Method and material for use with dental composites for improving conversion of monomers to polymers and reducing volume shrinkage
A composition for use in dental treatments of damaged or diseased teeth is provided. The composition comprises a combined filler material, photoinitiator and comonomer resin mixture polymerizable upon incidence of light. The comonomer resin mixture comprises a comonomer resin blend comprising at least two monomers from the same monomer series with at least a first monomer having a first molecular weight and a second monomer having a second molecular weight with the second molecular weight being greater than the first molecular weight of the first monomer. The comonomer resin mixture further comprises a third monomer combined with the comonomer resin blend.
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Claims
1. A composition for use in dental treatments of damaged or diseased teeth, the composition comprising:
- a filler material;
- a photoinitiator combined with the filler material; and
- a comonomer resin mixture polymerizable upon incidence of light, the mixture being combined with the filler material and the photoinitiator, the mixture comprising:
- a comonomer resin blend comprising at least a first monomer having a first molecular weight and a second monomer having a second molecular weight, the second molecular weight being greater than the first molecular weight of the first monomer; and
- a third monomer combined with the comonomer resin blend.
2. The composition of claim 1 wherein the third monomer comprises approximately between 50-80 wt % of the comonomer resin mixture and the comonomer resin blend comprises approximately between 20-50 wt % of the comonomer resin mixture.
3. The composition of claim 1 wherein the third monomer comprises a monomer selected from the group consisting of BIS-GMA, CH.sub.3 BIS-GMA and 3F BIS-GMA.
4. The composition of claim 1 wherein the second monomer comprises at least 1 wt % of the comonomer resin blend.
5. The composition of claim 1 wherein the first monomer comprises approximately between 70-95 wt % of the comonomer resin blend and the second monomer comprises approximately between 5-30% of the comonomer resin blend.
6. The composition of claim 5 wherein the first monomer comprises a monomer selected from the group consisting of diethylene glycol dimethacrylate and triethylene glycol dimethacrylate and the second monomer comprises poly(ethylene glycol 600) dimethacrylate.
7. The composition of claim 1 wherein the first monomer and the second monomer comprise monomers selected from the series consisting of poly(ethylene glycol) dimethacrylates, poly(alkane diol) dimethacrylates, and poly(ethylene diol) dimethacrylates.
8. The composition of claim 1 wherein the comonomer resin blend comprises at least two monomers from the same monomer series.
9. The composition of claim 1 wherein the second monomer has a molecular weight of greater than 286 g/mol.
10. The composition of claim 1 wherein the resin blend comprises an molecular weight greater than 286 g/mol.
11. A method for restoring a lesion in a tooth, the method comprising;
- combining at least two monomer resins creating a comonomer resin blend, the comonomer resin blend comprising a first monomer resin having a first molecular weight with a second monomer resin having a second molecular weight, the second molecular weight being greater than the first molecular weight of the first monomer resin;
- mixing a third monomer with the first and second monomers to create a comonomer resin mixture, the third monomer increasing the viscosity of the comonomer resin mixture;
- adding a photoinitiator to the comonomer resin mixture;
- blending a filler material into the comonomer resin mixture; and
- photopolymerizing the comonomer resin mixture, photoinitiator and filler material to convert at least a portion of the first, second and third monomers in the comonomer resin mixture into a copolymer resin composition.
12. The method of claim 11 wherein the third monomer comprises approximately between 50-80 wt % of the comonomer resin mixture and the comonomer resin blend comprises approximately between 20-50 wt % of the comonomer resin mixture.
13. The method of claim 11 wherein the third monomer comprises a monomer selected from the group consisting of BIS-GMA, CH.sub.3 BIS-GMA and 3F BIS-GMA.
14. The method of claim 11 wherein the second monomer comprises at least 1 wt % of the comonomer resin blend.
15. The method of claim 11 wherein the first monomer comprises approximately between 70-95 wt % of the comonomer resin blend and the second monomer comprises approximately between 5-30% of the comonomer resin blend.
16. The method of claim 11 wherein the first monomer and the second monomer comprise monomers selected from the series consisting of poly(ethylene glycol) dimethacrylates, poly(alkane diol) dimethacrylates, and poly(ethylene diol) dimethacrylates.
17. The method of claim 16 wherein the first monomer comprises a monomer selected from the group consisting of diethylene glycol dimethacrylate and triethylene glycol dimethacrylate and the second monomer comprises poly(ethylene glycol 600) dimethacrylate.
18. The composition of claim 16 wherein the comonomer resin blend comprises at least two monomers from the same monomer series.
19. The method of claim 11 wherein the second monomer has a molecular weight of greater than approximately 286 g/mol.
20. The method of claim 11 wherein the comonomer resin blend comprises an average molecular weight greater than approximately 286 g/mol.
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- Anseth, et al, Polymeric Dental Composites: Properties and Reaction Behavior of Multimethacrylate Dental Restorations, Anseth et al, Advances In Polymer Science pp. 179-212, 1995.
Type: Grant
Filed: Mar 11, 1996
Date of Patent: Mar 24, 1998
Assignee: The Regents of the University of Colorado (Boulder, CO)
Inventors: Christopher N. Bowman (Nederland, CO), Kristi S. Anseth (Boston, MA), Anandkumar R. Kannurpatti (Boulder, CO), Michael D. Goodner (Lafayette, CO)
Primary Examiner: Nicholas D. Lucchesi
Attorney: Emery L. Tracy
Application Number: 8/613,348
International Classification: A61C 500;
