Abstract: The invention relates to a method for producing rigid polyurethane-polyisocyanurate (PUR/PIR) foams using partially trimerized isocyanate blends. The invention further relates to the rigid polyurethane-polyisocyanurate foams obtainable by said method and to the use thereof in manufacturing composite elements made of the rigid polyurethane-polyisocyanurate foams and suitable coatings. The invention also relates to the composite elements obtainable thereby.

Abstract: A method of producing PUD by a solvent free process includes drying polyol in vacuum; placing the dried polyol and DMBA in a reaction vessel to mix until a first mixture becomes transparent; adding diisocyanate which having functional group of isocyanate(—NCO) to the first mixture to react until —NCO terminated first prepolymer is formed; decreasing temperature of the —NCO terminated first prepolymer to 65° C.; adding a neutralizing agent to the —NCO terminated first prepolymer until —NCO terminated second prepolymer is formed; adding the remaining diisocyanate having isocyanate functional group to the —NCO terminated second prepolymer to form a second mixture; adding deionized water to the second mixture to form prepolymer dispersion; and adding chain extension agent to the prepolymer dispersion to rotate at a range of 200 to 2,000 rpm for chain extension for 1-3 hours until solid content 40.0 wt. % solvent free PUD is produced.

Abstract: A flame-retardant rigid polyurethane foam contains a flame retardant, the foam having a ratio of the maximum peak intensity ratio (P1) of the foam after moist heat treatment of the foam for one week at a temperature of 80° C. and a humidity of 85% to the maximum peak intensity ratio (P2) of the foam before this moist heat treatment of 85% or more (P1/P2×100). The P1 and P2 each refer to the ratio of the maximum peak intensity of 1390 to 1430 cm?1 to the maximum peak intensity of 1500 to 1520 cm?1 when the infrared absorption spectrum is measured at a position 5 to 10 mm from the surface of the foam, and the average intensity of 1900 to 2000 cm?1 is adjusted to zero.

Abstract: The present invention relates to a thermoplastic polyurethane obtainable or obtained by the conversion of at least a polyisocyanate composition, ethane-1,2-diol as chain extender and a polyol composition, wherein no further chain extender is used aside from ethane-1,2-diol, to a process for preparing such a thermoplastic polyurethane, and to the use of such a polyurethane for production of injection molded products, extrusion products, films and shaped bodies.

Abstract: A high-resiliency polyurethane foam comprises the reaction product of an isocyanate and an isocyanate-reactive component. The isocyanate-reactive component comprises a first polyether polyol in an amount of greater than about 5 parts by weight and a second polyether polyol in an amount of less than about 80 parts by weight, with parts by weight based on the total weight of the isocyanate-reactive component. The high-resiliency polyurethane foam has a resilience of about 45 to about 70% when tested in accordance with ASTM D3574-11. A method of forming a high-resiliency polyurethane foam includes the steps of providing the isocyanate and the isocyanate-reactive component and reacting the isocyanate and the isocyanate-reactive component.

Abstract: The invention relates to a method for producing polyurethane foams by reacting an isocyanate component with a component that is reactive to isocyanates and that comprises at least one polyether carbonate polyol, the reaction taking place in the presence of an amine antioxidant. The invention also relates to polyurethane foams produced according to the claimed method and to the use of said foams.

Abstract: This invention relates to a process for preparing viscoelastic polyurethane foam in which the isocyanate-reactive component comprises a specific polyol blend, and to viscoelastic polyurethane foam wherein the isocyanate-reactive comprises the specific polyol blend. The polyol blend may be an in situ formed polyol blend.

Abstract: An epoxy resin composition produces a cured product having improved elastic modulus and improved nominal strain at compressive fracture. The epoxy resin composition is a fiber-reinforced composite material having excellent compression strength and interlayer toughness. The epoxy resin composition contains at least the following constituent components [A], [B] and [C]. [A] A specific ortho type epoxy resin. [B] At least one component selected from the group consisting of: thermoplastic resins that are compatible with the epoxy resin [A]; and core-shell type polymers. [C] An amine curing agent.

Abstract: Provided are an anion exchange resin being capable of producing an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer, which have an improved physical property (anion conductivity); a method for producing thereof; an electrolyte membrane for a fuel cell, a binder for forming an electrode catalyst layer and a fuel cell electrode catalyst layer produced from the anion exchange resin; and a fuel cell having the electrolyte membrane or the electrode catalyst layer.

Abstract: The present invention provides a copolymerized polyester resin which can produce an adhesive resin having an excellent color tone and an excellent durability when used for an adhesive to be applied to various uses. A copolymerized polyester resin, comprising, as constituting ingredients, a dicarboxylic acid ingredient containing 75 molar % or less of terephthalic acid and a diol ingredient containing two or more kinds of diols, characterized in that the copolymerized polyester resin satisfies the following (1) and (2): (1) A decrease in a reduced viscosity after the copolymerized polyester resin is subjected to a heat treatment in a nitrogen atmosphere at 275° C. for 2 hours is 0.20 dl/g or less; and (2) A color b value is 5 or less.

Abstract: The present disclosure relates to copolymers and methods for copolymer preparation. Disclosed herein are high molecular weight copolymers of lactones and epoxides and methods for their synthesis.

Abstract: Provided herein are methods of producing polymers from furan and optionally diol compounds, using an organocatalyst. The furan compounds may include, for example, 2,5-furandicarboxylic acid or 2,5-tetrahydrofurandicarboxylic acid. Provided herein are also polymer compositions, such as poly(alkylene-2,5-furandicarboxylate). The polymer compositions herein have a low metal content.

Abstract: A biodegradable cross-linked polymer and methods of preparing same are provided. The biodegradable cross-linked polymer is formed from a biodegradable polymeric material having two or more arms, which is a random copolymer formed of a first monomer and a second monomer different from the first monomer. The first monomer is selected from the group consisting of L-lactide, DL-lactide, glycolid, ?-caprolactone, trimethylene carbonate, p-dioxanone, amino acid-derived polycarbonates and polyorthoesters. The second monomer is one or two selected from the group consisting of D-lactide, DL-lactide, glycolide, ?-caprolactone, trimethyl carbonate, salicylic acid, carbonates, amino acids and derivatives thereof. The biodegradable polymeric material has a molecular weight of from 5,000 to 1,200,000 and an intrinsic viscosity of from 0.1 to 9.0 dl/g. Each of the terminal groups on the arms of the biodegradable polymeric material is selected from the group consisting of hydroxyl amino and carboxyl groups.

Abstract: A process of forming a side-chain-functionalized polyhydroxyalkanoate (PHA) material is disclosed. The process includes forming a PHA material having a hydroxyl-terminated side-chain. The process also includes utilizing the PHA material having the hydroxyl-terminated side-chain to form a side-chain-functionalized PHA material having a side-chain with a terminal cross-linkable functional group.

Abstract: The present invention relates to an organic zinc catalyst which exhibits more improved catalytic activity than conventional organic zinc catalysts during a polymerization process for the preparation of a polyalkylene carbonate resin and is capable of preventing an aggregation phenomenon during a reaction, a method for preparing the same, and a method for preparing a polyalkylene carbonate resin using the organic zinc catalyst. The method for preparing an organic zinc catalyst includes the step of reacting a zinc precursor with a dicarboxylic acid in the presence of a polyether derivative to form a zinc dicarboxylate-based catalyst.

Abstract: A binder comprising the products of a carbohydrate reactant and polyamine is disclosed. The binder is useful for consolidating loosely assembled matter, such as fibers. Uncured fibrous products comprising fibers in contact with a carbohydrate reactant and a polyamine are also disclosed. The binder composition may be cured to yield a fibrous product comprising fibers bound by a cross-linked polymer. Further disclosed are methods for binding fibers with the carbohydrate reactant and polyamine based binder.

Abstract: A compound containing at least one species of formula (I): where: Ax? is an anion of valency x equal to 1 or 2 chosen from sulfonate, sulfonylimide of —SO2—N?—SO2CyF2y+1 type with y being an integer between 0 and 4; borate, borane, phosphate, phosphinate, phosphonate, silicate, carbonate, sulfide, selenate, nitrate and perchlorate anions; Cx+ is a counter-cation of the anion Ax?, chosen from a proton H+ and alkali metal and alkaline-earth metal cations; p is an integer ranging from 1 to 10; E is an organic spacer comprising a linear sequence of at least two covalent bonds; n is an integer greater than or equal to 2; and G represents: (a) a group or (b) a group the anion Ax? being covalently bonded to the polycyclic group Ar.

Abstract: Various embodiments disclosed relate to a silane-functionalized polyalkyleneimine (PAI) clay stabilizer for treatment of subterranean formations. In various embodiments, the present invention provides a method of treating a subterranean formation. The method can include placing in the subterranean formation a silane-functionalized PAI clay stabilizer.

Abstract: The present invention is to provide a method that can produce polyarylene sulfide having a high viscosity at a high yield. The method of producing polyarylene sulfide according to an embodiment of the present invention includes: a preparation step of preparing a mixture containing an organic amide solvent, a sulfur source, a dihalo aromatic compound, and an alkali metal hydroxide; a first-stage polymerization step of initiating a polymerization reaction by heating the mixture and producing a prepolymer until a pH of a reaction system reaches a range of 10 to 11; and a second-stage polymerization step of continuing the polymerization reaction.

Abstract: According to one preferred embodiment of the present invention, a composition for optical materials, which contains a compound represented by formula (1) and a compound represented by formula (2), is able to be provided. This composition for optical materials enables stable storage of a compound represented by formula (2) at low cost, and also enables stable storage thereof with respect to temperature change. In addition, this composition for optical materials enables the achievement of an optical material which has good light resistance. (In formula (1), in represents an integer of 0-4; and n represents an integer of 0-2.) (In formula (2), m represents an integer of 0-4; and n represents an integer of 0-2.

Abstract: According to the present invention, it is possible to provide a photocurable composition which comprises a cyclic compound (a) represented by formula (1), an episulfide compound (b), and a photopolymerization initiator (c). In a preferred embodiment, the proportion of the cyclic compound (a) in the photocurable composition is 5-80 mass %, the proportion of the episulfide compound (b) is 20-95 mass %, and the proportion of the photopolymerization initiator (c) is 0.1-10 parts by mass per 100 parts by mass of the sum of the cyclic compound (a) and the episulfide compound (b). In the formula, C represents a carbon atom, X represents S, Se, or Te, and a to f are integers of 0-3, provided that 8?(a+c+e)?1, 8?(b+d+f)?2, and (b+d+f)?(a+c+e).

Abstract: Process for the preparation of a polysulfide comprising the step of reacting in the absence of a dihaloalkane a bis(2-dihaloalkyl)formal in the presence of (i) a pre-polymer (I) according to structure (I) X—(R2—O)n—CH2—O—(R1—O)m—CH2—(O—R2)p—X??(I), wherein R1 and R2 can be the same or different and are selected from alkane chains containing 2-10 carbon atoms, X is a halogen atom, and n, m, and p are integers that can be the same or different and have a value in the range 1-6, with either (i) sodium polysulfide or (ii) a combination of sodium hydrosulfide and sulfur.

Abstract: Multistep continuous and semicontinuous hydrolysis and condensation of chlorosilanes with alcohol containing minimal water in a column in a first step to form a silicone resin intermediate, followed by further condensation provides silicone resins in reproducible fashion substantially free of hydrogen chloride, without reactor gelatin.

Abstract: The field of the invention is that of crosslinkable or crosslinked silicone compositions that can be used, in particular, to form a non-stick and water-repellent coating or film for flexible substrates, for example made of paper or the like, and in the form of natural or synthetic polymer films. These compositions are of the type of those comprising crosslinking organopolysiloxanes bea-ring SiH units and unsaturated organopolysiloxanes, preferably vinyl organopolysiloxanes, capable of reacting with the crosslinker by addition reaction, in the presence of platinum in order to form the non-stick crosslinked coating on the flexible substrate, and at least one crosslinking and attachment-promoting additive X.

Abstract: An organic group-modified organosilicon resin having the average compositional formula (1), which is solid or liquid at 25° C., is suited for use in cosmetics. The resin is able to form an emulsion having a pleasant feel on use, a high internal water phase, and stability over time. In formula (1), a, b, c, d, e, and fare numbers: 0?a?400, 0<b?200, 0?c?400, 0?d?320, 0?e?320, 0<f?1,000, and 0.5?(a+b+c)/f?1.5.

Abstract: The present invention relates to a segmented block copolymer composition based on diblock and/or triblock copolymers of vinyl aromatic monomer and hydrogenated butadiene blocks and thermoplastic polyurethane blocks which are linearly bonded by N or O atoms, and its procedure of obtainment based on reactive extrusion. Furthermore, the present invention relates to a thermoplastic composition, a laminate structure and a polyurethane foam, with improved properties, comprising the segmented block copolymer composition.

Abstract: Particulate compositions solid at 20° C. and comprising at least one copolymer based on at least the following comonomers a) to d) a) conjugated diene, b) ?,?-unsaturated nitrile, c) at least one polyfunctional radically polymerizable comonomer and d) at least one carboxyl-, hydroxyl-, epoxy- and/or amino-group-functional radically polymerizable comonomer, which possess an average particle diameter of the primary particles of 5 to 500 nm, characterized in that these compositions possess a pourability to EN DIN 6186:1998 (funnel diameter 15 mm) of not more than 33 s.

Abstract: The present invention relates to a method for manufacturing a super absorbent resin, the method for manufacturing a super absorbent resin can provide a super absorbent resin which has an optimized pore size and porosity, wherein an absorbent surface area is increased accordingly. The super absorbent resin can exhibit a fast absorption rate under pressure and under no-pressure.

Abstract: The present invention relates to a method for preparing a superabsorbent polymer, and a superabsorbent polymer prepared thereby. A superabsorbent polymer prepared by the preparation method exhibits minimized deterioration of physical properties after being pulverized, and thus basic absorbance performance is excellent and an excellent liquid permeability and absorbance rate can be exhibited.

Abstract: A gas hydrate hydrogel inhibitor comprising at least one polymer hydrogel particle having from 50 to 100% hydrogel content, the at least one polymer hydrogel particle including an inhibitor selected from the group consisting of: at least one thermodynamic hydrate inhibitor, at least one kinetic hydrate inhibitor, or a combination thereof.

Abstract: A process is described for the preparation of a homogeneous spinning solution for the production of acrylic fibers, which comprises i) a preparation step of an aqueous suspension of homopolymer or copolymer of acrylonitrile through the polymerization of monomers in aqueous suspension, removal of the unreacted monomers, filtration and washing of the aqueous suspension, obtaining a filtration cake, ii) a step for dispersing the filtration cake and a step iii) for evaporating the dispersion of polymer or obtaining the homogeneous spinning solution.

Abstract: The subject matter of the present invention is a method for producing a biodegradable, non-porous composite material made water-absorbent and/or lipid-absorbent, used for obtaining diversely shaped solid objects to be subsequently loaded with active liquid hydrophilic and/or lipophilic compositions comprising at least one active ingredient intended to be delivered into an environment in a controlled and continuous manner. The absorption of the hydrophilic and/or lipophilic composition by said objects is achieved using a network of hydrophilic and/or lipophilic wicks formed in the non-porous material by the co-absorbents. Said method according to the invention is discontinuous, insofar as it comprises storage steps which are steps involving partial interruption of the process insofar as the intermediate products are storable.

Abstract: A composition is provided that comprises at least the following: polymer particles comprising a coating on at least a portion of the total surface of the polymer particles, and wherein the coating is formed from a powder composition comprising at least one inorganic powder, and at least one organic powder selected from a metal stearate and/or a polymer powder, and wherein the weight ratio of the total amount of the inorganic powder to the total amount of the organic powder is from 3.0 to 50.0.

Abstract: Carbodiimide is added to a molten aromatic polyamide resin so as to provide resin pellets. The percentage of residual unreacted carbodiimide to each resin pellet is 0.03% to 0.33% by mass.

Abstract: Disclosed are macroscopic systems of highly concentrated, cross-linked biopolymers. The macroscopic system is created by combining a biopolymer with a cross-linking agent, submerging the resulting product in an aqueous solution which contains additional cross-linking agents, to allow the biopolymer to undergo a second cross-linking process. The resulting macroscopic biopolymer has an increased biopolymer concentration and increased longevity within the body.

Abstract: Provided are a preparation method of a superabsorbent polymer, and a superabsorbent polymer prepared thereby. The preparation method of the superabsorbent polymer according to the present disclosure enables preparation of the superabsorbent polymer which is excellent in absorption properties such as centrifuge retention capacity and absorbency under pressure, and also has improved permeability. In addition, the preparation method exhibits excellent operability during the preparation (in particular, surface crosslinking of the polymer) and excellent productivity due to low production of coarse particles and fine particles.

Abstract: The present invention aims to provide a method for producing a modified molded article that has favorable appearance, high breaking strength, and excellent abrasion resistance, as well as excellently low permeability to nitrogen gas and hydrochloric acid. The method for producing a modified molded article of the present invention includes molding a fluororesin to provide a molded article and irradiating the molded article with radiation at an irradiation dose of lower than 100 kGy at 50° C. to 200° C. to provide a modified molded article.

Abstract: A uniaxially-stretched, high yield extruded capacitor film comprising a miscible polymer blend comprising a polyetherimide and a polyester, wherein the polyetherimide comprises units derived from polymerization of an aromatic dianhydride with a diamine comprising a m-phenylenediamine, a p-phenylenediamine, or combinations thereof, wherein the polyetherimide is endcapped with a substituted or unsubstituted aromatic primary monoamine, wherein the polyester comprises repeating structural units derived from polymerization of an aromatic dicarboxylic acid with a dihydroxy compound, and wherein the high yield extruded capacitor film comprises equal to or greater than about 90 wt. % of the miscible polymer blend entering an extruder used for manufacturing the capacitor film, based on the total weight of miscible polymer blend prior to entering the extruder.

Abstract: A water-soluble film comprises a polyvinyl alcohol resin (A), wherein a difference (?R) between a phase retardation (R?) of one of opposite surfaces (? surface) of the water-soluble film and a phase retardation (R?) of the other surface (? surface) of the water-soluble film is not greater than 8 nm as measured on a middle portion of the water-soluble film with respect to a transverse direction (TD) of the water-soluble film. Therefore, the water-soluble film has a reduced difference in crystallinity between the front and back surfaces thereof and, hence, is less liable to be curled to thereby ensure a higher productivity.

Abstract: Provided are films such as high-stalk films made from polyethylene polymers, and methods for making these films. Such films preferably have at least one of the following properties: (a) MD 1% Secant Modulus of less than 400 MPa, (b) Elmendorf Tear MD of at least 100 g/mil, (c) Dart drop of at least 200 g/mil, (d) puncture resistance break energy of at least 120 mJ/?m, (e) TD shrink at 150° C. of at least 40% or at least 30% at 120° C.; and (f) haze value of less than 40%.

Abstract: The invention provides a biaxially oriented polyamide-based resin film comprising a polyamide 6 resin and 1 to 5% by mass of a polyamide-based elastomer, wherein the polyamide-based elastomer is a polyamide-based block copolymer which comprises a hard part of a cyclic lactam residue having 4 to 10 carbon atoms and a soft part of a residue of a polyoxypropylene glycol or a polyoxytetramethylene glycol having a number average molecular weight of 850 to 2500. The film satisfies the conditions of (1) the number of Gelbo pinhole defects is not more than 3 when a twist and bend test is carried out 1,000 times at 1° C. using a Gelbo Flex tester, (2) the impact strength is not less than 0.9 J, (3) the total transmission haze value is not more than 5.0%, and (4) the coefficient of static friction at a temperature of 23° C. and a relative humidity of 50% is not more than 0.7.

Abstract: Provided are a tow prepreg comprising a reinforcing fiber bundle impregnated with a matrix resin composition, wherein the matrix resin composition contains a component (A) (an epoxy resin), a component (B) (dicyandiamide), a component (C) (a curing accelerator), and a component (D) (a core-shell type rubber particle), and a content of the component (D) with respect to 100 parts by mass of the component (A) is from 20 to 70 parts by mass, a viscosity is from 3 Pa·s to 80 Pa·s at 30° C., and a minimum viscosity to be obtained when a viscosity is measured by raising a temperature from room temperature to 130° C. at a rate of temperature rise of 2.0° C./min is from 0.04 Pa·s to 1 Pa·s, which exhibits excellent drape property and tackiness and less stickiness and can be unwound at a high speed; and a composite material-reinforced pressure vessel having fewer voids in a reinforcing layer which is obtainable by using the tow prepreg, a high burst pressure, and an excellent appearance due to appropriate resin flow.

Abstract: Some embodiments described herein relate to a substrate with a surface comprising a silane or a silane derivative covalently attached to optionally substituted cycloalkene or optionally substituted heterocycloalkene for direct conjugation with a functionalized molecule of interest, such as a polymer, a hydrogel, an amino acid, a nucleoside, a nucleotide, a peptide, a polynucleotide, or a protein. In some embodiments, the silane or silane derivative contains optionally substituted norbornene or norbornene derivatives. Method for preparing a functionalized surface and the use in DNA sequencing and other diagnostic applications are also disclosed.

Abstract: A styrene resin extruded foam includes a styrene resin, a flame retarder, a hydrofluoroolefin, an alcohol, and at least one selected from the group consisting of a saturated hydrocarbon having 3 to 5 carbon atoms, dimethyl ether, and alkyl chloride. An amount of the flame retarder is 0.5 to 8.0 parts by weight relative to 100 parts by weight of the styrene resin. The styrene resin extruded foam has an apparent density of 20 to 45 kg/m3 and a closed cell ratio of not less than 90%. An amount of the hydrofluoroolefin added is 65 to 90 mol % relative to 100 mol % in total of the hydrofluoroolefin and the alcohol which are added. An amount of the alcohol added is 10 to 35 mol % relative to 100 mol % in total of the hydrofluoroolefin and the alcohol which are added.

Abstract: An apparatus and a method for expanding a slurry of thermally expandable thermoplastic microsphere is disclosed. The apparatus and method expand the slurry of thermally expandable thermoplastic microsphere without any direct contact to a fluid heat transfer medium. The apparatus and method utilise a distribution pipe attached to an outlet pipe.

Abstract: A manufacturing method for porous resin microparticles comprising steps of: heating a polyester thermoplastic resin having biodegradability to a temperature of 80° C. or higher and 200° C. or lower in a glycol ether solvent to obtain a solution, and cooling the solution to precipitate the polyester thermoplastic resin as porous resin microparticles.

Abstract: Materials and methods are described herein that include forming a porous polymer network with antimicrobial and antifouling properties. The antifouling portion may be a polymer, such as polyethylene glycol, and the antimicrobial portion may be a metal, or a different cationic species, such as a quaternary ammonium salt. The method generally includes forming a reaction mixture comprising a formaldehyde, a bridging group, and moieties with antifouling and antimicrobial properties.

Abstract: The present invention relates to a method of making a foamed cellulosic fiber-thermoplastic composite article. The method includes the steps of providing a copolymer composition, combining the copolymer composition and cellulosic fibers, applying heat, mixing energy and pressure to form a foamable mixture, and forming the foamable article in a molding or extruding operation. The method is characterized in that at least 10% of the cellulosic fibers have been thermally modified prior to being combined with the copolymer composition.

Abstract: Compounds having an elastomer material, a filler material, at least one additive material, and at least one accelerant material are disclosed. In various embodiments, the filler material comprises a graphene-based carbon material. In various embodiments, the graphene-based carbon material comprises graphene comprising up to 15 layers, carbon aggregates having a median size from 1 to 50 microns, a surface area of the carbon aggregates at least 50 m2/g, when measured via a Brunauer-Emmett-Teller (BET) method with nitrogen as the adsorbate, and no seed particles.

Abstract: A polytrimethylene terephthalate composition including a polyester having a trimethylene terephthalate unit as a main repeating unit, which satisfies all the following requirements: (a) the intrinsic viscosity is 0.50 to 1.60 dL/g; (b) titanium dioxide whose weight distribution of particles having a particle size of more than 1.0 ?m is 5.0% by weight or less is contained in an amount of 0.05 to 3.0% by weight; (c) the crystallization exothermic peak top temperature is 165° C. or more; and (d) the half-width of the crystallization exothermic peak is 20° C. or less. In addition, the invention further encompasses a method for producing a polytrimethylene terephthalate composition using titanium dioxide that has been subjected to a wet-grinding treatment, and also a fiber obtained from the composition.