Abstract: A flash memory device includes a semiconductor substrate, a gate insulating layer having a first width formed on the semiconductor substrate to trap carriers tunneled from the semiconductor substrate and a metal electrode on the gate insulating layer to receive a voltage required for tunneling. The metal electrode having a second width smaller than the first width. The flash memory device further includes a sidewall spacer surrounding a side surface of the metal electrode to prevent oxidation of the metal electrode.

Abstract: A non-volatile memory device comprises a substrate, a tunneling layer over the substrate, a charge trapping layer comprising a stoichiometric silicon nitride layer and a silicon-rich silicon nitride layer over the tunneling layer, a blocking layer over the charge trapping layer, and a control gate electrode over the blocking layer.

Abstract: A semiconductor memory device may include a semiconductor substrate, at least one control gate electrode, at least one storage node layer, at least one tunneling insulating layer, at least one blocking insulating layer, and/or first and second channel regions. The at least one control gate electrode may be recessed into the semiconductor substrate. The at least one storage node layer may be between a sidewall of the at least one control gate electrode and the semiconductor substrate. The at least one tunneling insulating layer may be between the at least one storage node layer and the at least one control gate electrode. The at least one blocking insulating layer may be between the storage node layer and the control gate electrode. The first and second channel regions may be between the at least one tunneling insulating layer and the semiconductor substrate to surround at least a portion of the sidewall of the control gate electrode and/or may be separated from each other.

Abstract: A method of forming a memory device includes forming a first insulating pattern and a polysilicon pattern in a peripheral region of a substrate, forming a cell gate insulating pattern including a second insulating pattern, a charge storage pattern, and a third insulating pattern in a cell region of the substrate, forming a barrier metal layer on the polysilicon pattern and on the third insulating pattern, forming a conductive layer on the barrier metal layer, patterning the conductive layer to simultaneously form a first conductive pattern on the polysilicon pattern and a second conductive pattern on the third insulating pattern, and patterning the barrier metal layer to simultaneously form a first barrier metal pattern on the polysilicon pattern and a second barrier metal pattern on the third insulating pattern.

Abstract: In a memory device and a method of manufacturing the memory device, the memory device includes a first gate electrode enclosed by a first gate insulating layer, a second gate electrode enclosed by a second gate insulating layer that can be an ONO layer, and a channel region vertically extending between the first gate electrode and the second gate electrode. The first gate electrode is used for removing a charge trapped in the second gate insulating layer. Thus, the memory device can have an improved characteristic when performing an erase operation.

Abstract: A vertical power MOSFET includes a semiconductor substrate including a trench, a gate electrode layer having a prescribed impurity concentration and being formed inside the trench, and a cap insulating layer having a lower impurity concentration than the impurity concentration of the gate electrode layer and covering the gate electrode layer to provide insulation.

Abstract: A semiconductor device having a simple structure with selectively formed full-silicide (FUSI) and partial silicide gate electrodes and a manufacturing method thereof are provided. According to one aspect, there is provided a semiconductor device includes a first field effect transistor (MOSFET), and a second MOSFET, the first MOSFET including a first gate electrode provided on a gate insulator on a semiconductor substrate and formed of a first metal silicide layer, a first insulator provided to be adjacent to the first gate electrode, and a first sidewall including the first insulator, the second MOSFET including a second gate electrode provided on a gate insulator on the semiconductor substrate and formed of a conductor film including a polysilicon layer and a second metal silicide layer, a second insulator provided to be adjacent to the second gate electrode, and a second sidewall including the second insulator.

Abstract: An MOS device includes a semiconductor layer of a first conductivity type and first and second source/drain regions of a second conductivity type formed in the semiconductor layer proximate an upper surface of the semiconductor layer. The first and second source/drain regions are spaced apart relative to one another. A gate is formed above and electrically isolated from the semiconductor layer, at least partially between the first and second source/drain regions. At least a given one of the first and second source/drain regions is configured having an effective width that is substantially greater than a width of a junction between the semiconductor layer and the given source/drain region.

Abstract: The invention relates to a semiconductor device (10) having a semiconductor body (2), comprising a field effect transistor, a first gate dielectric (6A) being formed on a first surface at the location of the channel region (5) and on it a first gate electrode (7), a sunken ion implantation (20) being executed from the first side of the semiconductor body (2) through and on both sides of the first gate electrode (7), which implantation results in a change of property of the silicon below the first gate electrode (7) compared to the silicon on both sides of the gate electrode (7) in a section of the channel region (5) remote from the first gate dielectric (6A), and on the second surface of the semiconductor body (2) a cavity (30) being provided therein by means of selective etching while use is made of the change of property of the silicon. A second gate (6B,8) is deposited in the cavity thus formed.

Abstract: The present invention aims at offering the semiconductor device which has the structure which are a high speed and a low power, and can be integrated highly. The present invention is a semiconductor device formed in the SOI substrate by which the BOX layer and the SOI layer were laminated on the silicon substrate. And the present invention is provided with the FIN type transistor with which the gate electrode coiled around the body region formed in the SOI layer, and the planar type transistor which was separated using partial isolation and full isolation together to element isolation, and was formed in the SOI layer.

Abstract: The present invention describes a method including the steps of providing a single crystal semiconductor substrate, forming a layer of rare earth silicide on a surface of the semiconductor substrate, forming a first layer of insulating material on the layer of rare earth silicide, forming a layer of electrically conductive material on the first layer of insulating material, and forming a second layer of insulating material on the layer of electrically conductive material. In one embodiment the step of forming the layer of rare earth silicide includes depositing a layer of rare earth metal on a surface of the semiconductor substrate depositing a layer of insulating material on the layer of rare earth metal, and annealing the structure to form a layer of rare earth silicide in conjunction with the surface of the semiconductor substrate and a rare earth doped insulating layer in conjunction with the layer of insulating material.

Abstract: In order to protect a semiconductor component against overvoltages, the steps which are used for production of bipolar transistors and CMOS structures in the semiconductor component are used for integrated parallel production of a zener diode. This has a first and a second n-doped zone, which extend between the surface of a semiconductor substrate and an n-doped buried region. The first n-doped zone is oppositely doped with p-doping in an area adjacent to the surface, and represents a p-doped region. A first contact is provided to the p-doped region, and a contact is on the other hand provided to the second n-doped zone, with the two contents forming the two connections of the zener diode.

Abstract: The present invention relates to an electrostatic discharge (ESD) protection scheme and particularly to a string contact structure for an improved ESD performance. In an embodiment, the invention provides a method for forming an ESD protection circuit for protecting an internal circuit from damage due to an ESD voltage appearing on a pad coupled to a clamp device including a first terminal and a second terminal. The method includes forming a string contact along the first terminal and the second terminal of the clamp device. The method further includes forming one or more conductive layers on the string contact to couple the first terminal and the second terminal of the clamp device to the pad and a ground pad.

Abstract: A semiconductor device includes a first MIS transistor on a first active region of a semiconductor substrate, the first MIS transistor including: a first gate insulating film provided on the first active region; a first gate electrode provided on the first gate insulating film; a first stressor insulating film provided on an upper face and side faces facing in a gate length direction of the first gate electrode such that first stress acts on a channel of the first MIS transistor in the gate length direction; and a first base insulating film provided on side faces of the first gate electrode facing in a gate width direction, wherein the side faces of the first gate electrode facing in the gate width direction are not covered with the first stressor insulating film.

Abstract: In a fin field effect transistor (FET), an active pattern protrudes in a vertical direction from a substrate and extends across the substrate in a first horizontal direction. A first silicon nitride pattern is formed on the active pattern, and a first oxide pattern and a second silicon nitride pattern are sequentially formed on the substrate and on a sidewall of a lower portion of the active pattern. A device isolation layer is formed on the second silicon nitride pattern, and a top surface of the device isolation layer is coplanar with top surfaces of the oxide pattern and the second silicon nitride pattern. A buffer pattern having an etching selectivity with respect to the second silicon nitride pattern is formed between the first oxide pattern and the second silicon nitride pattern.

Abstract: A semiconductor structure includes a substrate, a gate stack on the substrate, a source/drain region adjacent the gate stack, a source/drain silicide region on the source/drain region, a protection layer on the source/drain silicide region, wherein a region over the gate stack is substantially free from the protection layer, and a contact etch stop layer (CESL) having a stress over the protection layer and extending over the gate stack.

Abstract: A semiconductor device having a field effect transistor (FET) with enhanced performance by reduction of electrical contact resistance of electrodes and resistance of the electrodes per se is disclosed. The FET includes an n-type FET having a channel region formed in a semiconductor substrate, a gate electrode insulatively overlying the channel region, and a pair of source and drain electrodes which are formed at both ends of the channel region. The source/drain electrodes are made of silicide of a first metal. An interface layer that contains a second metal is formed in the interface between the substrate and the first metal. The second metal is smaller in work function than silicide of the first metal, and the second metal silicide is less in work function than the first metal silicide. A fabrication method of the semiconductor device is also disclosed.

Abstract: Provided are semiconductor devices and methods of fabricating the same. A semiconductor device may include a semiconductor substrate with a device isolation layer defining HVE and HVD active regions. Gate insulation layer patterns may be disposed on the HVE and HVD active regions. Gate electrodes may be disposed on the gate insulation layer patterns to intersect the HVE and HVD active regions and the device isolation layer. An ion implantation layer may be disposed on the semiconductor substrate under the gate electrode of the HVD active region, spaced apart from the device isolation layer, and serves to adjust a threshold voltage.

Abstract: A NAND type non-volatile memory device and a method for forming the same. Well bias lines are disposed substantially parallel to other wiring lines at equal intervals. Active regions that are electrically connected to the well bias line are disposed substantially parallel to other active regions at the same equal intervals. As a result, continuity and repeatability in patterns may be maintained and pattern defects may be minimized or prevented.

Abstract: At least part of an element isolation region, an interlayer insulating film, and a protection insulating film, other than a gate insulating film (silicon oxide film), is formed of carbon fluoride (CFx, 0.3<x<0.6) or hydrocarbon (CHy, 0.8<y<1.2).

Abstract: A method of making a semiconductor structure comprises forming an oxide layer on a substrate; forming a silicon nitride layer on the oxide layer; annealing the layers in NO; and annealing the layers in ammonia. The equivalent oxide thickness of the oxide layer and the silicon nitride layer together is at most 25 Angstroms.

Abstract: A semiconductor device includes: a semiconductor substrate; an isolation region formed on a semiconductor substrate, the top surface of the isolation region being located above the top surface of the semiconductor substrate; a fully silicided gate line continuously formed to cover part of the top surface of an active region of the semiconductor substrate surrounded by the isolation region and part of the top surface of the isolation region; and an insulative sidewall formed on a side of the gate line. The vertical length of a part of the sidewall on the isolation region is different from that of a part of the sidewall on the active region.

Abstract: Semiconductor structures having a silicided gate electrode and methods of manufacture are provided. A device comprises a first silicided structure formed in a first active region and a second silicided structure formed in a second active region. The two silicided structures have different metal concentrations. A method of forming a silicided device comprises forming a polysilicon structure on the first and second device fabrication regions. Embodiments include replacing a first portion of the polysilicon structure on the first device fabrication region with a metal and replacing a second portion of the polysilicon structure on the second device fabrication region with the metal. Preferably, the second portion is different than the first portion. Embodiments further include reacting the polysilicon structures on the first and second device fabrication regions with the metal to form a silicide.

Abstract: An apparatus and method are disclosed for an improved semiconductor interconnect scheme using a simplified process. In an embodiment of the apparatus, a polysilicon shape is formed on a silicon area. The polysilicon shape is created having a bridging vertex. When a spacer is created on the polysilicon shape, the spacer width is formed to be small enough near the bridging vertex to allow a silicide bridge to form that creates an electrical coupling between the silicon area and the bridging vertex. Semiconductor devices and circuits are created using the improved semiconductor interconnect scheme using the simplified process.

Abstract: A micro electro mechanical system (MEMS) device includes: a fixed electrode made of silicon and provided above a semiconductor substrate; a movable electrode made of silicon and arranged in a mechanically movable manner by having a gap from the semiconductor substrate; and a wiring layered part that is provided around the movable electrode, covers a portion of the fixed electrode and includes wiring. One of the fixed electrode and the movable electrode is implanted with an impurity ion and at least a part of the portion of the fixed electrode covered by the wiring layered part is silicidized.

Abstract: A microelectromechanical system (MEMS) device includes a semiconductor substrate, a MEMS including a fixed electrode and a movable electrode formed on the semiconductor substrate through an insulating layer, and a well formed in the semiconductor substrate below the fixed electrode. The well is one of an n-type well and a p-type well. The p-type well applies a positive voltage to the fixed electrode while the n-type well applies a negative voltage to the fixed electrode.

Abstract: Electromechanical non-volatile memory devices are provided including a semiconductor substrate having an upper surface including insulation characteristics. A first electrode pattern is provided on the semiconductor substrate. The first electrode pattern exposes portions of a surface of the semiconductor substrate therethrough. A conformal bit line is provided on the first electrode pattern and the exposed surface of semiconductor substrate. The bit line is spaced apart from a sidewall of the first electrode pattern and includes a conductive material having an elasticity generated by a voltage difference. An insulating layer pattern is provided on an upper surface of the bit line located on the semiconductor substrate. A second electrode pattern is spaced apart from the bit line and provided on the insulating layer pattern. The second electrode pattern faces the first electrode pattern.

Abstract: A flexible pressure sensor has a first set of substantially parallel conductors in the x direction, a second set of substantially parallel conductors in the y direction, and a composite material disposed between the first set and second set of conductors. The composite material is capable of returning to substantially its original dimensions on release of pressure. The composite material includes conductive particles at least partially embedded in an elastomeric layer that have no relative orientation and are disposed within the elastomeric layer for electrically connecting the first set and second set of conductors in the z direction under application of sufficient pressure there between.

Abstract: An interferometric modulator manufactured according to a particular set of processing parameters may have a non-zero offset voltage. A process has been developed for modifying the processing parameters to shift the non-zero offset voltage closer to zero. For example, the process may involve identifying a set of processing parameters for manufacturing an interferometric modulator that results in a non-zero offset voltage for the interferometric modulator. The set of processing parameters may then be modified to shift the non-zero offset voltage closer to zero. For example, modifying the set of processing parameters may involve modifying one or more deposition parameters used to make the interferometric modulator, applying a current (e.g., a counteracting current) to the interferometric modulator, and/or annealing the interferometric modulator. Interferometric modulators made according to the set of modified processing parameters may have improved performance and/or simpler drive schemes.

Abstract: A low-cost ceramic package, in land-grid array or ball-grid array configuration, for micromechanical components is fabricated by coating the whole integrated circuits wafer with a protective material, selectively etching the coating for solder ball attachment, singulating the chips, flip-chip assembling a chip onto the opening of a ceramic substrate, underfilling the gaps between the solder joints with a polymeric encapsulant, removing the protective material form the components, and attaching a lid to the substrate for sealing the package. It is an aspect of the present invention to be applicable to a variety of different semiconductor micromechanical devices, for instance actuators, motors, sensors, spatial light modulators, and deformable mirror devices. In all applications, the invention achieves technical advantages as well as significant cost reduction and yield increase.

Abstract: A micromechanical component and a method for manufacturing such a component, the component having a micromechanical structure and an integrated circuit, the micromechanical structure being monolithically integrated into the circuit, the circuit being provided in a circuit area of the substrate, and the micromechanical structure being provided in a sensor area of the substrate, the material of the substrate being provided in the area of a sacrificial layer as well as in the area of a function layer without a transition.

Abstract: A MEM device and method for fabricating a MEM device. A MEM device comprising a lever mechanism residing along a substrate is disclosed. A contact material is deposited on a first surface of the lever mechanism. In one arrangement, the first surface is disposed towards the substrate. A first contact region may be deposited on the substrate. The first contact region attracts the lever mechanism towards the substrate such that the contact material becomes operationally coupled to a second contact region. The MEM device may also comprise a first anchor portion and a second anchor portion. The first and second anchor portions may be integral to a top surface of the substrate. Aspects of the invention are also particularly useful in providing an encapsulated MEM switching device.

Abstract: The invention regards an audio processing device with at least one encapsulated electronic component mounted and electrically connected to electric leads in a mounting substrate. Further electric components are mounted for connection with the encapsulated electronic component through the substrate and the encapsulation material is moulded onto the substrate. According to the invention at least one metal layer is deposited on a surface part of the encapsulation material. The invention further regards a method for producing an amplifier for an audio device whereby at least one encapsulated electronic component is mounted on, and electrically connected to a PCB and where the encapsulation material is provided to protect the electronic component wherein further a metal layer is generated at least on a surface area of the encapsulation material.

Abstract: A nanowire sensor is operable to detect one or more species. The nanowire sensor includes a nanowire having a plurality of variant selectively interactive segments. Each of the variant selectively interactive segments are configured to simultaneously interact with the species to modulate the conductance of the nanowire for detecting the species.

Abstract: In a method for manufacturing a semiconductor component having a semiconductor substrate, a flat, porous diaphragm layer and a cavity underneath the porous diaphragm layer are produced to form unsupported structures for a component. In a first approach, the semiconductor substrate may receive a doping in the diaphragm region that is different from that of the cavity. This permits different pore sizes and/or porosities to be produced, which is used in producing the cavity for improved etching gas transport. Also, mesopores may be produced in the diaphragm region and nanopores may be produced as an auxiliary structure in what is to become the cavity region.

Abstract: An image sensor including a substrate having a plurality of semiconductor devices formed thereon, an interconnection layer disposed on the substrate, and a plurality of isolated photo-diodes embedded in the interconnection layer is provided. The isolated photo-diodes are located above the semiconductor devices and electrically connected to the semiconductor devices through the interconnection layer. In the above-mentioned image sensor, thickness of the interconnection layer is not limited so as to facilitate fabrication of the SOC CMOS image sensor. In addition, the image sensor is advantageous in relatively high fill-factor, layout area saving and easy being implanted. Furthermore, a method for fabricating the image mentioned above is also provided.

Abstract: A light shielding film, an insulating layer, a planarizing layer, and a color filter are formed consecutively on a semiconductor substrate having plural photodiodes in a matrix arrangement. A transparent conductive film is formed on the color filter, and micro-lenses are formed directly on the conductive film such that they reside above each photodiode. Static charges on a surface of each micro-lens are discharged to the conductive film, and static charge buildup on the micro-lenses is therefore prevented.

Abstract: A second impurity region is surrounded by a first impurity region at a first main surface. A third impurity region of the first main surface sandwiches the second impurity region with the first impurity region. Fourth and fifth impurity regions of a second main surface sandwich the first impurity region with the second impurity region. A control electrode layer is opposite to the second impurity region with an insulating film interposed. That portion of the second main surface which is opposite to the portion of the first main surface where the first impurity region is formed surrounds the regions for forming the fourth and fifth impurity regions of the second main surface, and it is a region of the first conductivity type or a region of the second conductivity type having impurity concentration not higher than that of the first impurity region.

Abstract: A method for forming an array of elongated nanostructures, includes in one embodiment, providing a substrate, providing a template having a plurality of pores on the substrate, and removing portions of the substrate under the plurality of pores of the template to form a plurality of cavities. A catalyst is provided in the plurality of cavities in the substrate, and the pores of the template are widened to expose the substrate around the catalyst so that the catalyst is spaced from the sides of the plurality of pores of the template. A plurality of elongated nanostructures is grown from the catalyst spaced from the sides of the pores of the template.

Abstract: The semiconductor device includes a plurality of transistors at least having different channel widths from each other. Threshold voltages of those transistors are set to be substantially equal to each other, by using both of substantially the same channel dose for each of those transistors, and work function control using a predetermined metal to be deposited on a gate insulating of those transistors and/or a gate electrode material of each of those transistors (that is, work function control based on a gate structure (gate insulating film and/or gate electrode) with respect to a channel region of each of those transistors).

Abstract: A method for operating a semiconductor device is described, the semiconductor device including a high-voltage device and a control circuit coupled to each other on a single chip and the high-voltage device including a source, a drain and a gate. This method applies a drain voltage of about 20V or higher to the drain while the gate and the source are floated, such that the high-voltage device self-turns on to produce a current from the drain to the source charging up the source and forming a source voltage. The source voltage serves as a power source of the control circuit, and the control circuit is driven when the source voltage is higher than the threshold voltage thereof.

Abstract: A semiconductor device includes a device isolation layer on a semiconductor substrate defining an active region in the semiconductor substrate, a low voltage well of a first conductivity type in the active region of the semiconductor substrate, a high voltage impurity region of a second conductivity type in the active region of the semiconductor substrate, the high voltage impurity region positioned in an upper portion of the low voltage well, a high concentration impurity region of the second conductivity type within the high voltage impurity region and spaced apart from the device isolation layer, and a floating impurity region of the first conductivity type between the device isolation layer and the high concentration impurity region, the floating impurity region being a portion of an upper surface of the active region.

Abstract: The present invention relates to a semiconductor device having a passive device. The semiconductor device includes a substrate and at least one passive device. The substrate has at least one via. The via has at least two conductive elements therein. The conductive elements are not electrically connected to each other. The passive device has at least two electrodes, and is disposed on the substrate. The electrodes are electrically connected to the conductive elements respectively. The passive device needs only one via, so the amount of vias can be reduced effectively. In addition, the conductive path formed by the conductive elements and the passive device is relatively short, so that the inductance is lowered and the electrical performance is raised.

Abstract: A semiconductor fuse and methods of making the same. The fuse includes a fuse element and a compressive stress liner that reduces the electro-migration resistance of the fuse element. The method includes forming a substrate, forming a trench feature in the substrate, depositing fuse material in the trench feature, depositing compressive stress liner material over the fuse material, and patterning the compressive stress liner material.

Abstract: A semiconductor device having a moisture-proof dam and a method of fabricating the same are provided. The semiconductor device includes an interlayer insulating layer provided on a substrate having a fuse region. A fuse guard dam is provided on the interlayer insulating layer to surround the fuse region. A cover insulating layer is provided on the interlayer insulating layer to cover the fuse guard dam and have a fuse window exposing a middle part of the fuse region, and at least two upper extension dams are provided in the cover insulating layer to sequentially surround the fuse region and be connected to the fuse guard dam.

Abstract: A semiconductor device having a fuse structure that can prevent a bridge between a fuse pattern and a guard ring, and a method of fabricating the same are provided. The fuse pattern formed on a multiple-layered metal interconnect layer is stepped shape increasing a vertical distance between the fuse pattern and the guard ring.

Abstract: Provided is a semiconductor device that solves the problem of a conventional semiconductor device. In the conventional semiconductor device, a resistor is connected with a wiring layer via a contact hole, so that a reduction in parasitic capacitance of the resistor and a substrate is hard to be accomplished. In the semiconductor device of the present invention, a resistor made of a titanium nitride (TiN) film is directly connected with wiring layers on an insulating layer. This structure contributes to an increase in the contact area between the resistor and the wiring layers, and then to a reduction in the contact resistance. Furthermore, a broader separation distance between the resistor and an epitaxial layer contributes to a reduction in the parasitic capacitance in the resistor and to an improvement in the high-frequency characteristics of the semiconductor device.

Abstract: A semiconductor device has a first conductivity-type first semiconductor region, a second conductivity-type second semiconductor region and a second conductivity-type third semiconductor region both located on or above the first semiconductor region, a second conductivity-type fourth semiconductor region between the second semiconductor region and the third semiconductor region, and a first conductivity-type fifth semiconductor region between the third semiconductor region and the fourth semiconductor region. The fourth semiconductor region and the fifth semiconductor region are electrically connected by a conductive member. A distance between the fourth semiconductor region and the third semiconductor region is larger than a width of the fourth semiconductor region.

Abstract: A manufacturing method of a semiconductor device formed in a chip size package is improved to enhance a yield and reliability. A window to expose first wirings is formed only in a region of a semiconductor substrate where the first wirings exist. As a result, area of the semiconductor substrate bonded to a supporting body through an insulation film and a resin is increased to prevent cracks in the supporting body and separation of the semiconductor substrate from the supporting body. A slit is formed along a dicing line after forming the window, the slit is covered with a protection film and then the semiconductor substrate is diced into individual semiconductor dice. Thus, separation on a cut surface or at an edge of the semiconductor dice, which otherwise would be caused by contact of the blade in the dicing can be prevented.

Abstract: A semiconductor substrate in a state that an inter-layer insulation film is formed is loaded in a chamber, air in the chamber is purged by introducing a large amount of a nitrogen gas in the chamber, and an atmospheric gas in the chamber is substituted with a nitrogen gas. After that, UV cure is performed by introducing a small amount of an oxygen gas adjusted to an atmospheric pressure or a little more positive pressure in the chamber by nitrogen purge. For the introduction of an oxygen gas, an oxygen gas is introduced while controlling the flow rate by using a flow meter, and adjustment is performed using the flow meter so that the oxygen concentration in the chamber becomes a constant value in the range of 5 ppm to 400 ppm.