System and method for thermophilic anaerobic digester process
A new approach is proposed that contemplates systems and methods to support an environmentally-friendly, “green” thermophilic anaerobic digestion system. The system includes a thermophilic anaerobic digester as well as various independent modular anaerobic units to generate bio-methane from certain organic energy sources, including but not limited to, among other things, green municipal waste, restaurant and organic waste and effluents from industries such as breweries, grocery stores, food processing plants, granaries, wineries, pulp and paper mills, ethanol and biodiesel plants, fat and animal rendering, agricultural field crops, organic sludge accumulation within lagoons and waterways, marine organic matter and animal manure.
This application claims the benefit of U.S. Application 61/106,836, filed Oct. 20, 2008, which application is fully incorporated herein by reference.
BACKGROUNDThe primary anaerobic digester processes on the market, that are available for industry/agriculture/municipal waste treatment and environmental remediation, include digesters which are either in ground or above ground. In addition, they operate generally at the psychrophilic or mesophilic temperature ranges; however, there are some thermophilic units in operation. The psychrophilic units operate normally at a temperature of 18° C. (65° F.) and the mesophilic units at a temperature range of 35° C. to 40.5° C. (95° F. to 105° F.). There are many variations with these designed anaerobic systems, and each has certain advantages. Detailed below are general descriptions of the three major classes of digester with a further explanation as to some of their critical limitations.
The least expensive digester is an in ground system, such as a lagoon, which is generally an excavated shallow basin with a very large surface area. The sidewalls can be earthen and may include flexible membrane covers. There is generally no agitation in these units and most operate at ambient temperature, i.e.—psychrophilic. In-ground systems (i.e. lagoons) have certain intrinsic problems such as dilution of the process from either groundwater beneath the lagoon or rainwater from the sides or top. Rainwater and snow/ice that accumulates on the flexible membrane cover will depress the cover in certain areas and cause the biogas to collect in pockets. Unintended water within the process dilutes the organic matter, and disrupts the digester temperatures within the unit, affecting the performance and efficiency. High winds and UV radiation also cause problems, damaging the flexible covering. Given the geometry of these lagoons, which are relatively shallow with a large surface area, evaporation combined with the lack of uniform agitation, causes a significant and inevitable accumulation of inorganic and heavy organic matter. Generally, these systems are shut down annually for over a month to allow for solids removal and subsequent restart of the process. Maintaining proper operating temperature is recognized as a technical problem endemic to these units. This lack of temperature and exposure time results in a marginal and unpredictable pathogen kill. Most if not all in ground lagoons require a secondary lagoon in which the processed feedstock needs up to an additional 180 days to complete the process to meet nutrient management requirements. Additional aerobic composting in windrows may also be required.
Some in-ground units may incorporate concrete channels, which are laid out in either a long linear fashion or are in a U-shaped configuration. These units typically have concrete walls with concrete lids (or flexible membrane covers) and are built into the ground to retain process heat. These units are generally mesophilic. Heating is typically provided by heating coils or pipes installed either under the digester concrete channel or in the central concrete wall, which separates the two adjacent channels of the U-shaped configuration. In all cases, the heat is transferred by a combination of conduction and convection through the wall and then across the full width of the plug flow within the channel. The hydraulic residence time (HRT), which is the duration for which material to be digested will remain in the digester, ranges from 18 to 28 days. This long duration time necessitates a long digester chamber length and/or a slow throughput which in turn introduces mechanical difficulty providing proper and uniform agitation along the full length of the digester. As a result, without consistent agitation, heating is not uniform and hot and cold areas develop along the length of the digester. Negatively impacting digester performance as measured by throughput, volatile solids destruction, methane gas production and pathogen kill rates. In addition, the lack of uniform agitation along the length of the digester results in the accumulation of inorganic and heavy organic materials that have been introduced into the digester. It should be noted that although the heavy organic matter can be broken down within the digester, any overlay of inorganic matter above the heavy organic matter (such as sand) may isolate the organic matter from the anaerobes. Over time, and generally within one year, the digester needs to be shut down to remove this accumulation of material. This is necessary as the digester's operating volume slowly decreases, due to this buildup, which, if left unattended, will ultimately blind off and restrict the flow through the digester. When this type of digester is shut down, cleaned out and restarted, up to a month of operating time is generally lost.
The above ground, anaerobic digester systems are normally made of poured in place concrete or steel construction materials and insulated as required. These materials are sturdy and water tight thus eliminating many of the intrinsic problems associated with lagoons such as water and wind. However, heat management is very critical to the efficient performance of this type digester. Generally, these vessels are cylindrical in nature and are approximately 12 m (40 ft.) in diameter, and 12 m to 15.25 m (40 to 50 ft.) in height with a vessel volume of 2500 m3 (88,290 ft3) and greater. In the case of the mesophilic units researched, hot water piping is usually located around the interior circumference of the vessel used as an aid in maintaining the optimal operating temperature. An efficient digester should have uniform temperatures throughout the vessel, within a tight tolerance of +/−1.2° C. or 2° F. However, convective and conductive heat transfer alone do not provide for homogenous heating throughout a vessel of this size. Therefore, in order to move heat to the center of the vessel mass, agitation is required. This is normally provided by a top or side mounted unit with blades and sufficient energy to occasionally roll over the vessel contents. Top mounted agitators are usually located off centre with horizontal paddles near the top and bottom of the shaft. These agitators attempt to distribute the heat and achieve more uniform temperatures within the digester; however the flow related process requirements for the digester are compromised. The fresh feedstock is mixed in with the older feedstock very quickly, negatively impacting volatile solids destruction, methane gas production, yield, and pathogen kill.
In addition to these above ground anaerobic mesophilic digester systems, there are similar units (far fewer) operating at the thermophilic temperature range of 44° C. to 70° C. (110° F. to 160° F.). Heat management is even more critical to the efficient performance of this type of digester. Generally, as in the case of the mesophilic type of digester described above, these thermophilic units have similar dimensions, capacities and heating/agitation systems. Due to the higher operating temperature of these other thermophilic units, the quantity and resulting surface area of the hot water piping located around the interior circumference of the vessel is increased. To attain the tight temperature tolerances required for digester efficiency, external heat exchangers may be required as convection and conduction alone may not suffice. The temperature of the hot water must also be increased to accelerate the heat transfer rate. This increased ΔT then leads to localized caking and subsequent insulation of the heating pipes. The intensity or level of agitation must also be increased to aid in the heat transfer and the required tight temperature control demanded by the thermophilic process. This increased agitation has the side effect of causing the methane producing bacteria to become dormant and produce less gas. The flows of the contents through the vessel as a result of the increased agitation will also short circuit the passage of the feedstock through the unit, compromising pathogen kill certainty. This short circuit condition does not permit the feedstock to be held at the higher system operating temperatures for the length of time mandated to achieve pathogen kill levels.
Consequently, many of the systems in use as described above require a secondary vessel to finish the digestion process, adding to the Hydraulic Retention Time (HRT). In the event that a secondary anaerobic digester is not installed, the discharge from these digesters can be dewatered and transferred to storage areas for wind rowing. Wind rowing, which is aerobic digestion, is used to complete the overall digestion process to meet nutrient management requirements. Each incremental process step adds significantly to the overall digestion time duration, as well as project cost, operational cost, and overall area requirements. If these additional process steps are not included, the digester performance (as measured by methane gas production, quality, volatile solids destruction, pathogen kill, hydraulic residence time and the final digestate chemical inertness), will be measurably less than the results from the digester technology as covered by this patent description.
The foregoing examples of the related art and limitations related therewith are intended to be illustrative and not exclusive. Other limitations of the related art will become apparent upon a reading of the specification and a study of the drawings.
The approach is illustrated by way of example and not by way of limitation in the figures of the accompanying drawings in which like references indicate similar elements. It should be noted that references to “an” or “one” or “some” embodiment(s) in this disclosure are not necessarily to the same embodiment, and such references mean at least one.
A new approach is proposed that contemplates systems and methods to support an environmentally-friendly, “green” thermophilic anaerobic digestion system. The system includes a thermophilic anaerobic digester as well as various independent modular anaerobic units to generate bio-methane from certain organic energy sources, including but not limited to, among other things, green municipal waste, restaurant and organic waste and effluents from industries such as breweries, grocery stores, food processing plants, granaries, wineries, pulp and paper mills, ethanol and biodiesel plants, fat and animal rendering, agricultural field crops, organic sludge accumulation within lagoons and waterways, marine organic matter and animal manure. The thermophilic anaerobic digestion system is uniquely designed to handle many types of industrial and municipal organic waste streams simultaneously or separately. It also offers advantages over current digester systems, including its more modular and inter-changeable design (which expedites project construction), faster throughput digestion, smaller space requirements, higher gas production, superior pathogen and BOD/COD destruction rates, better odor capture and control, higher flexibility of feedstock usage.
The thermophilic anaerobic digestion system is primarily aimed at the effect of inorganic matter on system. An anaerobic digester modular unit has been designed for experimental purposes and information gained from the design, installation, testing, operational monitoring and recording of the unit has been accumulated, verified and incorporated herein. Among those operational findings it is discovered that, regardless of the separating pretreatment used, inorganics, if originally in the feedstock cannot be completely removed. Thus one of the novel characteristics of this system is its self-cleaning attribute, which enables the system to continuously operate using a contaminated feedstock. Additionally, other design attributes provide for ease of operation. The presence of wood shavings as a bedding material, found frequently in agricultural manure, does at times plug associated process pipelines of diameters 3 inches and smaller. This is remedied by installation of water lines where outlets are attached in strategic locations with valves for back flushing for both above ground and in ground lines.
The thermophilic anaerobic digester 100 depicted in
In some embodiments, the dimensions of the digester vessel 42 provide for a modular system that can be transported by rail or road to the installation site. This transportation flexibility allows the thermophilic anaerobic digester 100 depicted in
One of the key distinctions of the thermophilic anaerobic digester 100 depicted in
In some embodiments, the digester heating system 52 and 170 are external to the digester vessel 42. The vessel 42 is fabricated with a water jacket along the underbelly of the vessel 42, utilizing convection and conduction heat transfer for homogenous heating throughout the vessel 42. There is no potential for contamination of the vessel contents due to leakage of any re-circulated glycol or other heating solutions.
In some embodiments, the thermophilic anaerobic digester 100 depicted in
In some embodiments, the thermophilic anaerobic digester 100 depicted in
Solids Retention Time (SRT) is the most significant variable, which indicates the amount of solids conversion (Volatile Solids (VS)) to biogas and liquid in the digestion process (i.e., the quantity of VS destroyed each day). As stated above, the SRT value represents the total amount of conversion from volatile solids to biogas within the digestion process and therefore represents the overall efficiency of the digestion process in converting volatile solids to biogas. The equation below defines how SRT can be calculated:
- V=Daily Infeed Volume into the Digester Process
- Cd=Solids Concentration of the Infeed
- Qw=Daily Quantity of VS destroyed, (COD infeed−COD discharge) where COD means chemical oxygen demand.
- Cw=Solids Concentration of the Waste Effluent (discharge from the digester process)
Volatile Solids destroyed is related to the reduction in Chemical Oxygen Demand. Initial destruction rates are relatively fast but, at some point in the digestion process, the rate of VS destruction will drop dramatically, as indicated by a decrease in biogas production. At that point, it is concluded that there will be limited benefit in retaining the material with in the digester process any longer and therefore, the material is discharged. The total volatile solids destruction claimed is therefore based only on the destruction achieved while at the initial faster rates. Therefore the Chemical Oxygen Demand of the thermophilic anaerobic digester 100 depicted in
A measure of the success of biomass retention is the SRT/HRT (solids retention time/hydraulic retention time) ratio. The thermophilic anaerobic digester 100 depicted in
In some embodiments, the thermophilic anaerobic digester 100 depicted in
First: the thermophilic anaerobic digester 100 inoculates incoming fresh feedstock with a recirculated volume from the thermophilic anaerobic digester 100 by transferring digestate from the end of the unit back into upstream blend tank 102 through digester infeed valve 130 in the anaerobic digestion system depicted in
Second: the variable decanting capability at the discharge of the digester enables the anaerobic digestion system 200 depicted in
In some embodiments, the thermophilic anaerobic digester 100 depicted in
In some embodiments, each of the agitator components—agitator shaft 32, paddle frame structure 34, paddle plate 36, and localized end-of-paddle sweeps 38—of the agitator 30 depicted in
In some embodiments, the agitator 30 depicted in
In some embodiments, the length to diameter ratio geometry of 3:1 to 5:1 of the vessel 42 permits the agitator 30 depicted in
In some embodiments, the agitator 30 depicted in
Note that all agitator wearable parts and accessories (such as pumps, valves, etc.) are external and easy to replace or repair, should such need arises to external agitator bearings 46, ratchet and pawl agitator drive 50 and agitator drive 144. Repairs are expeditious and only a few hours downtime are required. The system is modular and thus the upset of one digester is also not catastrophic.
The anaerobic digestion system 200 depicted in
In some embodiments, a feedstock of known low nutritive value (as pertains to commonly held digester nutrients) can be used for the purposes of prototypical testing of the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
The slat barn collection process made impossible to collect fresh manure and transfer to the anaerobic digestion system. The anaerobic digestion system digests the volatile organic compounds (heretofore Volatile Solids or VS), which are normally >80% of the Total Solids (TS), as confirmed by independent lab analysis. VS degrades with time, so fresh manure produces the optimum amount of biogas energy and higher digester efficiency, as measured by solids destruction rates.
Decanted DigestateGoverning bodies and regulatory agencies worldwide recognize the benign (and even beneficial) environmental aspects of the anaerobic digestion system digestate. Therefore, regulations are much less stringent than those applied to the storage and disposal of untreated waste. In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
The following is a detailed description outlining the attributes of the design of the anaerobic digestion system depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
Throughout this pre-treatment phase, blend tank agitator 108 may aggressively blend and bring about homogeneity of feedstock particle size within the blend tank 102. The blend is generally constructed of carbon steel and is insulated to retain process heat. Additionally, the specifically configured conical section of the blend tank 102 combined with the tangential material flow located at the bottom of the blend tank 102 will remove large solid material greater than ⅝ inch in diameter. This step is required to reduce variations in oversize organic material and optimize hydrolysis. Without doing so, the digester performance will be sub-optimal leading to reduced volatile solids destruction within the digester. In addition, this hydrolysis step must be completed to facilitate the downstream acidification step.
In some embodiments, the anaerobic digestion system 200 depicted in
During acidification stage following the hydrolysis, a new group of bacteria called acetogens become active. These bacteria decompose amino acids into acetic acid and hydrogen, nitrogen and carbon dioxide gases. To do this, they need oxygen, which they obtain from O2 dissolved in the feedstock structure and liquid. While acetogens are anaerobic bacteria, oxygen is not as poisonous to them as to other anaerobes. The chemical reaction that occurs when acetogens decompose amino acids is:
2C3H7NO3+O2→2HC2H3O2+3H2+N2+2CO2
serine (amino acid)+oxygen→acetic acid+hydrogen+nitrogen+carbon dioxide
In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
HC2H3O2+4H2+CO2→2CH4+2H2O+CO2
acetic acid+hydrogen gas+carbon dioxide→methane+water+carbon dioxide
Feedstocks come with a wide variety of C:N ratios. Therefore, the critical need to adjust the C:N ratio in the blend tank 102, prior to the digester in-feed, can be done by blending feedstocks. In the case of a feedstock that is too low in carbon, it can be blended with another feedstock high in nitrogen, to attain an optimal C:N ratio. This pre-treatment practice is done at the blend tank 102 and the blending facilitates the chemical reactions.
In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the blend tank 102 of the anaerobic digestion system 200 depicted in
In some embodiments, the blend tank 102 of the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
Once the Pre-treatment process is completed, the inoculated feedstock is transferred to the thermophilic anaerobic digester 100 as depicted in
In some embodiments, the water jacket on the underbelly of the thermophilic anaerobic digester 100 is generally comprised of two zones for temperature management of the digester 100. Such multi-zone configuration heats the vessel contents along the entire digester length, maintaining constant and uniform feedstock/digestate internal temperatures. Quantity of heat zones is based upon application and scale of each usage environment. These zones can be controlled independently, sequentially or together. Two zones 170 are shown on
In some embodiments, the thermophilic anaerobic digester 100 of the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
In some embodiments, the anaerobic digestion system 200 depicted in
Expected variations or differences in the results are contemplated in accordance with the objects and practices of the anaerobic digestion system. It is intended, therefore, that the anaerobic digestion system be defined by the scope of the claims which follow and that such claims be interpreted as broadly as is reasonable.
Claims
1. A thermophilic anaerobic digester, comprising:
- a cylindrical vessel mounted horizontally above ground and optimally sloped to maximize hydraulic plug flow characteristics and integrity;
- a mechanical agitator which components are located 90 degrees apart on a radial basis to propel inorganic material along the bottom.
2. The digester of claim 1, further comprising:
- a digester heating system external to the vessel.
3. The digester of claim 1, further comprising:
- one or more internal baffles to enhance and maintain biological integrity of a plug flow through the digester.
4. The digester of claim 1, wherein:
- a length to diameter ratio of the vessel is set to 3:1 to 5:1 to optimize thermophile and feedstock mixing through a longitudinal agitation arrangement.
5. The digester of claim 1, wherein:
- the vessel length to diameter ratio geometry of 3:1 to 5:1 permits the agitator to achieve optimum thermophile and feedstock mixing without excess agitation.
6. The digester of claim 1, wherein:
- the vessel is designed to maximize hydraulic plug flow characteristics and integrity.
7. The digester of claim 1, wherein:
- the digester requires a short Hydraulic Retention Time (HRT) of 3 to 7 days.
8. The digester of claim 1, wherein:
- the digester achieves volatile solids destruction (VSD) levels of 50% to 65% for animal waste.
9. The digester of claim 1, wherein:
- the digester achieves 99.999% pathogen kill.
10. The digester of claim 1, wherein:
- the digester is adjustable in order to achieve a SRT/HRT ratio that optimizes the volatile destruction and the corresponding gas production.
11. The digester of claim 1, wherein:
- the digester avoids buildup of heavy organic and inorganic material at the bottom of the vessel via self-cleaning and agitation.
12. The digester of claim 1, wherein:
- each of the components of the agitator adopts an adjustable leading edge to cope with contamination.
13. The digester of claim 1, wherein:
- the agitator turns the material within the plug flow zone into itself by mixing radically away from the central component of the agitator out toward the outer vessel circumference.
14. The digester of claim 1, wherein:
- the agitator has self-cleaning capability and is able to achieve complete, uniform but non-violent homogenization of the vessel contents.
15. An anaerobic digestion system, comprising:
- a blend tank operable to control and perform pre-treatment of feedstock;
- an anaerobic digester operable to digest the feedstock provided from the blend tank in a totally enclosed oxygen-free environment within a specific temperature range;
- a bio mass tank operable to process liquid digestate from the anaerobic digester.
16. The anaerobic digestion system of claim 15, wherein:
- the aerobic digestion system operates with a multiplicity of feedstock materials.
17. The anaerobic digestion system of claim 15, wherein:
- the aerobic digestion system draws a specific volume of digestate from the digester and re-circulates it to the blend tank.
18. The anaerobic digestion system of claim 17, further comprising:
- a pH adjust chemical metering pump and/or a pH sensor operable to adjust pH of the feedstock by chemical injection during recirculation.
19. The anaerobic digestion system of claim 15, further comprising:
- an agitator operable to aggressively blend and bring about homogeneity of particle size of the feedstock in the blend tank.
20. The anaerobic digestion system of claim 19, wherein:
- the blend tank and the agitator expedite hydrolysis, acidification and ammonia to ammonium conversion of the feedstock as a multi-functional apparatus.
21. The anaerobic digestion system of claim 15, further comprising:
- a heat exchanger and/or a temperature sensor operable to bring up the feedstock in the blend tank to processing temperatures required in the downstream digester.
22. The anaerobic digestion system of claim 15, wherein:
- the blend tank performs and accomplishes acidification upstream before injecting the feedstock into the digester.
23. The anaerobic digestion system of claim 15, wherein:
- the blend tank converts over 95% of ammonia to ammonium.
24. The anaerobic digestion system of claim 15, wherein:
- the blend tank breaks down proteins by an enzyme called protease that is secreted by fermentative bacteria.
25. The anaerobic digestion system of claim 15, wherein:
- the blend tank inoculates the pre-treated feedstock with bacteria at pre-treatment stage using anaerobe digestate taken from the discharge of the digester.
26. The anaerobic digestion system of claim 15, wherein:
- the blend tank operates within a percent of total incoming solids.
27. The digester of claim 15, further comprising:
- an inorganics valve operable to remove large inorganic matter from the blend tank during pretreatment.
28. The anaerobic digestion system of claim 15, wherein:
- the feedstock is conditioned in the anaerobic digester to where methanogen is predominant.
29. The anaerobic digestion system of claim 15, wherein:
- the anaerobic digester process organic waste within a temperature range of 35° C. to 70° C. to operate optimally.
30. The anaerobic digestion system of claim 15, wherein:
- water jacket on the underbelly of the anaerobic digester is comprised of multiple zones for temperature management of the digester.
31. The anaerobic digestion system of claim 15, wherein:
- the anaerobic digester utilizes multiple decanting valves for variable decanting in a digestate and capacity specific manner.
32. The anaerobic digestion system of claim 15, further comprising:
- a programmable logic controller (PLC) system operable to optimize and control one or more of in-feed plug flow volume, consistency, temperature, pH, digester operating temperature, decanting, and agitation of the system.
33. The anaerobic digestion system of claim 15, further comprising:
- a water seal tank operable to draw off biogas to maintain an operating pressure within the digester.
34. The anaerobic digestion system of claim 15, further comprising:
- a solids liquid separator operable to separate and process solids and liquids stored in the bio mass tank.
Type: Application
Filed: Oct 19, 2009
Publication Date: Jun 24, 2010
Inventors: Keith Wilson (Thunder Bay), Jeff Stubbings (Thunder Bay), Rod Wade (Thunder Bay), Robert Knoop (Lake Oswego, OR)
Application Number: 12/581,527
International Classification: C02F 11/04 (20060101); C02F 103/20 (20060101); C02F 101/30 (20060101);