JOINED STRUCTURAL BODY OF MEMBERS, JOINING METHOD OF MEMBERS, AND PACKAGE FOR CONTAINING AN ELECTRONIC COMPONENT
According to one embodiment, a joined structural body for mounting an electronic component on the body which is provided with a first member, a second member and a joining portion. The joining portion is provided between the first member and the second member so as to connect the first member and the second member with each other mechanically. The joining portion contains at least one metal of a tin, an indium or a zinc, and a copper. The content of the metal in the joining portion decreases toward a side of at least one of the first member and the second member, and the content of the copper in the joining portion increases in the same direction as the decreasing direction of the content of the metal.
Latest Kabushiki Kaisha Toshiba Patents:
- Transparent electrode, process for producing transparent electrode, and photoelectric conversion device comprising transparent electrode
- Learning system, learning method, and computer program product
- Light detector and distance measurement device
- Sensor and inspection device
- Information processing device, information processing system and non-transitory computer readable medium
This application is based upon and claims the benefit of priority from the prior Japanese Patent Application No. 2011-235385, filed on Oct. 26, 2011, the entire contents of which are incorporated herein by reference.
FIELDEmbodiments described herein relate generally to a joined structural body of members, a method of joining members, and a package for containing an electronic component.
BACKGROUNDAn electronic component, which is represented by a semiconductor element, is bonded to a substrate which supports the electronic component. The electronic component bonded to the substrate is mounted on another substrate such as a mounting board. Many of the electronic components are hermetically sealed within a package provided with a substrate in order to enhance the reliability of the electronic components. Such a substrate or a package needs to be stable against a temperature during bonding or operation of the electronic component. Accordingly, a plurality of members which constitute such a substrate or a package is joined using a silver solder having a melting point higher than a bonding temperature of the electronic component normally, for example.
In general, the substrate or the package is a complex which includes a circuit element for use of input/output of a signal or power supply from a power source, and a heat radiation element for radiating heat from an electronic component to outside. Members constituting such a complex may have different linear expansion coefficients. When the members are assembled by a silver solder under a high temperature, a warp or a strain is generated in the members due to the difference of the linear expansion coefficients of the members. The warp or strain deteriorates a characteristic of an electronic component, and lowers the reliability of the electronic component. Thus, it is needed to present a joined structural body of members and a method of joining members which are stable against a temperature during bonding or operation of an electronic component and can suppress warp and strain.
According to one embodiment, a joined structural body for mounting an electronic component on the body which is provided with a first member, a second member and a joining portion. The joining portion is provided between the first member and the second member so as to connect the first member and the second member with each other mechanically. The joining portion contains at least one metal of a tin, an indium or a zinc, and a copper. The content of the metal in the joining portion decreases toward a side of at least one of the first member and the second member, and the content of the copper in the joining portion increases in the same direction as the decreasing direction of the content of the metal.
Hereinafter, further embodiments will be described with reference to the drawings.
In the drawings, the same reference numerals denote the same or similar portions respectively.
A first embodiment will be described with reference to
In
The feed through terminals 7 are arranged between the substrate 3 and the frame body 5 in an up-and-down direction. The feed through terminals 7 are provided so as to connect an electronic component which is mounted on the component mounting portion 12 and is hermetically sealed in the package 10 with an external circuit electrically. Two leads 9 which are connected with the external circuit are respectively connected to the feed through terminals 7. An electronic component and strip lines 7b of the feed through terminals 7 can be respectively connected via wires (or conductive plates or ribbons).
As illustrated in
In manufacturing the package 10, an electronic component is bonded to a surface 3a (a component mounting portion 12) of the substrate 3 by using a solder of gold (Au) and tin (Sn), for example. Further, a lid is fixed to an upper surface of the frame body 5 so as to seal the inside hermetically, if required. In the bonding process, the package 10 is heated to about 280 to 300° C. Accordingly, the remelting temperature of the joining portion 13 is desired to be more than or equal to 300° C. As the temperature difference between a bonding temperature and the remelting temperature (melting point) of the joining portion 13 becomes larger, the manufacture is stable more.
When a silver solder which is widely used as a joining material is employed, for example, bonding of an electronic component can be carried out stably against a bonding temperature since the melting point of the silver solder is more than or equal to 780° C. However, when the substrate 3 is made of a copper alloy, the frame body 5 is made of a kovar, and the substrate 3 and the frame body 5 are joined using a silver solder, warp or strain is large due to the difference between the linear thermal expansion coefficients of the substrate 3 and the frame body 5 during the cooling process of the silver solder, the substrate 3 and the frame body 5. It is because the melting point of the sliver solder is high,
As a result, when the package 10 which contains a semiconductor element is attached to a mount board, a gap is created between the rear surface 3b of the substrate 3 and the mount board, which lowers performance of heat dissipation. Further, when one of the substrate 3 and the frame body 5 is formed of ceramics, a crack may be produced.
According to the embodiment, the joining portion 13 can be formed by a liquid phase diffusion of copper and tin. The liquid phase diffusion of copper and tin is caused within a temperature range of 250 to 300° C., which allows forming the joining portion 13 at a temperature lower than that of the silver solder. When the joining portion 13 is formed by such a method, warp or strain of the substrate 3 and the frame body 5 can be suppressed. The melting point of a chemical compound formed by a liquid phase diffusion of copper and tin is 750° C., for example, which is substantially the same as the melting point of a silver solder. Accordingly, the chemical compound is stable against a bonding temperature for an electronic component and an operating temperature of the electronic component.
Hereinafter, examples of forming process of the joining portion 13 and examples of the structure of the joining portion 13 will be described in detail.
In a manufacturing process of the package 10, the substrate 3 as the first member and the frame body 5 as the second member are prepared. As illustrated in
As illustrated in
The joining metal layer 21 may be formed using a vacuum deposition, a sputtering, or plating. On the other hand, the joining metal layer 23 may be formed by sputtering copper on a surface of the substrate 3 and patterning a deposited copper layer to a predetermined shape. Further, adhesion layers containing titanium or nickel may be provided, respectively, between the joining metal layer 21 and the frame body 5, and between the joining metal layer 23 and the substrate 3, in order to strengthen adhesion.
Then, the substrate 3 is heated, and the temperature of the joining metal layers 21, 23 is maintained within a range of 250 to 300° C., for example. As a result, as illustrated in
As illustrated in
The joining portion 13 contains at least one metal of a low melting point among tin (Sn), indium (In) or zinc (Zn), and copper (Cu). The content of the metal of the low melting point decreases toward a side of the substrate 3, and the content of copper increases toward the side of the substrate 3.
For example, the joining metal layer 21 is made of a tin layer having a thickness of 4 μm, and the joining metal layer 23 is made of a copper layer having a thickness of 4 μm. The joining metal layers 21, 23 are brought into contact with each other. The joining metal layers 21, 23 are heated and maintained at 250° C. for about 30 minutes, for example. Under such a temperature, the joining portion 13 can be formed by diffusing tin into the joining metal layer 23 (a copper layer).
For example, when the solid solution is a composition containing copper of 90 wt % and tin of 10 wt % that is a composition indicated by a broken line extending vertically in
The thicknesses of the joining metal layers 21, 23 are set in consideration of a joining time and a joining strength. For example, when the thickness of the joining metal layer 21 is small, the unevenness of the joining surface cannot be sufficiently suppressed so that voids may be created, resulting in weakening the joining strength. In contrast, when the thickness is too large, the joining process needs a long time, resulting in lowering the manufacturing efficiency. Desirably, the thickness of the joining metal layer 21 is less than or equal to 10 μm, and more than or equal to 2 μm.
As illustrated in
Subsequently, as illustrated in
As schematically illustrated in
As illustrated in
Then, as illustrated in
In the modification, the joining metal layer 25 to be provided on the frame body 5 may be omitted. In this case, the joining portion 13 becomes to have a diffusion region 31a formed on the substrate 31, and the proportion of the metal of the low melting point decreases in the direction from the frame body 5 to the substrate 31, and the proportion of copper increases in the same direction.
The metal of the low melting point contained in the joining metal layer 21 and the copper contained in the joining metal layer 23 are metals which are easy to be oxidized. When oxidized layers are formed on the surface of the joining metal layer 21 and the surface of the joining metal layer 23, the oxidized layers prevents diffusion of the metal of the low melting point from the joining metal layer 21 to the joining metal layer 23. The protective metal layers 35, 33 are formed on the respective surfaces of the joining metal layer 21 and the joining metal layer 23 in order to enhance the diffusion.
The protective metal layers 33, 35 may be made using gold (Au), or platinum (Pt). The protective metal layer 35 provided on the surface of the joining metal layer 21 and the protective metal layer 33 provided on the surface of the joining metal layer 23 are brought into contact with each other, and maintained in a range of 250 to 300° C., for example.
Under the temperature range, when the metal of the low melting point contained in the joining metal layer 21 is melted, the protective metal layers 33, 35 are introduced into the liquid phase. As illustrated in
The joining metal layers 23, 25 are maintained in a state of contacting with each other via the joining metal layer 21 so that a joining portion as the joining portion 13 shown in
The joining portion 13 contains a high proportion of the metal of the low melting point at an intermediate position between the substrate 3 and the frame body 5. The proportion of the metal of the low melting point decreases toward both sides of the substrate 3 and the frame body 5, and the proportion of copper increases toward both sides of the substrate 3 and the frame body 5. Further, the joining portion becomes to contain at least one of gold (Au) or platinum (Pt) which are introduced from the protective metal layers 33, 35.
As illustrated in
Further, as illustrated in
In order to fix the feed through terminals 7 having the above-mentioned structure between the substrate 3 and the frame body 5, the substrate 3 and the feed through terminals 7 are connected via a joining portion 13a, and the frame body 5 and the feed through terminals 7 are joined via a joining portion 13b. As illustrated in
Further, conductive layers 13c are sandwiched between the strip lines 7b provided in the feed through terminals 7 and the leads 9. A lid (not shown) may be fixed to an upper surface of the frame body 5 so as to sealing the inside hermetically.
The joining portions 13a, 13b contain at least one metal of a low melting point among tin (Sn), indium (In), and zinc (Zn), and copper (Cu), respectively. In the joining portion 13a, the proportion of the metal of the low melting point decreases, and the proportion of copper increases, toward at least one of the insulating material layers 7a and the substrate 3. In the joining portion 13b, the proportion of the metal of the low melting point decreases, and the proportion of copper increases, toward at least one side of the insulating material layer 7c and the frame body 5.
As described above, the joined structural body described in the first embodiment is provided with a joining portion produced by diffusing at least one metal of a low melting point among tin (Sn), indium (In) or zinc (Zn) into a joining metal layer containing copper. The structure present a package which can suppress warp and strain.
The temperature for diffusing the metal of the low melting point is not limited to the range of 250 to 300° C., and may be different depending on the kind of the metal of the low melting point. For example, when indium is used, diffusion can be performed under a range of lower temperature, and in a case of using zinc, diffusion can be performed under a range of higher temperature.
Further, in the first embodiment mentioned above, a package which contains an electronic component is described as an example, but the package is not limited to such a package. For example, the invention can be applied to a so-called carrier of a structure that members having strip lines are joined to a substrate.
Further, in the first embodiment, at least one of the first member and the second member may be ceramics such as alumina (Al2O3) or aluminum nitride (AlN).
In
As illustrated in
As illustrated in
Further, a lid 49 is fixed on an upper surface of a frame body 5 so as to seal the transistor 41 hermetically. A nitrogen gas or a similar gas is filled in the inside of the package 100 so as to make the operation of the transistor 41 stable and to enhance the reliability of the transistor 41. The lid 49 is soldered to the frame body 5 using AuSn, for example.
In the package 100, insulating material layers 7a and an insulating material layer 7c are provided. The insulating material layers 7a are formed on the substrate 3. The insulating material layers 7a and the insulating material layer 7c sandwich strip lines 7b respectively. The insulating material layer 7c and the frame body 5 are joined via a joining portion 13b. The joining portion 13b may be formed by a liquid phase diffusion of tin and copper. Such a joining process is performed under a temperature lower than a temperature of silver soldering so that warp or strain of the substrate 3 and the frame body 5 can be suppressed. As a result, when a rear surface of the substrate 3 is adhered to a mount board or a heat sink, heat which is generated in the power transistor 41 can be efficiently dissipated. Accordingly, the operation of the power transistor can be stable, and the reliability of the power transistor can be enhanced.
An operation temperature of a transistor which uses a wide-gap semiconductor material such as GaN or SiC reaches 600° C. Even in such a case, the melting point of the joining portion where tin is diffused into copper is above the operation temperature so that the transistor can be stably operated.
The package 100 according to the embodiment is not limited to using the transistor mentioned above. A photo semiconductor element such as a LED or a laser element, or a piezo-electric element such as a SAW filter can be used.
While certain embodiments have been described, these embodiments have been presented by way of example only, and are not intended to limit the scope of the inventions. Indeed, the novel embodiments described herein may be embodied in a variety of other forms; furthermore, various omissions, substitutions and changes in the form of the embodiments described herein may be made without departing from the spirit of the inventions. The accompanying claims and their equivalents are intended to cover such forms or modifications as would fall within the scope and spirit of the inventions.
Claims
1. A joined structural body for mounting an electronic component on the body, comprising:
- a first member;
- a second member; and
- a joining portion provided between the first member and the second member so as to connect the first member and the second member with each other mechanically, the joining portion containing at least one metal of a tin, an indium or a zinc, and a copper, the content of the metal in the joining portion decreasing toward a side of at least one of the first member and the second member, the content of the copper in the joining portion increasing in the same direction as the decreasing direction of the content of the metal.
2. The joined structural body according to claim 1, wherein the content of the metal decreases toward both sides of the first member and the second member, and the content of the copper increases toward both sides of the first member and the second member.
3. The joined structural body according to claim 2, wherein the joining portion includes a first layer containing copper which is provided on a side of the first member, and a second layer containing copper which is provided on a side of the second member.
4. The joined structural body according to claim 1, wherein the joining portion contains at least one of a gold or a platinum.
5. The joined structural body according to claim 2, wherein the joining portion contains at least one of a gold or a platinum.
6. The joined structural body according to claim 3, wherein the joining portion contains at least one of a gold or a platinum.
7. The joined structural body according to claim 1, wherein the first member is made of one of a copper or a copper alloy, and the second member is made of an alloy containing an iron.
8. The joined structural body according to claim 1, wherein at least one of the first member and the second member contains a ceramic material.
9. A method of joining members which forms a joined structural body for mounting an electronic component on the body, comprising:
- bringing a surface of a first member containing a copper into contact with a surface of a first joining metal layer of at least one metal of a tin (Sn), an indium (In) or a zinc (Zn) which is formed on a second member, and
- heating the first member and the second member so as to diffuse the at least one metal from the surface of the first member containing the copper into an inside of the first member while maintaining the contact between the first member and the first joining metal layer.
10. The method of joining members according to claim 9, wherein a second joining metal layer containing a copper is formed on the surface of the first member, and a surface of the second joining metal layer and the surface of the first joining metal layer are brought into contact with each other.
11. The method of joining members according to claim 9, wherein a third joining metal layer containing a copper is formed between the first member and the first joining metal layer.
12. The method of joining members according to claim 10, wherein a third joining metal layer containing a copper is formed between the first member and the first joining metal layer.
13. The method of joining members according to claim 9, wherein protective metal layers are provided on the surface of the first member and the surface of the first joining metal layer respectively.
14. The method of joining members according to claim 13, wherein the protective metal layers contains at least one of a gold or a platinum.
15. A package comprising:
- a substrate on which an electronic component is mounted; and
- a frame body which surrounds a portion on which the electronic component is mounted, the frame body being joined mechanically with the substrate via a joining portion containing at least one metal of a tin, an indium or a zinc, and a copper,
- wherein the content of the at least one metal in the joining portion decreases toward a side of at least one of the substrate or the fame body, and the content of the copper in the joining portion increases in the same direction as the decreasing direction of the content of the at least one metal.
16. The package according to claim 15, further comprising a feed through terminals for inputting a signal into the electronic component and for outputting a signal from the electronic component respectively, wherein
- the joining portion includes a first joining portion and a second joining portion, and
- the substrate and the feed through terminals are joined via the first joining portion, and the frame body and the feed through terminals are joined via the second joining portion.
17. The package according to claim 15, wherein
- the content of the metal decreases toward both sides of the substrate and the frame body, and
- the content of the copper increases toward both sides of the substrate and the frame body.
18. The package according to claim 15, wherein the joining portion has a first layer containing a copper which is provided on a side of the substrate, and a second layer containing a copper which is provided on a side of the frame body.
19. The package according to claim 15, wherein the joining portion contains at least one of a gold or a platinum.
Type: Application
Filed: Jul 26, 2012
Publication Date: May 2, 2013
Applicant: Kabushiki Kaisha Toshiba (Tokyo)
Inventor: Kazutaka TAKAGI (Kanagawa-ken)
Application Number: 13/558,765
International Classification: H05K 1/09 (20060101); B23K 20/00 (20060101); B32B 5/14 (20060101);