Aluminum Compound Or Silicon Containing Patents (Class 106/442)
  • Patent number: 7682441
    Abstract: The invention relates to a weather resistant titanium dioxide pigment with good optical properties having a SiO2 dense skin doped with metal atoms. Particularly suitable elements for doping are tin, zirconium and titanium. The SiO2 dense skin is composed of multiple layers whereby the innermost layer does not contain any significant quantity of metal atoms. The coating according to the invention is produced by adding the components to the alkaline suspension (pH at least 9) one after the other with a sliding pH. Complete formation of the doped SiO2 dense skin requires that the pH subsequently be lowered to below 9. The pigment is particularly suitable for use in surface coatings and plastics.
    Type: Grant
    Filed: June 21, 2005
    Date of Patent: March 23, 2010
    Assignee: Kronos International, Inc.
    Inventors: Lydia Drews-Nicolai, Siegfried Bluemel
  • Publication number: 20090301350
    Abstract: Use of pyrogenic metal oxide for the manufacture of a selfcompacting composition comprising hydraulic binders and having high early strength, the composition comprising at least one hydraulic binder and water as further constituents and the product of the BET surface area, in m2/g, of the pyrogenic metal oxide and the proportion by weight of the pyrogenic metal oxide based on the hydraulic binder being 20 to 200 m2/100 g of hydraulic binder.
    Type: Application
    Filed: March 12, 2007
    Publication date: December 10, 2009
    Applicant: Evonik Degussa Gmbh
    Inventors: Christoph Tontrup, Reinhard Trettin, Michael Geyer
  • Publication number: 20090297852
    Abstract: A method for coating the surface of inorganic solid particles in an aqueous suspension, particularly for coating titanium dioxide with SiO2 includes: a) disagglomeration of the solid particles contained in aqueous suspension, b) addition of a water-soluble precursor of the coating substance to the suspension, c) immediately following step b) homogenization of the suspension, where the temperature and pH value of the suspension do not change significantly in steps a) to c), d) feeding the slurry into a tank and precipitation of the coating substance onto the particle surface and, optionally, application of further coatings, and e) separation of the solid particles from the suspension. The method produces to a highly homogeneous and continuous skin on the particle surface, and to less separately precipitated coating substance.
    Type: Application
    Filed: May 27, 2009
    Publication date: December 3, 2009
    Inventors: Heiko Frahm, Joerg Friedrich, Mark Kaminski, Erwin Schmeier, Lydia Drews-Nicolai, Volker Juergens
  • Publication number: 20090275686
    Abstract: A pigment, the production and use thereof, furthermore a polymeric material delustered with pigments, processes for producing this polymeric material, and the use thereof.
    Type: Application
    Filed: June 11, 2007
    Publication date: November 5, 2009
    Inventors: Jurgen Kastner, Hartmut Wagner, Bernard Becker
  • Publication number: 20090258251
    Abstract: This invention relates to a pearlescent pigment, which is composed of flaky alumina substrate particles produced by a hydrothermal process and coat layers formed on the flaky substrate particles and composed of at least one metal oxide including at least a titanium oxide. The metal oxide has an average particle size of from 1 to 500 nm. According to this invention, it is possible to provide a pearlescent pigment, which has wholly uniform photoluminescence and an elegant and silky feel in combination and can fully satisfy artistry as desired.
    Type: Application
    Filed: October 2, 2006
    Publication date: October 15, 2009
    Applicant: DAINICHISEIKA COLOR & CHEMICALS MFG. CO., LTD.
    Inventors: Takashi Abe, Satoru Matsuzaki, Shotoku Takami
  • Patent number: 7578878
    Abstract: A pigment grade corrosion inhibitor and a method of applying the inhibitor is disclosed. The inhibitor is comprised of a host species comprised of an inorganic compound having a layered structure and a guest species comprised an anionic species of a weak acid. The host species is preferably a double hydroxide having a structure of: [M(II)1?xM(III)x(OH?)2][An?x/n.yH2O], where M(II) is a divalent metal cationic species, M(III) is a trivalent metal cationic species, and An? is an anionic species, preferably with the species present in a range of: 0.2?M(III)/(M(II)+M(III))?0.4.
    Type: Grant
    Filed: June 25, 2004
    Date of Patent: August 25, 2009
    Assignee: Wayne Pigment Corp.
    Inventors: John Sinko, Martin W. Kendig
  • Publication number: 20090126604
    Abstract: A flame spray pyrolysis process for the preparation of ultrafine titania particles coated with a smooth, homogeneous coating of one or more metal oxides is provided. The metal oxide coating is achieved by contacting the titania particles with a metal oxide precursor downstream of the titania formation zone, after the titania particles have formed. The process provides titania particles with a high rutile content and a smooth and homogeneous coating of a metal oxide.
    Type: Application
    Filed: November 16, 2007
    Publication date: May 21, 2009
    Inventors: M. Kamal Akhtar, Sotiris Emmanuel Pratsinis, Martin Christian Heine, Alexandra Teleki Harsanyi, Reto Strobel
  • Patent number: 7517404
    Abstract: The present invention relates to pigments, the particles of which generally have a length of from 2 ?m to 5 mm, a width of from 2 ?m to 2 mm, and a thickness of from 20 nm to 2 ?m, and a ratio of length to thickness of at least 2:1, wherein the particles contain a core of SiOy with 0.70?y?1.8, especially 1.40?y?1.8, having two substantially parallel faces, the distance between which is the shortest axis of the core, comprising (a) a material, especially a metal oxide, having a high index of refraction; or (a) a thin semi-transparent metal layer; a process for their production and their use in paints, ink-jet printing, for dyeing textiles, for pigmenting coatings (paints), printing inks, plastics, cosmetics, glazes for ceramics and glass.
    Type: Grant
    Filed: October 7, 2003
    Date of Patent: April 14, 2009
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Patrice Bujard, Holger Leybach
  • Patent number: 7503970
    Abstract: A particulate metal oxide having the mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.
    Type: Grant
    Filed: April 13, 2007
    Date of Patent: March 17, 2009
    Assignee: Croda International PLC
    Inventors: Graham Paul Dransfield, Susan Cutter, Phillip Laurence Lyth
  • Patent number: 7476272
    Abstract: The present invention relates to Aluminum trihydrate slurries comprising aluminum trihydrate particles, an acrylic dispersant, citric acid, synthetic hectorite clay, optionally a compound to adjust pH, a biocide and water. These slurries may be mixed with titanium dioxide slurries to produce a stable slurry blends useful in paper and paper-board applications.
    Type: Grant
    Filed: November 29, 2006
    Date of Patent: January 13, 2009
    Assignee: E.I. Du Pont de Nemours & Company
    Inventors: Maureen A. Defeo, Glenn Richard Evers, Patrick F. McIntyre
  • Publication number: 20090004390
    Abstract: The present invention is directed to pigment compositions, thick film black pigment compositions, conductive single layer thick film compositions, black electrodes made from such black conductive compositions and methods of forming such electrodes, and to the uses of such compositions, electrodes, and methods in flat panel display applications, including alternating-current plasma display panel devices (AC PDP).
    Type: Application
    Filed: June 28, 2007
    Publication date: January 1, 2009
    Inventors: Jerome David Smith, Pedro A. Jimenez, Tony Jackson
  • Patent number: 7465430
    Abstract: There is described an apparatus for making metal oxide particles which are substantially free of coarse tail from an oxidizing agent and a metal reactant in a flow reactor. The apparatus can be a concentric tubular flow reactor comprising a substantially funnel-shaped reactant contacting region located adjacent to a reaction zone which is able to direct a flow of a hot oxidizing agent towards a flow of the metal reactant to form a reaction stream which flows downstream into a reaction zone, whereby the hot oxidizing agent of the reaction stream is able to surround the flow of metal reactant sufficient to prevent the metal reactant from contacting the wall of the reactant contacting region and forming scale on the wall.
    Type: Grant
    Filed: July 18, 2005
    Date of Patent: December 16, 2008
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Juergen Kurt Plischke, Stephan Claude De La Veaux, Scott Rickbeil Frerichs, Jodi Lynn Witt, Christian Normand
  • Patent number: 7455726
    Abstract: The present invention relates to photostabilised effect pigments in which one or more calcined and vanadium-containing oxide layers, alone or mixed with sulfates, borates or phosphates, have been applied to a substrate, to a process for the preparation thereof, and to the use thereof in plastics, paints, coatings, printing inks, cosmetics, films, in security printing, for laser marking, in thermal protection or for colouring seed.
    Type: Grant
    Filed: April 27, 2004
    Date of Patent: November 25, 2008
    Assignee: Merck Patent GmbH
    Inventors: Ulrich Schoenefeld, Padma Kaviratna
  • Publication number: 20080168924
    Abstract: The present invention relates to pearlescent pigments based on glass flakes which are distinguished by the fact that they have the following layer structure: A) optionally a layer of SiO2, B) a high-refractive-index coating have a refractive-index n>1.8 which essentially consists of TiO2, C) a low-refractive-index layer comprising SiO2 and/or Al2O3 and optionally D) an outer protective layer, and to the use thereof in paints, coatings, automobile paints, powder coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, paper, in toners for electrophotographic printing processes, in seed, in greenhouse sheeting and tarpaulins, as absorbers in the laser marking of paper and plastics, as absorbers for the laser welding of plastics, in cosmetic formulations, for the preparation of pigment pastes with water, organic and/or aqueous solvents, for the preparation of pigment compositions and dry preparations.
    Type: Application
    Filed: August 10, 2005
    Publication date: July 17, 2008
    Inventors: Sabine Melson, Marc Entenmann, Marita Jekel, Marcus Mathias
  • Publication number: 20080156229
    Abstract: The present invention provides hydrothermal processes for the production of titanium dioxide from titanyl hydroxide. The use of specific crystallization directors, or additives, can promote the formation of rutile, anatase, or brookite. Variation of process operating parameters can lead to either pigmentary-sized or nano-sized rutile.
    Type: Application
    Filed: December 28, 2006
    Publication date: July 3, 2008
    Applicant: E. I. DUPONT DE NEMOURS AND COMPANY
    Inventors: DAVID RICHARD CORBIN, KEITH W. HUTCHENSON, SHENG LI, CARMINE TORARDI, EUGENE MICHAEL MCCARRON
  • Patent number: 7390355
    Abstract: A dispersion containing zinc oxide particles having a dispersion particle size of (i) median volume particle diameter in the range from 70 to 130 nm, (ii) less than 16% by volume of particles having a volume diameter of less than 35 nm below the median volume particle diameter, and (iii) more than 84% by volume of particles having a volume diameter of less than 57 nm above the median volume particle diameter. The zinc oxide dispersion can be used in a sunscreen product that exhibits both effective UV protection and improved transparency. The zinc oxide is particularly suitable for use in combination with transparent titanium dioxide.
    Type: Grant
    Filed: June 10, 2004
    Date of Patent: June 24, 2008
    Assignee: Croda International Plc
    Inventor: Philip Laurence Lyth
  • Patent number: 7371275
    Abstract: Coated titanium dioxide pigment having high UV absorption properties and use in polymer compositions, especially PVC for building and residential construction is described.
    Type: Grant
    Filed: July 2, 2004
    Date of Patent: May 13, 2008
    Assignee: E.I. du Pont de Nemours and Company
    Inventors: John Davis Bolt, Robert William Johnson
  • Patent number: 7344590
    Abstract: The present invention relates to silver pigments based on transparent, low-refractive-index, platelet-shaped substrates which have a high-refractive-index coating consisting of TiO2 having a layer thickness of 5-300 nm and optionally an outer protective layer, and to the use thereof in paints, coatings, printing inks, security printing inks, plastics, button pastes, ceramic materials, glasses, for seed coloring, as dopants in the laser marking of plastics and papers, as additives for coloring in the foods and pharmaceuticals sectors, and in cosmetic formulations and for the preparation of pigment compositions and dry preparations.
    Type: Grant
    Filed: March 29, 2004
    Date of Patent: March 18, 2008
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Christoph Schmidt, Tanja Delp, Johann Dietz
  • Patent number: 7318861
    Abstract: An effect pigment is constituted by coated laminar platelets in which the platelets are a mixture of different platelet materials, one of which is platy glass or platy aluminum oxide, and in which the pigment exhibits visual homogeneity.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: January 15, 2008
    Assignee: BASF Catalysts LLC
    Inventors: Frank Bagala, Sr., Curtis J. Zimmermann
  • Patent number: 7291217
    Abstract: A corrosion-inhibiting pigment comprising a rare earth element and a valence stabilizer combinded to form a rare earth/valence stabilizer complex. The rare earth element is selected from cerium, terbium, praseodymium, or a combination thereof, and at least one rare earth element is in the tetravalent oxidation state. An inorganic or organic material is used to stabilize the tetravalent rare earth ion to form a compound that is sparingly soluble in water. Specific stabilizers are chosen to control the release rate of tetravalent cerium, terbium, or praseodymium during exposure to water and to tailor the compatibility of the powder when used as a pigment in a chosen binder system. Stabilizers may also modify the processing and handling characteristics of the formed powders. Many rare earth-valence stabilizer combinations are presented that can equal the performance of conventional hexavalent chromium systems.
    Type: Grant
    Filed: July 23, 2003
    Date of Patent: November 6, 2007
    Assignee: University of Dayton
    Inventors: Andrew Wells Phelps, Jeffrey Allen Sturgill, Joseph Thomas Swartzbaugh
  • Publication number: 20070215005
    Abstract: A coated titanium dioxide pigment with good opacity and simultaneously good retention for use in decorative laminating paper characterized by a surface coating containing aluminium oxide phosphate and attached hollow bodies, e.g., hollow microbodies. A manufacturing method is characterized in that an aluminium containing component and a phosphorus containing component are first added to a TiO2 suspension, during which time the pH value does not drop below 10. The hollow bodies are subsequently added, followed by addition of at least one acidic component, as a result of which the pH value of the suspension is lowered to the range from about 4 to 9. In an alternative embodiment of the method, the suspension has a pH value of under 4 at the time of addition of the aluminium containing component and a phosphorus containing component.
    Type: Application
    Filed: February 23, 2007
    Publication date: September 20, 2007
    Inventors: Lydia Drews Nicolai, Siegfried Blumel
  • Patent number: 7264672
    Abstract: A process for producing an improved titanium dioxide pigment composite is provided, as are particles produced thereby. The process comprises producing a slurry comprising titanium dioxide particles, leaching alumina from the surface of the titanium dioxide particles in the presence of a soluble phosphate and precipitating aluminum phosphate from the slurry onto the surface of the titanium dioxide particles thereby forming a uniform coating of aluminum phosphate on the surfaces of the titanium dioxide particles. An anionic poly-electrolyte can be added to the resulting slurry. The slurry can then be treated such that the anionic poly-electrolyte forms an additional coating on the aluminum phosphate-coated titanium dioxide particles.
    Type: Grant
    Filed: October 31, 2006
    Date of Patent: September 4, 2007
    Assignee: National Titanium Dioxide Co. Ltd. (Cristal)
    Inventors: Fadi Mohammed Saeed Trabzuni, Chathangat Cheroolil Gopalkrishnan
  • Patent number: 7255735
    Abstract: Pyrogenically prepared surface-modified silicon dioxide-titanium dioxide mixed oxides are prepared by spraying pyrogenically prepared silicon dioxide-titanium dioxide mixed oxides with a surface-modifying agent. The surface-modified pyrogenically prepared silicon dioxide-titanium dioxide mixed oxides can be used in sun protection formulation.
    Type: Grant
    Filed: December 21, 2005
    Date of Patent: August 14, 2007
    Assignee: Degussa AG
    Inventors: Jürgen Meyer, Kai Schumacher, Steffen Hasenzahl, Heike Riedemann, Ann Gray
  • Publication number: 20070175364
    Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.
    Type: Application
    Filed: January 30, 2007
    Publication date: August 2, 2007
    Applicant: Kronos International Inc.
    Inventors: Siegfried Blumel, Lydia Drews-Nicolai
  • Publication number: 20070175365
    Abstract: A method of predicting photostability of coatings with various dopants on titanium dioxide pigment particles is disclosed. Calculations of the density of states show that a doped coating which reduces the density of states near the band edge or increases the density of states within the band gap of the pigment particles increases the photostability of the doped pigment.
    Type: Application
    Filed: January 30, 2007
    Publication date: August 2, 2007
    Applicant: Kronos International Inc.
    Inventors: Lydia Drews-Nicolai, Siegfried Blumel
  • Publication number: 20070175363
    Abstract: The invention relates to a rutile titanium dioxide pigment for use in decorative laminating papers that yields higher opacity of the papers compared to the prior art, as well as a method for its manufacture. The pigment displays a surface coating that contains aluminium phosphate, aluminium oxide, silicon oxide and titanium oxide. The silicon oxide is precipitated in fluffy form. The coated particles display a BET value of at least 15 m2/g. The manufacturing method is characterized in that an aluminium and a phosphorus component are first added to a TiO2 suspension. Thereafter, an alkaline silicon component, an acid-reacting titanium component and, optionally, a further pH-regulating component are added, the pH value being set in the range from 4 to 9 in this context.
    Type: Application
    Filed: January 30, 2007
    Publication date: August 2, 2007
    Applicant: Kronos International Inc.
    Inventors: Siegfried Blumel, Lydia Drews-Nicolai, Volker Jurgens, Volker Schmitt
  • Patent number: 7250080
    Abstract: An improved process for making an organosilicon compound surface-treated titanium dioxide material, comprising (a) forming a mixture of the titanium dioxide material in water, (b) wet milling the mixture, (c) adjusting the pH of the slurry resulting from step (b) to between about 5.0 and about 8.5, (d) after step (c), removing the titanium dioxide material from the mixture by vacuum or pressure filtration, (e) after step (d), washing the titanium dioxide material so removed, (f) after step (e), converting the washed titanium dioxide material to a fluid dispersion having a pH of from about 3.5 to less than about 7 via addition of a fluidizing agent comprising a water-soluble monoprotic acid, (g) after, or concurrently with, step (f), adding to the resulting dispersion of titanium dioxide material an organosilicon compound, with mixing, and (h) spray drying the dispersion of the washed titanium dioxide material resulting from step (g) to yield a dry titanium dioxide pigment powder.
    Type: Grant
    Filed: September 6, 2006
    Date of Patent: July 31, 2007
    Assignee: Tronox LLC
    Inventors: Daniel H. Craig, Mark D. Westmeyer
  • Patent number: 7220305
    Abstract: A particulate metal oxide having the mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.
    Type: Grant
    Filed: November 4, 2005
    Date of Patent: May 22, 2007
    Assignee: Croda International PLC
    Inventors: Graham Paul Dransfield, Susan Cutter, Phillip Lawrence Lyth
  • Patent number: 7214264
    Abstract: The present invention relates to a hydrous kaolin product having improved optical properties, for example, when used in the production of paper products. The present invention comprises an improved barrier coating for paper and a method of making the coated paper. The present invention also comprises an improved method from making filled and coated paper products. The present invention uses a composition comprising kaolin having a shape factor of at least about 70:1, such as at least about 80:1 or at least about 100:1.
    Type: Grant
    Filed: April 19, 2005
    Date of Patent: May 8, 2007
    Assignee: Imerys Pigments, Inc.
    Inventors: J. Philip E. Jones, Robert J. Pruett, Jun Yuan, Michael J. Garska, David O. Cummings, Bomi M. Bilimoria, Robin Wesley
  • Patent number: 7169322
    Abstract: Aqueous dispersion containing a silicon-aluminum mixed oxide powder, the powder containing 0.1 to 99.9 wt. % Al2O3 and Si—O—Al-bonds. The dispersion can be produced using dispersing and/or grinding devices which a achieve an energy input of at least 200 KJ/m3. The dispersion can be used for the chemical-mechanical polishing of semiconductor substrates.
    Type: Grant
    Filed: February 21, 2002
    Date of Patent: January 30, 2007
    Assignee: Degussa AG
    Inventors: Frank Menzel, Wolfgang Lortz, Helmut Mangold
  • Patent number: 7135206
    Abstract: A method for producing nanoscale titanium dioxide particles which are coated with an oxide, a hydroxide or an oxide hydroxide of Al, Ce, Zr and/or Si wherein the enzymatic precipitant system urease/urea is used. Said coated titanium dioxide particles can have an average size of less than 50 nm, the coating providing effective protection against photocatalytic reactions. The coated particles are suitable, in particular, as UV absorbers in a transparent organic matrix.
    Type: Grant
    Filed: October 30, 2002
    Date of Patent: November 14, 2006
    Assignee: Leibniz-Institut Fuer Neue Materialien Gemeinnuetzige GmbH
    Inventor: Martin Schichtel
  • Patent number: 7135065
    Abstract: The invention relates to a method for the post-treatment of titanium dioxide, in order to produce particularly weather-resistant titanium dioxide pigments with good optical properties. The method is characterized in that, together with the hydrous oxides of tin and zirconium, at least one other from the group comprising aluminium, silicon and titanium is additionally precipitated onto the particle surface. The post-treatment components are added to the aqueous TiO2 suspension either in the acidic range (pH value of 3 at most) or in the alkaline range (pH value of 10 at least). The pH value is subsequently set to between 6 and 8. Final tempering of the pigment at elevated temperatures from over 125° C. to up to 500° C. can improve the tone b. The pigment is particularly suitable for use in paints, coatings and plastics.
    Type: Grant
    Filed: July 12, 2005
    Date of Patent: November 14, 2006
    Assignee: Kronos International
    Inventors: Lydia Drews-Nicolai, Siegfried Bluemel
  • Patent number: 7118622
    Abstract: An unsupported platy titanium dioxide pigment containing an organic dye laked thereon. The dyed TiO2 pigment is useful to color cosmetic, food, and drug formulations.
    Type: Grant
    Filed: May 11, 2005
    Date of Patent: October 10, 2006
    Assignee: Engelhard Corporation
    Inventors: Frank A. Mazzella, Gabriel E. Uzunian
  • Patent number: 7101427
    Abstract: A particulate metal oxide having a mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.
    Type: Grant
    Filed: December 20, 2002
    Date of Patent: September 5, 2006
    Assignee: Imperial Chemical Industries plc
    Inventors: Graham Paul Dransfield, Susan Cutter, Philip Laurence Lyth
  • Patent number: 7060126
    Abstract: The invention relates to multilayered luster pigments based on metallic substrates, which are completely surrounded by a plurality of layers, where these layers comprise at least one layer pack (A) having a colorless dielectric layer of a material with a refractive index n of ?1.8, and a colorless dielectric layer of a material with a refractive index n of >1.8, and a selectively or non-selectively absorbent layer (B), and to a process for their production, and to their use.
    Type: Grant
    Filed: June 12, 2002
    Date of Patent: June 13, 2006
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Martin Friz, Gerhard Pfaff, Siegfried Raabe, Michael Uhlig
  • Patent number: 7029648
    Abstract: The present invention relates to a process for making durable titanium dioxide pigment by vapor phase deposition of surface treatments on the titanium dioxide particle surface by reacting titanium tetrachloride vapor, an oxygen containing gas and aluminum chloride in a plug flow reactor to form a product stream containing titanium dioxide particles; and introducing silicon tetrachloride into the reactor at a point down stream of the point where the titanium tetrachloride and oxygen were contacted and where at least 97% of the titanium tetrachloride has been converted to titanium dioxide or where the reaction temperature is no greater than about 1200° C., and preferably not more than about 1100° C.
    Type: Grant
    Filed: July 8, 2004
    Date of Patent: April 18, 2006
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Narayanan Sankara Subramanian, Russell Bertrum Diemer, Jr., Pratibha Laxman Gai
  • Patent number: 7018465
    Abstract: A spray glaze or opaque composition for coating dental restorations and other surfaces and objects such as hobby ceramics that comprises about 4 to about 50 weight % glaze material, about 5 to about 60 weight % restoration wetting agent, and about 10 to about 90% non CFC propellant. An opaque composition further comprises about 5 to about 30% opaque material.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: March 28, 2006
    Assignee: Enamelite, LLC
    Inventors: Phillip G. Pitts, James R. Vinson
  • Patent number: 6962622
    Abstract: The invention relates to a titanium dioxide pigment mixture comprising a pigment having high greying stability (pigment type A) and a pigment having increased SiO2 and Al2O3 content in flaky precipitation (pigment type B). Said mixture provides, for example in paper, a high level of opacity for sufficient greying stability. If necessary, the light-fastness of the paper can be further increased by means of known production-conditioned measures on pigment type B.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: November 8, 2005
    Assignee: Kronos Titan GmbH
    Inventors: Jürgen Bender, Siegfried Blümel, Volker Schmitt, Brigitte Vielhaber-Kirsch
  • Patent number: 6929690
    Abstract: A pigment with a metallic luster, comprising a wafer-like substrate made of aluminium dioxide having a thickness of more than 250 nm and less than 1 ?m, which is fully enveloped by a metal layer.
    Type: Grant
    Filed: September 27, 2002
    Date of Patent: August 16, 2005
    Assignee: Merck Patent GmbH
    Inventors: Reiner Vogt, Gerhard Pfaff, Stephanie Andes, Michael Uhlig, Martin Friz, Katsuhisa Nitta
  • Patent number: 6884289
    Abstract: The present invention relates to colored pigments based on multicoated platelet-shaped substrates which are distinguished by the fact that they comprise (A) a coating having a refractive index of n>1.8 and a layer thickness of 20-500 nm, (B) a colorless coating having a refractive index of n?1.8 and a layer thickness of 10-100 nm, (C) a colorless coating having a refractive index of n>1.8 and a layer thickness of 20-500 nm, (D) a covering of absorbent pigment particles having a particle size of 1-500 nm, and optionally (E) an outer protective layer, and to their use in paints, coatings, printing inks, plastics, ceramic materials, glasses, for laser marking, in cosmetic formulations and for the production of pigment preparations and dry preparations.
    Type: Grant
    Filed: April 24, 2002
    Date of Patent: April 26, 2005
    Assignee: Merck Patent Gmbh
    Inventors: Sabine Schoen, Christoph Schmidt
  • Patent number: 6875264
    Abstract: A multilayer effect pigment includes a transparent substrate, a layer of high refractive index material on the substrate, and alternating layers of low refractive index and high refractive index materials on the first layer, the total number of layers being an odd number of at least three, all adjacent layers differing in refractive index by at least about 0.2 and at least one of the layers having an optical thickness which is different from all of the other layers. The resulting multilayer effect pigment is not a quarter-wave stack.
    Type: Grant
    Filed: January 17, 2003
    Date of Patent: April 5, 2005
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, Daniel Stevenson Fuller
  • Patent number: 6866710
    Abstract: The present invention relates to inorganic spherical absorption pigments which have a bimodal particle-size distribution, at least one color-providing layer and a final SiO2 layer, and to the use thereof in paints, coatings, printing inks, security printing inks, plastics, ceramic materials, glasses, as tracers, in cosmetic formulations and for the preparation of pigment preparations and dry preparations.
    Type: Grant
    Filed: December 17, 2003
    Date of Patent: March 15, 2005
    Assignee: Merck Patent GmbH
    Inventors: Lilia Heider, Martin Knapp, Gisela Lenz, Norbert Rick
  • Patent number: 6849115
    Abstract: A method of manufacturing aluminum-substituted hematite represented by ?-(Fe1-xAlx)2O3 where x=0.01 to 0.15, by mixing an iron compound and an aluminum compound such that an atomic ratio of Fe to Al falls within the range of 99:1 to 85:15, adding citric acid and ethylene glycol to the mixture of the iron compound and aluminum compound to produce a gel, and pyrolyzing the gel, followed by calcining the pyrolyzed product.
    Type: Grant
    Filed: July 2, 2003
    Date of Patent: February 1, 2005
    Assignee: President of Okayama University
    Inventors: Jun Takada, Tatsuo Fujii, Makoto Nakanishi
  • Patent number: 6840993
    Abstract: The present invention relates to silver-colored luster pigments based on multiply coated platelet-shaped substrates, which has at least one layer sequence of TiO2, a colorless coating and another TiO2 layer. The pigment can optionally have an outer protective layer. These luster pigments are useful and to the use thereof in paints, coatings, printing inks, including security printing inks, plastics, ceramic materials, glasses, cosmetic formulations and for producing pigment preparations and dry product forms such as granules, chips, pellets and briquettes.
    Type: Grant
    Filed: April 21, 2003
    Date of Patent: January 11, 2005
    Assignee: Merck Patent GmbH
    Inventors: Christoph Schmidt, Andrea Heyland, Claudia Fornoff, Hans-Dieter Brückner
  • Patent number: 6821333
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective layer which acts as a reflector to light directed thereon and a spacer pigment layer which is selectively transparent to light directed thereon.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: November 23, 2004
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, James D. Christie, Vivian K. Doxey, Daniel Stevenson Fuller
  • Patent number: 6805739
    Abstract: A method of manufacturing a photo-catalyst including titanium dioxide and silicon dioxide is provided, wherein titanium dioxide is synthesized by a collosol gelatinization utilizing the water generated by the esterification of acid and alcohol to conduct a reaction of hydrolysis condensation. The silicon dioxide is synthesized by a collosol gelatinization by adding Si(OC2H5)4, n-C4H9OH and water or Si(OC2H5)4, (CH3)Si(OC2H5)3 and water.
    Type: Grant
    Filed: July 29, 2002
    Date of Patent: October 19, 2004
    Assignee: China Textile Institute
    Inventors: Lien-Hua Chiu, Wen-Tung Chen, Jan-An Guu, Jeffrey Chi-Sheng Wu, I-Hsiang Tseng, Chih-Hsien Chen
  • Publication number: 20040202601
    Abstract: The present invention provides methods and compositions comprising inorganic solids for use as pigments in paints, papers and plastics.
    Type: Application
    Filed: April 30, 2004
    Publication date: October 14, 2004
    Applicant: Millennium Inorganic Chemicals, Inc.
    Inventors: Fu-Chu Wen, Duen-Wu Hua, Deborah E. Busch
  • Patent number: 6800125
    Abstract: A color effect material is described as composed of a plurality of encapsulated substrate platelets in which each platelet is encapsulated with a highly reflective silver layer which acts as a reflector to light directed thereon and an iron oxide layer.
    Type: Grant
    Filed: December 13, 2002
    Date of Patent: October 5, 2004
    Assignee: Engelhard Corporation
    Inventors: Curtis J. Zimmermann, Steven A. Jones
  • Patent number: 6793720
    Abstract: A solid marking composition comprises a solid matrix containing at least one type of optically variable interference pigment flakes. The solid marking composition provides a document or article with a copy and counterfeit protection feature, and is preferably used in a writing instrument for applying hand-written anti-counterfeit markings and signatures.
    Type: Grant
    Filed: September 26, 2002
    Date of Patent: September 21, 2004
    Assignee: SICPA Holding S.A.
    Inventors: Edgar Müller, Olivier Rozumek
  • Patent number: 6783586
    Abstract: The present invention relates to a TiO2 pigment coated sequentially in a wet treatment process with hydrous silica and hydrous alumina both in the presence of citric acid wherein the resulting pigment is coated with from 1 to 4% amorphous alumina based on the weight of the untreated TiO2; from 3 to 6% silica glass based on the weight of the untreated TiO2.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: August 31, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Charles Robert Bettler, Michael Patrick Deibold