Method of manufacturing a cathode assembly
A method of forming a coating on an electron emitting cathode, in which (1) a black coating is formed on the inner surface of a cathode sleeve constituting the electron emitting cathode, (2) the cathode sleeve is filled with a suspension as a coating material, and (3) a porous absorbent member is brought into contact with or near an opening portion of the cathode sleeve at the same time or after the cathode sleeve is filled with the suspension, thereby causing the porous absorbent member to absorb an unnecessary portion of the suspension. Thereafter, the cathode sleeve to which the coating material is adhered is heat-treated. As a result, a black coating having a uniform thickness is formed, on the inner surface of the cathode sleeve, as a sintered layer obtained by mixing tungsten having an average particle diameter in a range of 0.5 .mu.m (inclusive) to 2 .mu.m (inclusive) with alumina having an average particle diameter in a range of 0.1 .mu.m (inclusive) to 1 .mu.m (exclusive) at a weight ratio of the tungsten to the alumina in a range of (90:10) to (65:35).
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Claims
1. A cathode assembly manufacturing method for forming a black coating on an inner surface of a cathode sleeve, comprising the steps of:
- coating a suspension on the inner surface of said cathode sleeve, the suspension being obtained by mixing tungsten having an average particle size in a range of 0.5.mu.m (inclusive) to 2.mu.m (inclusive) and alumina having an average particle size in a range of 0.1.mu.m (inclusive) to 1.mu.m (exclusive) in a dispersion at a weight ratio of the tungsten to the alumina in a range of (90:10) to (65:35); and
- sintering the suspension coating in a substantially nonoxidizing atmosphere at a temperature in a range of 1,250.degree. C. to 1,580.degree. C., to form a black coating.
2. A method according to claim 1, wherein said cathode sleeve is made of a component selected from the group consisting of tantalum, an alloy containing tantalum as a main component, niobium, and an alloy containing niobium as a main component.
3. A method according to claim 1, wherein the suspension coating is sintered at a temperature in a range of 1,400.degree. C. to 1,550.degree. C.
4. A cathode assembly manufacturing method of forming a black coating on an inner surface of a cathode sleeve, comprising the steps of:
- preparing a suspension of powders or particles for the black coating;
- filing said cathode sleeve with the suspension;
- bring a porous absorbent member into contact with the suspension in an opening portion of said cathode sleeve, at the same time or after said cathode sleeve is filled with the suspension, thereby causing said porous absorbent member to absorb unnecessary portion of the suspension, leaving a suspension residue on the inner surface of said cathode sleeve as a black coating; and
- heat-treating said cathode sleeve to which the black coating material is attached.
5. A method according to claim 4, wherein the suspension, as the material for the black coating, is prepared by mixing a refractory fine powder with a dispersion.
6. A method according to claim 5, wherein a weight ratio of the refractory fine powder to the dispersion is in a range of (30:70) to (70:30).
7. A method according to claim 5, wherein the refractory fine powder has an average particle size of not more than 2.mu.m.
8. A method according to claim 5, wherein the refractory fine powder is a powder mixture obtained by mixing tungsten having an average particle size in a range of 0.5.mu.m (inclusive) to 2.mu.m (inclusive) with alumina having an average particle size in a range of 0.1.mu.m (inclusive) to 1.mu.m (exclusive) at a weight ratio of the tungsten to the alumina in a range of (90:10) to (65:35).
9. A method according to claim 8, wherein the weight ratio of the tungsten to the alumina is in a range of (70:30) to (85:15).
10. A method according to claim 4, wherein the dispersion is composed of a solution mixture constituted by nitrocellulose and butyl acetate.
11. A method according to claim 4, wherein said cathode sleeve is fabricated from a component selected from the group consisting of a single component composed of a Group 5B element, a single component composed of a Group 6B element, and alloys respectively composed thereof as main components.
12. A method according to claim 4, wherein said cathode sleeve is made of a component selected from the group consisting of tantalum, an alloy containing tantalum as a main component, niobium, and an alloy containing niobium as a main component.
13. A method according to claim 4, wherein said porous absorbent member has an initial speed of water absorption of not less than 3 mm/sec.
14. A method according to claim 4, wherein said porous absorbent member has an initial speed of water absorption of not less than 7 mm/sec.
15. A method according to claim 4, wherein said porous absorbent member is fabricated from a material selected from the group consisting of cotton and a material containing cotton as a main component.
16. A cathode assembly manufacturing method of forming a black coating on an inner surface of a cathode sleeve, comprising the steps of:
- preparing a suspension of powders or particles for the black coating;
- filling said cathode sleeve with the suspension;
- bringing a porous absorbent member into contact with the suspension in an opening portion of said cathode sleeve, at the same time or after said cathode sleeve is filled with the suspension, thereby causing said porous absorbent member to absorb unnecessary portion of the suspension, leaving a suspension residue on the inner surface of said cathode sleeve as a black residue;
- separating said porous absorbent member and said cathode sleeve; and
- heat-treating said cathode sleeve to which the black coating material is attached.
17. A method according to claim 16, wherein the suspension, as the material for the black coating, is prepared by mixing a refractory fine powder with a dispersion.
18. A method according to claim 16, wherein a weight ratio of the refractory fine powder to the dispersion is in a range of (30:70) to (70:30).
19. A method according to claim 16, wherein the dispersion is composed of a solution mixture constituted by nitrocellulose and butyl acetate.
20. A method according to claim 16, wherein the refractory fine powder has an average particle size of not more than 2.mu.m.
21. A method according to claim 16, wherein the refractory fine powder is a power mixture obtained by mixing tungsten having an average particle size in a range of 0.5.mu.m (inclusive) to 2.mu.m (inclusive) with alumina having an average particle size in a range of 0.1.mu.m (inclusive) to 1.mu.m (exclusive) at a weight ratio of the tungsten to the alumina in a range of (90:10) to (65:35).
22. A method according to claim 16, wherein the weight ratio of the tungsten to the alumina is in a range of (70:30) to (85:15).
23. A method according to claim 16, wherein said cathode sleeve is fabricated from a component selected from the group consisting of a single component composed of a Group 5B element, a single component composed of a Group 6B element, and alloys respectively composed thereof as main components.
24. A method according to claim 16, wherein said cathode sleeve is made of a component selected from the group consisting of tantalum, an alloy containing tantalum as a main component, niobium, and an alloy containing niobium as a main component.
25. A method according to claim 16, wherein said porous absorbent member has an initial speed of water absorption of not less than 3 mm/sec.
26. A method according to claim 16, a wherein said porous absorbent member has an initial speed of water absorption of not less than 7 mm/sec.
27. A method according to claim 16, wherein said porous absorbent member is fabricated from a material selected from the group consisting of cotton and material containing cotton as a main component.
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Type: Grant
Filed: Mar 22, 1996
Date of Patent: Jun 9, 1998
Assignee: Kabushiki Kaisha Toshiba (Kawasaki)
Inventors: Akihito Hara (Yokohama), Toshiharu Higuchi (Yokohama), Toru Yakabe (Yokosuka), Shigeo Kanda (Sagamihara), Eiji Yamamoto (Yokohama)
Primary Examiner: Janyce Bell
Law Firm: Cushman Darby & Cushman IP Group of Pillsbury Madison & Sutro LLP
Application Number: 8/620,161
International Classification: B05D 512;
