System and method for supplying a lighter-than-air vehicle with hydrogen gas
A system for supplying hydrogen gas to a lighter-than-air (LTA) vehicle includes a manifold having multiple vessels. Each vessel has a first chamber that is separated from a second chamber by a barrier. A trigger assembly integrated with the barrier allows a liquid to be combined with a reactant and a catalyst in the second chamber to form a chemical reaction to generate hydrogen gas. A pressure relief valve located on each vessel opens to allow the hydrogen gas to exit when a predetermined pressure is reached, and the hydrogen gas is supplied to the LTA vehicle connected to the manifold.
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The System and Method for Supplying a Lighter-Than-Air Vehicle with Hydrogen Gas is assigned to the United States Government. Licensing inquiries may be directed to the Office of Research and Technical Applications, Space and Naval Warfare Systems Center Pacific, Code 72120, San Diego, Calif. 92152. Phone: (619) 553-5118; email: ssc_pac_t2@navy.mil. Reference Navy Case No. 103431.
CROSS-REFERENCE TO RELATED APPLICATIONThis application claims the benefit of U.S. Provisional Application No. 62/353,723, filed 23 Jun. 2016, entitled “Method for Interactive Automatic Controlled Generation of Hydrogen to Inflate Lighter Than Air Vehicles.”
BACKGROUNDAn increase in worldwide manufacturing processes using helium has correspondingly increased the demand for helium. Since helium is a non-renewable source, this increased use in manufacturing has led to decreased helium supplies and a corresponding increase in costs. At the same time, the use of lighter-than-air (LTA) vehicles for military and commercial applications has increased. Traditionally, LTA vehicles have been inflated using helium; however, with the rising costs and scarcity of helium, the use of hydrogen gas to inflate LTA vehicles is gaining greater acceptance.
The elements in the figures may not be drawn to scale. Some elements and/or dimensions may be enlarged to provide emphasis or further detail.
References in the specification to “one embodiment” or “an embodiment” means that a particular element, feature, structure, or characteristic described in connection with the embodiments is included in at least one embodiment. The appearances of the phrases “in one embodiment”, “in some embodiments,” and “in other embodiments” in various places in the specification are not necessarily all referring to the same embodiment or the same set of embodiments.
As used herein, the terms “comprises,” “comprising,” “includes,” “including,” “has,” “having,” or any other variation thereof, are intended to cover a non-exclusive inclusion. For example, a process, method, article, or apparatus that comprises a list of elements is not necessarily limited to only those elements but may include other elements not expressly listed or inherent to such process, method, article, or apparatus. Further, unless expressly stated to the contrary, “or” refers to an inclusive or and not to an exclusive or.
Additionally, use of “the,” “a,” or “an” are employed to describe elements and components of the embodiments herein; this is done merely for grammatical reasons and to conform to idiomatic English. This detailed description should be read to include one or at least one, and the singular also includes the plural unless it is clearly meant otherwise.
The embodiments disclosed herein describe a system and method suitable for generating hydrogen gas in order to, e.g., inflate an LTA vehicle or for using in hydrogen fuel cells. Focuses of the system and method include providing hydrogen generation vessels in a manifold assembly, storing hydrogen in a chemically dense form as a metal hydride, generating dry hydrogen gas at a controlled, constant rate, and supplying the hydrogen gas to an LTA vehicle.
As shown in
The types of materials that may be used in construction of vessel 110 and manifold 170 are meant to withstand the temperatures and pressures generated during the chemical reaction. The materials are also chemically resistant to the reaction products. In some embodiments, such materials may include anodized aluminum, polytetrafluoroethylene-coated aluminum, copper, and polyvinyl chloride. In some embodiments, vessel 110 and/or manifold may be fabricated from aluminum and then given a polytetrafluoroethylene-impregnated, hard anodic coating. In some embodiments, vessel 110 may have a rounded, conical bottom-shape.
A plurality of temperature sensors 126, 128, 130, 132 may be positioned at various places within vessel 110. In some embodiments, the temperature sensors used may be thermocouples, thermistors, or resistance temperature detectors (RTDs). A smart temperature sensor having a temperature sensor and bias circuitry could also be used. No one configuration of the placement of temperature sensors within the vessel is controlling. For example, a sensor may be placed near the bottom of reactant container 120, which may have a perforated bottom plate (not shown), while other sensors may be placed on the upper walls of the various chambers within vessel 110 or at other locations within the various chambers.
Trigger assembly 118 may open at a desired or programmed time to allow liquid 134 to combine with reactant 122, and catalyst 124 (if present), in second chamber 114, as shown in
In some embodiments, pressure relief valve 136 may be located on a safety rupture disc 138 of vessel 110. Pressure relief valve 136 may aid in maintaining a minimum pressure to prevent reactant volume from exceeding the available vessel size. Pressure relief valve 136 may also provide a more consistent pressure for cooling and an output pressure for the gas product. The predetermined pressure may be a programmed pressure that is within the tolerance rating of the pressure relief valve used in the system. An example of a pressure relief valve is Circle Seal Controls 5-80-A-3MP-100, which is rated for 100 pounds per square inch (psi); however, other pressure relief valves may be utilized.
In embodiments where safety rupture disc 138 is located on vessel 110, it may prevent vessel 110 from over-pressurization during the hydrogen gas generation. An example of a safety rupture disc is the Fike Axius SC, which is rated for a burst pressure of 275 psi; however, other safety rupture discs may be utilized.
Manifold 170 may have interior plumbing (not shown) that connects vessels 110 and directs hydrogen gas 140 to a hose (not shown) connected to LTA vehicle 180 for purposes of inflation.
Reactant 122 may be a hydride capable of absorbing and desorbing hydrogen in both the hydrogen-depleted (dehydrided) and the hydrogen-rich (hydrided) states. In some embodiments, the hydride may be one of an alkali metal, alkaline earth hydrides, and hydrides of the group III metals, for example, hydrides of lithium, sodium, potassium, rubidium, cesium, beryllium, magnesium, calcium, aluminum, and combinations thereof. In some embodiments, the hydride used does not require a catalyst to be present and is also not affected by the dissolved organics and ammonia present in seawater, thus allowing the seawater to be used as-is. For example, the hydride may be one of LiH, NaH, KH, RbH, CsH, MgH2, and CaH2. In some embodiments, the hydride is a borohydride, which contains a significant amount of hydrogen on a weight percent basis. For example, the borohydride may be one of lithium borohydride, sodium borohydride, and magnesium borohydride. In some embodiments, the hydride may be one of, for example, LiBH4, NaBH4, KBH4, Mg(BH4)2, Ca(BH4)2, LiAlH4, NaAlH4, KAlH4, Li3AlH6, and Na3AlH6.
If present, catalyst 124 may be a substance involved in catalyzing the reaction of a hydride with a liquid such as water. Transition metals such as one of the precious metals, or other metals such as iron, cobalt, and nickel, or combinations thereof, are non-limiting examples of useful catalysts. In some embodiments, ruthenium, ruthenium chloride, or other Ru3+ salts are useful catalysts. Soluble transition metal salts that can be reduced to pure metal by hydrides are also useful for generating finely divided metal particles that can serve as catalysts. In some embodiments, the catalyst may be one of, for example, Ruthenium Chloride, Rhodium Chloride, Cobalt Chloride, Nickel Chloride, and Chloroplatinic acid. In some embodiments, a catalyst such as an acidic accelerant may be used, which is not affected by the dissolved organics and ammonia present in seawater, thus allowing the seawater to be used as-is. For example, acidic accelerants such as Boric acid, Citric acid, Tartaric acid, and Acetic acid may be used.
As shown in
Controller 160 may regulate the temperature within vessels 110 utilizing pump 150 and thermal regulators 142 and 144.
As an example, PD control functions may include a closed feedback loop in which a process variable (e.g., temperature) needs to be controlled. A set point, which may be a selected value for the process variable, may be compared to a measured value of the process variable (e.g., a temperature sensor reading), and the difference between the set point and the process variable may be used to determine an output (e.g., turning the pump on/off as necessary) in order to decrease the difference between the set point and the process variable. The PD control functions may be performed by PD control system 164 and may include additional steps pertaining to proportional, integral, and derivative control.
In some embodiments, controller 160 may turn pump 150 on and off as necessary in attempt to regulate the temperatures within vessels 110 when the reaction reaches a set temperature as measured by at least one of temperature sensors 126, 128, 130, and 132. Controller 160 may use at least one of temperature sensors 126, 128, 130, and 132 to monitor the chemical reaction. A temperature profile may be used by controller 160 to ramp the set temperature by a certain number of degrees Celsius (e.g., 1° C.) at timed intervals (e.g., every 2 minutes), but the profile may vary depending on system configurations. The ramping may begin when the chemical reaction is activated. The set temperature may have over/undershoots that may be reduced by using PD control system 164 in addition to ramping the set temperature. This type of automated control may allow the temperatures within vessels 110 to remain within a desired range that is close to the set temperature without significant over/undershoots. For example, the set temperature may be 42° C. with over/undershoots of ±1 or 2° C.; therefore, the desired temperature range in this example may be 41-43 or 40-44° C. As an example, the set temperature may be ramped from 42-57° C., but this may vary depending on the particular system configurations.
In some embodiments, such as
In some embodiments, a pressure transducer may be placed outside of the H2 gas outlet (e.g., pressure relief valve 636) along with a temperature sensor in order to measure the temperature and pressure of the exiting hydrogen gas as it enters a hose. A flowmeter may be placed at the entrance end of the hose to measure gas flow rate, pressure, and temperature. A data logger may be placed at the exit end of the hose to measure temperature and relative percent humidity of the hydrogen gas. In some embodiments, data acquisition pertaining to the abovementioned instruments is performed under computer control (e.g., via controller 160).
The embodiments of manifolds described herein may have interior plumbing that connects the vessels and directs the generated hydrogen gas to a hose connected to an LTA vehicle for purposes of inflation. In some embodiments, the interior plumbing may also connect the pump to the vessels for the purpose of circulating the cooling liquid, but this may vary depending on system configurations. For example, the interior plumbing may be configured differently depending on whether the pump is integrated with the manifold (e.g,
Some of the steps of method 1100 may be stored on a non-transitory computer readable storage medium, wherein the steps are represented by computer-readable programming code. Some of the steps of method 1100 may also be computer-implemented using a programmable device, such as a computer-based system. Method 1100 may comprise instructions that, when loaded into a computer-based system, cause the system to execute some of the steps of method 1100. Some of the steps of method 1100 may be computer-implemented using various programming languages, such as “Java,” “C,” “C++,” etc.
For illustrative purposes, method 1100 will be discussed with reference to the steps being performed in system 100. Additionally, while
In
Step 1120 involves opening a trigger assembly 118 integrated with barrier 116 to allow a liquid 134 to pass into second chamber 114 from first chamber 112 at a desired or programmed time. As an example, trigger assembly 118 may be opened electronically by controller 160 at the desired or programmed time. Upon transition from first chamber 112 to second chamber 114, liquid 134 combines with a reactant 122 and a catalyst 124 in second chamber 114 to form a chemical reaction that generates hydrogen gas 140. The desired or programmed time may vary depending on the particular system configurations.
Step 1130 involves determining, via a controller 160 connected to temperature sensors 126, 128, 130, and 132, that a temperature within vessel 110 is moving outside a desired temperature range. As previously explained, controller 160 may include a proportional and derivative (PD) control system 164 stored in a non-transitory computer readable medium 162 and configured to keep the temperature within the desired temperature range. PD control system 164 may include a controlling temperature algorithm 166 and a derivative component 168.
Step 1140 involves activating a pump 150, via controller 160, to circulate cooling liquid through at least one thermal regulator 144 within second chamber 114 to keep the temperature within the desired temperature range. As previously explained, the set temperature may be 42° C. with over/undershoots of ±1 or 2° C.; therefore, the desired temperature range in this example may be 41-43 or 40-44° C.
Step 1150 involves opening a pressure relief valve 136 disposed on vessel 110 to allow hydrogen gas 140 to exit when a predetermined pressure is reached. As previously explained, pressure relief valve 136 may be disposed on a safety rupture disc 138. As an example, pressure relief valve 136 may be set to open when the pressure within vessel 110 reaches about 7 atmospheres (ATM).
The pressure within vessel 110 may vary depending on system configurations. In some embodiments, the pressure may be from about 1 ATM to about 10 ATM. Pressurization may allow the chemical reaction to be conducted while suppressing foaming. Prevention of foaming utilizing pressure may also prevent excess reactant volume and the generation of hydrogen gas having excess water vapor. As a result, the size of the vessel used in the system and method can be reduced, and pressurization may aid in generating hydrogen gas that is drier than the ambient environment. The humidity of the hydrogen gas generated by the System and Method for Supplying a Lighter-Than-Air Vehicle with Hydrogen Gas may range between about 10% to about 50% lower than the humidity of an ambient environment. The described system and method may generate up to 330 standard cubic feet (SCF) of hydrogen gas.
Step 1160 involves connecting an LTA vehicle 180 to manifold 170 to supply LTA vehicle 180 with hydrogen gas 140. In some embodiments, LTA vehicle 180 is connected to manifold 170 by a hose (e.g.,
Various storage media, such as magnetic computer disks, optical disks, and electronic memories, as well as non-transitory computer-readable storage media and computer program products, can be prepared that can contain information that can direct a device, such as a micro-controller, to implement portions of the above-described systems and/or methods. Once an appropriate device has access to the information and programs contained on the storage media, the storage media can provide the information and programs to the device, enabling the device to perform portions of the above-described systems and/or methods.
EXPERIMENTAL RESULTSUsing Cobalt Chloride as a catalyst and Sodium Borohydride as a reactant in the experiments described below, the following chemical reaction is involved in generating the hydrogen gas:
CoCl2+2NaBH4+3H2O→0.5Co2B↓+2NaCl+1.5HBO2+6.25H2↑
The use of any examples, or exemplary language (“e.g.,” “such as,” etc.), provided herein is merely intended to better illuminate and is not intended to pose a limitation on the scope of the subject matter unless otherwise claimed. No language in the specification should be construed as indicating that any non-claimed element is essential.
Many modifications and variations of the System and Method for Supplying a Lighter-Than-Air Vehicle with Hydrogen Gas are possible in light of the above description. Within the scope of the appended claims, the embodiments described herein may be practiced otherwise than as specifically described. The scope of the claims is not limited to the implementations and embodiments disclosed herein but extends to other implementations and embodiments as may be contemplated by those having ordinary skill in the art.
Claims
1. A system for generating hydrogen gas comprising:
- a vessel that includes: a first chamber for holding liquid water; a second chamber, wherein the first chamber is separated from the second chamber by a barrier; a trigger valve integrated into the barrier, the trigger valve opening to transition the liquid water from the first chamber to the second chamber and thereby initiate generating the hydrogen gas; a reactant container disposed within the second chamber for containing a solid reactant, wherein the hydrogen gas is generated from a chemical reaction between the liquid water and the solid reactant when the liquid water contacts the solid reactant inside the reactant container; a thermal regulator surrounding the reactant container within the second chamber for controlling a pre-reaction temperature of the liquid water passing though the thermal regulator before the liquid water reaches the solid reactant in the reactant container and reacts in the chemical reaction; a pressure relief valve disposed on the vessel and configured to allow the generated hydrogen gas to exit the vessel at a predetermined pressure; and a temperature sensor disposed in the second chamber for sensing a sensed temperature inside the second chamber; and
- a controller adapted to control a flow of a coolant through the thermal regulator for limiting the sensed temperature to a set temperature so that the generated hydrogen gas exiting the vessel at the predetermined pressure attains a substantially constant flow rate during the chemical reaction.
2. The system of claim 1, wherein the trigger valve opens at a desired time allowing the liquid water to combine with the solid reactant in the second chamber and undergo the chemical reaction that produces the generated hydrogen gas.
3. The system of claim 1, wherein a humidity of the generated hydrogen gas is between a range of about 10% to about 50% lower than an ambient humidity.
4. The system of claim 1, wherein the solid reactant is chosen from at least one of Lithium Borohydride, Sodium Borohydride, and Magnesium Borohydride.
5. The system of claim 1, wherein an amount of the hydrogen gas generated by the vessel is at least 300 standard cubic feet.
6. The system of claim 1, wherein the reactant container further comprises a lid and at least one wall having a plurality of perforations, the lid configured to inhibit the liquid water from directly entering the reactant container and to instead direct the liquid water to pass through the thermal regulator and through the perforations before reaching the solid reactant in the reactant container.
7. The system of claim 1, wherein the controller includes a proportional and derivative (PD) control system stored in a non-transitory computer readable medium and configured to keep the sensed temperature within a desired temperature range around the set temperature.
8. The system of claim 1 further comprising:
- a manifold including a plurality of vessels including the vessel, each of the vessels being identical to the vessel,
- wherein the controller is adapted to control a respective flow of the coolant through the thermal regulator of each of the vessels for limiting the sensed temperature sensed in each of the vessels to the set temperature, such that the hydrogen gas exiting at the predetermined pressure from the vessels attains a combined flow rate that is substantially constant.
9. The system of claim 8 further comprising:
- a lighter-than-air (LTA) vehicle, wherein the LTA vehicle is connected to the manifold for supplying the hydrogen gas generated in the vessels to the LTA vehicle.
10. The system of claim 9, further comprising:
- a catalyst disposed within the second chamber but initially outside the reactant container, wherein the liquid water carries the catalyst into the reactant container via a plurality of perforations in at least one wall of the reactant container to participate in the chemical reaction within the reactant container among the liquid water, the solid reactant, and the catalyst.
11. The system of claim 10, wherein the catalyst is chosen from at least one of Ruthenium Chloride, Rhodium Chloride, Cobalt Chloride, and Chloroplatinic acid.
12. The system of claim 1, wherein:
- the reactant container includes at least one wall having a plurality of perforations,
- the thermal regulator includes tubing surrounding the reactant container and through which flows the flow of the coolant, wherein the liquid water reaching the solid reactant passes through the thermal regulator and through the perforations in the at least one wall of the reactant container, and
- the controller is adapted to control the flow of the coolant through the tubing of the thermal regulator.
13. The system of claim 1, further comprising a pump for pumping the flow of the coolant through tubing of the thermal regulator surrounding the reactant container, wherein the controller is adapted to activate the pump for controlling the flow of the coolant through the tubing of the thermal regulator.
14. A method for generating hydrogen gas comprising:
- providing a manifold including a plurality of vessels, wherein each vessel includes a first chamber and a second chamber, the first chamber holding liquid water and separated from the second chamber by a barrier, the second chamber having within a reactant container containing a solid reactant;
- opening a trigger valve integrated with the barrier of each vessel to transition the liquid water from the first chamber to the second chamber at a desired time for generating the hydrogen gas;
- passing the liquid water through a thermal regulator for controlling a pre-reaction temperature of the liquid water before the liquid water reacts in a chemical reaction upon the liquid water reaching the solid reactant in the reactant container of each vessel, the thermal regulator surrounding the reactant container within the second chamber of each vessel;
- combining the liquid water with the solid reactant and a catalyst in the reactant container within the second chamber of each vessel to generate the hydrogen gas from the chemical reaction among the liquid water, the solid reactant, and the catalyst;
- opening a pressure relief valve disposed on each vessel to allow the generated hydrogen gas to exit the vessel at a predetermined pressure;
- sensing a sensed temperature inside the second chamber of each vessel with a temperature sensor disposed in the second chamber;
- controlling a flow of a coolant through the thermal regulator of each vessel for limiting the sensed temperature to a set temperature so that the generated hydrogen gas exiting the vessels at the predetermined pressure attains a substantially constant flow rate during the chemical reaction; and
- connecting a lighter-than-air (LTA) vehicle to the manifold to supply the LTA vehicle with the hydrogen gas generated in the vessels.
15. The method of claim 14, further comprising:
- determining, via a controller connected to the temperature sensor and a plurality of additional temperature sensors within each vessel, that the sensed temperature within each vessel is moving outside a desired temperature range around the set temperature, wherein the controller includes a proportional and derivative (PD) control system stored in a non-transitory computer readable medium and configured to keep the sensed temperature within the desired temperature range.
16. The method of claim 14, wherein a humidity of the hydrogen gas is between a range of about 10% to about 50% lower than an ambient humidity, and
- wherein the pressure relief valve is disposed on a safety rupture disc on the vessel.
17. The method of claim 14, wherein the solid reactant is within the reactant container including a lid and at least one wall having a plurality of perforations, the lid configured to inhibit the liquid water from directly entering the reactant container and to instead direct the liquid water to pass through the thermal regulator and through the perforations before reaching the solid reactant in the reactant container.
18. The method of claim 14, wherein the solid reactant is chosen from at least one of Lithium Borohydride, Sodium Borohydride, and Magnesium Borohydride.
19. The method of claim 14, wherein the catalyst is chosen from at least one of Ruthenium Chloride, Rhodium Chloride, Cobalt Chloride, and Chloroplatinic acid.
20. The method of claim 14, wherein an amount of the hydrogen gas generated by each vessel is at least 300 standard cubic feet.
2721789 | October 1955 | Gill |
5423247 | June 13, 1995 | Rodrigues-Ely |
7261749 | August 28, 2007 | Pettit |
7306780 | December 11, 2007 | Kravitz et al. |
7763087 | July 27, 2010 | Hajiaghajani |
8187348 | May 29, 2012 | Eickhoff |
8240602 | August 14, 2012 | Lloyd et al. |
8771634 | July 8, 2014 | Becker et al. |
8926866 | January 6, 2015 | Kim, II |
9005321 | April 14, 2015 | Barton |
9102528 | August 11, 2015 | Wallace |
9214683 | December 15, 2015 | Eickhoff |
9266727 | February 23, 2016 | Stimits |
20050036941 | February 17, 2005 | Bae |
20080014481 | January 17, 2008 | Fiebig |
20090050522 | February 26, 2009 | Barber |
20110033342 | February 10, 2011 | Horiguchi |
20110070151 | March 24, 2011 | Braithwaite |
20130028809 | January 31, 2013 | Barton |
20130036736 | February 14, 2013 | Hart |
20130244128 | September 19, 2013 | Barton |
20140050625 | February 20, 2014 | Zheng |
20140140919 | May 22, 2014 | Langan |
20170369310 | December 28, 2017 | Wiedemeier |
- Boss, P.A.; Becker, C.A.; Anderson, G.W.; Wiedemeier, B.J. “Laboratory Studies of Hydrogen Gas Generation Using the Cobalt Chloride Catalyzed Sodium Borohydride-Water Reaction.” Spawar Systems Center Pacific Technical Report 2082, Jul. 2015.
- Mosier-Boss, P.A.; Becker, C.A.; Anderson, G.W.; Wiedemeier, B.J. “Feasibility Studies of the NaBH4/H20 Hydrolysis to Generate Hydrogen Gas to Inflate Lighter than Air (LTA) Vehicles.” Ind. Eng. Chem. Res. 2015, 54, 7706-7714.
- “Proportional and Derivative Control.” MIT OpenCourseWare 2011. http://ocw.mit.edu/courses/electrical-engineering-and-computer-science/6-003-signals-and-systems-fall-201l/readings/MIT6_03F11_chap8.pdf.
- Ferreira, M.J.F.; Gales, L.; Fernandes, V.R.; Rangel, C.M.; Pinto, A.M.F.R. “Alkali Free Hydrolysis of Sodium Borohydride for Hydrogen Generation Under Pressure.” Int. J. Hydrogen Energy 2010. doi:10.1016/j.ijhydene.2010.02.121.
- “PID Theory Explained.” National Instruments White Paper, Mar. 29, 2011. http://www.ni.com/white-paper/3782/en/.
- Becker-Glad, et al., Acid Acceleration of Hydrogen Generation Using Seawater as a Reactant, International Journal of Hydrogen Energy (2016), http://dx.doi.org/10.1016/j.ijhydene.2016.02.132.
- Schlesinger, Herbert E. et al., Sodium Borohydride, Its Hydrolysis and its Use as a Reducing Agent and in the Generation of Hydrogen, J. Am. Chem. Soc. 75(1): 215-219.
Type: Grant
Filed: Jul 26, 2023
Date of Patent: Apr 30, 2024
Assignee: United States of America as represented by the Secretary of the Navy (Washington, DC)
Inventors: Pamela A. Boss (San Diego, CA), Gregory W. Anderson (San Diego, CA), Brandon J. Wiedemeier (San Diego, CA), Carol A. Becker (Del Mar, CA), Brooke Bachmann (San Diego, CA), Mark Gillcrist (San Diego, CA), Jeffrey M. Lloyd (San Diego, CA), Charles Ringer (San Diego, CA)
Primary Examiner: William E Dondero
Application Number: 18/226,691
International Classification: C01B 3/06 (20060101); B01J 7/00 (20060101); B01J 27/128 (20060101); B64B 1/58 (20060101); B64B 1/62 (20060101); B64B 1/64 (20060101);