Methods for Confinement of Foam Delivered by a Proximity Head
A method suctions liquid from an upper surface of a substrate as the substrate is transported by a carrier under a head in a chamber. This operation is performed by the first section of the head. The method causes a first film of cleaning foam to flow onto the upper surface of the substrate as the substrate proceeds under the head. This operation is performed by a second section which is contiguous to the first section in the head. The method causes a second film of rinsing fluid to flow onto the upper surface of the substrate as the substrate is carried under the head. This rinsing operation is performed by a third section which is contiguous to the second section in the head and which is defined partially around the second section and up to the first section.
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This application is a divisional application of U.S. patent application Ser. No. 12/324,316, entitled “Confinement of Foam Delivered by a Proximity Head”, which was filed on Nov. 26, 2008, and was published on May 27, 2010, as U.S. Published Patent Application No. 2010/0126528, whose disclosure is hereby incorporated herein by reference in its entirety.
BACKGROUNDDue to advances in device scaling for semiconductors, semiconductor device features have become smaller at the same time their aspect ratios have become larger. Consequently, semiconductor-device structures have become susceptible to damage from wet cleaning and drying. This susceptibility is exacerbated by the use of new materials in the process flows for semiconductor manufacturing.
In response to this susceptibility and other shortcomings in the technology for wet cleaning and drying, a system has been developed that uses mechanical and chemical cleaning to selectively remove residue without damage to semiconductor-device structures. This system transports a single semiconductor wafer linearly between an opposing pair of proximity heads that deliver a cleaning fluid to the wafer in an exposure time on the order of a few seconds.
In particular implementations, the cleaning fluid delivered by the opposing proximity heads is a high viscosity, non-Newtonian fluid in the form of a foam generated by mechanically mixing (a) a gas such as nitrogen (N2) and (b) a fluid containing water and a surfactant. See e.g., U.S. Published Patent Application No. 2006/0128600 entitled “Cleaning Compound and Method and System for Using the Cleaning Compound,” filed on Feb. 3, 2006, U.S. application Ser. No. 11/820,590 entitled “System, Method and Apparatus for Maintaining Separation of Liquids in a Controlled Meniscus” filed on Jun. 19, 2007, and U.S. application Ser. No. 12/185,780 entitled “Generator for Foam to Clean Substrate,” filed on Aug. 4, 2008. The disclosures of all three of these applications are hereby incorporated by reference.
If the surfactant is allowed to escape into the system's chamber during the deposition of the foam onto the semiconductor wafer, the surfactant can dry into a solid and contaminate later semiconductor wafers processed by the system. Consequently, a need exists for an inexpensive and effective means of confining the cleaning foam during its deposition onto a semiconductor wafer by the system. However, the invention claimed below has wide applicability to other applications beyond this particular application, as will become apparent from the following description and drawings.
SUMMARYIn an example embodiment, a linear wet system includes a carrier and a proximity head in a chamber. The carrier includes pins on which a semiconductor wafer rests, exposing both surfaces of the wafer as the wafer is transported through the system. The proximity head might be positioned above, below, or on both sides of the carrier. In this example embodiment, the proximity head might include three sections in a linear arrangement. The first section suctions liquid from the upper surface of the wafer as the wafer moves under the proximity head. The second section, which is contiguous to the first section, causes a film (or meniscus) of cleaning foam to flow onto the upper surface of the wafer as the wafer proceeds under the head. The third section, which is contiguous to the second section, causes a film (or meniscus) of rinsing fluid to flow onto the upper surface of the wafer as the wafer is carried under the proximity head. In this example embodiment, the third section is partially defined around the second section and up to the first section so that the third section and the first section create a confinement of the cleaning foam in the second section
In another example embodiment, a linear wet system includes a carrier and a proximity head in a chamber. The carrier includes pins on which a semiconductor wafer rests, exposing surfaces of the wafer as the wafer is transported through the system. The proximity head might be positioned above and/or below the carrier. In this example embodiment, the proximity head might include two sections in a linear arrangement. The first section suctions liquid from the upper surface of the wafer as the wafer moves under the proximity head. The second section, which is contiguous to the first section, causes a film (or meniscus) of cleaning foam to flow onto the upper surface of the wafer as the wafer proceeds under the head. In this example embodiment, the cleaning foam from is prevented from escaping into the chamber by a barrier of suction surrounding the cleaning foam.
In another example embodiment, an automated method for a linear wet system includes three operations. In the method's first operation, a first section in a proximity head suctions liquid from the upper surface of a semiconductor wafer as the wafer is transported by a carrier under the proximity head in a chamber. In the method's second operation, a second section in a proximity head, contiguous to the first section, causes a film (or meniscus) of cleaning foam to flow onto the upper surface of the wafer as the wafer proceeds under the head. In the method's third operation, a third section in the proximity head, contiguous to the second section, causes a film (or meniscus) of rinsing fluid to flow onto the upper surface of the wafer as the wafer is carried under the proximity head. In this example embodiment, the third section is partially defined around the second section and up to the first section so that the third section and the first section create a confinement of the cleaning foam in the second section.
The advantages of the present invention will become apparent from the following detailed description, which taken in conjunction with the accompanying drawings, illustrates by way of example the principles of the invention.
In the following description, numerous specific details are set forth in order to provide a thorough understanding of the example embodiments. However, it will be apparent to one skilled in the art that the example embodiments may be practiced without some of these specific details. In other instances, implementation details and process operations have not been described in detail, if already well known.
It will be appreciated that the fluid meniscus 105 does not confine the P3 so as to prevent it from escaping into the chamber that houses the carrier 101 and the proximity heads 103 and 104, where the P3 might dry and release the solid surfactant as a contaminant in the linear wet system. In an example embodiment, the solid surfactant might be stearic acid, though other fatty acids can be used as alternatives as explained in U.S. Published Patent Application No. 2006/0128600, incorporated by reference above. Those other fatty acids include lauric, palmitic, oleic, linoleic, linolenic, arachidonic, gadoleic, eurcic, butyric, caproic, caprylic, myristic, margaric, behenic, lignoseric, myristoleic, palmitoleic, nervanic, parinaric, timnodonic, brassic, and clupanodonic acid, either alone or in combination with themselves or with stearic acid.
The AMC head 106 shown in
Also depicted in
It will be appreciated that the deflecting edge 120a protects the semiconductor wafer from damage caused by direct downward flow onto the surface of the wafer. Further, the deflecting edge 120a and its opposing deflecting edge 120b physically confine the P3 meniscus 121, through creation of a circular flow, among other things. In turn, this physical confinement reduces the flow of P3 to the “mixed inner return” 119c, which is responsible for suctioning the DIW in the DIW confinement meniscus.
Also shown in
In P3 zone 117, P3 flows out of an input channel 117a across the bottom of an AMC head to a return channel 117b. Similarly, in P3 zone 118, P3 flows out of an input channel 118a across the bottom of an AMC head to a return channel 118b. As depicted in this figure, the shear rate of the P3 near an input channel is in a range of 175-275 reciprocal seconds. As the P3 spreads across the bottom of the AMC head, the shear rate of the P3 decreases to a range of 50-175 reciprocal seconds until the P3 nears a return channel, where the shear rate increase to a range of 125-225 reciprocal seconds.
It will be appreciated that both the staggered locations and the sizes of the input and return channels in P3 zones 117 and 118 create a radial flow pattern on the surface of the wafer that is gentle and non-directional with respect to shear rate. Such a radial flow pattern deposits P3 on the surface of the wafer without preferential direction in a manner that prevents damage to structures on the wafer.
Additionally,
Although the foregoing example embodiments have been described in some detail for purposes of clarity of understanding, it will be apparent that certain changes and modifications may be practiced within the scope of the appended claims. For example, the AMC head might confine a fluid other than a high-viscosity, non-Newtonian foam such as P3, in alternative example embodiments. Accordingly, the example embodiments are to be considered as illustrative and not restrictive, and the invention is not to be limited to the details given herein, but may be modified within the scope and equivalents of the appended claims.
Claims
1. A method for processing a substrate, comprising:
- suctioning liquid from an upper surface of a substrate as the substrate is transported by a carrier under a head in a chamber, wherein the carrier includes pins on which the substrate rests and which exposes surfaces of the substrate and wherein this suctioning operation is performed by the first section of the head;
- causing a first film of cleaning foam to flow onto the upper surface of the substrate as the substrate proceeds under the head, wherein this cleaning operation is performed by a second section which is contiguous to the first section in the head; and
- causing a second film of rinsing fluid to flow onto the upper surface of the substrate as the substrate is carried under the head, wherein this rinsing operation is performed by a third section which is contiguous to the second section in the head and which is defined partially around the second section and up to the first section and wherein the third section and the first section create a confinement of the cleaning foam with respect to the chamber.
2. A method as in claim 1, wherein the second section includes one or more input channels for delivering the first film of cleaning foam and one or more output channels for removing the first film of cleaning foam.
3. A method as in claim 2, wherein the input and output channels are arranged to cause the first film to flow in a radial pattern across the upper surface of the substrate.
4. A method as in claim 2, wherein each of the input channels in the second section includes an edge that projects over the mouth of the input channel.
5. A method as in claim 2, wherein a group of the input channels are located at the bottom of one side of a triangular reservoir fed by a main passage above the intersection of the other two sides.
6. A method as in claim 2, further comprising an operation of:
- causing a third film of cleaning foam to flow onto the upper surface of the substrate as the substrate proceeds under the head, wherein this cleaning operation is performed by a third section included in the head, contiguous to the second section, and wherein the cleaning foam in the third film has a composition which differs from the composition of the cleaning foam in the first film.
7. A method as in claim 6, wherein the input and output channels of both the second section and the third section are arranged to cause cleaning foam to flow in radial patterns across the upper surface of the substrate.
8. A method as in claim 1, wherein the cleaning foam comprises a liquid, a gas, and a surfactant.
9. A method as in claim 1, wherein the substrate is a semiconductor wafer.
10. A method for processing a substrate, comprising:
- suctioning liquid from an upper surface of a substrate as the substrate is transported by a carrier under a head in a chamber, wherein the carrier includes pins on which the substrate rests and which exposes surfaces of the substrate and wherein this suctioning operation is performed by the first section of the head;
- causing a first film of cleaning foam to flow onto the upper surface of the substrate as the substrate proceeds under the head, wherein this cleaning operation is performed by a second section which is contiguous to the first section in the head and wherein a group of the input channels are located below a horizontal triangular reservoir fed by a main passage above an intersection of the other two sides of the triangular reservoir; and
- causing a second film of rinsing fluid to flow onto the upper surface of the substrate as the substrate is carried under the head, wherein this rinsing operation is performed by a third section which is contiguous to the second section in the head and which is defined partially around the second section and up to the first section and wherein the third section and the first section create a confinement of the cleaning foam with respect to the chamber.
11. A method as in claim 10, wherein the second section includes one or more input channels for delivering the first film of cleaning foam and one or more output channels for removing the first film of cleaning foam.
12. A method as in claim 11, wherein the input and output channels are arranged to cause the first film to flow in a radial pattern across the upper surface of the substrate.
13. A method as in claim 11, wherein each of the input channels in the second section includes an edge that projects over the mouth of the input channel.
14. A method as in claim 11, wherein a group of the input channels are located at the bottom of one side of a triangular reservoir fed by a main passage above the intersection of the other two sides.
15. A method as in claim 11, further comprising an operation of:
- causing a third film of cleaning foam to flow onto the upper surface of the substrate as the substrate proceeds under the head, wherein this cleaning operation is performed by a third section included in the head, contiguous to the second section, and wherein the cleaning foam in the third film has a composition which differs from the composition of the cleaning foam in the first film.
16. A method as in claim 15, wherein the input and output channels of both the second section and the third section are arranged to cause cleaning foam to flow in radial patterns across the upper surface of the substrate.
17. A method as in claim 10, wherein the cleaning foam comprises a liquid, a gas, and a surfactant.
18. A method as in claim 10, wherein the substrate is a semiconductor wafer.
19. A method for processing a substrate, comprising:
- suctioning liquid from an upper surface of a substrate as the substrate is transported by a carrier under a head in a chamber, wherein the carrier includes pins on which the substrate rests and which exposes surfaces of the substrate and wherein this suctioning operation is performed by the first section of the head;
- causing a film of cleaning foam to flow onto the upper surface of the substrate as the substrate proceeds under the head, wherein this cleaning operation is performed by a second section which is contiguous to the first section in the head, wherein the cleaning foam is a non-Newtonian fluid with a viscosity in a range of about 200-2000 centipoise (cP); and
- causing a film of rinsing fluid to flow onto the upper surface of the substrate as the substrate is carried under the head, wherein this rinsing operation is performed by a third section which is contiguous to the second section in the head and which is defined partially around the second section and up to the first section and wherein the third section and the first section create a confinement of the cleaning foam with respect to the chamber.
20. A method as in claim 19, wherein the cleaning foam comprises a liquid, a gas, and a surfactant.
Type: Application
Filed: May 22, 2014
Publication Date: Sep 11, 2014
Applicant: Lam Research Corporation (Fremont, CA)
Inventors: Arnold Kholodenko (San Francisco, CA), Cheng-Yu Lin (Sunnyvale, CA), Leon Ginzburg (Santa Clara, CA), Mark Mandelboym (Santa Clara, CA), Greg Tomasch (Kelseyville, CA), Anwar Husain (Pleasanton, CA)
Application Number: 14/285,603
International Classification: H01L 21/67 (20060101);