Silicon Containing Patents (Class 106/481)
  • Patent number: 6423773
    Abstract: Polymer coating composition for a plastics substrate including a polymeric binder and an inert filler. The composition also includes polyamide epichlorohydrin and an ionic insolubilizing agent that is capable of reacting with the binder to render the binder insoluble in water.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: July 23, 2002
    Assignee: Arjobex Limited
    Inventor: John Victor Shepherd
  • Patent number: 6419735
    Abstract: The composition is based on a samarium sesquisulphide, it exhibits a samarium purity with respect to other rare earth metals of greater than 99% and it comprises at least one alkali metal or alkaline earth metal element, at least a portion of which is included in the crystal lattice of the said sesquisulphide. According to another embodiment, the composition is based on a sesquisulphide of samarium and of at least one rare earth metal which is solely trivalent and it comprises at least one alkali metal or alkaline earth metal element, at least a portion of which is included in the crystal lattice of the said sesquisulphide. According to a third embodiment, the composition exhibits a samarium purity such that the cerium content is less than 1%. The process consists in reacting samarium, trivalent rare earth metal and alkali metal or alkaline earth metal compounds with a gaseous mixture of hydrogen sulphide and of carbon disulphide.
    Type: Grant
    Filed: May 19, 2000
    Date of Patent: July 16, 2002
    Assignee: Rhodia Chimie
    Inventors: Sylvain Busnot, Pierre Macaudiere
  • Patent number: 6413307
    Abstract: In a method of manufacturing a gold containing pigment, a vaporizable gold compound, a vaporizable compound of another metal, which includes an oxide or a nitride with a melting temperature above the melting temperature of gold, and a reaction gas consisting of a mixture of argon and oxygen are introduced into a first microwave plasma, whereby cores covered with gold clusters are formed from the oxide or nitride and the gold cluster covered cores are subjected to a tempering process at 150° C. to 300° C. for causing coloration of the gold cluster covered oxide or nitride cores.
    Type: Grant
    Filed: November 29, 2000
    Date of Patent: July 2, 2002
    Assignee: Forschungszentrum Karlsruhe
    Inventors: Dieter Vollath, Steffen Heidenreich, Friedrich Wacker
  • Publication number: 20020056399
    Abstract: The present invention relates to a pigment preparation comprising a mixture of coated and/or uncoated SiO2 flakes, one or more special-effect pigments, and a phosphate derivative, and to the use thereof, especially in printing inks.
    Type: Application
    Filed: October 19, 2001
    Publication date: May 16, 2002
    Applicant: Merck Patent GmbH
    Inventors: Sabine Schoen, Reiner Vogt, Norbert Schul, Karl Osterried, Gerhard Herget
  • Publication number: 20020051802
    Abstract: A rod-shaped mesoporous powder which is mainly composed of silicon oxide and has homogenous pore, and obtained by a process comprises, a dissolution step wherein a concentration of 0.3-1.2M of a silicate which is in the range of 0<SiO2/Y2O<2 (Y:alkali metal atom) is dissolved in the presence of a cationic surfactant and the pH is 11 or more, a condensation step wherein the pH is adjusted to 10.5 or less within 30 minutes, a rod micelle is formed with said cationic surfactant and a silicate is condensed on said rod micelle, and a removal step wherein said cationic surfactant is removed from a micelle state condensation which has an outer shell made of the silicate by said condensation.
    Type: Application
    Filed: September 28, 2001
    Publication date: May 2, 2002
    Applicant: Shiseido Co., Ltd.
    Inventors: Shoichiro Shio, Asa Kimura
  • Patent number: 6368400
    Abstract: An absorbing ether-like compound including a siliconethoxy, silicondiethoxy, or silicontriethoxy species attached to a naphthalene or anthracene chromophore via an oxygen linkage is used as an organic light-absorbing compound. The absorbing ether-like compound is incorporated into spin-on glass materials to provide anti-reflective coating materials for deep ultraviolet photolithography. A method of synthesizing the light-absorbing ether compounds is based on the reaction of an alcohol-substituted chromophore with an acetoxysilicon compound in the presence of alcohol. A method of making absorbing spin-on-glass materials including the absorbing ether-like compounds is also provided.
    Type: Grant
    Filed: July 17, 2000
    Date of Patent: April 9, 2002
    Assignee: Honeywell International
    Inventors: Teresa Baldwin, Mary Richey, James S. Drage, Hui-Jung Wu, Richard Spear
  • Patent number: 6365269
    Abstract: The adhesion of plastic to metal surfaces is improved by adding a specific filler in the sheathing material. The filler is formed of spherical SiO2 particles with a graduated diameter distribution defining individual diameter stages wherein the standard deviation in mean particle diameter of at least one diameter stage of said SiO2 particles is less than 10%. Spherical SiO2 particles with a graduated diameter distribution defining individual diameter stages are also mixed together in such ratio to obtain packing densities of 90% or more. Said spherical SiO2 particles with a graduated diameter distribution defining individual diameter stages may also be characterized as having an index of refraction which increases from the center of a particle to the surface.
    Type: Grant
    Filed: November 20, 1998
    Date of Patent: April 2, 2002
    Assignee: Infineon Technologies AG
    Inventors: Alexandra Atzesdorfer, Klaus Heckmann, Josef Thumbs
  • Patent number: 6358574
    Abstract: Crosslinkable LC organosiloxanes exhibiting excellent UV stability, contain units of the general formula 1 [RbMescSiO(4−b−c)/2]  (1) in which R are C1-C4-alkyl radicals, Mes is at least one group of the general formula 2 and, if desired, of the general formula 3, b has the value 0, 1 or 2, and c has the value 0, 1, 2, 3 or 4, with the proviso that the sum of the values of b and c is a maximum of 4, where the Mes groups of the general formulae 2 and 3 exhibit the following structure: —(CH2)p—(O)q—A—[B—A]r—E—F—VN  (2) —(CH2)m—(O)n—(A)t—Q—X  (3) in which A, B, Q, X, E, F, VN, m, p, n, q, t and r have the meanings given in claim 1, with the proviso that the LC organosiloxanes do not constitute a phenyl ester derivative of an aliphatic, aromatic or heteroaromatic carboxylic acids.
    Type: Grant
    Filed: December 6, 1999
    Date of Patent: March 19, 2002
    Assignee: Consortium fur Elektrochemische Industrie GmbH
    Inventors: Norman Häberle, Jürgen Küpfer, Horst Leigeber
  • Patent number: 6358495
    Abstract: To provide a complex which is excellent in transparency and protective ability of UVB region by containing titanium oxide in a specific silica carrier and a cosmetic preparation which has natural finishing i.e., excellent in transparency by the complex and is excellent in protective ability of UVB region, a titanium-silica complex in accordance with the present invention comprises a silica carrier and titanium oxide, wherein said silica carrier is mainly composed of silicon oxide and wherein titanium oxide is contained in said silica carrier.
    Type: Grant
    Filed: March 24, 2000
    Date of Patent: March 19, 2002
    Assignee: Shiseido Co., Ltd.
    Inventors: Shuji Nishihama, Shoichiro Shio
  • Patent number: 6342560
    Abstract: Described are fillers, e.g., inorganic oxides, that have been modified to have a carbon content of greater than 1 weight percent, a sulfur content of greater than 0.1 weight percent, a Silane Conversion Index of at least 0.3 and a Standard Tensile Stress @ 300% elongation of 7 or more. Polymeric compositions that contain such modified fillers are also described.
    Type: Grant
    Filed: August 11, 2000
    Date of Patent: January 29, 2002
    Assignee: PPG Industries Ohio, Inc.
    Inventor: Timothy A. Okel
  • Patent number: 6312601
    Abstract: A process and system for removing heavy metals, fluoride, silica and other contaminants from large volumes of wastewater is disclosed. In the process, a wastewater stream containing the contaminant is treated with a chemical coagulant to create a particle having a diameter greater than 5 microns. Treated wastewater is passed through a microfiltration membrane which physically separates the metal contaminant particle from the wastewater. Commercially available microfiltration membranes having a pore size from 0.5 micron to 5 microns may be used. The treated wastewater flow rate through the microfiltration membranes can range from 700 gallons per square foot of membrane per day (“GFD”) to 1500 GFD. Solids are removed from the membrane surface by periodically backflushing the micro-filtration membranes and draining the filtration vessel within which the membranes are located. The dislodged solid material within the filtration vessel is flushed into a holding tank for further processing of the solids.
    Type: Grant
    Filed: August 30, 2000
    Date of Patent: November 6, 2001
    Assignee: Microbar Incorporated
    Inventors: Stephen D. Allen, Josh H. Golden
  • Patent number: 6262187
    Abstract: Objects of the present invention are to provide colored coating compositions which can form easily a colored glass gel coating film being excellent in water resistance, boiling water resistance, alkali resistance, weather resistance, etc. at low temperatures on the outer surface of glass products, metal products, etc. and to provide colored coating compositions with which colored bottles having no haze can be obtained even if the bottles are coated in a high-humidity environment. The colored coating compositions according to the present invention comprise a sol-gel liquid obtained by polycondensation of phenyltrialkoxysilane or an oligomer thereof, acryl polyol, polyester polyol, polyether polyol and/or lower alkyl polyol (or the acryl polyol, the polyester polyol and/or the polyether polyol and a polyisocyanate resin), and an organic coloring agent.
    Type: Grant
    Filed: January 13, 2000
    Date of Patent: July 17, 2001
    Assignee: Nagase Chemtex Corporation
    Inventors: Tsutomu Minami, Hiroyuki Nakazumi, Yoshiaki Sakashita, Kazuhisa Ishii, Hidefumi Kanazawa, Mikio Ueda, Masayuki Funato
  • Publication number: 20010003358
    Abstract: Scaly silica particles having a laminated structure, consisting essentially of secondary particles of foliar silica, each formed by a plurality of flaky primary particles of scaly silica which are overlaid one on another and aligned face-to-face in parallel with one another, said secondary particles being present independent of one another.
    Type: Application
    Filed: December 6, 2000
    Publication date: June 14, 2001
    Applicant: Asahi Glass Company, Limited
    Inventors: Kunihiko Terase, Masaki Inoue, Atsunari Fujii, Takayoshi Sasaki, Shikou Minohara, Yosimi Ohba
  • Patent number: 6242098
    Abstract: A method for producing a mineral filler and pozzolan product from fly ash is provided in which fly ash is dry processed in an air classifier to obtain a fine fraction having an average particle size of from about 0.1 to 5 microns and a coarse fraction having an average particle size of from about 6 to 20 microns. The fine fraction is then preferably passed through a magnetic separator to remove ferrous iron oxides and may optionally be treated with a surface modifier to form a mineral filler. The coarse fraction is preferably passed through a 100 mesh screen to form a pozzolan product.
    Type: Grant
    Filed: July 19, 1999
    Date of Patent: June 5, 2001
    Assignee: Mineral Resources Technologies, LLC
    Inventors: Robert William Styron, Kamal Seyi Abiodun
  • Patent number: 6231660
    Abstract: A manufactured granular substrate composition suitable for use as a carrier for active chemical agents. The composition includes about 65 wt % or more of one or more mineral components having a bulk density greater than about 70 pounds per cubic foot. The composition also contains about 5 wt % to about 25 wt % of one or more light weight additives and up to 20 wt % of one or more water soluble binders. The resulting manufactured granular substrate is readily dispersable in water and has a bulk density of less than about 55 pounds per cubic foot with a size guide number of about 100 to about 230.
    Type: Grant
    Filed: June 29, 1999
    Date of Patent: May 15, 2001
    Assignees: The National Lime and Stone Co., The Andersons, Inc.
    Inventors: James W. Welshimer, David L. Ashworth, Peter V. Cawlfield, Nadine C. Dunn, Gerald L. Gingrich, Karissa L. Fox, Kim W. Venable, Paul Weinstein, Timothy D. Birthisel
  • Patent number: 6207610
    Abstract: Compacts based on pyrogenically produced silicon dioxide and having the following physical and chemical characteristics: Outer diameter 0.8-20 mm BET surface area 30-400 m2/g Pore volume 0.5-1.3 ml/g Breaking strength 10-250N Composition >99.8 wt. % SiO2 Other constituents <0.2 wt. % Abrasion <5 wt. % Apparent weight 350-750 g/l are produced in that pyrogenically produced silicon dioxide is homogenized with methyl cellulose, microwax and polyethylene glycol with addition of water, dried at a temperature of 80-150° C. and comminuted to a powder, optionally the powder is compressed into compacts, and heat-treated at a temperature of 400 to 1200° C. for a time of 0.5 to 8 hours. These compacts can be used as catalysts or catalyst carriers in vinyl acetate monomer production and ethylene hydration.
    Type: Grant
    Filed: May 16, 1997
    Date of Patent: March 27, 2001
    Assignee: Degussa-Huls AG
    Inventors: Helmfried Krause, Hermanus Lansink Rotgerink, Thomas Tacke, Peter Panster, Roland Burmeister
  • Patent number: 6193795
    Abstract: A method of producing a low structure pyrogenic metal oxide filler is disclosed. The method involves subjecting pyrogenically produced metal oxide agglomerates and aggregates selected from silicon oxide, aluminum oxide, zirconium oxide, or titanium oxide to a dry milling process whereby the pyrogenically produced metal oxide is contacted in an agitating zone with an energy specific force.
    Type: Grant
    Filed: April 29, 1994
    Date of Patent: February 27, 2001
    Assignee: Degussa Corporation
    Inventors: Maria R. Nargiello, Gary J. Bush, Sturgis G. Allen
  • Patent number: 6193794
    Abstract: The iron oxide platelets comprise at least one layer packet comprising A) a colorless coating having a refractive index n≦1.8, and B) a colorless coating having a refractive index n≧2.0.
    Type: Grant
    Filed: March 2, 1999
    Date of Patent: February 27, 2001
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Oliver Seeger, Norbert Mronga
  • Patent number: 6176918
    Abstract: Modified pearl luster pigments for waterborn coating systems, based on a platelet-form substrate coated with metal oxides and, located on the topmost metal oxide layer, a top layer consisting of at least two oxides and/or mixed oxides from the group consisting of silicon dioxide, aluminium oxide, cerium oxide, titanium oxide and zirconium oxide, and on a water-based oligomeric silane system. The oligomeric silane system can be described, for example, by the following approximate structure: [HO[Si(A)(OH)z(CH3)1−zO]a[Si(B)(OH)y(CH3)1−yO]b[Si(E)(OH)w(CH3)1−wO]c[Si(D)(OH)v(CH3)1−vO]dH].
    Type: Grant
    Filed: May 22, 1998
    Date of Patent: January 23, 2001
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung and Huels AG
    Inventors: Ralf Glausch, Nicole Fornoff, Joachim Duschek, Burkhard Standke, Roland Edelmann
  • Patent number: 6156117
    Abstract: A method of preparing a polymer structured pigment slurry which comprises providing an anionic, aqueous slurry including a plurality of solid mineral particles, adding a low molecular weight, cationic polymer in an amount of less than about 0.20% by weight to the slurry and then adding a small amount of an inorganic dispersant to the polymer treated pigment slurry. The Malvern median particle size of the mineral particles treated with the polycationic polymer is less than about 20% larger than the Malvern median particle size of the untreated mineral particles.
    Type: Grant
    Filed: September 1, 1998
    Date of Patent: December 5, 2000
    Assignee: J. M. Huber Corporation
    Inventors: Gary M. Freeman, Sung-Tsuen Liu
  • Patent number: 6156284
    Abstract: An improved process for transforming clays that cannot be utilized in commercial pigment production to low-viscosity pigment for commercial application is described whereby a treated clay is produced having a reduced viscosity as compared to the initial clay when compared at equivalent solids content. The process comprises the steps of: drying the clay; mixing the dried clay with an aqueous solution of an alkali metal salt wherein the alkali metal salt is selected from the group consisting of lithium, potassium, rubidium and cesium salts; extruding the material obtained from alkali metal salt treatment; heat-treating the extruded material and high-shear blunging of the heat-treated material. Typically, a high viscosity clay that has been treated with this five-step procedure will exhibit a viscosity that is about 10% to about 20% of the viscosity of the starting clay.
    Type: Grant
    Filed: May 7, 1999
    Date of Patent: December 5, 2000
    Inventor: Vernon J. Hurst
  • Patent number: 6139960
    Abstract: A method for producing a mineral filler from fly ash is provided in which fly ash is dry processed in an air classifier to obtain a fine fraction having an average particle size of from about 0.1 to 5 microns. The fine fraction is then preferably passed through a magnetic separator to remove ferrous iron oxides and may optionally be treated with a surface modifier. The resulting processed fly ash may be used in a wide variety of filler applications.
    Type: Grant
    Filed: February 17, 1999
    Date of Patent: October 31, 2000
    Assignee: Mineral Resource Technologies, LLC
    Inventors: Robert William Styron, Kamal Seyi Abiodun
  • Patent number: 6133466
    Abstract: Mixtures of catenate and cyclic siloxane oligomers of formula I and II ##STR1## wherein the substituents R consist of 3-methacryloxypropyl or 3-acryloxypropyl groups and methoxy, ethoxy and/or propoxy groups alone or together with C.sub.1 -C.sub.18 alkyl, fluoroalkyl, isoalkyl or cycloalkyl groups and/or C.sub.6 -C.sub.12 aryl groups and where not more than one 3-methacryloxypropyl or 3-acryloxypropyl group is attached to one silicon atom and the degree of oligomerization of compounds of the formula I is within the range 2<m<25 and of compounds of the formula II is within the range 2<n<8 and the quotient of the molar proportion of Si/alkoxy groups is .gtoreq.0.5.
    Type: Grant
    Filed: August 2, 1999
    Date of Patent: October 17, 2000
    Assignee: Degussa-Huels Aktiengesellschaft
    Inventors: Roland Edelmann, Albert-Johannes Frings, Michael Horn, Peter Jenkner, Ralf Laven, Helmut Mack, Jaroslaw Monkiewicz, Wolfgang-Wilhelm Orlia, Burkhard Standke
  • Patent number: 6113682
    Abstract: Disclosed herein is a method for preparation of composite pigments for make-up cosmetics having improved skin-adhesion and spreadability, and excellent skin color-expression, and improved water resistance by silicon polymer coated on the surface of the complex particle of flaky silica and titanium dioxide coated thereon.
    Type: Grant
    Filed: November 6, 1998
    Date of Patent: September 5, 2000
    Assignees: Pacific Corporation, Bokwang Chemical Co. Ltd.
    Inventors: Dal Sik Shin, Dong Myong Kim, Sung Ho Lee, Ok Sob Lee, Kwang Soo Kim, Ju Hong Min
  • Patent number: 6110266
    Abstract: The present invention relates to pigment preparations containing(a) at least one pigment having an average primary particle size of 0.1 to 50 nm selected from the group consisting of carbides, nitrides, borides, and silicides of the elements Ti, Zr, Hf, Si, Ge, and Sn,(b) at least one dispersant having a weight average molecular weight (M.sub.w) greater than 1000, and(c) water.The invention further relates to the use of such pigment preparations in inks for ink-jet printing.
    Type: Grant
    Filed: October 28, 1998
    Date of Patent: August 29, 2000
    Assignee: Bayer Aktiengesellschaft
    Inventors: Juan Gonzalez-Blanco, Werner Hoheisel, Peter Roger Nyssen, Dirk Pfutzenreuter
  • Patent number: 6103003
    Abstract: A textured coating and method of applying same. The coating comprises a high-solids polyamide epoxy having a resin and a hardener, and the epoxy is mixed with a texture aggregate filler being selected from the group consisting of perlite, glass microballoons, glass bubbles, phenolic microballoons, Q cel microspheres, and extendospheres, with the filler preferably being expanded perlite of a size such that about 20% maximum by weight is retained on a U.S. Std. Sieve No. 50 and such that about 65% maximum by weight is retained on a U.S. Std. Sieve No. 100. The epoxy and the filler are mixed in about equal volume.
    Type: Grant
    Filed: March 28, 1998
    Date of Patent: August 15, 2000
    Inventor: C. Burgess Ledbetter
  • Patent number: 6086668
    Abstract: Metal oxide particles having a substantial uniform and homogeneous (across-particle) coating of a metal oxide or organofunctionalized metal oxide are disclosed and are prepared by hydrolysis of a monomeric precursor to the coating.
    Type: Grant
    Filed: October 2, 1998
    Date of Patent: July 11, 2000
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: William Edwin Farneth, Norman Herron
  • Patent number: 6068688
    Abstract: A modified particle is disclosed wherein a particle has an attached group having the formula: ##STR1## wherein Ar represents an aromatic group; R.sup.1 represents a bond, an arylene group, an alkylene ##STR2## wherein R.sup.4 is an alkyl or alkylene group or an aryl or arylene group; R.sup.2 and R.sup.3, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.5, --NHR.sup.5, --NR.sup.5 R.sup.5, or --SR.sup.5, wherein R.sup.5, which is the same or different, represents an alkyl group or an aryl group; and SFR represents a stable free radical. Also disclosed is a modified particle or aggregate having attached a group having the formula: ##STR3## wherein CoupA represents a Si-containing group, a Ti-containing group, or a Zr-containing group; R.sup.8 and R.sup.9, which can be the same or different, represent hydrogen, an alkyl group, an aryl group, --OR.sup.10, --NHR.sup.10, --NR.sup.10 R.sup.10, or --SR.sup.10, wherein R.sup.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: May 30, 2000
    Assignee: Cabot Corporation
    Inventors: Robert S. Whitehouse, Russell L. Warley, Thimma R. Rawalpally, Hairuo Tu
  • Patent number: 6068694
    Abstract: This invention relates to aggregates comprised of particles which contain silicon dioxide and to elastomers reinforced therewith. The invention also relates to tires having treads composed of such reinforced elastomers.
    Type: Grant
    Filed: March 2, 1998
    Date of Patent: May 30, 2000
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Yvon Andre Bernard, Uwe Ernst Frank, Wolfgang Lauer, Thierry Florent Edme Materne, Friedrich Visel, Rene Jean Zimmer
  • Patent number: 6068692
    Abstract: The invention relates to a process for manufacturing decorated ceramic and glass articles according to which a ceramic dye composition, including fine particles which comprise ceramic pigments and binding medium resin(s) as well as possible further additives, is applied by means of an electrophotographic reproduction process onto a transfer means, for example paper coated with gum arabic, the transfer means coated with the ceramic dye composition is applied onto the ceramic or glass article, and after removal of the transfer means, the ceramic dye composition is combined with the ceramic or glass article by baking. The invention also includes decorative ceramic or glass articles obtainable by means of the above process and a ceramic dye composition of the type mentioned above.
    Type: Grant
    Filed: March 22, 1999
    Date of Patent: May 30, 2000
    Inventor: Michael Zimmer
  • Patent number: 6063179
    Abstract: Goniochromatic luster pigments based on silicon dioxide platlets, CVD coated withA) a nonselectively absorbing filmlike layer at least partially transparent to visible light, andB) if desired an outer layer which consists essentially of colorless or selectively absorbing metal oxide and/or comprises phosphate, chromate and/or vanadate,are prepared and used for coloring paints, inks, including printing inks, plastics, glasses, ceramic products and decorative cosmetic preparations.
    Type: Grant
    Filed: October 13, 1998
    Date of Patent: May 16, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Raimund Schmid, Norbert Mronga
  • Patent number: 6004391
    Abstract: Purple pigments according to the invention based on a stovable support material, in particular a glass frit, having a coat applied by coprecipitation of an oxide hydrate of one or more elements from the range comprising Al, Si, Sn, Pb, Ti, Nb, Ta, Sc, Y, La, Ce and Zn and a water-insoluble gold compound or colloidal gold are distinguished from prior art pigments of a similar composition by improved color stability in high temperature firing. The pigments are obtainable in the aqueous phase by coprecipitation of an oxide hydrate and a gold compound or colloidal gold in the presence of a support material and in the absence of a reducing agent. Pigments containing gold compounds assume a purple color on heat treatment or by chemical reduction. Preferred pigments containing gold compounds, which may directly be used as decorative colorants, conveniently develop their color during firing of the decoration.
    Type: Grant
    Filed: November 28, 1997
    Date of Patent: December 21, 1999
    Assignee: Cerdec Aktiengesellschaft Keramische Farben
    Inventors: Hans-Peter Letschert, Jenny Wilfert
  • Patent number: 5997627
    Abstract: The disclosure describes pigment compositions containing a small particle size porous filler and a pigment, and their use for preparing effect coating compositions which produce thin film finishes exhibiting strong lightness and color flop with a pronounced three dimensional effect. The thin film finishes are particularly interesting as automotive finishes.
    Type: Grant
    Filed: November 12, 1997
    Date of Patent: December 7, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Fridolin Babler
  • Patent number: 5948471
    Abstract: The invention relates to a process for manufacturing decorated ceramic and glass articles according to which a ceramic dye composition, including fine particles which comprise ceramic pigments and binding medium resin(s) as well as possible further additives, is applied by means of an electrophotographic reproduction process onto a transfer means, for example paper coated with gum arabic, the transfer means coated with the ceramic dye composition is applied onto the ceramic or glass article, and after removal of the transfer means, the ceramic dye composition is combined with the ceramic or glass article by baking. The invention also includes decorative ceramic or glass articles obtainable by means of the above process and a ceramic dye composition of the type mentioned above.
    Type: Grant
    Filed: February 20, 1997
    Date of Patent: September 7, 1999
    Inventor: Michael Zimmer
  • Patent number: 5935314
    Abstract: By removing a fraction of fine particles having a particle size of less than 2 .mu.m from starting inorganic filler particles having a mean particle size of 10-50 .mu.m and adding thereto particles having a mean particle size of 0.1-2 .mu.m and a specific surface area of 3-10 m.sup.2 /g (BET), there is obtained a particulate inorganic filler having a mean particle size of 5-40 .mu.m. When a large amount of the inorganic filler is loaded in an epoxy resin composition, the composition maintains a low melt viscosity enough to mold and is effective for encapsulating a semiconductor device without causing die pad deformation and wire deformation. The encapsulated semiconductor device is highly reliable.
    Type: Grant
    Filed: August 28, 1997
    Date of Patent: August 10, 1999
    Assignees: Mitsubishi Denki Kabushiki Kaisha, Shin-Etsu Chemical Ltd., Co.
    Inventors: Noriaki Higuchi, Takaaki Fukumoto, Toshio Shiobara, Eiichi Asano, Kazutoshi Tomiyoshi
  • Patent number: 5891235
    Abstract: An additive for resins, a process for preparing amorphous definite particles used as an inorganic additive, and an olefin resin composition blended with the additive, and an agricultural film blended with the additive and a lithium-aluminum composite hydroxide carbonate. The additive for resins comprises amorphous definite particles having (1) a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 of from 2.1 to 3.3 on the basis of oxides, (2) an average particle diameter of from 0.3 to 10 .mu.m, (3) a moisture regain at equilibrium (RH90%) of not greater than 10%, (4) a bulk density of from 0.5 to 1.2 g/ml, and (5) a pH in the form of an aqueous suspension of from 6 to 10, said amorphous definite particles being obtained by acid-treating and then heat-treating a Pc zeolite having a spherical particle shape, a notched surface and a molar ratio SiO.sub.2 /Al.sub.2 O.sub.3 of from 2 to 3.
    Type: Grant
    Filed: May 22, 1997
    Date of Patent: April 6, 1999
    Assignee: Mizusawa Industrial Chemicals, Ltd.
    Inventors: Kazuhiko Suzuki, Hiroshi Ogawa, Hideyuki Nakagawa, Hiroo Inoue
  • Patent number: 5891237
    Abstract: Spherical agglomerates of finely divided material such as inorganic oxides are prepared by admixing a slurry of finely divided material with a solution of a partially neutralised carboxylic acid.
    Type: Grant
    Filed: October 8, 1997
    Date of Patent: April 6, 1999
    Assignee: Millennium Inorganic Chemicals, Ltd.
    Inventor: Stephen Phillip Kinniard
  • Patent number: 5858906
    Abstract: Compacts produced from a pyrogenically produced oxide, magnesium stearate, methyl cellulose and urea are mixed together in the presence of water, compacted, dried, comminuted to a powder, and the powder is pressed with an isostatic press to compacts and the compacts tempered. The resulting compacts have an outside diameter of 16 to 100 mm.
    Type: Grant
    Filed: August 1, 1995
    Date of Patent: January 12, 1999
    Assignee: Degussa Aktiengesellschaft
    Inventors: Klaus Deller, Helmfried Krause, Roland Burmeister
  • Patent number: 5770640
    Abstract: Finishing agents comprise the combination of an alkoxysilane surface active agent, a silanol condensing catalyst, and a nonaqueous liquid or solid medium, or the combination of an alkoxysilane surface active agent, an acid catalyst and a liquid or solid medium. In the latter embodiment, it is preferred that at least one of the alkoxysilane surface active agent and the acid catalyst be microencapsuled. The finishing agent permits formation of chemically adsorbed protecting films. Such protecting films are used for substrates of such equipments as electronics products, electric domestic products, automobiles, industrial equipment, mirrors, lenses for glasses and the like. The protecting films have a durability and heat, weather and abrasion resistance, and also water and oil repellent properties.
    Type: Grant
    Filed: January 2, 1997
    Date of Patent: June 23, 1998
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Kazufumi Ogawa
  • Patent number: 5766335
    Abstract: The invention relates to colored luster pigments consisting of a transparent or metallic reflecting core, of a coating consisting of at least one silicon oxide of the composition SiO.sub.0.25 to SiO.sub.0.95 and of further optional coatings, to coating processes by coating metallic silicon in the presence of oxygen, if required with changing its partial pressure, as well as to the use of these luster pigments for pigmenting plastic materials, paints and printing inks, and to pigmented compositions comprising these luster pigments.
    Type: Grant
    Filed: April 23, 1997
    Date of Patent: June 16, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Patrice Bujard, Natacha Bonnard
  • Patent number: 5753026
    Abstract: Reaction spray process for preparing inclusion pigments by suspending the pigment to be encapsulated in an aqueous solution or suspension of a precursor of the inclusion material, spraying the suspension, with or without the addition of nitric acid and fuel, in a tubular reactor heated at from 850.degree. to 1100.degree. C., separating the inclusion pigment from the product stream and, if desired post-calcining the pigment at a temperature of at least 816.degree. C.
    Type: Grant
    Filed: October 21, 1996
    Date of Patent: May 19, 1998
    Assignee: Merck Patent Gesellschaft mit Beschrankter Haftung
    Inventors: Mathias Kuntz, Hubert Linne, Joachim Weitzel, Dieter Heinz, Rodney Riddle
  • Patent number: 5747003
    Abstract: A statistically large population of particles of amorphous precipitated silica comprising pigmentary phase particles and glassy phase particles and having a glassy phase fraction in the range of from 0.3 to 30 area percent is useful as an abrasive for dentifrice compositions, especially toothpaste.
    Type: Grant
    Filed: March 22, 1995
    Date of Patent: May 5, 1998
    Assignee: PPG Industries, Inc.
    Inventors: Shantilal M. Mohnot, Harold E. Swift, Thomas G. Krivak, Robert H. Fear, Laura M. Randall, Laurence E. Jones
  • Patent number: 5738718
    Abstract: A process for producing zinc oxide-containing spherical silica, which comprises emulsifying, in an organic solvent containing a surfactant, a dispersion having zinc oxide with a particle size of from 0.005 to 0.5 .mu.m dispersed in an aqueous alkali metal silicate solution in an amount of from 10 to 70 wt % based on the total amount of zinc oxide and SiO.sub.2 in the aqueous alkali metal silicate solution, followed by gelation of the resulting emulsion with carbon dioxide gas.
    Type: Grant
    Filed: April 7, 1997
    Date of Patent: April 14, 1998
    Assignee: Asahi Glass Company Ltd.
    Inventors: Hiroo Mori, Hiroshi Funaki, Kunihiko Terase, Hachirou Hirano
  • Patent number: 5735944
    Abstract: This invention relates to free flowing additive preparations, particularly for powder coatings, which can be obtained by incorporating one or more liquid or viscous-adhesive additives in a wax melt consisting of one or more waxes, cooling the mixture obtained to a temperature below its melting point, and comminuting the solidified mixture or converting the mixture which is still liquid into a finely divided form and cooling the particles obtained. The invention also relates to a process for producing such preparations and to their use.
    Type: Grant
    Filed: May 20, 1996
    Date of Patent: April 7, 1998
    Assignee: BYK-Chemie GmbH
    Inventors: Karlheinz Haubennestel, Alfred Bubat
  • Patent number: 5720806
    Abstract: The invention provides a filler for ink jet recording paper which is composed of an amorphous silica containing 0.3-1.0% by weight of Al.sub.2 O.sub.3 and having a BET specific surface area of 250-400 m.sup.2 /g, a mean particle size of 3.6-10.0 .mu.m and a peak position of pore radius as measured by mercury injection method of 37.5-75 angstrom. A coat layer of ink jet recording paper formed of this filler excels not only in true circle property of dots and ink absorbing property when printed by ink jet recording system, but also in surface strength and writing quality. Furthermore, the coating liquid containing this filler has a low viscosity and hence exhibits good coating workability.
    Type: Grant
    Filed: September 27, 1996
    Date of Patent: February 24, 1998
    Assignee: Tokuyama Corporation
    Inventors: Tsuneo Fujii, Hiroshi Tonoike, Daisaku Isomura
  • Patent number: 5667892
    Abstract: Multicolored flakes with two faces, having a thickness between approximately 60 .mu.m and approximately 200 .mu.m, consist in a film of uniform color of polymer, copolymer or terpolymer, or a mixture thereof, having on at least part of one face only a decorative coating different from the uniform color.
    Type: Grant
    Filed: April 18, 1995
    Date of Patent: September 16, 1997
    Assignee: Sarl Quadra Industries
    Inventor: Robert Marillier
  • Patent number: 5601807
    Abstract: The invention is directed to provide novel sunscreen materials which are to protect human skin from the harmful ultraviolet radiation. Said sunscreen materials, designated Bolite-S, according to the invention having a composition, expressed in terms of moles of oxides as follows:mRO:vB.sub.2 O.sub.3 :wFe.sub.2 O.sub.3 :xSiO.sub.2 :yTiO.sub.2 :zH.sub.2 Owherein "R" is selected from the group consisting of hydrogen, alkyl groups containing 1-4 carbon atoms, and mixtures thereof, "m" is a value between 0 and about 1200, "v" is a value between 0 and about 500, "w" is a value between 0 and about 100, "x" is a value between 0 and about 200, "y" is a value between 1 and about 300 and "z" is a value of from 0 to about 300, said Bolite-S materials in calcined form having a characteristic X-ray powder diffraction pattern which contains the interplanar spacings and their assigned strengths set forth in Table 1.
    Type: Grant
    Filed: May 19, 1995
    Date of Patent: February 11, 1997
    Inventor: Hisatoshi Asaoka
  • Patent number: 5597408
    Abstract: A composition having 1.0-50.0 wt % of a compound having both a structure of organosilane, organosilazane, or organosiloxazane and a structure of a dye compound which has light-absorbing capabilities in a particular wavelength band, 50.0-99.0 wt % of solvent, and optionally 0"10 wt % of a water-soluble polymer, improves adhesion to a photoresist film and anti-reflection characteristics in exposure.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: January 28, 1997
    Assignee: Samsung Electronics Co., Ltd.
    Inventor: Young-joon Choi
  • Patent number: 5543538
    Abstract: Acryloyloxypropylalkoxysilane compositions containing one or more acryloyloxypropylalkoxysilanes of the formula ##STR1## wherein R.sup.1 and R.sup.2 are, independently, identical or different alkyl groups having 1 to 4 carbon atoms, m is an integer from 0 to 2 and R is hydrogen or a methyl group, and an amount of one or more tertiary amines sufficient to provide a pH higher than the intrinsic pH of the acryloyloxypropylalkoxysilane itself and to improve shelf storage, a process for their preparation, and to their use in preparing silicon-containing coating materials and paints.
    Type: Grant
    Filed: August 30, 1995
    Date of Patent: August 6, 1996
    Assignee: Huels Aktiengesellschaft
    Inventors: Margret Haas, Guenther Bernhardt
  • Patent number: 5536447
    Abstract: Substrate-free electrically conductive pigment containing 90 to 98% by weight of tin oxide and 1 to 10% by weight of at least one doping substance consisting of an oxide of an element form main group III, IV or V of the Periodic Table with the exception of tin, which pigment is preparable by intimate mixing of tin dioxide with at least one doping substance, followed by calcining of the resulting mixture at 800.degree. to 1,000.degree. C. for 30 to 120 minutes.
    Type: Grant
    Filed: September 30, 1994
    Date of Patent: July 16, 1996
    Assignee: Merck Patent Gesellschaft mit beschrankter Haftung
    Inventors: Gerhard Pfaff, Gerd Bauer