Organic Material Containing Patents (Class 106/487)
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Patent number: 8083848Abstract: Disclosed herein are kaolin compositions, such as beneficiated fine sedimentary kaolin compositions. The beneficiated fine sedimentary kaolins may be obtained from the upper bed of the Rio Capim Kaolin deposit. The compositions may have at least one property chosen from a low iron content and low Hinckley crystallinity index, such as Fe2O3 in an amount less than about 0.8% by weight relative to the total weight of the solids content and wherein the Hinckley crystallinity index of the kaolin is less than about 0.5. Also disclosed are products obtained therefrom, such as paint and paper coating compositions.Type: GrantFiled: February 8, 2006Date of Patent: December 27, 2011Assignee: Imerys Pigments, Inc.Inventors: Robert J. Pruett, Paula R. Alves
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Publication number: 20110237726Abstract: The present invention relates to treated mineral filler products comprising a) at least one mineral filler, b) a treatment layer located on the surface of said mineral filler(s), said treatment layer comprising at least one saturated C8 to C24 aliphatic carboxylic acid; and at least one di and/or trivalent cation salt of one or more saturated C8 to C24 aliphatic carboxylic acid, wherein the weight ratio of all of said aliphatic carboxylic acid salt(s):all of said aliphatic carboxylic acid(s) is from 51:49 to 75:25; and said treatment layer is present in an amount of at least 2.5 mg/m2 of said mineral filler. Furthermore the present invention relates to processes to prepare such treated mineral filler products, and to their uses, notably in plastic applications, and especially in polypropylene (PP)- or polyethylene (PE)-based breathable or extrusion coating film applications.Type: ApplicationFiled: August 19, 2009Publication date: September 29, 2011Inventors: Patrick A.C. Gane, Matthias Buri, René Burkhalter
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Patent number: 8007586Abstract: A clay plaster formulation and application. The clay plaster is a mixture of various clays, and aggregate. This plaster is both functional and decorative and is for use on new and existing construction.Type: GrantFiled: June 23, 2010Date of Patent: August 30, 2011Inventor: Armin Croft Elsaesser
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Publication number: 20110155018Abstract: Disclosed herein are stabilized kaolin slurries comprising a kaolin comprising no more than about 80% by weight of particles having an equivalent spherical diameter of less than 2 microns and at least one stabilizer, wherein the stabilized kaolin slurry has a 28-day pour test result of at least about 80% poured. Also disclosed are methods of making such stabilized kaolin slurries.Type: ApplicationFiled: October 22, 2010Publication date: June 30, 2011Inventors: Jun Yuan, Michael J. Garska, Robert J. Pruett
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Publication number: 20110144251Abstract: A coated particulate solid composition includes a particulate inorganic solid having deposited on its surface a treatment oil comprising lipids. The particulate inorganic solid can include a base particle of titanium dioxide, zinc sulfide, zinc oxide, iron oxide, lead oxide, aluminum oxide, silicon dioxide, zirconium oxide and/or chromium oxide. The treatment oil is optionally a vegetable oil. The treatment oil containing lipids optionally contains glycerides such as triglycerides, and diglycerides, and can contain phospholipids. In one embodiment, the coated particulate solid composition includes particulate titanium dioxide, wherein the treatment oil provides increased bulk density, and enhanced dispersibility in plastic as well as improved lacing resistance.Type: ApplicationFiled: December 16, 2009Publication date: June 16, 2011Inventor: Modasser El-Shoubary
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Publication number: 20110123792Abstract: A hybrid pigment composition is provided including a pigment or a dye and a fibrous clay. The pigment composition has higher reflectance in a near infrared region than a visible light region of the electromagnetic spectrum. The fibrous clay can be selected from palygorskite, sepiolite, and mixtures thereof. The hybrid pigment composition is tunable to provide high reflectance at a desired wavelength in the near infrared region.Type: ApplicationFiled: March 10, 2009Publication date: May 26, 2011Inventor: Lori Niewold
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Publication number: 20110113986Abstract: A hybrid pigment composition and method of forming the hybrid pigment composition is provided. The hybrid pigment composition is formed from a fibrous clay and a dye or pigment. The dye or pigment includes perinones, diphenylmethanes, acridines, xanthenes, triarylmethanes, thiazines, indophenols, indulines, nigrosines, aminoazobenzenes, anilines, monoazos, benzimidazoles, diazos, phthalocyanines, quinacridones, metal complexes, azo/metal complexes, and mixtures thereof.Type: ApplicationFiled: March 10, 2009Publication date: May 19, 2011Inventors: Lori Ann Niewold, Robyn Torres, Gary E. Williams
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Patent number: 7875151Abstract: A particulate product comprising kaolin produced from a method wherein the kaolin of a feed suspension is such that not more than 30% by weight has a particle size less than 2 ?m and not more than 30% by weight has a particle size greater than 10 ?m, wherein the kaolin of a product suspension produced is such that not more than 10% by weight has a particle size greater than 10 ?m and not more than 10% by weight has a particle size less than 0.25 ?m, and wherein the particulate product comprises kaolin produced from a fine fraction suspension.Type: GrantFiled: September 19, 2008Date of Patent: January 25, 2011Assignee: Imerys Minerals Ltd.Inventors: Philip Kenneth Johns, David Leslie Light
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Publication number: 20100319585Abstract: Disclosed herein are defoamers comprising ethylene glycol, a defoaming hydrocarbon base fluid, and a non-ionic surfactant wherein the hydrocarbon base fluid comprises an internal olefin or a straight-chain n-alcohol, and wherein the non-ionic surfactant is present in the defoamer in an amount in the range of from about 1% to about 10% by weight of the defoamer. Also disclosed herein are cement compositions comprising water, hydraulic cement, and a defoamer, wherein the defoamer comprises ethylene glycol, a non-ionic surfactant, and a defoaming hydrocarbon base fluid wherein the hydrocarbon base fluid comprises an internal olefin or a straight-chain n-alcohol, and wherein the non-ionic surfactant is present in the defoamer in an amount in the range of from about 1% to about 10% by weight of the defoamer.Type: ApplicationFiled: August 30, 2010Publication date: December 23, 2010Inventors: Michael J. Szymanski, Samuel J. Lewis, J. Michael Wilson, Arron L. Karcher
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Patent number: 7842632Abstract: A pulling roll for glass manufacture comprised of a high-temperature millboard material. The millboard comprises aluminosilicate refractory fiber, silicate, mica, and kaolin clay. A method of manufacturing a pulling roll is disclosed, together with a roll produced by the methods disclosed herein. The method comprises forming a pulling roll and densifying at least a portion of the pulling roll by exposing to the pulling roll to high temperatures.Type: GrantFiled: February 10, 2009Date of Patent: November 30, 2010Assignee: Corning IncorporatedInventors: Dean Veral Neubauer, Maurice Lacasse
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Publication number: 20100298482Abstract: An organic-inorganic hybrid pigment composition is provided comprising an organic pigment, an inorganic pigment, and a fibrous clay. The fibrous clay can be selected from palygorskite, sepiolite, or a combination thereof. The inorganic pigment is selected from rutile pigments, spinel pigments, bismuth vanadate pigments, cerium sulfide pigments, and combinations thereof. The organic pigment is selected from anthraquinone pigments, anthrathrone pigments, anthrapyrimidine pigments, azo pigments, azomethine pigments, quinacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, inanthrone pigments, isoindoline pigments, metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments, pyranthrone pigments, pyrazolo-quinazolone pigments, thioindigo pigments, and combinations thereof.Type: ApplicationFiled: January 21, 2009Publication date: November 25, 2010Inventors: Lori A. Niewold, Robyn Torres, Gary E. Williams
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Patent number: 7806978Abstract: The present invention relates to a kaolin composition having improved physical properties, for example, for use in the production of paper products. The composition can comprise kaolin having a shape factor of at least about 20. The kaolin can have a particle size distribution such that at least about 94% by weight of the kaolin can have an esd of less than about 2 ?m and/or at least about 80% by weight of the kaolin can have an esd of less than 1 ?m. The amount of the kaolin having an esd of less than about 0.25 ?m can range from about 25% to about 60% by weight. The Hercules viscosity of the kaolin product is less than 4000 rpm at 18 dynes at 63% solids and less than 1500 rpm at 18 dynes at 69% solids when measured using the “A” bob. The present invention also relates to an improved method for making the kaolin product from sedimentary kaolin.Type: GrantFiled: December 15, 2003Date of Patent: October 5, 2010Assignee: Imerys Pigments, Inc.Inventors: Robert J. Pruett, Jun Yuan, Bomi M. Bilimoria, Roger W. Wygant, Anthony V. Lyons
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Patent number: 7789960Abstract: A clay plaster formulation and application. The clay plaster is a mixture of various clays, and aggregate. This plaster is both functional and decorative and is for use on new and existing construction.Type: GrantFiled: February 3, 2009Date of Patent: September 7, 2010Inventor: Armin Croft Elsaesser
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Patent number: 7758691Abstract: The invention relates to interspersed clay, comprising clay and a seaweed extract used as an interspacing component, particularly an ulva extract. The invention also relates to a method for the preparation thereof and to foodstuffs and nanocomposites comprising said interspersed clay.Type: GrantFiled: January 21, 2005Date of Patent: July 20, 2010Inventors: Herve Demais, Jocelyne Brendle, Herve Le Deit, Anca Laza, Luc Lurton, Dominique Brault
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Patent number: 7740682Abstract: An improved composite material, and method of manufacture thereof, comprising varying amounts tungsten powder, or metal/alloy powder of similar density, and clay or silicone is disclosed. The improved composite material may be useful as a replacement for lead and lead-based composites where similar densities are required but the use of lead is undesirable. The disclosed composite material permits a large variety of tungsten powder particle sizes to be utilized and results in improved ductility over known tungsten powder composites.Type: GrantFiled: July 19, 2006Date of Patent: June 22, 2010Inventors: Randall C. Ragan, Randall M. Ragan, Richard Vaughn Culbertson
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Patent number: 7727324Abstract: Disclosed herein is a kaolin composition having nanosize dimensions. At least about 75% of the kaolin particles by weight have an equivalent spherical diameter (esd) of less than about 0.25 ?m. The kaolin can also have a particle size distribution wherein at least about 99% of the particles by weight have an esd of less than about 2 ?m, and/or wherein at least about 98% of the particles by weight have an esd of less than about 1 ?m, and/or wherein at least about 97% of the particles by weight have an esd of less than about 0.5 ?m. The kaolin can have a mean diameter ranging from about 0.075 ?m to about 0.2 ?m, and a shape factor of about 30 or less.Type: GrantFiled: April 28, 2005Date of Patent: June 1, 2010Assignee: Imerys Pigments, Inc.Inventors: H. Vincent Brown, Robert J. Pruett
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Publication number: 20100031852Abstract: Water repellents based on reactive siloxanes with polyfunctional silylalkoxy modification of the siloxane backbone and processes for hydrophobizing mineral fiber components.Type: ApplicationFiled: August 5, 2009Publication date: February 11, 2010Inventors: Sascha Herrwerth, Frank Koenig, Michael Ferenz, Christian Mund
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Patent number: 7641729Abstract: A ball clay powder having a moisture content of less than 5% and at least about 25% of indigenous silica, said powder comprising a blend of at least two natural ball clays, wherein one of the ball clays is naturally silica rich and has at least about 40% indigenous silica.Type: GrantFiled: November 7, 2006Date of Patent: January 5, 2010Assignee: Unimin CorporationInventors: Claud E. Westbrook, Russell J. Fish
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Patent number: 7611575Abstract: The present invention relates to coarse calcined kaolin slurries having a high solids content. The invention also relates to methods of making such slurries. The resulting slurries can have a solids content of at least about 58% by weight wherein at least about 40% by weight of the calcined kaolin particles has a particle size of at least about 1 ?m. The slurries can be stabilized where the solids show little settling from suspension. The slurries have many uses, including fillers or extenders in paint and coating compositions for paper or paper board. More generally, the inventive products may be used wherever calcined kaolins are used. The present invention also related to coarse calcined kaolin slurries having a multimodal particle size distribution and a high solids content.Type: GrantFiled: December 1, 2003Date of Patent: November 3, 2009Assignee: Imerys Pigments, Inc.Inventors: Edward J. Sare, Tommy L. Adkins, Stephen C. Raper
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Patent number: 7597755Abstract: A pigment product for use in a coating composition to provide a gloss coating on paper, the pigment product comprising a processed particulate kaolin having a particle size distribution such that at least about 80% by weight of the particles have an equivalent spherical diameter less than about 2 p,m and in the range of from about 10% to about 20% by weight of the particles have an equivalent spherical diameter less than about 0.25 wm, the particles have a shape factor in the range of from about 20 to about 36 and the particles have a particle steepness in the range of about greater than about 35, more preferably in the range of about 35 to about 40, and wherein the kaolin is derived from a secondary kaolin source.Type: GrantFiled: August 15, 2003Date of Patent: October 6, 2009Assignee: Imerys Pigments, Inc.Inventors: David L. Light, Christopher R. L. Golley, Ernest Gay, Milton Constantin
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Patent number: 7563317Abstract: Silanised, structurally modified silicas, characterised by groups fixed on the surface, the groups being alkylsilyl (SiCnH2n+1, with n=2-18). They are produced in that pyrogenically produced silicas are treated with the silanising agent and structurally modified. They are used to improve scratch resistance in lacquers.Type: GrantFiled: July 29, 2003Date of Patent: July 21, 2009Assignee: Degussa AGInventors: Jürgen Meyer, Stephanie Frahn, Manfred Ettlinger
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Publication number: 20090145333Abstract: A method for dispersing a pigment in a solvent comprises mixing the pigment in a nanoscale with clay in a layered or platelet form and mixing the resultant mixture with the solvent. The method is based on geometric inhomogeneity and mutually exclusive aggregation. The layered or platelet clay having a high aspect ratio is provided to hinder aggregation of the pigment nanoparticles. The pigment nanoparticles can be stably dispersed in a matrix containing an organic solvent and water without aggregation again.Type: ApplicationFiled: July 18, 2008Publication date: June 11, 2009Inventors: Jiang-Jen Lin, Yi-Fen Lan, Yen-Chi Hsu
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Publication number: 20090050021Abstract: A process of producing a kaolin product for paper coating includes mining kaolin ores by hydromechanization and then producing kaolin slurry; classifying by centrifugal sedimentation; chemical bleaching; eliminating iron ions by circular rinsing; removing water by pressure filtration; producing slurry by dispersing filter cakes, in which complex dispersants, pH adjustor and intercalator are added; delaminating; classifying by vibrating sieve; and spray drying: spray driers are restructured by adding insulating layers on packing auger, elevator scoop and bunker at first; the kaolin slurry J which has passed through vibrating sieves is dried in high speed centrifugal spray drying tower and the moisture of kaolin powder is controlled in 3 wt. %-5 wt. %, and the kaolin product for paper coating is obtained. The process characterizes in stable properties, high efficiency, and high viscosity content and fine particle size of the kaolin products produced.Type: ApplicationFiled: August 3, 2008Publication date: February 26, 2009Applicants: CHINA UNIVERSITY OF GEOSCIENCES (Wu Han), MAOMING PETROCHEMICAL MINING CO., LTD.Inventors: Chunjie Yan, Xiaoyan Zhu, Jieyu Chen, Shujie Hai, Jielin Xu, Xiaoming Chen, Yizhi Cui, Weiqing Zeng
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Patent number: 7494541Abstract: Disclosed are methods of processing kaolin to produce two distinct grades of kaolin in a simultaneous manner. The methods involve processing kaolin by degritting a kaolin crude; subjecting the degritted kaolin crude to flotation to provide a kaolin having reduced titania content; ozonating the kaolin having reduced titania content; centrifuging the kaolin to provide a coarse stream and fine stream; refining the coarse stream into a coarse engineered kaolin pigment; and refining the fine stream into a fine glossing kaolin pigment. Also disclosed are systems for the automated processing of kaolin to produce two distinct grades of kaolin with real time feedback.Type: GrantFiled: July 7, 2004Date of Patent: February 24, 2009Assignee: BASF CorporationInventors: Sharad Mathur, Kenneth W. Folmar, David Kirk Thompson, Barry L. Daniels
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Patent number: 7485186Abstract: A clay plaster formulation and application. The clay plaster is a mixture of various clays, and aggregate. This plaster is both functional and decorative and is for use on new and existing construction.Type: GrantFiled: June 17, 2003Date of Patent: February 3, 2009Assignee: American Clay Enterprises, LLCInventor: Armin Croft Elsaesser
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Publication number: 20080265222Abstract: Multifunctional surface-modified cellulose-containing fibers, especially for producing paper and cardboard packagings, are provided with numerous specific advantages regarding production and the product. The invention particularly relates to cellulose compounds and microcomposites in which solid materials, liquids, and dispersed or amorphous additives, for example, are coated onto the surface of the cellulose, and methods for the production of said compounds.Type: ApplicationFiled: November 3, 2005Publication date: October 30, 2008Inventors: Alex Ozersky, Ralf Recknagel, Hans-Georg Brendle
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Patent number: 7442281Abstract: There is provided a method of producing a kaolin particulate material suitable for use as an improved super-calendered filler. This method includes: (a) preparing an aqueous feed suspension of kaolin; (b) treating the kaolin of the feed suspension by attrition grinding in a vessel using grinding media granules; (c) delivering an aqueous suspension of the kaolin ground in (b) to a particle size classifier and separating the kaolin of the suspension into a coarse fraction and a fine fraction; (d) returning an aqueous suspension of the coarse fraction produced in (c) to the grinding vessel to be further attrition ground; and (e) extracting an aqueous suspension of the fine fraction produced in (c) as a product suspension. Advantageously, the kaolin of the feed suspension in (a) is such that not more than 30% by weight has a particle size less than 2 ?m and not more than 30% by weight has a particle size greater than 10 ?m.Type: GrantFiled: August 17, 2001Date of Patent: October 28, 2008Assignee: Imerys Minerals LimitedInventors: Philip Kenneth Johns, David Leslie Light
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Patent number: 7429294Abstract: The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis conditions and changing particle size of the clay. The paint has unprecedented stability.Type: GrantFiled: May 30, 2006Date of Patent: September 30, 2008Assignee: Board of Regents, The University of Texas SystemInventors: Russell Chianelli, Lori A. Polette
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Patent number: 7425235Abstract: The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis conditions and changing particle size of the clay.Type: GrantFiled: February 10, 2006Date of Patent: September 16, 2008Assignee: The Board of Regents of the University of Texas SystemInventors: Russell Chianelli, Lori A. Polette
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Patent number: 7419540Abstract: A swellable layer silicate is described based on smectite or sepiolite/palygorskite for use in media containing di- or polyvalent cations that reduce swellability, characterized by a swelling volume of about 5 to 50 mL, measured by addition of 2 g layer silicate (air-dried) to 100 mL water, and by a fineness of maximum 5 wt. % >40 ?m and maximum 20% >20 ?m, as dry sieve residue.Type: GrantFiled: August 29, 2001Date of Patent: September 2, 2008Assignee: Sud-Chemie AGInventors: Markus Möller, Helmut Coutelle, Robert Warth, Wolfgang Heininger
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Publication number: 20080190324Abstract: A composition includes a compound selected from the group consisting of formula (I), (III), and (IV). The compound of formula (I) is: wherein A is N, C, or S; the A-R5 bond is a single bond or a double bond; R1 is H, —NH2, or —S-aryl; R2 is H or together with R3 form a fused bicyclic group; R3 is H, or together with R2 form a fused bicyclic group, or together with R4 and R5 form a fused tricyclic group; R4 is H, or together with R3 and R5 form a fused tricyclic group, or R5 is H, O, or together with R3 and R4 form a fused tricyclic group; R6 is H, OH, —NH-alkyl, or —NH-aryl; R7 is H; R8 is H, —O-aryl, or halogen; and R9 is H, NH2, —NH-alkyl, —NH-aryl, OH, or —S-aryl.Type: ApplicationFiled: February 1, 2008Publication date: August 14, 2008Inventors: Russell R. Chianelli, Lori A. Niewold, Gary Williams
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Patent number: 7377975Abstract: Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.Type: GrantFiled: September 20, 2006Date of Patent: May 27, 2008Assignee: J.M. Huber CorporationInventors: Ching-Yih Chen, Ricky L. Giddens, Richard D. Carter
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Patent number: 7306668Abstract: The present invention provides high brightness kaolins exhibiting a Brightness (GE) of at least about 90.0. The hydrous kaolin pigments of the present invention may also have, inter alia, a steepness index (d30/d70×100) of at least about 39 and/or a titania concentration less than or equal to about 0.40% by weight of the pigment on a dry basis. (062) The hydrous kaolin pigment is produced by a process comprising: a) forming an aqueous suspension of a hydrous kaolin clay; b) forming a primary product by subjecting the suspension to classification or a combination of classification and griding; c), separating the kaolin from impurities by selective flocculation; and d) defining the separated kaolin. (063) The hydrous kaolins of the present invention allow coated papers to be produced at high brightness while maintaining acidic conditions on a paper machine. The invention pigmets exhibit brightness levels unexpectedly higher, e.g., about 2 to about 2.Type: GrantFiled: January 29, 2003Date of Patent: December 11, 2007Assignee: Imerys Pigments, Inc.Inventors: Graham Pring, Christopher R. L. Golley
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Patent number: 7279037Abstract: Disclosed are methods of processing Chinese kaolin involving providing Chinese kaolin having a desired powder size, delaminating the Chinese kaolin, pulverizing the delaminated Chinese kaolin at least two times, and heating the at least twice pulverized Chinese kaolin. Also disclosed are systems for automated processing of Chinese kaolin containing a pulverizer for pulverizing Chinese kaolin, a tester for testing and generating data of at least one parameter of the Chinese kaolin or at least one parameter of the pulverizer, a controller, operatively coupled to the pulverizer and the tester, for controlling operation of the pulverizer based on data received from the tester.Type: GrantFiled: February 12, 2004Date of Patent: October 9, 2007Assignee: Engelhard CorporationInventors: Saad N. Nemeh, Danny Williams, Francis Yin, Randall P. Brown, Ernie Finch
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Patent number: 7261770Abstract: In various embodiments, a pigment composition is provided comprising a base particle and a dispersing agent, the dispersing agent comprising a salt and/or ester of: (i) an amine, alcohol, and/or alkanol amine and (ii) a polyprotic acid, wherein the mole ratio of the amine, alcohol, and/or alkanol amine to the polyprotic acid is greater than 3:1. In various embodiments, the pigments have improved stability, hiding power, tint strength, and/or gloss.Type: GrantFiled: November 24, 2004Date of Patent: August 28, 2007Assignee: Millennium Inorganic Chemicals, Inc.Inventors: Modasser El-Shoubary, Robert M. Hopkins, Karen L. Bowen, David E. Bell
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Patent number: 7258733Abstract: A clay slurry is described using smectite clay, water, and a defined phosphonate additive that is hydrolytically stable over time. The viscosity of the clay slurry remains pourable and relatively unchanged over time compared to prior art slurries. The slurry is useful to provide rheological control to paints and coatings and is particularly useful as an anti-bleed additive for concrete.Type: GrantFiled: July 17, 2003Date of Patent: August 21, 2007Assignee: Elementis Specialties, Inc.Inventors: Wouter Ijdo, Wilbur S. Mardis, Fred Whitton
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Patent number: 7214264Abstract: The present invention relates to a hydrous kaolin product having improved optical properties, for example, when used in the production of paper products. The present invention comprises an improved barrier coating for paper and a method of making the coated paper. The present invention also comprises an improved method from making filled and coated paper products. The present invention uses a composition comprising kaolin having a shape factor of at least about 70:1, such as at least about 80:1 or at least about 100:1.Type: GrantFiled: April 19, 2005Date of Patent: May 8, 2007Assignee: Imerys Pigments, Inc.Inventors: J. Philip E. Jones, Robert J. Pruett, Jun Yuan, Michael J. Garska, David O. Cummings, Bomi M. Bilimoria, Robin Wesley
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Patent number: 7172651Abstract: Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.Type: GrantFiled: June 17, 2003Date of Patent: February 6, 2007Assignee: J.M. Huber CorporationInventors: Ching-Yih Chen, Ricky L. Giddens, Richard D. Carter
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Patent number: 7153356Abstract: The invention relates to a washable paint comprising about 2.5 to 10 weight percent of a high molecular weight polyethylene glycol having a molecular weight between 2,000 and 20,000, a water swellable clay in the amount of 0.5 to 1.5 weight percent; and a high molecular weight cellulosic thickener in the amount of about 1.0 to 2.5 weight percent, wherein the high molecular weight cellulosic thickener has a viscosity between 500 and 15,000 cps tested as a 2% by weight solution in water at 25° C. using a Brookfield DV-II+ viscometer with a number 21 spindle and a speed of 2 rpm, and wherein the paint has a viscosity of between 5,000 and 50,000 cps tested on a Brookfield DV-II+ viscometer with a number 6 spindle at 10 rpm and 52° C.Type: GrantFiled: October 17, 2005Date of Patent: December 26, 2006Assignee: Milliken & CompanyInventors: Philip G. Harris, William G. Hopkins, Jr., Kerrie L. Bryant, E. Kyle Stephenson
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Patent number: 7122080Abstract: The present invention provides an improved method of beneficiating and dewatering kaolin clays. The product of the improved process is a brightened, dewatered kaolin, suitable for use in pigments and paper coating compositions. The improved beneficiation process provides refined kaolin for pigments and other purposes of the same or better quality as prior art processes, but with the use of fewer steps and materials, at significant cost and environmental savings.Type: GrantFiled: August 8, 2002Date of Patent: October 17, 2006Inventors: Robert J. Pruett, Jun Yuan, Christopher R. L. Golley, Michael J. Garska
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Patent number: 7052541Abstract: The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis conditions and changing particle size of the clay. The paint has unprecedented stability.Type: GrantFiled: February 18, 2003Date of Patent: May 30, 2006Assignee: Board of Regents, The University of Texas SystemInventors: Russell Chianelli, Lori A. Polette
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Patent number: 6958091Abstract: Inorganic pigments treated with at least one amide of a fatty acid and an aliphatic amine possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.Type: GrantFiled: September 7, 2004Date of Patent: October 25, 2005Assignee: Kerr-McGee Chemical LLCInventor: Daniel H. Craig
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Patent number: 6946028Abstract: Inorganic pigments treated with one or more of the ?,?-dialkyl substituted linear or branched carboxylic acids and the salts thereof possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.Type: GrantFiled: September 7, 2004Date of Patent: September 20, 2005Assignee: Kerr-McGee Chemical LLCInventor: Daniel H. Craig
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Patent number: 6921432Abstract: A number of stable mixtures are disclosed containing specific combinations and levels of extender pigments and thickeners. These stable mixtures may be employed, inter alia, as a mixture in a method of making paints using prepaints or as a conventional component in a coating, such as a paint, or other end-use where opacifying pigments are employed.Type: GrantFiled: August 8, 2002Date of Patent: July 26, 2005Assignee: Rohm & Haas CompanyInventors: Edwin Hugh Nungesser, Jerry William Washel, John Michael Friel
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Patent number: 6837925Abstract: A coloring pearlescent flake pigment capable of providing pearl-like luster caused by interference color and a vivid color caused by a tar color is provided as a new material which contributes to the diversification of cosmetics and paints thanks to its powdery smoothness and the visual effect as well as covering protection effect in an application layer. The coloring pearlescent flake pigment having a double coating layer which is formed on inorganic flake-like particles and which is composed of a high-refraction-index metal oxide (e.g.Type: GrantFiled: May 29, 2003Date of Patent: January 4, 2005Assignees: Daito Kasei Kogyo Co., Ltd.Inventors: Yasushi Kubo, Hideji Kagawa
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Patent number: 6814797Abstract: The present invention provides a gel composition capable of maintaining a high viscosity controlling ability over a wide polarity range from a low to a high polarity and also capable of exhibiting an excellent viscosity stability over a prolonged period as well as such nail enamel. The composition comprises cation-modified clay mineral, wherein cations of said cation-modified clay mineral comprise quaternary ammonium cation represented by Formula (I): wherein R1 is a C1-9 alkyl group, a phenyl group or a C7-9 aralkyl group and R2 is a C10-36 alkyl group, and Formula (II): wherein R3 and R4 are independent from each other and each represents a C10-36 alkyl group. Preferably, said cation-modified clay mineral comprises cation-modified clay minerals A and B whose cations are Cations (I) and (II) respectively in a weight ratio of A:B from 55:45 to 99.9:0.1.Type: GrantFiled: March 12, 2002Date of Patent: November 9, 2004Assignee: Shiseido Co., Ltd.Inventors: Katsuyuki Kaneko, Hirotaka Takada, Tsuneo Suhara, Yoshikazu Soyama
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Patent number: 6811599Abstract: A biodegradable thermoplastic material comprising a natural polymer, a plasticizer and an exfoliated clay having a layered structure and a cation exchange capacity of from 30-250 milliequivalents per 100 grams and a process of preparing a biodegradable thermoplastic material comprising preparing a suspension of clay, combining said suspension with a natural polymer and a plasticizer and extruding the resultant composition at a temperature of 35-200° C.Type: GrantFiled: December 9, 2002Date of Patent: November 2, 2004Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNOInventors: Hartmut Rudolf Fischer, Sabine Fischer
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Patent number: 6811600Abstract: In a process for preparing a white pigment mixture suitable for coating paper wherein a cationically bulked kaolin clay pigment is dispersed in water in the presence of an anionic dispersant and mixed with a calcium carbonate pigment, the improvement which comprises using an epichlorohydrin amine complex to bulk said kaolin, and employing as the dispersant the combination of at least 0.2% based on the dry weight of said cationically bulked kaolin of a condensed naphthalene sulfonate complex having a molecular weight of 2000 to 10,000 and a sodium polyacrylate salt having a molecular weight of 2000 to 5000, said dispersant being free from lignosulfonate.Type: GrantFiled: January 23, 2003Date of Patent: November 2, 2004Assignee: Engelhard CorporationInventors: Sharad Mathur, Richard R. Berube
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Patent number: 6808808Abstract: A coating composition and a pigment comprising a surface-treated clay mixture used therein, and, optionally, microspheres, in which the coating composition comprises a curable or hardenable resin system into which is dispersed the pigment. High build, corrosion resistant coating compositions are provided having high pigment content, which translates into lower material costs, attributable at least in part to the particle packing benefits derived from the unique clay mixture used as a filler.Type: GrantFiled: January 14, 2003Date of Patent: October 26, 2004Inventors: Gary M. Freeman, William G. Setser
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Publication number: 20040144509Abstract: In a process for preparing a white pigment mixture suitable for coating paper wherein a cationically bulked kaolin clay pigment is dispersed in water in the presence of an anionic dispersant and mixed with a calcium carbonate pigment, the improvement which comprises using an epichlorohydrin amine complex to bulk said kaolin, and employing as the dispersant the combination of at least 0.2% based on the dry weight of said cationically bulked kaolin of a condensed naphthalene sulfonate complex having a molecular weight of 2000 to 10,000 and a sodium polyacrylate salt having a molecular weight of 2000 to 5000, said dispersant being free from lignosulfonate.Type: ApplicationFiled: January 23, 2003Publication date: July 29, 2004Inventors: Sharad Mathur, Richard R. Berube