doped amorphous semiconductor film.
Type: Application
Filed: Oct 29, 2004
Publication Date: Apr 21, 2005
Applicant:
Inventors: Dharam Pal Gosain (Kanagawa), Jonathan Westwater (Kanagawa), Miyako Nakagoe (Kanagawa), Setsuo Usui (Kanagawa)
Application Number: 10/976,493