Bituminous Emulsion Patents (Class 106/277)
  • Patent number: 6576050
    Abstract: The present invention relates to a process for the manufacture of an emulsion of bituminous binder, comprising a) the preparation of a concentrated primary. emulsion containing a surfactant and at least 65% by weight in the case of an anionic emulsion, or at least 70% by weight in the case of the other emulsions, of bituminous binder, by mixing an initial aqueous phase and a liquid bituminous phase under the effect of a mechanical shear energy and in the presence of the said surfactant; and b) the addition of an aqueous dilution phase to the said primary emulsion.
    Type: Grant
    Filed: January 7, 2000
    Date of Patent: June 10, 2003
    Assignee: Colas
    Inventor: Jacques Samanos
  • Publication number: 20030084824
    Abstract: A process for producing building materials, such as asphalt, cement, concrete, mortar, or plaster board from liquid paint sludge containing water and paint solids produced from overspray in commercial paint booth operations. The preferred embodiment comprises adding the liquid paint sludge as the hydrating agent directly to the building material mix.
    Type: Application
    Filed: October 3, 2002
    Publication date: May 8, 2003
    Inventors: Robert R. Matheson, Dennis M. Dixon, John R. Moore, David A. Fischer
  • Patent number: 6559206
    Abstract: The invention consists of a bitumen/resin composite emulsion for a road surface protection layer against the attacks of petroleum derivates, realised by mixing a first emulsion comprising at least one resin with a second emulsion comprising a bituminous binder and a resin crosslinking agent. A pigmentary preparation and/or a load made of a filler or sand or a fine sand or their combinations, can be incorporated to the first emulsion, the second emulsion or into the composite emulsion resulting from the mixture of both emulsions. The loaded composite emulsion enables the realisation of thin film-type surface coatings made of one or several layers.
    Type: Grant
    Filed: August 6, 2001
    Date of Patent: May 6, 2003
    Assignee: Colas
    Inventors: Graziella Durand, Eric Godard, Jean-François Gal
  • Patent number: 6540822
    Abstract: A method of emulsifying asphalt using a polyamine polybetaine, preferably a dibetaine, as an emulsifier or co-emulsifier and an emulsion of asphalt, water and a polybetaine, preferably a diamine dibetaine. The advantages of using a polyamine polybetaine as an emulsifier or co-emulsifier include its ability to provide superior cationic and anionic emulsions, and slow-setting emulsions at low use levels, and the excellent adhesion of the cured asphalt film.
    Type: Grant
    Filed: March 20, 2001
    Date of Patent: April 1, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Julia Mary Wates, Alan James
  • Patent number: 6503306
    Abstract: Composition for impregnating porous materials, in which the composition contains at lease one component having preservative properties or which release a component having preservative properties on heating, the composition comprising an emulsion of water and oil containing a primary surfactant and an amphoteric additive, the pH of the emulsion being equal or approximately equal to the iso-electric point of the amphoteric additive. The compositions of the invention are particularly useful in the preservation of timber.
    Type: Grant
    Filed: November 27, 2000
    Date of Patent: January 7, 2003
    Assignee: Monash University Act 1958
    Inventor: John Bernard Watkins
  • Patent number: 6495074
    Abstract: A method of maintaining as well as restoring the condition of weathered asphalt shingles and strips which are applied to flat roofs, pitched roofs, or vertical walls. The process involves applying resaturant neat or as a water emulsion. Suitable resaturants include fatty acid methyl esters, petroleum distillates, and water emulsions thereof. The process restores the suppleness and softness of the weathered shingles or strip and adds about three years to the lifetime of the roof. The process may be repeated for additional lifetime extension.
    Type: Grant
    Filed: May 2, 2000
    Date of Patent: December 17, 2002
    Assignee: Clipper Roof Coatings, Inc.
    Inventor: Charles W. Carr
  • Patent number: 6494944
    Abstract: A method of emulsifying asphalt using a polyamine polyoxide, preferably a diamine dioxide, as an emulsifier or co-emulsifier and an emulsion of asphalt, water and a polyamine polyoxide, preferably a diamine dioxide. The advantages of using a polyamine polyoxide as an emulsifier or co-emulsifier include its ability to provide superior cationic and anionic emulsions, and slow-setting emulsions at low use levels, and the excellent adhesion of the cured asphalt film.
    Type: Grant
    Filed: March 2, 2000
    Date of Patent: December 17, 2002
    Assignee: Akzo Nobel N.V.
    Inventors: Julia Mary Wates, Bengt-Arne Thorstensson, Alan James
  • Publication number: 20020129737
    Abstract: Aqueous bitumen emulsion intended for producing cold bituminous mixes and comprising at least one ionic-type surfactant and a continuous aqueous phase with a buffered pH, the pH value of the continuous phase being such that the ionic surfactant is present in its ionized form within the said emulsion.
    Type: Application
    Filed: January 15, 2002
    Publication date: September 19, 2002
    Inventor: Christine Deneuvillers
  • Patent number: 6451885
    Abstract: The invention concerns an aqueous bitumen emulsion, consisting of the following constituents expressed in weight percentages of the emulsion total weight: 50% to 70% of bitumen; 0.5% to 10% of surfactant; 0% to 5% of thickening agent; 0% to 1% of antifoaming agent; a sufficient quantity of water to make up 100%. Said emulsion is characterised in that the surfactant consists of at least a surfactant selected among the group consisting of an ethylene oxide and a propylene oxide copolymer, with PO/EO ratio ranging between 1.5 and 10, an ethoxylated and/or propoxylated epoxidized surfactant, and a polyvinyl alcohol having molecular mass ranging between 10000 and 150000. The invention also concerns the method for obtaining said emulsions, the compositions containing them, and the use of said bitumen emulsions for the formulation of compositions comprising a hydraulic or organic binder, and/or a mineral or organic filler.
    Type: Grant
    Filed: May 7, 2001
    Date of Patent: September 17, 2002
    Assignee: Lafarge
    Inventors: Jean-Marc Dresin, Nadège Picard, Brice Siaud, Claude Stock
  • Patent number: 6403659
    Abstract: An asphalt based sealer for driveways and the like is disclosed. The material uses a blend of solvent deasphalted (SDA) asphalt blended with a cutter stock as the binder or sealer base. Driveway sealer (an emulsion of clay, water and binder) made with this binder has acceptable durability and can be essentially free of coal tar pitch, greatly reducing the toxicity and odor of the sealer.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: June 11, 2002
    Assignee: Marathon Ashland Petroleum LLC
    Inventors: D. Chris Boyer, Patricia K. Doolin
  • Patent number: 6384091
    Abstract: A process for preparing a hydrocarbon in water emulsion includes the steps of providing a hydrocarbon phase containing inactive natural surfactant; mixing a solid carbon additive with the hydrocarbon phase, the solid additive being selected from the group consisting of coal, coke and mixtures thereof so as to provide a hydrocarbon suspension including the solid carbon additive; and forming an emulsion from the hydrocarbon suspension and an aqueous phase in the presence of a surfactant activating additive so as to activate the inactive natural surfactant and form a hydrocarbon in water emulsion having the solid carbon additive suspended in the hydrocarbon phase. A hydrocarbon in water emulsion is also provided including a hydrocarbon phase, a water phase, a surfactant, and a solid carbon additive suspended in the hydrocarbon phase, the solid carbon additive being selected from the group consisting of coal, coke and mixtures thereof.
    Type: Grant
    Filed: July 23, 1999
    Date of Patent: May 7, 2002
    Assignee: Intevep, S.A.
    Inventors: Ignacio A. Layrisse, Nilia Romero, Gustavo A. Nunez
  • Patent number: 6384112
    Abstract: A bitumen emulsion comprising bituminous binder, emulsifier, and water. The bituminous binder comprises bitumen and an oxidised wax, and optionally one or more polymers. The incorporation of the oxidised wax into the bituminous binder provides modified bitumen with both a high softening point and a low enough viscosity to allow it to be emulsified. The emulsion may be used as a tack coat in applying a waterproofing layer to a roof base. The emulsion may be made using a static mixing emulsion process.
    Type: Grant
    Filed: May 8, 2000
    Date of Patent: May 7, 2002
    Assignee: ExxonMobil Research and Engineering Company
    Inventor: Nadjib Boussad
  • Publication number: 20020038615
    Abstract: The invention is in a composition which is useful to dampen noise and vibrations which in composition can be applied to and adhered to a substrate. The composition comprises an emulsion or dispersion of asphalt in water and fillers. Preferably the fillers are alkaline earth metal or alkaline metal carbonates, or sulfates. In another embodiment, the invention is a process for applying a damping composition to a substrate which comprises contacting a composition of an emulsion of asphalt in water and a filler with a substrate. Preferably the asphalt emulsion on the surface of the substrate is exposed to a source of heat so as to dry the composition on the substrate. In a preferred embodiment the substrate is a surface in an automobile such as the floor-board, trunk well, wheel well, rocker panel or underbody.
    Type: Application
    Filed: June 13, 2001
    Publication date: April 4, 2002
    Inventors: Hong Xiao, Daniel P. Sophiea, John M. Dumas, Horace R. Gore
  • Patent number: 6361591
    Abstract: A better asphalt based sealer for driveways and the like is disclosed. The material uses as a hybrid sealer base or binder comprising a blend of pitch, asphaltic material and cut-back oil as a partial or complete replacement for pure coal tar materials. Driveway sealer (an emulsion of clay, water and binder) made with this hybrid binder has significantly better durability and color than like materials made with a binder of asphalt and cut-back oil. The hybrid binder has less odor and fewer toxins than a binder made of pure coal tar material.
    Type: Grant
    Filed: December 20, 1999
    Date of Patent: March 26, 2002
    Assignee: Marathon Ashland Petroleum LLC
    Inventors: D. Chris Boyer, Patricia K. Doolin
  • Patent number: 6309456
    Abstract: A three component multi-color asphalt emulsion coating is provided in which a water-based carrier, an emulsified asphalt base and at least one globular color components are mixed together. The color components are prevented from mixing with the emulsified asphalt base by relative viscosity and colloidal strength of the color components. The resultant product has enhanced wear characteristics, and is easier and less expensive to apply than traditional roofing such as asphalt shingles. A process for forming the multi-color asphalt emulsion coating is provided wherein the water-based carrier, the emulsified asphalt base, and the globular color components are formed separately prior to first mixing the emulsified asphalt base with the water-based carrier and then blending as many prepared globular color components as desired.
    Type: Grant
    Filed: February 25, 2000
    Date of Patent: October 30, 2001
    Assignee: The Brewer Company
    Inventor: Brian James Anthony
  • Patent number: 6267809
    Abstract: A low softening point pitch is disclosed. A high melting point (100° C.+) pitch is blended with an aromatic rich liquid hydrocarbon stream to form a pourable pitch mixture having a softening point of 30-50° C. which can be used as a partial or complete replacement for coal tar pitch used in driveway sealer and other sealer and coating applications. Driveway sealer (an emulsion of clay, water and binder) made with this pitch has enhanced durability. The low softening point pitch, even when blended with coal tar pitch, is phase stable on storage.
    Type: Grant
    Filed: November 16, 1999
    Date of Patent: July 31, 2001
    Assignee: Marathon Ashland Petroleum LLC
    Inventors: D. Chris Boyer, Patricia K. Doolin
  • Patent number: 6245850
    Abstract: A reflective asphalt emulsion is formed by dispersing asphalt into a slurry of colloidal clay at high shear and thereafter blending titanium dioxide and diatomaceous earth filler, and optionally acrylic latex, at low shear into the emulsion of clay and asphalt to form a white to light gray emulsion having a soft consistency and good shelf life. Particle sizes of the employed asphalt are controlled in order to preserve reflectivity of the finished emulsion.
    Type: Grant
    Filed: April 2, 1998
    Date of Patent: June 12, 2001
    Inventor: John R. Fields
  • Patent number: 6197837
    Abstract: A process for the preparation of an aqueous tar suspoemulsion includes the steps of mixing a mixture including (a) a viscous tar composition formed from a tar, from inorganic solids and, optionally, from water; (b) water (W); (c) a surface-active agent (SA) exhibiting a hydrophilicity/lipophilicity balance (HLB) of at least 10; and, optionally, (d) a thickening water-soluble polymer (TWP) with a molecular mass of greater than 10,000. The relative amounts of constituents (W), (SA) and, optionally, (TWP) are such that the viscosity of the (W)+(SA)+optional (TWP) mixture is preferably equal to or greater than the viscosity of the tar. An optional embodiment of the process provides for dilution of the mixture obtained with water or with an aqueous acidic solution.
    Type: Grant
    Filed: March 5, 1999
    Date of Patent: March 6, 2001
    Assignee: Rhodia Inc.
    Inventors: Philip Dean Hill, Thomas Edwin Pruitt, Forrest Lee Sanders, Gilles Guerin, Bruno Langlois
  • Patent number: 6193793
    Abstract: Asphaltic concrete compounds comprised of asphalt cement and aggregate have, as a substantial portion of their respective aggregates, anthracite coal particles and fines, which are added specially as a lossy microwave material. These asphaltic concrete compounds are particularly useful when laid down as a pavement, or a top layer of a pavement, which thereafter can be freed of ice, by using microwave energy to debond the ice. The debonding of the ice occurs without causing any noticeable melting of the ice, and the debonded ice is thereafter easily lifted and removed from the pavement of the way, serving as a roadway, highway, runway, or walkway. Also these asphaltic concrete compounds are particularly useful as patching materials when damaged pavement is being repaired, especially during cold weather.
    Type: Grant
    Filed: June 5, 1995
    Date of Patent: February 27, 2001
    Inventor: Howard W. Long
  • Patent number: 6194472
    Abstract: A composition of a hydrocarbon in water colloidal dispersion including hydrocarbon particles having a mean softening point exceeding 95° C., a water soluble dispersion agent and water, process and apparatus for the production thereof are disclosed. These dispersions have a median particle size below about 4.5 microns and 90% of the hydrocarbon particles have a size less than about 60 microns. These dispersions are storage stable, stable towards transportation, and can be pumped without destabilizing.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: February 27, 2001
    Assignee: Akzo Nobel N.V.
    Inventors: Sundaram Logaraj, Thomas J. Ernzen, Moon-Sun Lin, Antonio C. Ng, Todd Lesley Hays, Calvin Lynn Stegemoeller, Li Feng, Mark Aldrich Stroder
  • Patent number: 6162453
    Abstract: A stable monophasic liquid composition characterized by the ability to solubilize increased amounts of surfactant into the composition while retaining a monophasic state, the composition comprising: one or more surfactants selected from the group consisting of cationic surfactants, anionic surfactants, amphoteric surfactants, nonionic surfactants, and mixtures thereof; a hydrophobic material; and one or more coupling agents selected from the group consisting of straight, branched and cyclic alkanes containing 7 to 12 carbon atoms and substituted with two hydroxyl groups, and alkoxylates thereof containing up to 20 alkoxy units each of which is ethoxy, propoxy, or butoxy, and mixtures thereof, in an amount of the one or more coupling agents effective to increase the amount of the one or more surfactants that can be solubilized in the monophasic composition.
    Type: Grant
    Filed: September 3, 1999
    Date of Patent: December 19, 2000
    Assignee: Witco Corporation
    Inventor: Robert O. Keys
  • Patent number: 6156828
    Abstract: A gel-like emulsion containing natural rubber and crumb rubber from used vehicle tires which may be added to an asphalt paving emulsion at ambient temperature for chip coating, slurry sealing, microsurfacing, soil stabilization or pavement recycling.
    Type: Grant
    Filed: October 26, 1998
    Date of Patent: December 5, 2000
    Inventor: Steve R. Wickett
  • Patent number: 6149351
    Abstract: Methods are disclosed for preparation of chemically-stabilized emulsions of tall oil in water. Temperature and pH are controlled during preparation of the emulsions so as to prevent saponification and neutralization of acids in the tall oil component. The final emulsions have pHs in the range of from about 3.0 to 5.0 and remain phase stable for extended periods of time. Methods are disclosed for using the emulsions for soil treatment to improve soil stabilization and load bearing capacity for roadbed use, for treatment of reclaimed asphalt pavement for reuse as a stabilized base course for roadway construction and for remediation of heavy metal contaminated soil.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: November 21, 2000
    Assignee: Vinzoyl Technical Services, L.L.C.
    Inventor: Michael P. Doyle
  • Patent number: 6136082
    Abstract: Coating is carried out with the aid of an emulsion which consists of the mixture of a fast-breaking emulsion and a slow-breaking emulsion. It is advantageous to take a soft bitumen emulsion as fast emulsion and a hard bitumen emulsion as slow emulsion.
    Type: Grant
    Filed: August 7, 1998
    Date of Patent: October 24, 2000
    Assignee: CECA S.A.
    Inventors: Gilles Barreto, Lionel Grampre, Luc Navascues
  • Patent number: 6114418
    Abstract: The present invention provides an oil-in-water asphalt emulsion having excellent stability in a stationary state. That is, the present invention provides a method for emulsifying an asphalt in water, which comprises the step of mixing the asphalt and water with an emulsifier comprising a nonionic compound (1) having the formula (1):R--O--(C.sub.2 H.sub.4 O).sub.x --(CH(CH.sub.3)--CH.sub.2 --O).sub.y --(C.sub.2 H.sub.4 O).sub.z --H (1)in which R is an alkyl or an alkenyl, having 8 to 22 carbon atoms, being either straight or branched; x is a number of 0 to 40; y is a number of 1 to 10; and z is a number of 1 to 80.
    Type: Grant
    Filed: October 16, 1998
    Date of Patent: September 5, 2000
    Assignee: Kao Corporation
    Inventors: Kazuo Isobe, Ryoichi Tamaki
  • Patent number: 6113659
    Abstract: A fuel composition comprising a hydrocarbon in water colloidal dispersion including spherical hydrocarbon particles having a mean softening point exceeding about 95.degree. C., and a water soluble dispersion agent comprising a surfactant and stabilizer. The process for the production thereof is disclosed. These dispersions have a median particle size below about 4.5 microns and about 90% of the particles have a mean particle size diameter less than about 60 microns. These dispersions are storage stable, stable towards transportation, and can be pumped and passed through a burner apparatus without destabilizing.
    Type: Grant
    Filed: February 3, 1999
    Date of Patent: September 5, 2000
    Assignee: Akzo Nobel nv
    Inventors: Sundaram Logaraj, Thomas J. Ernzen, Antonio Chan Ng, Mark Aldrich Stroder, Stephen J. DeCanio, Ronald J. McKeon, Shailaja M. Shirodkar
  • Patent number: 6106604
    Abstract: Bitumen emulsion including bituminous phase having one of pure bitumen, fluxed bitumen, and modified bitumen. The bitumen emulsion also includes an aqueous phase including water and an emulsifying agent. The bitumen emulsion further includes a breaking agent encapsulated in capsules allowing control of breaking of the bitumen emulsion, the control involving rupture of the capsules from a mechanical effect by a mechanical action produced on the bitumen emulsion. Processes of producing a bitumen emulsion. Processes of controlling breaking of a bituminous emulsion.
    Type: Grant
    Filed: March 9, 1998
    Date of Patent: August 22, 2000
    Assignee: Colas
    Inventors: Graziella Durand, Jean-Eric Poirier, Michel Chappat
  • Patent number: 6103000
    Abstract: The invention relates to an improved surfactant mixture which permits use of lower concentrations of polyphenolics including natural vegetable polyphenolic extracts and/or synthetic phenolic resins to produce stable anionic slow-setting asphalt-in-water emulsion compositions suitable for use as pavement sealers and coatings. The polyphenolics are selected from natural vegetable polyphenolic extracts including Chestnut A, Chestnut N and Sumac-K10; or from synthetic phenolic resins including phenol-formaldehyde, resorcinol-formaldehyde and novolak resins; or mixtures thereof; in amounts of about 0.1% to 10% polyphenolics in the final emulsion, to form and stabilize the emulsion. The emulsions employ a surfactant mixture comprising a nonionic surfactant with a hydrophilic/lipophilic balance index of from about 16 to about 20, and an anionic lignin sulfonate, in amounts of about 0.1% to 3.0% surfactant mixture in the final emulsion. Optionally 0.02% to 2.00% w/w of sodium borate decahydrate may be included.
    Type: Grant
    Filed: December 31, 1997
    Date of Patent: August 15, 2000
    Assignee: Saramco, Inc.
    Inventor: Robert S. Custer
  • Patent number: 6077340
    Abstract: Methods are disclosed for preparation of chemically-stabilized emulsions of tall oil in water. Temperature and pH are controlled during preparation of the emulsions so as to prevent saponification and neutralization of acids in the tall oil component. The final emulsions have pHs in the range of from about 3.0 to 5.0 and remain phase stable for extended periods of time. Methods are disclosed for using the emulsions for soil treatment to improve soil stabilization and load bearing capacity for roadbed use, for treatment of reclaimed asphalt pavement for reuse as a stabilized base course for roadway construction and for remediation of heavy metal contaminated soil.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: June 20, 2000
    Inventor: Michael P. Doyle
  • Patent number: 6077888
    Abstract: This invention relates to improved bituminous emulsions, specifically to cationic medium-set and slow-set mixing grade emulsions. More particularly, it relates to emulsifying compositions which can be used to produce bituminous emulsions exhibiting high viscosity and low asphalt residues. The emulsifying compositions are combinations of fatty amine and/or polyamine, lignin, and nonionic surfactant. A preferred emulsifying composition can be produced by reacting the combinations of fatty amine and/or polyamine, lignin, and nonionic surfactant with formaldehyde.
    Type: Grant
    Filed: January 14, 1999
    Date of Patent: June 20, 2000
    Assignee: Westvaco Corporation
    Inventor: Peter Schilling
  • Patent number: 6069178
    Abstract: A process for preparing a hydrocarbon in water emulsion includes the steps of providing a hydrocarbon phase containing inactive natural surfactant; mixing a solid carbon additive with the hydrocarbon phase, the solid additive being selected from the group consisting of coal, coke and mixtures thereof so as to provide a hydrocarbon suspension including the solid carbon additive; and forming an emulsion from the hydrocarbon suspension and an aqueous phase in the presence of a surfactant activating additive so as to activate the inactive natural surfactant and form a hydrocarbon in water emulsion having the solid carbon additive suspended in the hydrocarbon phase. A hydrocarbon in water emulsion is also provided including a hydrocarbon phase, a water phase, a surfactant, and a solid carbon additive suspended in the hydrocarbon phase, the solid carbon additive being selected from the group consisting of coal, coke and mixtures thereof.
    Type: Grant
    Filed: April 9, 1998
    Date of Patent: May 30, 2000
    Assignee: Intevep, S.A.
    Inventors: Ignacio A. Layrisse, Nilia C Romero, Gustavo A. Nunez
  • Patent number: 6065903
    Abstract: Methods are disclosed for preparation of chemically-stabilized emulsions of tall oil in water. Temperature and pH are controlled during preparation of the emulsions so as to prevent saponification and neutralization of acids in the tall oil component. The final emulsions have pHs in the range of from about 3.0 to 5.0 and remain phase stable for extended periods of time. Methods are disclosed for using the emulsions for soil treatment to improve soil stabilization and load bearing capacity for roadbed use, for treatment of reclaimed asphalt pavement for reuse as a stabilized base course for roadway construction and for remediation of heavy metal contaminated soil.
    Type: Grant
    Filed: December 22, 1998
    Date of Patent: May 23, 2000
    Assignee: Vinzoyl Technical Services, L.L.C.
    Inventor: Michael P. Doyle
  • Patent number: 6048905
    Abstract: The present invention provides a liquid amine composition for an emulsifier for bitumen which can impart, to a bituminous emulsion, more excellent emulsifying stability and adhesive properties to aggregates than conventional products. The liquid amine composition for the emulsifier for bitumen of the present invention comprises (1) 5 to 70% by weight a monoamine having an aliphatic hydrocarbyl group of 8 to 22 carbon atoms, (2) 20 to 80% by weight of a polyamine having an aliphatic hydrocarbyl group of 8 to 22 carbon atoms, and (3) 10 to 75% by weight of an organic acid of 4 to 18 carbon atoms.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: April 11, 2000
    Assignee: Kao Corporation
    Inventors: Katsuhiko Asamori, Shigeru Nagao, Ryoichi Tamaki, Takao Taniguchi, Keiichiro Tomioka, Kouji Koyanagi
  • Patent number: 6019830
    Abstract: Aqueous colloidal dispersion driveway sealer compositions especially adapted for cold application are made available through the controlled utilization of fly ash.
    Type: Grant
    Filed: February 18, 1997
    Date of Patent: February 1, 2000
    Assignee: Gardner Asphalt Corporation
    Inventors: Michael L. Yap, Raymond T. Hyer, Barton J. Malina
  • Patent number: 6013681
    Abstract: A liquid amine compound which can be applied to various uses such as emulsification for bitumens since it has as high surface activity as those of solid amines and is more excellent in workability as compared with the solid amines, and an emulsifier for bitumens produced by using the amine compound. Furthermore, a process for producing an emulsifier a bituminous emulsion by reacting an aliphatic amine having at least one hydrocarbon group having not less than 8 carbon atoms with a carbonyl compound and adding an acid thereto to adjust the pH of the amine compound so as to be not more than 5, and a process for producing a bituminous emulsion composition by using the amine compound.
    Type: Grant
    Filed: February 17, 1998
    Date of Patent: January 11, 2000
    Assignee: Kao Corporation
    Inventors: Katsuhiko Asamori, Ryoichi Tamaki, Hitoshi Funada, Takao Taniguchi, Francisco Castaneda Juarez, Cesar Alvarez Ortiz, Alvaro Gutierrez Muniz, Humberto Ramirez Hernandez
  • Patent number: 5981632
    Abstract: Product and method for making an asphaltic emulsion enjoying the weather-resistant and durability advantages of a fully-oxidized asphaltic base. Preferred compositions according to the invention comprise a fully-oxidized asphalt having a softening point of between about 110.degree. F. and about 160.degree. F. and a slurry, the slurry comprising water, a colloidal clay (preferably bentonite clay), barium chloride, and citric acid. Optionally sodium dichromate, fillers such as cellulose fibers, and biocidal agents are added as well. The method for making such asphalts comprises oxidation of a flux asphalt in an air still, preparation of the slurry, and combination of the oxidized asphalt and the slurry in a high speed mixing machine such as a colloidal mill.
    Type: Grant
    Filed: October 7, 1998
    Date of Patent: November 9, 1999
    Inventor: John R. Fields
  • Patent number: 5968245
    Abstract: Solid waste contaminated with cationic metals is remediated with a composition that reduces the mobility of the metals. A recycled product is formed having improved structural properties for possible use as engineered fill such as road base material. Said composition comprising an emulsion of asphalt or tall oil pitch in water and a chemical fixing agent.
    Type: Grant
    Filed: November 19, 1997
    Date of Patent: October 19, 1999
    Assignee: Encapco
    Inventors: William M. Jones, Michael P. Doyle, Bruce W. Page
  • Patent number: 5928418
    Abstract: An asphalt emulsion comprising water, asphalt, (A) an emulsifier selected from the group consisting of specific aliphatic amines, aminated lignins, imidazolines having a hydrocarbon group having 7 or more carbon atoms, and amidobetaines having a hydrocarbon group having 7 or more carbon atoms, (B) a polyphenolic compound, and (C) at least one member selected from the group consisting of anionic polumeric dispersants, hydroxycarboxylic acids and/or (D) at least one member selected from the group consisting of saccharides, sugar alcohols and polyhydric alcohols, which is excellent in storage stanility, mixability with aggregate and low foaming properties of the emulsion itself, in adherence of the products of breaking thereof to aggregate, and in stripping resistance of the construction executed by the use of the emulsion.
    Type: Grant
    Filed: August 4, 1997
    Date of Patent: July 27, 1999
    Assignee: Kao Corporation
    Inventors: Ryoichi Tamaki, Katsuhiko Asamori, Hirotaka Sasaki, Hitoshi Funada, Takao Taniguchi
  • Patent number: 5919573
    Abstract: A process for the bituminous coating of any supports by providing a cold coating of the supports by bituminous emulsions, comprising first obtaining a hydrophobic powder of positive electric charge by the conjoint action of a metallic salt soluble in water and a long chain organic acid, then introducing this powder, either into a mass of the supports to be coated, or into a bituminous anionic emulsion and then mixing the supports and bituminous emulsion in a mixer so as to effect cold coating. An anionic emulsion is mixed with a hydrophobic powder of positive electric charge so as to confer on the emulsion a cationic behavior and coating and covering properties.
    Type: Grant
    Filed: September 2, 1997
    Date of Patent: July 6, 1999
    Inventors: Emile Jacques Muntzer, Paul Emile Muntzer, Jean Muntzer, Isabelle Muntzer
  • Patent number: 5895347
    Abstract: Methods are disclosed for preparation of chemically-stabilized emulsions of tall oil in water. Temperature and pH are controlled during preparation of the emulsions so as to prevent saponification and neutralization of acids in the tall oil component. The final emulsions have pHs in the range of from about 3.0 to 5.0 and remain phase stable for extended periods of time. Methods are disclosed for using the emulsions for soil treatment to improve soil stabilization and load bearing capacity for roadbed use, for treatment of reclaimed asphalt pavement for reuse as a stabilized base course for roadway construction and for remediation of heavy metal contaminated soil.
    Type: Grant
    Filed: March 17, 1997
    Date of Patent: April 20, 1999
    Assignee: Vinzoyl Technical Services, L.L.C.
    Inventor: Michael P. Doyle
  • Patent number: 5851430
    Abstract: An HIPR emulsion of bitumen in water is prepared by a method which comprises directly mixing 70 to 98% by volume of bitumen having a viscosity in the range 200 to 500,000 mPa.s at the mixing temperature with 30 to 2% by volume of an aqueous solution of an emulsifying surfactant, percentages being expressed as percentages by volume of the total mixture. Mixing is effected under low shear conditions in the range 10 to 1,000 reciprocal seconds in such manner that an emulsion is formed comprising highly distorted bitumen droplets having mean droplet diameters in the range 2 to 50 micron separated by thin films of water.The emulsions can be cut back to provide stable emulsions of lower bitumen content which are useful in roadmaking and the formation of protective coatings.
    Type: Grant
    Filed: April 18, 1997
    Date of Patent: December 22, 1998
    Assignee: Intevep, S.A.
    Inventors: Maria Luisa Chirinos, Alistair Stewart Taylor, Spencer Edwin Taylor
  • Patent number: 5827360
    Abstract: The invention relates to a method and equipment for producing foam bitumen. Water is mixed to hot bitumen under a pressure which is lower than the prevailing absolute pressure, and after this the pressure is allowed to rise and the flow rate to drop. The mixing of water and bitumen occurs in a foaming reactor (17), which is connected via a pipeline (6, 8, 9, 10) to a spray bar (1), which also acts as a heat exchanger, and the changes in the flow caused by an inclination in the spray bar are compensated by means of pipes (6) and valves (7). The entire equipment is thermally insulated, and a part of it may be provided with electric heating to prevent the bitumen from solidifying. It is possible to circulate hot bitumen in the equipment by opening a valve (12), whereby the entire equipment is brought to an operating temperature.
    Type: Grant
    Filed: October 22, 1997
    Date of Patent: October 27, 1998
    Assignee: CMI Corporation
    Inventor: Nestor Mikael Salminen
  • Patent number: 5788756
    Abstract: Film-forming bitumen-in-water mixed emulsions comprising intimate immixture of (i) an oil-in-water emulsion of a hard bituminous material and (ii) an oil-in-water emulsion of a soft bituminous material, are well suited for the production of storage-stable coated particulates, notably cold dense building and paving materials such as aggregate and gravel, useful for the construction of, e.g., road and highway surfaces via compaction thereof.
    Type: Grant
    Filed: August 28, 1995
    Date of Patent: August 4, 1998
    Assignee: CECA S.A.
    Inventors: Pascal Cheneviere, Jean-Claude Fabre, Luc Navascues
  • Patent number: 5776606
    Abstract: Insulating and anticorrosive composition for electrical devices consisting of two semifluid components that are mixed together at the time of application, whereinA) the first component includesfrom 20 to 35 parts (w/w) of a bitumen having a softening point of at least 90.degree. C.,from 1.5 to 7 parts (w/w) of a hydrocarbon resin,from 0.5 to 5 parts (w/w) of an alkylbenzene,from 35 to 60 parts (w/w) of resin oil, andfrom 10 to 30 parts (w/w) of olein,B) the second component includesfrom 40 to 60 parts (w/w) of a mixture of partially hydrogenated terphenyls and quaterphenyls,from 0.5 to 5 parts (w/w) of a styrene/butadiene block copolymer,from 5 to 30 parts (w/w) of calcium oxide, andfrom 10 to 50 parts (w/w) of calcium hydroxide.
    Type: Grant
    Filed: April 4, 1996
    Date of Patent: July 7, 1998
    Assignee: Pirelli Cavi S.p.A.
    Inventors: Emilio Locatelli, Claudio Bosisio
  • Patent number: 5776234
    Abstract: This invention relates to rapid set, medium set, and slow set anionic emulsions prepared from straight bitumen or bitumen modified by the incorporation of polymers such as styrene butadiene rubbers (SBR), styrene block copolymers (SBS), ethylene vinyl acetate copolymers (EVA), and other suitable modifiers. The invention also relates to emulsions modified by the incorporation of solvents (such as diesel oil or kerosene) or by the addition of polymer latices (such as SBR-latex or natural rubber latex). More particularly, the invention relates to improved methods for enhancing adhesion between asphalt and aggregate in anionic solventless and solvent-containing bituminous emulsions wherein the emulsifiers are alkali earth salts of tall oil fatty acids, fortified tall oil fatty acids, tall oil rosin, and fortified rosin as well as combinations of kraft lignin and nonionic emulsifiers.
    Type: Grant
    Filed: August 12, 1996
    Date of Patent: July 7, 1998
    Assignee: Westvaco Corporation
    Inventor: Peter Schilling
  • Patent number: 5772749
    Abstract: This invention relates to rapid set, medium set, and slow set anionic emulsions prepared from straight bitumen or bitumen modified by the incorporation of polymers such as styrene butadiene rubbers (SBR), styrene block copolymers (SBS), ethylene vinyl acetate copolymers (EVA), and other suitable modifiers. The invention also relates to emulsions modified by the incorporation of solvents (such as diesel oil or kerosene) or by the addition of polymer latices (such as SBR-latex or natural rubber latex). More particularly, the invention relates to improved methods for enhancing adhesion between asphalt and aggregate in anionic solventless and solvent-containing bituminous emulsions wherein the emulsifiers are alkali earth salts of tall oil fatty acids, fortified tall oil fatty acids, tall oil rosins, and fortified rosins as well as combinations of kraft lignins and nonionic emulsifiers.
    Type: Grant
    Filed: September 15, 1997
    Date of Patent: June 30, 1998
    Assignee: Westvaco Corporation
    Inventors: Peter Schilling, Everett Crews
  • Patent number: 5769567
    Abstract: A process and a machine for forming a bonding layer for bonding a bituminous coated material layer on a support. The process includes application of a surface-active agent on the support, application of a bituminous emulsion on the surface-active agent on the support, and application of a breaking agent on the bituminous emulsion to form the bonding layer. A road-type coating made by the process and, therefore, including such a support layer, a bonding layer on the support, and a bituminous coated materials layer on the bonding layer. To perform the process, a machine includes a frame, a displacement mechanism on the frame, a bituminous-emulsion spreader on the frame, a surface-active agent applicator on the frame, and a breaking agent applicator on the frame.
    Type: Grant
    Filed: March 27, 1996
    Date of Patent: June 23, 1998
    Assignee: Colas
    Inventors: Graziella Durand, Pierre Montmory
  • Patent number: 5743950
    Abstract: The present invention provides a process for preparing a dense-graded asphalt composition which comprises adding a hard binder component to a mixture of a soft binder component and aggregate at a temperature of less than 140.degree. C.
    Type: Grant
    Filed: November 25, 1996
    Date of Patent: April 28, 1998
    Assignee: Shell Oil Company
    Inventors: Henricus Engelbertus Johannes Hendriks, Dirk Adriaan Stoker
  • Patent number: 5713996
    Abstract: A coating composition useful for coating a surface, such as a pipe surface, includes a water-based emulsion containing an asphalt having a penetration value of no greater than about 10 dmm at 25.degree. C., a latex, at least one thickener and a surface active wetting agent.
    Type: Grant
    Filed: January 20, 1997
    Date of Patent: February 3, 1998
    Assignee: Kimberton Enterprises, Inc.
    Inventors: Paul A. Morris, Ronald H. Vega, Wesley A. Schmidt
  • Patent number: 5711796
    Abstract: Bituminous compositions of enhanced physical/performance properties comprising an oxidation product of a naturally occurring asphalt from the Orinoco Belt of Venezuela and the bitumen base material, and methods for their preparation.
    Type: Grant
    Filed: October 16, 1995
    Date of Patent: January 27, 1998
    Assignee: Air Products and Chemicals, Inc.
    Inventors: Kenneth Francis Grzybowski, David Reese Jones, IV, William Russell Welliver, Timothy Jay Roth