Patents Issued in December 7, 2017
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Publication number: 20170352867Abstract: The present invention provides, as a lithium-containing transition metal oxide, a substance which is given by the chemical compositional formula Li4M5O12 (M=Cr, Co, or Zr) and has a spinel-type crystal structure. Provided is a lithium ion secondary cell having a positive electrode configured from a lithium-containing transition metal oxide which has a spinel-type crystal structure and has the chemical compositional formula Li4M5O12 (M=Cr or Co). The present invention further provides a lithium ion secondary cell having a negative electrode configured from a lithium-containing transition metal oxide which has a spinel-type crystal structure and has the chemical compositional formula Li4M5O12 (M=Zr).Type: ApplicationFiled: March 31, 2015Publication date: December 7, 2017Applicant: HITACHI, LTD.Inventor: Yusuke ASARI
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Publication number: 20170352868Abstract: Provided is a lithium or sodium metal battery having an anode, a cathode, and a porous separator and/or an electrolyte, wherein the anode contains an integral 3D graphene-carbon hybrid foam composed of multiple pores, pore walls, and a lithium-attracting metal residing in the pores; wherein the metal is selected from Au, Ag, Mg, Zn, Ti, Na, K, Al, Fe, Mn, Co, Ni, Sn, V, Cr, or an alloy thereof and is in an amount of 0.1% to 50% of the total hybrid foam weight or volume, and the pore walls contain single-layer or few-layer graphene sheets chemically bonded by a carbon material having a carbon material-to-graphene weight ratio from 1/200 to 1/2, wherein graphene sheets contain a pristine graphene or non-pristine graphene selected from graphene oxide, reduced graphene oxide, graphene fluoride, graphene chloride, graphene bromide, graphene iodide, hydrogenated graphene, nitrogenated graphene, doped graphene, chemically functionalized graphene, or a combination thereof.Type: ApplicationFiled: June 7, 2016Publication date: December 7, 2017Applicant: Nanotek Instruments, Inc.Inventors: Aruna Zhamu, Bor Z. Jang
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Publication number: 20170352869Abstract: Provided is a lithium or sodium metal battery having an anode, a cathode, and a porous separator and/or an electrolyte, wherein the anode contains a graphene-metal hybrid foam composed of multiple pores, pore walls, and a lithium- or sodium-attracting metal residing in the pores; wherein the metal is selected from Au, Ag, Mg, Zn, Ti, Na (or Li), K, Al, Fe, Mn, Co, Ni, Sn, V, Cr, or an alloy thereof and is in an amount of 0.1% to 90% of the total hybrid foam weight or volume, and the pore walls contain single-layer or few-layer graphene sheets, wherein graphene sheets contain a pristine graphene or non-pristine graphene selected from graphene oxide, reduced graphene oxide, graphene fluoride, graphene chloride, graphene bromide, graphene iodide, hydrogenated graphene, nitrogenated graphene, doped graphene, chemically functionalized graphene, or a combination thereof.Type: ApplicationFiled: June 7, 2016Publication date: December 7, 2017Applicant: Nanotek Instruments, Inc.Inventors: Aruna Zhamu, Bor Z. Jang
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Publication number: 20170352870Abstract: Tin-containing carbon fibers may be produced by centrifugal spinning of a precursor composition that includes a base polymer and a tin-containing compound. The produced fibers are heated at a temperature sufficient to convert at least a portion of the base polymer in the collected fibers into carbon fibers comprising tin.Type: ApplicationFiled: August 16, 2016Publication date: December 7, 2017Inventors: Mataz Alcoutlabi, Victor Anafo Agubra
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Publication number: 20170352871Abstract: An anode active material for lithium secondary battery includes a secondary particle formed by agglomerating primary particles, an average diameter of the primary particles is in a range from 5 ?m to 15 ?m, and an average diameter of the secondary particle is in a range from 10 ?m to about 25 ?m. The primary particles include an artificial graphite, and an I(110)/I(002) of the secondary particle is in a range from about 0.0075 to 0.012.Type: ApplicationFiled: May 26, 2017Publication date: December 7, 2017Inventors: Hyo Sang KIM, Sang Jin KIM, Jung Hwan KIM, Jee Hee LEE
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Publication number: 20170352872Abstract: Provided is a novel method of preparing a negative electrode for nonaqueous electrolyte secondary batteries, which contains silicon and is capable of improving cycle characteristics and is also capable of suppressing aggregation of active material particles in a slurry. After formation of a molten liquid by any one of methods (i) to described in the specification, the molten liquid is micronized by atomization or liquid quenching, thereby forming a micronized active material in the form of powder, and the micronized active material is pulverized and classified in a nitrogen atmosphere in which air is present in an amount of less than 1%, and the balance is composed of nitrogen, to thereby adjust the particle size of the micronized active material.Type: ApplicationFiled: August 22, 2017Publication date: December 7, 2017Inventors: Daisuke Inoue, Shinya Kagei, Yanko Marinov Todorov
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Publication number: 20170352873Abstract: The present invention relates to an active material suitable for the production of an electrode, in particular an electrode for a Li—S battery. The active material according to the invention comprises carbon nanofillers homogeneously dispersed in the substance of a sulphur material, the active material being obtainable according to a method involving melting in the presence of intense mechanical energy. The quantity of carbon nanofillers in the active material represents 1 to 25% by weight with respect to the total weight of the active material. The active material according to the invention allows an improvement in the electronic conductivity of the formulation of the electrode. Another aspect of the invention is the use of the active material in an electrode, in particular in a Li—S battery cathode.Type: ApplicationFiled: December 21, 2015Publication date: December 7, 2017Inventors: Alexander KORZHENKO, Christophe VINCENDEAU
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Publication number: 20170352874Abstract: A method for manufacturing an electrode for a lithium ion battery is provided. A powder layer is formed by using a squeegee roll to squeegee powder including an electrode active material and supplied onto a substrate, and then compacted on the substrate by means of a pair of press rolls while conveying the substrate vertically downward to form an electrode sheet. The method includes: supplying the powder onto the substrate; leveling the powder supplied onto the substrate to form the powder layer using the squeegee roll which is disposed in a position so that a squeegee angle formed by a vertical line passing through the rotating axis of one of the press rolls and a line passing through said rotating axis and the rotating axis of the squeegee roll is 0° to 60°; and compacting the powder layer on the substrate using the pair of press rolls.Type: ApplicationFiled: December 18, 2015Publication date: December 7, 2017Applicants: ZEON CORPORATION, TOYOTA JIDOSHA KABUSHIKI KAISHAInventors: Yuto HOSONO, Junya MORI
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Publication number: 20170352875Abstract: An object of the present disclosure is to provide a secondary battery system that functions at high voltage. The present disclosure attains the object by providing a secondary battery system comprising: a fluoride ion battery including a cathode active material layer, an anode active material layer, and an electrolyte layer formed between the cathode active material layer and the anode active material layer; and a controlling portion that controls charging and discharging of the fluoride ion battery; wherein the cathode active material layer contains a cathode active material with a crystal phase that has a Perovskite layered structure and is represented by An+1BnO3n+1-?Fx (A comprises at least one of an alkali earth metal element and a rare earth element; B comprises at least one of Mn, Co, Ti, Cr, Fe, Cu, Zn, V, Ni, Zr, Nb, Mo, Ru, Pd, W, Re, Bi, and Sb; “n” is 1 or 2; “?” satisfies 0???3.5; and “x” satisfies 0?x?5.Type: ApplicationFiled: June 1, 2017Publication date: December 7, 2017Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, KYOTO UNIVERSITYInventors: Hidenori MIKI, Zempachi OGUMI, Yoshiharu UCHIMOTO
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Publication number: 20170352876Abstract: Aspects of the invention are based on the discovery that cathode materials and lithium ion batteries comprising the cathode material, having improved thermal stability may be produced from a cathode material that is comprised of a mixture of a lithium metal oxide and a lithium metal phosphate wherein the lithium metal phosphate comprises a volume fraction of secondary particles having a size of 0.1 to 3 ?m that is from 5 to 100%, based on the total content of lithium metal phosphate. More specifically cathodes comprising lithium metal phosphates having the recited secondary particle ranges help provide cathode materials that are capable of passing the nail penetration test without generating smoke or flames. Methods of forming the cathode and lithium ion battery comprising the cathode are also provided.Type: ApplicationFiled: December 18, 2014Publication date: December 7, 2017Inventors: Maeda Hideaki, Daojin Hang, Xiangyang Tai, Jing Jin, Chunhua Huang
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Publication number: 20170352877Abstract: Composite powder for use in an anode of a lithium ion battery, whereby the particles of the composite powder comprise silicon-based domains in a matrix, whereby the individual silicon-based domains are either free silicon-based domains that are not or not completely embedded in the matrix or are fully embedded silicon-based domains that are completely surrounded by the matrix, whereby the percentage of free silicon-based domains is lower than or equal to 4 weight % of the total amount of Si in metallic or oxidized state in the composite powder.Type: ApplicationFiled: December 11, 2015Publication date: December 7, 2017Inventors: Stijn PUT, Dirk VAN GENECHTEN, Kris DRIESEN, Jin HU, Yvan STRAUVEN, Arihiro MUTO, Nobuaki ISHII, Masataka TAKEUCHI
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Publication number: 20170352878Abstract: A silicon—carbon composite material contains: a carbon material comprising layers; and silicon particles supported between the layers of the carbon material. The specific surface area of the silicon—carbon composite material is 200 m2/g or more as determined by the BET method using nitrogen gas adsorption.Type: ApplicationFiled: May 16, 2017Publication date: December 7, 2017Inventor: SUSUMU KAJITA
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Publication number: 20170352879Abstract: The present invention makes a lithium ion secondary cell exhibit high capacity when lithium manganese phosphate is used as the active material of the lithium ion secondary cell. The present invention is directed to lithium manganese phosphate nanoparticles having a ratio I20/I29 of the peak intensity at 20° to the peak intensity at 29° obtained by X-ray diffraction of greater than or equal to 0.88 and less than or equal to 1.05, and a crystallite size determined by X-ray diffraction of greater than or equal to 10 nm and less than or equal to 50 nm.Type: ApplicationFiled: August 17, 2017Publication date: December 7, 2017Applicant: TORAY INDUSTRIES, INC.Inventors: Hironobu TSUJI, Yasuo KUBOTA, Hiroaki KAWAMURA, Eiichiro TAMAKI, Miyuki TABAYASHI
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Publication number: 20170352880Abstract: A method of forming a carbon coating includes heat treating lithium transition metal composite oxide Li0.9+aMbM?cNdOe, in an atmosphere of a gas mixture including carbon dioxide and compound CnH(2n+2?a)[OH]a, or compound CnH(2n), wherein M and M? are different from each other and are selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, and Ba, and N is different from M and M? and is selected from Ni, Co, Mn, Mo, Cu, Fe, Cr, Ge, Al, Mg, Zr, W, Ru, Rh, Pd, Os, Ir, Pt, Sc, Ti, V, Ga, Nb, Ag, Hf, Au, Cs, B, Ba, and a combination thereof, or selected from B, F, S, and P, and at least one of the M, M?, and N comprises Ni, Co, Mn, Mo, Cu, or Fe.Type: ApplicationFiled: August 24, 2017Publication date: December 7, 2017Applicant: Samsung Electronics Co., Ltd.Inventors: In Hyuk SON, Jun Young MUN, Jin Hwan PARK, Chan Ho PAK, Seung Jae LEE, Hyo Rang KANG
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Publication number: 20170352881Abstract: A non-aqueous electrolyte secondary battery containing a silicon material, wherein the negative-electrode active material can constitute a non-aqueous electrolyte secondary battery having high charge capacity, high initial charge/discharge efficiency, and good cycle characteristics. A negative-electrode active material particle according to an embodiment includes a lithium silicate phase represented by Li2zSiO(2+z) {0<z<2} and particles dispersed in the lithium silicate phase. Each of the particles includes a silicon (Si) core particle and a surface layer formed of an iron alloy containing Si (FeSi alloy). In an XRD pattern of the negative-electrode active material particle obtained by XRD measurement, a diffraction peak of the FeSi alloy at 2?=approximately 45 degrees has a half-width of 0.40 degrees or more, and a diffraction peak of a Si (111) plane at 2?=approximately 28 degrees has a half-width of 0.40 degrees or more.Type: ApplicationFiled: January 18, 2016Publication date: December 7, 2017Applicant: SANYO Electric Co., Ltd.Inventors: Hiroshi Minami, Yoshio Kato, Taizou Sunano
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Publication number: 20170352882Abstract: A negative electrode active material for electric device is used which includes a silicon-containing alloy having a structure in which a silicide phase containing a silicide of a transition metal is dispersed in a parent phase containing amorphous or low crystalline silicon as a main component and a predetermined composition and in which a ratio value (B/A) of a diffraction peak intensity B of a silicide of a transition metal in a range of 2?=37 to 45° to a diffraction peak intensity A of a (111) plane of Si in a range of 2?=24 to 33° is 0.41 or more in an X-ray diffraction measurement of the silicon-containing alloy using a CuK?1 ray.Type: ApplicationFiled: December 17, 2014Publication date: December 7, 2017Inventors: Humihiro Miki, Tomohiro Kaburagi, Manabu Watanabe, Nobutaka Chiba
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Publication number: 20170352883Abstract: The present invention relates to a silicon-based anode active material and a method for manufacturing the same. The silicon-based anode active material according to an embodiment of the present invention comprises: particles comprising silicon and oxygen combined with the silicon, and having a carbon-based conductive film coated on the outermost periphery thereof; and boron doped inside the particles, wherein with respect to the total weight of the particles and the doped boron, the boron is included in the amount of 0.01 weight % to 17 weight %, and the oxygen is included in the amount of 16 weight % to 29 weight %.Type: ApplicationFiled: December 30, 2015Publication date: December 7, 2017Inventors: Young Tai Cho, Yong Gil Choi, Seung Chul Park, Seon Park, Hee Young Seo, Jee Hye Park, Yong Eui Lee, Chul Hwan Kim
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Publication number: 20170352884Abstract: A nickel cobalt manganese composite hydroxide with low impurity content and high reactivity when synthesizing a positive electrode active material, which can be used as a precursor of the positive electrode active material for non-aqueous electrolyte secondary batteries with low irreversible capacity, represented by a general formula: NixCoyMnzMt(OH)2+a (wherein x+y+z+t=1, 0.20?x?0.80, 0.10?y?0.50, 0.10?z?0.90, 0?t?0.10, 0?a?0.5, and M is at least one additive element selected from Mg, Ca, Al, Ti, V, Cr, Zr, Nb, Mo, W), which includes: spherical secondary particles formed by aggregation of a plurality of plate-shaped primary particles, which have an average particle diameter of 3 ?m to 20 ?m, a sulfate radical content of 1.0 mass % or less, a chlorine content of 0.5 mass % or less, and a carbonate radical content of 1.0 mass % to 2.5 mass %.Type: ApplicationFiled: November 16, 2015Publication date: December 7, 2017Applicant: SUMITOMO METAL MINING CO., LTD.Inventors: Motoaki SARUWATARI, Hiroko OSHITA
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Publication number: 20170352885Abstract: Provided is a method for producing a positive electrode active material for nonaqueous electrolyte secondary batteries, including: a water-washing step of mixing, with water, Li—Ni composite oxide particles represented by the formula: LizNi1-x-yCoxMyO2 and composed of primary particles and secondary particles formed by aggregation of the primary particles to water-wash it, and performing solid-liquid separation to obtain a washed cake; a mixing step of mixing a W compound powder free from Li with the washed cake to obtain a W-containing mixture; and a heat treatment step of heating the W-containing mixture, the heat treatment step including: a first heat treatment step of heating the W-containing mixture to disperse W on the surface of the primary particles; and subsequently, a second heat treatment step of heating it at a higher temperature than in the first heat treatment step to form a lithium tungstate compound on the surface of the primary particles.Type: ApplicationFiled: December 17, 2015Publication date: December 7, 2017Inventors: Kentaro Kondo, Jun Yokoyama, Yuki Furuichi, Tetsufumi Komukai
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Publication number: 20170352886Abstract: Provided is a binder for a nonaqueous electrolyte secondary battery electrode. The binder contains a crosslinked polymer having a carboxyl group, or salt thereof, a use therefor, and a method for manufacturing a carboxyl group-containing crosslinked polymer or salt thereof for use in the binder. The crosslinked polymer contains a structural unit derived from an ethylenically unsaturated carboxylic acid monomer in the amount of 50 to 100 mass % of total structural units, and after the crosslinked polymer neutralized to a degree of a neutralization of 80 to 100 mol % has been subjected to water swelling in water and then dispersed in a 1 mass % NaCl aqueous solution, the particle diameter thereof is 0.1 to 7.0 ?m in a volume-based median diameter.Type: ApplicationFiled: October 26, 2016Publication date: December 7, 2017Applicant: TOAGOSEI CO. LTD.Inventors: Hideo MATSUZAKI, Naohiko SAITO, Kinuko OGURA, Atsushi NISHIWAKI, Akitsugu SHIBATA
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Publication number: 20170352887Abstract: An object of the present disclosure is to provide an anode layer for a fluoride ion battery in which decomposition of a binder is restrained. The present disclosure attains the object by providing an anode layer to be used for a fluoride ion battery, the anode layer comprising an anode active material and a non-fluorine-based binder having aromaticity.Type: ApplicationFiled: May 31, 2017Publication date: December 7, 2017Applicants: TOYOTA JIDOSHA KABUSHIKI KAISHA, HONDA MOTOR CO., LTD., KYOTO UNIVERSITYInventors: Hirofumi NAKAMOTO, Masao ICHIKAWA, Zempachi OGUMI, Takeshi ABE
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Publication number: 20170352888Abstract: In accordance with some embodiments of the present disclosure, a method of changing the porosity of the anode is presented. The anode is formed from a composition comprising nickel oxide, a doped ceria, and a stabilized zirconia wherein the weight percentage of the nickel oxide is greater than twenty-five percent. The anode may comprise a single or multiple layers, and may comprise at least one of gadolinia doped ceria (GDC), samaria doped ceria (SDC), or lanthania doped ceria (LDC); and at least one of Yttria stabilized zirconia (YSZ) or scandia stabilized zirconia (ScSZ). The anode may comprise multiple layers. Each layer may comprise a composition having the general formula NiOx-(doped ceria)y wherein x and y are weight percentages of the composition, and wherein 25<x<100, and 25<y<100, and wherein each successive layer contains more nickel than the preceding layers.Type: ApplicationFiled: June 7, 2016Publication date: December 7, 2017Applicant: LG Fuel Cell Systems Inc.Inventors: Shung Ik Lee, Minjae Jung, Younghee Cho, Zhien Liu
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Publication number: 20170352889Abstract: A catalyst carrier, an electrode catalyst, an electrode including the catalyst, a membrane electrode assembly including the electrode, and a fuel cell including the membrane electrode assembly. The catalyst carrier includes a carbon material having a chain structure including a chain of carbon particles and an alumina-carbon composite particle in which a carbon particle encloses an alumina particle, the alumina-carbon composite particle is contained in the carbon material, and the catalyst carrier has a BET specific surface area of 450 to 1100 m2/g.Type: ApplicationFiled: December 25, 2015Publication date: December 7, 2017Applicant: SHOWA DENKO K.K.Inventors: Kunchan LEE, Hiroshi TAKAHASHI, Tomoya KITAGAWA
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Publication number: 20170352890Abstract: The present invention provides a novel and improved metal-air battery in which a lot of catalyst can be disposed in a triple phase boundary, and further, battery properties can be improved. In the metal-air battery according to the present invention, a catalyst layer of an air electrode of a metal-air battery contains a catalyst element and a carbon material, the carbon material comprises two materials of a carbon material A supporting thereon the catalyst element and a carbon material B not supporting the catalyst element, the catalyst layer comprises an agglomerate X containing the catalyst element, the carbon material A and the carbon material B as main components and an agglomerate Y containing the carbon material B as a main component, and the agglomerate X is a continuum and the agglomerate Y is dispersed in the agglomerate X.Type: ApplicationFiled: December 24, 2015Publication date: December 7, 2017Applicant: NIPPON STEEL & SUMITOMO METAL CORPORATIONInventors: Kenichiro TADOKORO, Noriyuki NEGI
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Publication number: 20170352891Abstract: A thermal battery can include: an anode of lithium alloy; a metal-fluoride cathode having Ni; and an electrolyte composition in contact with the anode and cathode. A thermal battery can also include: an anode of lithium alloy; a metal-fluoride cathode having an oxide selected from V2O5 or LiVO3; and an electrolyte composition in contact with the anode and cathode. In one aspect, a metal of the metal fluoride cathode includes Ni, Fe, V, Cr, Mn, Co, or mixture thereof. In one aspect, the metal-fluoride cathode includes NiF2, FeF3, VF3, CrF3, MnF3, CoF3, or a mixture thereof. A method of providing electricity can include: providing an electronic device having a thermal battery with a metal-fluoride cathode having Ni and/or having an oxide selected from V2O5 or LiVO3; and discharging the thermal battery to provide electricity.Type: ApplicationFiled: August 24, 2017Publication date: December 7, 2017Inventors: Pyoungho Choi, Sameer Singhal, Joe Don Edington
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Publication number: 20170352892Abstract: An electrolyteless fuel cell system includes an anode; a cathode; an electrical grid between the anode and cathode; an anode side grid bias electrode; a cathode side grid bias electrode; and an electrical grid power supply, wherein the electrical grid is biased negative with respect to the anode through the anode side grid bias electrode and the electrical grid power supply, or wherein the electrical grid is biased positive with respect to the cathode through the cathode side grid bias electrode and the electrical grid power supply.Type: ApplicationFiled: August 10, 2017Publication date: December 7, 2017Inventor: Emanuel E. Shah
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Publication number: 20170352893Abstract: The present invention relates to a gas diffusion layer for a fuel cell, made of a carbon substrate grafted with at least one aromatic group having formula (II): wherein: the asterisk * designates a carbon atom with no hydrogen and no Ri group, with i=1 to 5, and covalently bonded to the carbon substrate; at least two of the R1, R2, R3, R4, and R5 groups are different from a hydrogen atom; at least two of the R1, R2, R3, R4, and R5 groups are hydrophobic groups or hydrophilic groups or a hydrophobic group and a hydrophilic group.Type: ApplicationFiled: July 17, 2017Publication date: December 7, 2017Applicant: Commissariat A L'Energie Atomique Et Aux Energies AlternativesInventors: Yohann Thomas, Anass Benayad, Amaud Morin, Joël Pauchet, Maxime Schroder
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Publication number: 20170352894Abstract: An electrolyte-circulating battery according to the present invention includes a cell frame including a bipolar plate in contact with an electrode that forms a battery cell, and a frame that surrounds a peripheral edge of the bipolar plate; and a sealing member that is disposed on the frame and that prevents an electrolyte supplied to the battery cell from leaking out of the frame. The frame has a seal groove in which the sealing member is fitted. The seal groove includes a narrow section that causes the sealing member to elastically deform to prevent the sealing member from becoming detached from the seal groove. The narrow section has a width that is uniform in a depth direction of the seal groove.Type: ApplicationFiled: October 21, 2015Publication date: December 7, 2017Applicant: Sumitomo Electric Industries, Ltd.Inventors: Takashi Kanno, Ryo Sato, Katsuya Yamanishi, Takefumi Ito
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Publication number: 20170352895Abstract: A system for measuring a moisture content of an ion-exchange membrane in a fuel-cell stack is provided. The fuel-cell stack includes N electrochemical cells separated by bipolar plates, with N being a natural integer. The system includes a current generator, a voltage measurement device, and an impedance measurement device. The current generator enables a current to be applied to the fuel-cell stack. The voltage measurement device measures voltages of the cells of the fuel-cell stack. The impedance measurement device determines an impedance of an ion-exchange membrane according to a voltage ripple measured by the voltage measurement device across terminals of a corresponding one of the cells of the fuel-cell stack when the current is applied by the current generator. The impedance measurement device is installed in the voltage measurement device.Type: ApplicationFiled: December 17, 2015Publication date: December 7, 2017Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: VINCENT BRAILLARD, GINO PAGANELLI
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Publication number: 20170352896Abstract: A fuel-cell stack system includes a stack of electrochemical cells, a fuel gas supply circuit and an oxidant gas supply circuit, a cooling circuit, a micropump, a temperature measurement device, and a controller. The cells are separated by bipolar plates, with each bipolar plate including an anode, a cathode, and an ion-exchange membrane. The cooling circuit, which is structured to enable a coolant fluid to circulate therein, includes a secondary circuit and a primary circuit that is smaller in size than the secondary circuit, with the primary and secondary circuits being isolated from each other by a thermostatic valve. The micropump is installed at an outlet of the stack and enables a volume of water inside the stack to be mixed. The temperature measurement device determines an internal temperature of a core of the stack. The primary circuit is activated when the internal temperature rises above a predetermined threshold.Type: ApplicationFiled: December 17, 2015Publication date: December 7, 2017Applicants: COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN, MICHELIN RECHERCHE ET TECHNIQUE S.A.Inventors: VINCENT BRAILLARD, GINO PAGANELLI
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Publication number: 20170352897Abstract: A fuel cell stack assembly comprises a stack of fuel cells, each fuel cell having a cooling air conduit with an input/output ventilation aperture disposed on a ventilation face of the stack. The ventilation apertures form an array over said ventilation face of the stack. A first fan is configured to direct air flow through a first portion of the ventilation face and a second fan is configured to direct air flow through a second portion of the ventilation face. A reconfigurable plenum is in fluid communication with the first fan and the second fan and has a first configuration in which air is directed, by the first and second fans, through the first and second portions of the ventilation face in the same direction, and a second configuration in which air is directed, by at least one of the fans, respectively through the first and second portions of the ventilation face in opposing directions.Type: ApplicationFiled: June 21, 2017Publication date: December 7, 2017Applicant: Intelligent Energy LimitedInventors: Paul Leonard Adcock, Peter David Hood, Anthony Newbold, Tobias Reisch
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ELECTRICAL SYSTEM COMPRISING A STACK OF ELECTROCHEMICAL CELLS AND METHOD FOR CONTROLLING SAID SYSTEM
Publication number: 20170352898Abstract: An electrical system includes a stack (3) of electrochemical cells (5), a power converter (9) electrically connected to the stack (3), a voltage comparator (7) for comparing the voltage at the terminals of at least one group of at least one electrochemical cell (5) of the stack (3) to a threshold voltage, and a control module (11) for controlling the converter (9). The control module (11) includes a generator (74) for generating a control instruction for controlling the converter (9) and a transmission member (76) for transmitting the control instruction to the converter (9). The voltage comparator (7) is suitable for transmitting a signal to the transmission member (76).Type: ApplicationFiled: January 12, 2016Publication date: December 7, 2017Inventors: Vincent PHILIPPOTEAU, André RAKOTONDRAINIBE -
Publication number: 20170352899Abstract: A fuel cell system includes a supply unit configured to supply cathode gas to a fuel cell, a bypass valve configured to bypass the cathode gas to be supplied to the fuel cell by the supply unit, a detection unit configured to detect a state of the cathode gas to be supplied to the fuel cell without being bypassed by the bypass valve, a pressure adjusting unit configured to adjust a pressure of the cathode gas to be supplied to the fuel cell, a calculation unit configured to calculate a target flow rate and a target pressure of the cathode gas to be supplied to the fuel cell according to an operating state of the fuel cell, an operating state control unit configured to control an operation amount of at least one of the pressure adjusting unit and the supply unit on the basis of a flow rate and the pressure of the cathode gas detected by the detection unit and the target flow rate and the target pressure calculated by the calculation unit, a bypass valve control unit configured to open and close the bypass valvType: ApplicationFiled: August 20, 2014Publication date: December 7, 2017Applicant: NISSAN MOTOR CO., LTDInventors: Yoshitomo ASAI, Hiroshi TAKEDA
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Publication number: 20170352900Abstract: An end cell heater assembly includes: a case which has a first surface joined to an end plate of a fuel cell stack; a planar heating element installed in an accommodating groove formed in a second surface of the case; a terminal plate which is stacked and interposed between the planar heating element and an end cell of the fuel cell stack, joined and electrically connected to the end cell, and transferring heat generated by the planar heating element to the end cell; and a terminal which is integrally formed with the terminal plate so as to output electrical energy generated by the fuel cell stack and transferred through the terminal plate, to the outside.Type: ApplicationFiled: December 14, 2016Publication date: December 7, 2017Inventors: Ju Han KIM, Sun Heum BAEK, Young Bum KUM, Dae Jong KIM
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Publication number: 20170352901Abstract: The invention relates to a starting method for a fuel cell system (100), particularly for an air/air start of the fuel cell system (100). The method enables the reduction of damaging half-cell voltages in the fuel cell stack (10) through voltage limitation by means of a DC voltage converter. The homogeneous flushing of the fuel cell stack (10) required for this takes place by means of introduction of an anode operating medium into an anode inlet channel (17) of the otherwise sealed fuel cell stack (10) until a predetermined pressure is reached and flushing of the active areas of the fuel cells (11) of the stack (10) after said pressure is reached through opening of an anode discharge adjusting aid (26), preferably arranged in an exhaust coupling (29) connecting the anode exhaust line (22) and the cathode exhaust line (31).Type: ApplicationFiled: June 6, 2017Publication date: December 7, 2017Inventors: Ingmar HARTUNG, Maren Ramona KIRCHHOFF, Martin ARENDT, Heiko TURNER
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Publication number: 20170352902Abstract: A fuel cell system includes a battery, a fuel cell, an air pump, and a processor. The battery stores electric power. The fuel cell supplies electric power to the battery. The air pump is driven with the electric power supplied from the battery to supply air to the fuel cell. The processor, when starting the fuel cell system, is configured to compare an amount of the electric power stored in the battery with a threshold electric power. If the amount of the electric power is higher than or equal to the threshold electric power, the air pump is driven. If the amount of the electric power is lower than the threshold electric power, the air pump is prohibited to drive.Type: ApplicationFiled: May 12, 2017Publication date: December 7, 2017Applicant: HONDA MOTOR CO., LTD.Inventor: Kuniaki OJIMA
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Publication number: 20170352903Abstract: A fuel cell system includes first and second tanks, first and second pipes, a pipe, a first valve, a second valve, a pressure sensor, and circuitry. The first pipe is connected to the first tank. The second pipe is connected to the second tank. The pipe is connected to a fuel cell and connected to the first and second pipes to supply a reaction gas from the first and second tanks to the fuel cell. The first valve is provided at the first pipe. The second valve is provided at the second pipe. The pressure sensor is provided at the pipe between the joint point and the fuel cell. The circuitry determines whether a failure occurs in at least one of the first and second valves based on a change in the pressure detected by the pressure sensor while the first and second valves are controlled.Type: ApplicationFiled: May 17, 2017Publication date: December 7, 2017Applicant: HONDA MOTOR CO., LTD.Inventors: Yusai YOSHIMURA, Satoru KAWASE, Yuji MATSUMOTO
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Publication number: 20170352904Abstract: A method of operating a fuel cell assembly comprising a plurality of fuel cells connected together for collectively providing power to a load, each fuel cell including an anode and a cathode, the method comprising selectively providing an electrical connection between the anode and the cathode of at least one of the fuel cells of the assembly for lowering the voltage across the fuel cell independent of the load.Type: ApplicationFiled: December 7, 2015Publication date: December 7, 2017Applicant: Intelligent Energy LimitedInventors: Sean ASHTON, Zachary ELLIOTT, Harry John KARMAZYN, Kevin KUPCHO
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Publication number: 20170352905Abstract: This invention is directed to aqueous redox flow batteries comprising redox-active metal ligand coordination compounds. The compounds and configurations described herein enable flow batteries with performance and cost parameters that represent a significant improvement over that previous known in the art.Type: ApplicationFiled: August 22, 2017Publication date: December 7, 2017Inventors: JOHN GOELTZ, DESIREE AMADEO, ARTHUR J. ESSWEIN, THOMAS D. JARVI, EVAN R. KING, STEVEN Y. REECE, NITIN TYAGI
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Publication number: 20170352906Abstract: An end plate includes a plate body, fastening portions, and ribs. The plate body is rectangular and includes two long sides and two short sides. The plate body is arranged on an end of a cell stack of a fuel cell. The fastening portions are fastened to a case containing the cell stack. The fastening portions extend along edges of the plate body. The ribs are arranged in a grid-like manner on the plate body surrounded by the fastening portions. The ribs are arranged so that recesses defined between the ribs each have a quadrilateral shape in which two diagonals have different lengths. The ribs are arranged so that the recesses extend in a direction in which the ribs extend and so that a longer one of the two diagonals of each of the recesses extends parallel to the short sides of the plate body.Type: ApplicationFiled: May 25, 2017Publication date: December 7, 2017Applicant: TOYOTA BOSHOKU KABUSHIKI KAISHAInventor: Kunihiro YAMAURA
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Publication number: 20170352907Abstract: A method of fabricating a multilayered thin film solid state battery device. The method steps include, but are not limited to, the forming of the following layers: substrate member, a barrier material, a first electrode material, a thickness of cathode material, an electrolyte, an anode material, and a second electrode material. The formation of the barrier material can include forming a polymer material being configured to substantially block a migration of an active metal species to the substrate member, and being characterized by a barrier degrading temperature. The formation of cathode material can include forming a cathode material having an amorphous characteristic, while maintaining a temperature of about ?40 Degrees Celsius to no greater than 500 Degrees Celsius such that a spatial volume is characterized by an external border region of the cathode material. The method can then involve transferring the resulting thin film solid state battery device.Type: ApplicationFiled: April 13, 2017Publication date: December 7, 2017Applicant: Sakti3, Inc.Inventors: Ann Marie SASTRY, Chia-Wei WANG, Yen-Hung CHEN, HyonCheol KIM, Xiangchun ZHANG, Myoungdo CHUNG
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Publication number: 20170352908Abstract: An object of the present invention is to provide a secondary battery having high energy density with long-term life. The present invention relates to a secondary battery comprising a negative electrode comprising a silicon-containing compound and an electrolyte solution comprising a fluorine-containing ether compound, a fluorine-containing phosphoric acid ester, a sulfone compound and a cyclic carbonate compound in a predetermined amount respectively.Type: ApplicationFiled: October 21, 2015Publication date: December 7, 2017Applicant: NEC CorporationInventors: Takehiro NOGUCHI, Yuukou KATOU, Makiko TAKAHASHI
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Publication number: 20170352909Abstract: A cathode for a lithium-sulphur battery, said cathode comprising a particulate mixture deposited on a current collector, said particulate mixture comprising an admixture of (i) composite particles formed from a composite comprising electroactive sulphur material melt-bonded to electroconductive carbon material, and (ii) conductive carbon filler particles, wherein conductive carbon filler particles form 1 to 15 weight % of the total weight of the composite particles and conductive carbon filler particles.Type: ApplicationFiled: December 21, 2015Publication date: December 7, 2017Inventors: David AINSWORTH, Stephen E. ROWLANDS, Justyna Katarzyna KREIS, Lisset Amparo URRUTIA MUNOZ
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Publication number: 20170352910Abstract: Provided are an electrolyte solution for a lithium secondary battery, and a lithium secondary battery including the electrolyte solution. The electrolyte solution for a lithium secondary battery includes a lithium salt, an organic solvent, and further quaternary ammonium hexafluorophosphate as a solid salt.Type: ApplicationFiled: July 27, 2015Publication date: December 7, 2017Inventors: Joo Hwan KOH, Jong Ho JEON, Jin Hee KIM, Sung Nim JO, Tae Hwan YU, Jung Joo CHO
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Publication number: 20170352911Abstract: The present disclosure is to provide a negative electrode for a lithium secondary battery having high negative electrode efficiency and excellent capacity retention, and a lithium secondary battery including the negative electrode. In one aspect, there is provided a negative electrode for a lithium secondary battery, wherein the electrode contains 3 to 9% by weight of a silicon-based negative-electrode active material having a following composition formula (1); and 87.5 to 95.5% by weight of a graphite-based negative-electrode active material: SixTiyFezAlu??(i) where x, y, z and u are atomic %, x: 1?(y+z+u), y: 0.09 to 0.14, z: 0.09 to 0.14, u: 0.01 exclusive to 0.2 exclusive.Type: ApplicationFiled: February 26, 2016Publication date: December 7, 2017Applicant: ILJIN ELECTRIC CO., LTD.Inventors: Young Pil Choi, Cheol Ho Park, Min Hyun Kim, Myeong Han Kim, Seon Kyong Kim
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Publication number: 20170352912Abstract: To provide a non-aqueous electrolyte electricity-storage element including a positive electrode including a positive-electrode active material capable of inserting and releasing anions, a negative electrode including a negative-electrode active material capable of inserting and releasing cations, and a non-aqueous electrolyte, wherein the positive-electrode active material is porous carbon having pores having a three-dimensional network structure, and wherein a changing rate of a cross-sectional thickness of a positive electrode film including the positive-electrode active material defined by Formula (1) below is less than 45%.Type: ApplicationFiled: August 23, 2017Publication date: December 7, 2017Inventors: Naoto ABE, Yoshio ITOH, Tatsuya DAN, Yuka ARAKI, Shuhei TAKESHITA
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Publication number: 20170352913Abstract: The present invention relates to the field of organic lithium batteries having high energy and power densities. In particular, the present invention relates to an organic lithium battery comprising a positive electrode based on redox organic compounds and a porous separator made of biaxially oriented polypropylene, and to its process of manufacture.Type: ApplicationFiled: December 8, 2015Publication date: December 7, 2017Applicants: BLUE SOLUTIONS, CENTRE NATIONAL DE LA RECHERCH SCIENTIFIQUE, UNIVERSITE DE NANATESInventors: Margaud LECUYER, Marc DESCHAMPS, Joël GAUBICHER, Philippe POIZOT, Dominique GUYOMARD, Bernard LESTRIEZ
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Publication number: 20170352914Abstract: A lithium-cobalt-based composite oxide used for a positive electrode active material of an electrochemical device, wherein the lithium-cobalt-based composite oxide has elutable fluoride ions, the elutable fluoride ions being eluted to an eluate when the lithium-cobalt-based composite oxide is dispersed to ultrapure water, in a mass ratio of 500 ppm or more and 15000 ppm or less in comparison with the lithium-cobalt-based composite oxide, and the lithium-cobalt-based composite oxide has a composition shown by the following general formula (1): Li1-xCo1-zMzO2-aFa (?0.1?x<1, 0?z<1, 0?a<2) . . . (1) (wherein, M represents one or more kinds of metal element selected from the group of Mn, Ni, Fe, V, Cr, Al, Nb, Ti, Cu, and Zn).Type: ApplicationFiled: November 24, 2015Publication date: December 7, 2017Applicant: SHIN-ETSU CHEMICAL CO., LTD.Inventors: Hidekazu AWANO, Hiromichi KAMO, Takakazu HIROSE, Hiroki YOSHIKAWA
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Publication number: 20170352915Abstract: Provided is a binder composition for a non-aqueous secondary battery positive electrode that can form a positive electrode with which it is possible to obtain a non-aqueous secondary battery having excellent life characteristics even when aging treatment is carried out under low-temperature and low-depth of charge conditions. The binder composition contains a first binder, iron, and at least one of ruthenium and rhodium. The total iron, ruthenium, and rhodium content is no greater than 5×10?3 parts by mass per 100 parts by mass of the first binder.Type: ApplicationFiled: December 25, 2015Publication date: December 7, 2017Applicant: ZEON CORPORATIONInventors: Maki KATAGIRI, Yasuhiro WAKIZAKA, Mayumi FUKUMINE
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Publication number: 20170352916Abstract: Relating to a sulfide-based solid electrolyte compound for lithium ion batteries which has a cubic argyrodite-type crystal structure, to provide a compound which can suppress a generation amount of hydrogen sulfide when being left to stand in the air and which can maintain high conductivity even when being left to stand in dry air. Proposed is a sulfide-based solid electrolyte compound for lithium ion batteries containing a crystal phase of the cubic argyrodite-type crystal structure and represented by a composition formula (1): Li7-x+yPS6-xClx+y, wherein x and y in the composition formula (1) satisfy 0.05?y?0.9 and ?3.0x+1.8?y??3.0x+5.7.Type: ApplicationFiled: December 25, 2015Publication date: December 7, 2017Inventors: Norihiko Miyashita, Takashi Chikumoto, Tatsuya Aoki, Hitohiko Ide, Kenji Matsuzaki