Aluminum Compound Or Silicon Containing Patents (Class 106/442)
  • Patent number: 6740312
    Abstract: Anatase titanium dioxide particles with a size of at most 100 nm wherein the particles are at least partially covered with a layer of at least one metal oxide, hydroxide or hydroxide oxide and the particles exhibit a BET specific surface of at least 70 m2/g and a relative density of the order of 2.2. A process for preparing the anatase dioxide particles is also disclosed.
    Type: Grant
    Filed: June 17, 2002
    Date of Patent: May 25, 2004
    Assignee: Rhodia Chimie
    Inventors: Thierry Chopin, Dominique Dupuis, Claudie Willemin
  • Publication number: 20040094068
    Abstract: The invention relates to a titanium dioxide pigment mixture comprising a pigment having high greying stability (pigment type A) and a pigment having increased SiO2 and Al2O3 content in flaky precipitation (pigment type B). Said mixture provides, for example in paper, a high level of opacity for sufficient greying stability. If necessary, the light-fastness of the paper can be further increased by means of known production-conditioned measures on pigment type B.
    Type: Application
    Filed: August 13, 2003
    Publication date: May 20, 2004
    Inventors: J?uuml;rgen Bender, Siegfried Blmel, Volker Schmitt, Brigitte Vielhaber-Kirsch
  • Patent number: 6730156
    Abstract: A filler comprising a substantially amorphous cluster comprising non-heavy metal oxide particles and heavy metal oxide. The filler can be mixed into a hardenable resin to provide radiopaque dental materials having desirable strength and aesthetic character.
    Type: Grant
    Filed: October 28, 1999
    Date of Patent: May 4, 2004
    Assignee: 3M Innovative Properties Company
    Inventors: Mark Steven Windisch, Xiaodong Zhang, Richard Paul Rusin, Sumita Basu Mitra
  • Patent number: 6695906
    Abstract: Titanium dioxide pigments having improved gloss and durability are disclosed. These pigments are prepared by continuous processes, where pH, temperature, and addition times of hydrous silica and alumina coatings are carefully controlled.
    Type: Grant
    Filed: April 12, 2001
    Date of Patent: February 24, 2004
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Michael Hiew, Yarw-Nan Wang, Les Hamor, Brian Tear, Robert McIntyre
  • Publication number: 20040007159
    Abstract: An aluminum pigment composition comprising flaky aluminum, wherein said flaky aluminum as a base material is coated with a coating layer comprising hydrolyzates (a) of a titanium alcoholate represented by the general formula (1):
    Type: Application
    Filed: July 17, 2003
    Publication date: January 15, 2004
    Inventor: Shigeki Katsuta
  • Publication number: 20030235544
    Abstract: There is provided a pigment surface treated with N-acylglycine hydroxyaluminum and/or N-acyl-N-methylglycine hydroxyaluminum, and a pigment dispersion which contains such surface treated pigment and a cosmetically acceptable oily material, and has an excellent dispersion stability and versatility (ease of dispersion and wide rage of usage).
    Type: Application
    Filed: June 25, 2002
    Publication date: December 25, 2003
    Inventors: Shigeru Kishida, Mark Lepage, Tetsuo Murata, William Kalriess, Masaru Kobayashi, Isao Imai
  • Publication number: 20030223940
    Abstract: A particulate metal oxide having a mean length of the primary particles in the range from 50 to 90 nm, the mean width of the primary particles in the range from 5 to 20 nm, and the median volume particle diameter of the secondary particles is less than 45 nm. The metal oxide can be used in a sunscreen product that exhibits both effective UV protection and improved transparency.
    Type: Application
    Filed: December 20, 2002
    Publication date: December 4, 2003
    Applicant: Imperial Chemical Industrial PLC
    Inventors: Graham Paul Dransfield, Susan Cutter, Philip Laurence Lyth
  • Patent number: 6648957
    Abstract: Multilayer pearl lustre pigment on the basis of a platelet-shaped substrate comprising a material of low refractive index in the range from 1.35 to 1.8, which comprises at least (i) one first layer comprising a material having a refractive index of more than 1.8, (ii) optionally, a second layer comprising a material of low refractive index in the range from 1.35 to 1.8, (iii) a semitransparent metal layer which is applied to the substrate or to the layers (i) or (ii), and (iv) if desired, an aftercoating, the substrate being platelet-shaped silicon dioxide, aluminium oxide, boron oxide or magnesium fluoride.
    Type: Grant
    Filed: December 4, 2001
    Date of Patent: November 18, 2003
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Gerhard Pfaff
  • Patent number: 6648958
    Abstract: Highly light-scattering pigment mixture featuring (i) 70-99.9% by weight of a component A consisting of spherical silicon dioxide with a diameter of less than 50 &mgr;m, coated with titanium dioxide and optionally a further layer of SiO2, and (ii) 0.1-30% by weight of a component B consisting of spherical silicon dioxide with a diameter of less than 50 &mgr;m, coated with titanium dioxide as a first layer and iron(III) oxide as a second, outer layer, the refractive index of the pigment being adjusted to a value of between 1.45 and 1.65.
    Type: Grant
    Filed: November 13, 2002
    Date of Patent: November 18, 2003
    Assignee: Merck Patent Gesellschaft
    Inventors: Ralf Anselmann, Martin Knapp, Uta Hillgärtner
  • Publication number: 20030181329
    Abstract: A method of producing composite particles of titanium dioxide and a compound inactive as a photocatalyst, comprising the steps of preparing a water based slurry of pH 3 to 5 comprising titanium dioxide, preparing a water based solution comprising a compound inactive as a photocatalyst, and reacting the slurry and the water based solution together at a pH within a range from 4 to 10 is provided, together with highly active photocatalyst particles produced using such a method, and potential uses of such photocatalyst particles.
    Type: Application
    Filed: December 19, 2002
    Publication date: September 25, 2003
    Applicant: SHOWA DENKO K.K.
    Inventors: Jun Tanaka, Masayuki Sanbayashi, Yoshinori Ueyoshi
  • Patent number: 6620508
    Abstract: Firstly, a powder matrix is kept in a fluent state, said powder matrix consisting of a first oxide having an absorbed water amount of 0.1 to 50%, an averaged particle diameter of 0.005 to 0.5 &mgr;m and a surface hydroxyl group number of 0.1 to 25 &mgr;mol/m2. Then, one or both of a halide and an alkoxide including metal or semi-metal identical with or different from the metal or semi-metal constituting said first oxide is allowed to contact with said powder matrix kept in the fluent state, by means of an inert carrier gas, and then they are heated at a temperature of from 25 to 800° C., to thereby coat said powder matrix by a coating layer consisting of a second oxide. Further, a reaction by-product consisting of one or both of a hydrogen halide or an alcohol generated by said contacting is heated at a temperature of from 200 to 1000° C. within the inert carrier gas to thereby eliminate the reaction by-product.
    Type: Grant
    Filed: September 25, 2001
    Date of Patent: September 16, 2003
    Assignee: Nippon Aerosil Co., Ltd.
    Inventors: Akira Inoue, Eiji Komai, Takeyoshi Shibasaki, Hirokuni Shirono
  • Patent number: 6610136
    Abstract: Aggregated mineral pigments (such as kaolin clay pigments) having a high surface area and useful in coating and filling compositions for ink jet printing media are manufactured by dry grinding an unground mineral composition starting material and then optionally acid treating the ground material.
    Type: Grant
    Filed: March 21, 2002
    Date of Patent: August 26, 2003
    Assignee: Thiele Kaolin Company
    Inventors: Prakash B. Malla, Siva Devisetti
  • Publication number: 20030158316
    Abstract: A curable film-forming composition is provided comprising (i) 10 to 90 percent by weight based on the total weight of resin solids in the film-forming composition of a crosslinking agent; (ii) 10 to 90 percent by weight of a polymer containing a plurality of functional groups reactive with the crosslinking agent; and (iii) 5 to 85 percent by volume of particles having a mean particle size less than 100 nm. The particles comprise 1 to 99 percent by weight of at least one metal oxide wherein the metal is selected from zinc, titanium, cerium, manganese, bismuth, copper, zirconium and iron.
    Type: Application
    Filed: February 6, 2003
    Publication date: August 21, 2003
    Inventors: Noel R. Vanier, Calum H. Munro
  • Patent number: 6605147
    Abstract: The use of surface-coated rutile modification TiO2 pigments having a primary particle grain size d50 of 0.1 to 1.0 &mgr;m as an anticorrosive white pigment, with firstly magnesium phosphate and secondly aluminum oxides and/or aluminum hydroxides being precipitated onto the TiO2 pigments, is described.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: August 12, 2003
    Assignee: Sachtleben Chemie GmbH
    Inventors: Thomas Rentschler, Jochen Winkler
  • Patent number: 6599351
    Abstract: Anticorrosive white pigments useful for inhibiting corrosion include surface-coated TiO2 base bodies, preferably in the rutile modification, having Mn3(PO4)2 and one or more of the substances chosen from aluminum oxides, aluminum hydroxides, aluminum phosphates, aluminum hydrogen phosphates, aluminum dihydrogen phosphates and aluminum polyphosphates are precipitated on to the TiO2 base bodies. Mn3(PO4)2 may be replaced completely or partially by Zn3(PO4)2. Phosphates and/or oxides of cerium may be additionally deposited singly, or several of them may be deposited, on to the TiO2 base bodies.
    Type: Grant
    Filed: April 4, 2002
    Date of Patent: July 29, 2003
    Assignee: Metallgesellschaft Aktiengesellschaft
    Inventors: Thomas Rentschler, Fritz Muller, Jochen Winkler, Wolf-Rudiger Karl, Kirsten Fohr
  • Publication number: 20030138386
    Abstract: A UV screening composition comprising particles which are capable of absorbing UV light so that electrons and positively charged holes are formed within the particles, characterised in that the particles are adapted to minimise migration to the surface of the particles of the electrons and/or the positively charged holes when said particles are exposed to UV light in an aqueous environment.
    Type: Application
    Filed: September 30, 2002
    Publication date: July 24, 2003
    Inventors: John Sebastian Knowland, Peter James Dobson, Gareth Wakefield
  • Patent number: 6596070
    Abstract: The present invention relates to interference pigments on the basis of multiply coated, platelet-shaped substrates which comprise at least one layer sequence comprising (A) a coating having a refractive index n≧2.0, (B) a colorless coating having a refractive index n≦1.8, and (C) a nonabsorbing coating of high refractive index, and, if desired, (D) an external protective layer.
    Type: Grant
    Filed: April 17, 2000
    Date of Patent: July 22, 2003
    Assignee: Merck Patent Gesellschaft
    Inventors: Christoph Schmidt, Gerhard Pfaff, Christina Schank, Sabine Schoen
  • Patent number: 6596074
    Abstract: The present invention pertains to the use of phosphorescent pigments in cementious materials and allied applications, specifically in use for tile mortars and grouts, pool plasters, wall plasters, cementious roofing materials, cementious surface coatings, cement patches and self leveling compounds. The material will luminesce in the absence of an external source after irradiation with sunlight, visible, ultra-violet (UV) and/or infrared radiation without any degradation in the integrity of the cementious materials from their original applications. The cementious materials need to be capable of being applied by trowel, brush, or spray, forming a strong bond to the surface to which it has been applied. The phosphorescent material should be insoluble in water, compatible with cementious materials, remain fixed in the cementious material, effective at high pH, and produce a long lasting luminescence, for up to 8 to 12 hours, in the visible portion of the spectrum after exposure to a radiation source.
    Type: Grant
    Filed: July 20, 2001
    Date of Patent: July 22, 2003
    Assignee: Southern Grouts and Mortars, Inc.
    Inventor: Robert S. Pomeroy
  • Patent number: 6582506
    Abstract: Pigment flakes having cores preferably composed of resins, polymers, thermoplastics, and/or thermosets with colorant (pigment and/or dyes) deposited thereon, coating applications thereof, and a method for making pigment flakes which includes providing a core material, compounding the core material, processing the core material into uniform forms such as films, wires, thread with rectangular cross sections and bead strings, providing colorant material, vaporizing the colorant material, exposing a surface of core material to the vaporized colorant material to form a layer of colorant on thereon, and fracturing the resultant colorant layered core material into flakes.
    Type: Grant
    Filed: May 25, 2001
    Date of Patent: June 24, 2003
    Assignee: Hampden Papers, Inc.
    Inventor: Michael E. Archambeault
  • Publication number: 20030089278
    Abstract: The present invention relates to a TiO2 pigment coated sequentially in a wet treatment process with hydrous silica and hydrous alumina both in the presence of citric acid wherein the resulting pigment is coated with from 1 to 4% amorphous alumina based on the weight of the untreated TiO2; from 3 to 6% silica glass based on the weight of the untreated TiO2.
    Type: Application
    Filed: October 29, 2002
    Publication date: May 15, 2003
    Inventors: Charles Robert Bettler, Michael Patrick Deibold
  • Publication number: 20030082123
    Abstract: Highly light-scattering pigment mixture featuring
    Type: Application
    Filed: November 13, 2002
    Publication date: May 1, 2003
    Applicant: Merck Patent GmbH
    Inventors: Ralf Anselmann, Martin Knapp, Uta Hillgartner
  • Publication number: 20030075079
    Abstract: In a method for the manufacture of a nacreous pigment, in which a multilayer film is produced by vacuum evaporation coating on a substrate and, after release from the substrate, the particles thus produced are comminuted to pigment particles of a desired size, vapor deposition of a plurality of layers taking place at separate locations within an evacuable container and the substrate being passed along the sources of evaporation, it is provided that at least a backing (A), in particular a silicon oxide layer, and at least a metal oxide layer (B), in particular a titanium oxide layer, are vapor-deposited on the substrate, in particular a circulating metal belt.
    Type: Application
    Filed: August 5, 2002
    Publication date: April 24, 2003
    Inventor: Gunter Sommer
  • Patent number: 6544328
    Abstract: A process for preparing an improved pigment which is readily dispersible in paints and plastics concentrates is provided. In accordance with the process, a particulate pigment is mixed with water to form a slurry thereof, and a surface active agent is mixed with the slurry so that the pigment therein is coated therewith. A preferred surface active agent is a mixture of ethoxylated sorbitan derivatives, non-ethoxylated mono and diglycerides and ethoxylated mono and diglycerides. After the pigment has been coated with the surface active agent, the coated pigment is dried.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: April 8, 2003
    Assignee: Kerr-McGee Chemical LLC
    Inventors: Bruce L. Roberts, Jeffrey D. Elliott, Ronnie L. Hoskins, Bruce R. Palmer
  • Patent number: 6540824
    Abstract: The present invention provides a yellow pigment which contains a titanium-iron complex oxide of the pseudo-brookite type and produces a stabilized color more yellowish than conventionally and which is universally usable for coloring plastics, ceramics and coating compositions. The pigment of the invention is a titanium-iron complex oxide pigment which contains a pseudo-brookite complex oxide represented by the composition formula (M1-x•Fex)O•2TiO2 or the composition formula (Fe1-y•Aly)2O3•TiO2 wherein M is one of the bivalent metals Mg, Sr and Zn, the ratios of Fe, Al and M to Ti are in the respective ranges of 0.3≦Fe/Ti≦4.5, 0≦Al/Ti≦6.5 and 0≦M/Ti≦2.6, and x and y are in the respective ranges of 0≦x<1 and 0≦y<1.
    Type: Grant
    Filed: February 7, 2002
    Date of Patent: April 1, 2003
    Assignee: Ferro Enamels (Japan) Limited
    Inventors: Takayuki Suzuki, Koji Kataoka
  • Publication number: 20030056693
    Abstract: A colorant for ink-jet printing ink of the present invention, has an average particle diameter of 0.001 to 0.15 &mgr;m, and comprises: extender pigments as core particles; a gluing agent coating layer formed on at least a part of surface of said core particle; and an organic pigment coat uniformly formed on at least a part of said gluing agent coating layer. The colorant for ink-jet printing ink exhibits not only a high tinting strength and a clear hue, but also excellent dispersibility and light resistance in spite of fine particles.
    Type: Application
    Filed: June 4, 2002
    Publication date: March 27, 2003
    Inventors: Kazuyuki Hayashi, Hiroko Morii, Keisuke Iwasaki
  • Publication number: 20030047115
    Abstract: The invention relates to a platelet-like pigment having high lustre and high covering power or high transparency, consisting of a transparent, inorganic, platelet-like matrix which can contain an additional constituent, characterised in that the additional constituent is a soluble or insoluble colorant and in that the matrix is coated at least on one side with one or more thin, transparent or semi-transparent reflective layers of metal oxides or metals to achieve the lustre.
    Type: Application
    Filed: April 15, 1994
    Publication date: March 13, 2003
    Inventors: GERD BAUER, KARL OSTERRIED, CHRISTOPH SCHMIDT, REINER VOGT, HELGE-BETTINA KNIESS, MICHAEL UHLIG, NORBERT SCHUL, GUNTHER BRENNER
  • Patent number: 6517629
    Abstract: The present invention provides a process for generating titanium dioxide pigments that have reduced moisture retention. By leaching oxidizer discharge and removing alumina containing compounds, one is able to generate a low volatile pigmentary bases. These low volatile pigmentary bases may be processed into finished low volatile pigments that may be combined with polymers to form polymer matrices. These pigments may be incorporated into polymer matrices at high temperatures without significant lacing.
    Type: Grant
    Filed: February 5, 2001
    Date of Patent: February 11, 2003
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventor: Stephen P. Kinniard
  • Patent number: 6508877
    Abstract: The present invention relates to a process for the production of an aluminum-containing iron oxide crystallization nucleus with a &agr;-FeOOH crystal structure from FeCl2. This nucleus is suitable as starting material for the production of iron oxide red (&agr;-Fe2O3) via &agr;-FeOOH as an intermediate product.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: January 21, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventor: Ulrich Meisen
  • Patent number: 6508290
    Abstract: The invention relates to a method of preparing an aluminium-containing iron oxide nucleus with an &agr;-FeOOH crystal structure from FeCl2. This nucleus is a suitable starting material for the preparation of iron oxide yellow and for use as a yellow coloring pigment.
    Type: Grant
    Filed: August 31, 2001
    Date of Patent: January 21, 2003
    Assignee: Bayer Aktiengesellschaft
    Inventor: Ulrich Meisen
  • Publication number: 20030005859
    Abstract: The invention relates to multilayered luster pigments based on metallic substrates, which are completely surrounded by a plurality of layers, where these layers comprise at least one layer pack (A) having a colorless dielectric layer of a material with a refractive index n of ≦1.8, and a colorless dielectric layer of a material with a refractive index n of >1.8, and a selectively or non-selectively absorbent layer (B), and to a process for their production, and to their use.
    Type: Application
    Filed: June 12, 2002
    Publication date: January 9, 2003
    Applicant: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerald Fuchs-Pohl, Martin Friz, Gerhard Pfaff, Siegfried Raabe, Michael Uhlig
  • Patent number: 6500251
    Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolyzable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.
    Type: Grant
    Filed: March 9, 1999
    Date of Patent: December 31, 2002
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Stephanie Andes, Gerd Bauer, Günter Brenner, Dieter Brückner, Michael Schmelz, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff
  • Patent number: 6485656
    Abstract: Paint detackifiers and/or sedimentation agents are provided which contain amorphous alumina and/or alumina in pseudoboehmite or boehmite form having an average crystallite size of from 0.1 to 15 nm and/or the hydrates and hydroxyalkylpolysaccharides thereof.
    Type: Grant
    Filed: February 11, 2000
    Date of Patent: November 26, 2002
    Assignee: SASOL Germany GmbH
    Inventors: Arnold Meyer, Jens Juhl, Klaus Noweck
  • Publication number: 20020170462
    Abstract: Provided is an ink for writing instruments which contains an interference pigment as a colorant and is designed to change the color tone of a line drawn with the ink depending on the darkness of a writing surface. The ink for writing instruments therefore contains an interference pigment coated, on the surface of a flaky minute base material, with a metal oxide having a high refractive index.
    Type: Application
    Filed: October 2, 2001
    Publication date: November 21, 2002
    Applicant: Zebra Co., Ltd.
    Inventor: Mayumi Terai
  • Publication number: 20020166478
    Abstract: The present invention provides titanium dioxide pigments with improved gloss and/or durability. The titanium dioxide pigments are made by treating titanium dioxide with a plurality of metal salts under conditions suitable to form the titanium dioxide pigment having improved gloss and/or durability, wherein at least one metal salt is capable of providing a monovalent anion. Preferred pigments of the present invention are substantially-sulfate free.
    Type: Application
    Filed: March 9, 2001
    Publication date: November 14, 2002
    Inventors: Brian Tear, John Stratton, Robert Burniston
  • Patent number: 6432869
    Abstract: Moldings are disclosed for use as a catalyst or catalyst support for hydrating olefin, such as ethylene and propylene. The moldings are based on a pyrogenically produced mixed oxide having the following physicochemical parameters: External diameter 0.8-25 mm BET surface area 5-400 m2/g Pore volume 0.2-1.8 ml/g Fracture strength 5 to 350 N Composition At least two materials selected from the group of SiO2, Al2O3, TiO2 and ZrO2 in any desired combination, with the proviso that when the combination is a SiO2/Al2O3 mixed oxide, at least 75 wt. % of SiO2 is present based on the total weight of the mixed oxide. Other constituents <1 wt. % Bulk density 250-1500 g/l.
    Type: Grant
    Filed: September 22, 1999
    Date of Patent: August 13, 2002
    Assignee: Degussa AG
    Inventors: Helmfried Krause, Hermanus Gerhardus Josef Lansink Rotgerink, Thomas Tacke, Helmut Mangold, Heike Riedemann, Manfred Fuchs
  • Patent number: 6409815
    Abstract: Surface-modified conductive pigment obtainable by partial coating of a conductive pigment with an organic modifying agent. The modifying agent is an organometallic compound of the elements silicon, tin, titanium, zirconium or aluminum. The pigment is prepared by dispersing a conductive pigment, subsequently adding the modifying agent, if appropriate as a mixture with a solvent, to the pigment dispersion, and in particular in an amount such that the powder electrical conductance of the partly coated conductive pigment is in the range between 80% of the starting value and 10−7 S, removing the solvent present, if appropriate, with further agitation and heating of the pigment to 100° C. and finally drying the partly coated pigment.
    Type: Grant
    Filed: April 5, 1995
    Date of Patent: June 25, 2002
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Alfred Hennemann, Manfred Kieser
  • Patent number: 6395081
    Abstract: The present invention provides methods of preparing a titanium dioxide pigment having improved gloss properties which involves heating an aqueous slurry of base titanium dioxide pigment to a temperature below about 75° C., coating the base titanium dioxide pigment with a silica compound at a temperature below about 75° C. to form a silica coated titanium dioxide pigment; and coating the silica coated titanium dioxide pigment with an alumina compound at a temperature below about 75° C. to form the titanium dioxide pigment having improved gloss.
    Type: Grant
    Filed: November 3, 2000
    Date of Patent: May 28, 2002
    Assignee: Millennium Inorganic Chemical, Inc.
    Inventors: Michael Hiew, Yarw-Nan Wang, Les Hamor, Brian Tear, Robert McIntyre
  • Patent number: 6387498
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: May 14, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6383638
    Abstract: A flake-based pigment is provided having improved specular reflectance characteristics in the visible wavelength range. The flake-based pigment has a plurality of core flake sections each formed of a central reflector layer and dielectric support layers on opposing sides of the reflector layer. The resulting core flake section is a very thin three-layered structure that exhibits a uniaxial compressive strength much greater than a corresponding uniaxial tensile strength. This structure provides the benefits of rigidity and brittle fracture during manufacturing and application processes, which ultimately provides favorable planar and specular reflectance characteristics for the pigment in the visible wavelength range. A variety of outer coating layers can be formed around the core flake sections, such as various dielectric and absorber layers having thicknesses dependent upon the desired optical characteristics of the pigment.
    Type: Grant
    Filed: October 13, 2000
    Date of Patent: May 7, 2002
    Assignee: Flex Products, Inc.
    Inventors: Kent E. Coulter, Thomas Mayer, Roger W. Phillips, John S. Matteucci
  • Patent number: 6379452
    Abstract: Calcined kaolin clay pigments having improved color are manufactured by adding a blue agent to the kaolin clay pigment prior to calcination, and then calcining the pigment and blue agent mixture.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: April 30, 2002
    Assignee: Thiele Kaolin Company
    Inventors: Chris B. Maxwell, Zhenzhong Zhang, Haydn H. Murray
  • Patent number: 6358495
    Abstract: To provide a complex which is excellent in transparency and protective ability of UVB region by containing titanium oxide in a specific silica carrier and a cosmetic preparation which has natural finishing i.e., excellent in transparency by the complex and is excellent in protective ability of UVB region, a titanium-silica complex in accordance with the present invention comprises a silica carrier and titanium oxide, wherein said silica carrier is mainly composed of silicon oxide and wherein titanium oxide is contained in said silica carrier.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: March 19, 2002
    Assignee: Shiseido Co., Ltd.
    Inventors: Shuji Nishihama, Shoichiro Shio
  • Publication number: 20020017221
    Abstract: Titanium dioxide pigments having improved gloss and durability are disclosed. These pigments are prepared by continuous processes, where pH, temperature, and addition times of hydrous silica and alumina coatings are carefully controlled.
    Type: Application
    Filed: April 12, 2001
    Publication date: February 14, 2002
    Inventors: Michael Hiew, Yarw-Nan Wang, Les Hamor, Brian Tear, Robert McIntyre
  • Patent number: 6342099
    Abstract: The present invention provides a coated titanium dioxide pigment which includes a base titanium dioxide pigment; a first deposit of a phosphate compound contiguous with the base titanium dioxide pigment; a deposit of a silica or zirconia compound contiguous with the phosphate deposit; a second deposit of a phosphate compound contiguous with the silica or zirconia compound; and a deposit of an alumina compound contiguous with the second phosphate deposit. Titanium dioxide pigments of the present invention are easily dispersible, and display excellent durability and gloss.
    Type: Grant
    Filed: September 15, 2000
    Date of Patent: January 29, 2002
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Michael Hiew, Philip Chegwidden
  • Patent number: 6334893
    Abstract: The present invention relates to pigment mixtures containing at least two components component A being Al2O3 flakes coated with one or more metals, metal oxides and/or metal sulfides and component B being acicular or spherical colorants, and to their use in particular in varnishes, paints, printing inks, powder coating materials, plastics and cosmetic formulations.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: January 1, 2002
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Gerhard Pfaff, Sabine Schoen, Kaiman Shimizu
  • Patent number: 6335083
    Abstract: Transparent solid, fused microspheres are provided. In one embodiment, the microspheres contain alumina, zirconia, and silica in a total content of at least about 70% by weight, based on the total weight of the solid, fused microspheres, wherein the total content of alumina and zirconia is greater than the content of silica, and further wherein the microspheres have an index of refraction of at least about 1.6 and are useful as lens elements.
    Type: Grant
    Filed: April 17, 1998
    Date of Patent: January 1, 2002
    Assignee: 3M Innovative Properties Company
    Inventors: Toshihiro Kasai, Kenton D. Budd, Stephen L. Lieder, James A. Laird, Chikafumi Yokoyama, Toshinori Naruse, Kenji Matsumoto, Hirohiko Ono
  • Patent number: 6294010
    Abstract: The present invention relates to pigment mixtures containing at least two components, component A being Al2O3 flakes coated with one or more metals, metal oxides and/or metal sulfides and component B being one or more functional pigments, such as electrically conductive pigments, magnetic pigments, IR-reflective pigments or lasermarkable pigments, and to their use in varnishes, paints, printing inks, plastics and powder coatings.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: September 25, 2001
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Gerhard Pfaff, Sabine Schoen, Kaiman Shimizu
  • Patent number: 6284034
    Abstract: A pigment material for use in a coating composition suitable for coating a sheet material to be printed by an electrophotographic printer which pigment material comprises a blend of Components A and B as follows: Component A: a fine pigment material suitable for gloss coating of a sheet material the pigment material comprising particles at least 80% by weight of which have an equivalent spherical diameter (“esd”) of less than 2 &mgr;m and having a particle size distribution (“psd”) such that its d50 value, namely the particle esd value less than which 50% of the particles have an esd, is less than 1 &mgr;m; and Component B: a coarse pigment material having a psd such that its d50 value is from 2 &mgr;m to 10 &mgr;m, desirably 2 &mgr;m to 5 &mgr;m and such that not more than 2% by weight of the particles of the coarse pigment material have an esd greater than 15 &mgr;m, desirably not more than 2% have an esd greater than 10 &mgr;m; wherein the weight ratio of Component A to Component
    Type: Grant
    Filed: July 16, 1999
    Date of Patent: September 4, 2001
    Assignee: Imerys Minerals Limited
    Inventors: Anthony Gordon Hiorns, Janet Susan Preston, James Philip Eynon Jones
  • Patent number: 6284032
    Abstract: Multilayer interference pigment consisting of plateletlike titanium dioxide as carrier material, coated with alternating layers of metal oxides of low and high refractive index, the difference in the refractive indices being at least 0.1, which is obtainable by solidification and hydrolysis of an aqueous solution of a thermally hydrolysable titanium compound on a continuous belt, detachment of the resulting coat, coating of the resulting titanium dioxide platelets, with or without drying in between, by a wet method with, alternately, a metal oxide hydrate of high refractive index and a metal oxide hydrate of low refractive index by hydrolysis of the corresponding, water-soluble metal compounds, separation, drying and, if desired, calcining of the material obtained.
    Type: Grant
    Filed: January 11, 2001
    Date of Patent: September 4, 2001
    Assignee: Merck Patent GmbH
    Inventors: Stephanie Andes, Gerd Bauer, Günter Brenner, Dieter Brückner, Michael Schmelz, Andrea Heyland, Matthias Kuntz, Karl Osterried, Gerhard Pfaff
  • Patent number: 6270566
    Abstract: A process is disclosed for coloring building materials with inorganic pigments in the form of microgranulates. The granulates comprise one or more pigments and one or more compounds selected from boron, aluminum, silicon, titanium, zinc and tin.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: August 7, 2001
    Assignee: Bayer AG
    Inventors: Jakob Rademachers, Günther Teichmann
  • Patent number: 6267810
    Abstract: The present invention relates to pigment mixtures containing at least two components, component A being Al2O3 flakes coated with one or more metals, metal oxides and/or metal sulfides and component B being special-effect pigments, and to their use in varnishes, paints, printing inks, masterbatches, plastics and cosmetic formulations.
    Type: Grant
    Filed: December 23, 1999
    Date of Patent: July 31, 2001
    Assignee: Merck Patent Gesellschaft mit beschraenkter Haftung
    Inventors: Gerhard Pfaff, Sabine Schoen, Nishimagi Atsuko