Organic Material Containing Patents (Class 106/487)
  • Patent number: 8083848
    Abstract: Disclosed herein are kaolin compositions, such as beneficiated fine sedimentary kaolin compositions. The beneficiated fine sedimentary kaolins may be obtained from the upper bed of the Rio Capim Kaolin deposit. The compositions may have at least one property chosen from a low iron content and low Hinckley crystallinity index, such as Fe2O3 in an amount less than about 0.8% by weight relative to the total weight of the solids content and wherein the Hinckley crystallinity index of the kaolin is less than about 0.5. Also disclosed are products obtained therefrom, such as paint and paper coating compositions.
    Type: Grant
    Filed: February 8, 2006
    Date of Patent: December 27, 2011
    Assignee: Imerys Pigments, Inc.
    Inventors: Robert J. Pruett, Paula R. Alves
  • Publication number: 20110237726
    Abstract: The present invention relates to treated mineral filler products comprising a) at least one mineral filler, b) a treatment layer located on the surface of said mineral filler(s), said treatment layer comprising at least one saturated C8 to C24 aliphatic carboxylic acid; and at least one di and/or trivalent cation salt of one or more saturated C8 to C24 aliphatic carboxylic acid, wherein the weight ratio of all of said aliphatic carboxylic acid salt(s):all of said aliphatic carboxylic acid(s) is from 51:49 to 75:25; and said treatment layer is present in an amount of at least 2.5 mg/m2 of said mineral filler. Furthermore the present invention relates to processes to prepare such treated mineral filler products, and to their uses, notably in plastic applications, and especially in polypropylene (PP)- or polyethylene (PE)-based breathable or extrusion coating film applications.
    Type: Application
    Filed: August 19, 2009
    Publication date: September 29, 2011
    Inventors: Patrick A.C. Gane, Matthias Buri, René Burkhalter
  • Patent number: 8007586
    Abstract: A clay plaster formulation and application. The clay plaster is a mixture of various clays, and aggregate. This plaster is both functional and decorative and is for use on new and existing construction.
    Type: Grant
    Filed: June 23, 2010
    Date of Patent: August 30, 2011
    Inventor: Armin Croft Elsaesser
  • Publication number: 20110155018
    Abstract: Disclosed herein are stabilized kaolin slurries comprising a kaolin comprising no more than about 80% by weight of particles having an equivalent spherical diameter of less than 2 microns and at least one stabilizer, wherein the stabilized kaolin slurry has a 28-day pour test result of at least about 80% poured. Also disclosed are methods of making such stabilized kaolin slurries.
    Type: Application
    Filed: October 22, 2010
    Publication date: June 30, 2011
    Inventors: Jun Yuan, Michael J. Garska, Robert J. Pruett
  • Publication number: 20110144251
    Abstract: A coated particulate solid composition includes a particulate inorganic solid having deposited on its surface a treatment oil comprising lipids. The particulate inorganic solid can include a base particle of titanium dioxide, zinc sulfide, zinc oxide, iron oxide, lead oxide, aluminum oxide, silicon dioxide, zirconium oxide and/or chromium oxide. The treatment oil is optionally a vegetable oil. The treatment oil containing lipids optionally contains glycerides such as triglycerides, and diglycerides, and can contain phospholipids. In one embodiment, the coated particulate solid composition includes particulate titanium dioxide, wherein the treatment oil provides increased bulk density, and enhanced dispersibility in plastic as well as improved lacing resistance.
    Type: Application
    Filed: December 16, 2009
    Publication date: June 16, 2011
    Inventor: Modasser El-Shoubary
  • Publication number: 20110123792
    Abstract: A hybrid pigment composition is provided including a pigment or a dye and a fibrous clay. The pigment composition has higher reflectance in a near infrared region than a visible light region of the electromagnetic spectrum. The fibrous clay can be selected from palygorskite, sepiolite, and mixtures thereof. The hybrid pigment composition is tunable to provide high reflectance at a desired wavelength in the near infrared region.
    Type: Application
    Filed: March 10, 2009
    Publication date: May 26, 2011
    Inventor: Lori Niewold
  • Publication number: 20110113986
    Abstract: A hybrid pigment composition and method of forming the hybrid pigment composition is provided. The hybrid pigment composition is formed from a fibrous clay and a dye or pigment. The dye or pigment includes perinones, diphenylmethanes, acridines, xanthenes, triarylmethanes, thiazines, indophenols, indulines, nigrosines, aminoazobenzenes, anilines, monoazos, benzimidazoles, diazos, phthalocyanines, quinacridones, metal complexes, azo/metal complexes, and mixtures thereof.
    Type: Application
    Filed: March 10, 2009
    Publication date: May 19, 2011
    Inventors: Lori Ann Niewold, Robyn Torres, Gary E. Williams
  • Patent number: 7875151
    Abstract: A particulate product comprising kaolin produced from a method wherein the kaolin of a feed suspension is such that not more than 30% by weight has a particle size less than 2 ?m and not more than 30% by weight has a particle size greater than 10 ?m, wherein the kaolin of a product suspension produced is such that not more than 10% by weight has a particle size greater than 10 ?m and not more than 10% by weight has a particle size less than 0.25 ?m, and wherein the particulate product comprises kaolin produced from a fine fraction suspension.
    Type: Grant
    Filed: September 19, 2008
    Date of Patent: January 25, 2011
    Assignee: Imerys Minerals Ltd.
    Inventors: Philip Kenneth Johns, David Leslie Light
  • Publication number: 20100319585
    Abstract: Disclosed herein are defoamers comprising ethylene glycol, a defoaming hydrocarbon base fluid, and a non-ionic surfactant wherein the hydrocarbon base fluid comprises an internal olefin or a straight-chain n-alcohol, and wherein the non-ionic surfactant is present in the defoamer in an amount in the range of from about 1% to about 10% by weight of the defoamer. Also disclosed herein are cement compositions comprising water, hydraulic cement, and a defoamer, wherein the defoamer comprises ethylene glycol, a non-ionic surfactant, and a defoaming hydrocarbon base fluid wherein the hydrocarbon base fluid comprises an internal olefin or a straight-chain n-alcohol, and wherein the non-ionic surfactant is present in the defoamer in an amount in the range of from about 1% to about 10% by weight of the defoamer.
    Type: Application
    Filed: August 30, 2010
    Publication date: December 23, 2010
    Inventors: Michael J. Szymanski, Samuel J. Lewis, J. Michael Wilson, Arron L. Karcher
  • Patent number: 7842632
    Abstract: A pulling roll for glass manufacture comprised of a high-temperature millboard material. The millboard comprises aluminosilicate refractory fiber, silicate, mica, and kaolin clay. A method of manufacturing a pulling roll is disclosed, together with a roll produced by the methods disclosed herein. The method comprises forming a pulling roll and densifying at least a portion of the pulling roll by exposing to the pulling roll to high temperatures.
    Type: Grant
    Filed: February 10, 2009
    Date of Patent: November 30, 2010
    Assignee: Corning Incorporated
    Inventors: Dean Veral Neubauer, Maurice Lacasse
  • Publication number: 20100298482
    Abstract: An organic-inorganic hybrid pigment composition is provided comprising an organic pigment, an inorganic pigment, and a fibrous clay. The fibrous clay can be selected from palygorskite, sepiolite, or a combination thereof. The inorganic pigment is selected from rutile pigments, spinel pigments, bismuth vanadate pigments, cerium sulfide pigments, and combinations thereof. The organic pigment is selected from anthraquinone pigments, anthrathrone pigments, anthrapyrimidine pigments, azo pigments, azomethine pigments, quinacridone pigments, quinophthalone pigments, diketopyrrolopyrrol pigments, inanthrone pigments, isoindoline pigments, metal complex pigments, perinone pigments, perylene pigments, phthalocyanine pigments, pyranthrone pigments, pyrazolo-quinazolone pigments, thioindigo pigments, and combinations thereof.
    Type: Application
    Filed: January 21, 2009
    Publication date: November 25, 2010
    Inventors: Lori A. Niewold, Robyn Torres, Gary E. Williams
  • Patent number: 7806978
    Abstract: The present invention relates to a kaolin composition having improved physical properties, for example, for use in the production of paper products. The composition can comprise kaolin having a shape factor of at least about 20. The kaolin can have a particle size distribution such that at least about 94% by weight of the kaolin can have an esd of less than about 2 ?m and/or at least about 80% by weight of the kaolin can have an esd of less than 1 ?m. The amount of the kaolin having an esd of less than about 0.25 ?m can range from about 25% to about 60% by weight. The Hercules viscosity of the kaolin product is less than 4000 rpm at 18 dynes at 63% solids and less than 1500 rpm at 18 dynes at 69% solids when measured using the “A” bob. The present invention also relates to an improved method for making the kaolin product from sedimentary kaolin.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: October 5, 2010
    Assignee: Imerys Pigments, Inc.
    Inventors: Robert J. Pruett, Jun Yuan, Bomi M. Bilimoria, Roger W. Wygant, Anthony V. Lyons
  • Patent number: 7789960
    Abstract: A clay plaster formulation and application. The clay plaster is a mixture of various clays, and aggregate. This plaster is both functional and decorative and is for use on new and existing construction.
    Type: Grant
    Filed: February 3, 2009
    Date of Patent: September 7, 2010
    Inventor: Armin Croft Elsaesser
  • Patent number: 7758691
    Abstract: The invention relates to interspersed clay, comprising clay and a seaweed extract used as an interspacing component, particularly an ulva extract. The invention also relates to a method for the preparation thereof and to foodstuffs and nanocomposites comprising said interspersed clay.
    Type: Grant
    Filed: January 21, 2005
    Date of Patent: July 20, 2010
    Inventors: Herve Demais, Jocelyne Brendle, Herve Le Deit, Anca Laza, Luc Lurton, Dominique Brault
  • Patent number: 7740682
    Abstract: An improved composite material, and method of manufacture thereof, comprising varying amounts tungsten powder, or metal/alloy powder of similar density, and clay or silicone is disclosed. The improved composite material may be useful as a replacement for lead and lead-based composites where similar densities are required but the use of lead is undesirable. The disclosed composite material permits a large variety of tungsten powder particle sizes to be utilized and results in improved ductility over known tungsten powder composites.
    Type: Grant
    Filed: July 19, 2006
    Date of Patent: June 22, 2010
    Inventors: Randall C. Ragan, Randall M. Ragan, Richard Vaughn Culbertson
  • Patent number: 7727324
    Abstract: Disclosed herein is a kaolin composition having nanosize dimensions. At least about 75% of the kaolin particles by weight have an equivalent spherical diameter (esd) of less than about 0.25 ?m. The kaolin can also have a particle size distribution wherein at least about 99% of the particles by weight have an esd of less than about 2 ?m, and/or wherein at least about 98% of the particles by weight have an esd of less than about 1 ?m, and/or wherein at least about 97% of the particles by weight have an esd of less than about 0.5 ?m. The kaolin can have a mean diameter ranging from about 0.075 ?m to about 0.2 ?m, and a shape factor of about 30 or less.
    Type: Grant
    Filed: April 28, 2005
    Date of Patent: June 1, 2010
    Assignee: Imerys Pigments, Inc.
    Inventors: H. Vincent Brown, Robert J. Pruett
  • Publication number: 20100031852
    Abstract: Water repellents based on reactive siloxanes with polyfunctional silylalkoxy modification of the siloxane backbone and processes for hydrophobizing mineral fiber components.
    Type: Application
    Filed: August 5, 2009
    Publication date: February 11, 2010
    Inventors: Sascha Herrwerth, Frank Koenig, Michael Ferenz, Christian Mund
  • Patent number: 7641729
    Abstract: A ball clay powder having a moisture content of less than 5% and at least about 25% of indigenous silica, said powder comprising a blend of at least two natural ball clays, wherein one of the ball clays is naturally silica rich and has at least about 40% indigenous silica.
    Type: Grant
    Filed: November 7, 2006
    Date of Patent: January 5, 2010
    Assignee: Unimin Corporation
    Inventors: Claud E. Westbrook, Russell J. Fish
  • Patent number: 7611575
    Abstract: The present invention relates to coarse calcined kaolin slurries having a high solids content. The invention also relates to methods of making such slurries. The resulting slurries can have a solids content of at least about 58% by weight wherein at least about 40% by weight of the calcined kaolin particles has a particle size of at least about 1 ?m. The slurries can be stabilized where the solids show little settling from suspension. The slurries have many uses, including fillers or extenders in paint and coating compositions for paper or paper board. More generally, the inventive products may be used wherever calcined kaolins are used. The present invention also related to coarse calcined kaolin slurries having a multimodal particle size distribution and a high solids content.
    Type: Grant
    Filed: December 1, 2003
    Date of Patent: November 3, 2009
    Assignee: Imerys Pigments, Inc.
    Inventors: Edward J. Sare, Tommy L. Adkins, Stephen C. Raper
  • Patent number: 7597755
    Abstract: A pigment product for use in a coating composition to provide a gloss coating on paper, the pigment product comprising a processed particulate kaolin having a particle size distribution such that at least about 80% by weight of the particles have an equivalent spherical diameter less than about 2 p,m and in the range of from about 10% to about 20% by weight of the particles have an equivalent spherical diameter less than about 0.25 wm, the particles have a shape factor in the range of from about 20 to about 36 and the particles have a particle steepness in the range of about greater than about 35, more preferably in the range of about 35 to about 40, and wherein the kaolin is derived from a secondary kaolin source.
    Type: Grant
    Filed: August 15, 2003
    Date of Patent: October 6, 2009
    Assignee: Imerys Pigments, Inc.
    Inventors: David L. Light, Christopher R. L. Golley, Ernest Gay, Milton Constantin
  • Patent number: 7563317
    Abstract: Silanised, structurally modified silicas, characterised by groups fixed on the surface, the groups being alkylsilyl (SiCnH2n+1, with n=2-18). They are produced in that pyrogenically produced silicas are treated with the silanising agent and structurally modified. They are used to improve scratch resistance in lacquers.
    Type: Grant
    Filed: July 29, 2003
    Date of Patent: July 21, 2009
    Assignee: Degussa AG
    Inventors: Jürgen Meyer, Stephanie Frahn, Manfred Ettlinger
  • Publication number: 20090145333
    Abstract: A method for dispersing a pigment in a solvent comprises mixing the pigment in a nanoscale with clay in a layered or platelet form and mixing the resultant mixture with the solvent. The method is based on geometric inhomogeneity and mutually exclusive aggregation. The layered or platelet clay having a high aspect ratio is provided to hinder aggregation of the pigment nanoparticles. The pigment nanoparticles can be stably dispersed in a matrix containing an organic solvent and water without aggregation again.
    Type: Application
    Filed: July 18, 2008
    Publication date: June 11, 2009
    Inventors: Jiang-Jen Lin, Yi-Fen Lan, Yen-Chi Hsu
  • Publication number: 20090050021
    Abstract: A process of producing a kaolin product for paper coating includes mining kaolin ores by hydromechanization and then producing kaolin slurry; classifying by centrifugal sedimentation; chemical bleaching; eliminating iron ions by circular rinsing; removing water by pressure filtration; producing slurry by dispersing filter cakes, in which complex dispersants, pH adjustor and intercalator are added; delaminating; classifying by vibrating sieve; and spray drying: spray driers are restructured by adding insulating layers on packing auger, elevator scoop and bunker at first; the kaolin slurry J which has passed through vibrating sieves is dried in high speed centrifugal spray drying tower and the moisture of kaolin powder is controlled in 3 wt. %-5 wt. %, and the kaolin product for paper coating is obtained. The process characterizes in stable properties, high efficiency, and high viscosity content and fine particle size of the kaolin products produced.
    Type: Application
    Filed: August 3, 2008
    Publication date: February 26, 2009
    Applicants: CHINA UNIVERSITY OF GEOSCIENCES (Wu Han), MAOMING PETROCHEMICAL MINING CO., LTD.
    Inventors: Chunjie Yan, Xiaoyan Zhu, Jieyu Chen, Shujie Hai, Jielin Xu, Xiaoming Chen, Yizhi Cui, Weiqing Zeng
  • Patent number: 7494541
    Abstract: Disclosed are methods of processing kaolin to produce two distinct grades of kaolin in a simultaneous manner. The methods involve processing kaolin by degritting a kaolin crude; subjecting the degritted kaolin crude to flotation to provide a kaolin having reduced titania content; ozonating the kaolin having reduced titania content; centrifuging the kaolin to provide a coarse stream and fine stream; refining the coarse stream into a coarse engineered kaolin pigment; and refining the fine stream into a fine glossing kaolin pigment. Also disclosed are systems for the automated processing of kaolin to produce two distinct grades of kaolin with real time feedback.
    Type: Grant
    Filed: July 7, 2004
    Date of Patent: February 24, 2009
    Assignee: BASF Corporation
    Inventors: Sharad Mathur, Kenneth W. Folmar, David Kirk Thompson, Barry L. Daniels
  • Patent number: 7485186
    Abstract: A clay plaster formulation and application. The clay plaster is a mixture of various clays, and aggregate. This plaster is both functional and decorative and is for use on new and existing construction.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: February 3, 2009
    Assignee: American Clay Enterprises, LLC
    Inventor: Armin Croft Elsaesser
  • Publication number: 20080265222
    Abstract: Multifunctional surface-modified cellulose-containing fibers, especially for producing paper and cardboard packagings, are provided with numerous specific advantages regarding production and the product. The invention particularly relates to cellulose compounds and microcomposites in which solid materials, liquids, and dispersed or amorphous additives, for example, are coated onto the surface of the cellulose, and methods for the production of said compounds.
    Type: Application
    Filed: November 3, 2005
    Publication date: October 30, 2008
    Inventors: Alex Ozersky, Ralf Recknagel, Hans-Georg Brendle
  • Patent number: 7442281
    Abstract: There is provided a method of producing a kaolin particulate material suitable for use as an improved super-calendered filler. This method includes: (a) preparing an aqueous feed suspension of kaolin; (b) treating the kaolin of the feed suspension by attrition grinding in a vessel using grinding media granules; (c) delivering an aqueous suspension of the kaolin ground in (b) to a particle size classifier and separating the kaolin of the suspension into a coarse fraction and a fine fraction; (d) returning an aqueous suspension of the coarse fraction produced in (c) to the grinding vessel to be further attrition ground; and (e) extracting an aqueous suspension of the fine fraction produced in (c) as a product suspension. Advantageously, the kaolin of the feed suspension in (a) is such that not more than 30% by weight has a particle size less than 2 ?m and not more than 30% by weight has a particle size greater than 10 ?m.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: October 28, 2008
    Assignee: Imerys Minerals Limited
    Inventors: Philip Kenneth Johns, David Leslie Light
  • Patent number: 7429294
    Abstract: The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis conditions and changing particle size of the clay. The paint has unprecedented stability.
    Type: Grant
    Filed: May 30, 2006
    Date of Patent: September 30, 2008
    Assignee: Board of Regents, The University of Texas System
    Inventors: Russell Chianelli, Lori A. Polette
  • Patent number: 7425235
    Abstract: The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis conditions and changing particle size of the clay.
    Type: Grant
    Filed: February 10, 2006
    Date of Patent: September 16, 2008
    Assignee: The Board of Regents of the University of Texas System
    Inventors: Russell Chianelli, Lori A. Polette
  • Patent number: 7419540
    Abstract: A swellable layer silicate is described based on smectite or sepiolite/palygorskite for use in media containing di- or polyvalent cations that reduce swellability, characterized by a swelling volume of about 5 to 50 mL, measured by addition of 2 g layer silicate (air-dried) to 100 mL water, and by a fineness of maximum 5 wt. % >40 ?m and maximum 20% >20 ?m, as dry sieve residue.
    Type: Grant
    Filed: August 29, 2001
    Date of Patent: September 2, 2008
    Assignee: Sud-Chemie AG
    Inventors: Markus Möller, Helmut Coutelle, Robert Warth, Wolfgang Heininger
  • Publication number: 20080190324
    Abstract: A composition includes a compound selected from the group consisting of formula (I), (III), and (IV). The compound of formula (I) is: wherein A is N, C, or S; the A-R5 bond is a single bond or a double bond; R1 is H, —NH2, or —S-aryl; R2 is H or together with R3 form a fused bicyclic group; R3 is H, or together with R2 form a fused bicyclic group, or together with R4 and R5 form a fused tricyclic group; R4 is H, or together with R3 and R5 form a fused tricyclic group, or R5 is H, O, or together with R3 and R4 form a fused tricyclic group; R6 is H, OH, —NH-alkyl, or —NH-aryl; R7 is H; R8 is H, —O-aryl, or halogen; and R9 is H, NH2, —NH-alkyl, —NH-aryl, OH, or —S-aryl.
    Type: Application
    Filed: February 1, 2008
    Publication date: August 14, 2008
    Inventors: Russell R. Chianelli, Lori A. Niewold, Gary Williams
  • Patent number: 7377975
    Abstract: Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.
    Type: Grant
    Filed: September 20, 2006
    Date of Patent: May 27, 2008
    Assignee: J.M. Huber Corporation
    Inventors: Ching-Yih Chen, Ricky L. Giddens, Richard D. Carter
  • Patent number: 7306668
    Abstract: The present invention provides high brightness kaolins exhibiting a Brightness (GE) of at least about 90.0. The hydrous kaolin pigments of the present invention may also have, inter alia, a steepness index (d30/d70×100) of at least about 39 and/or a titania concentration less than or equal to about 0.40% by weight of the pigment on a dry basis. (062) The hydrous kaolin pigment is produced by a process comprising: a) forming an aqueous suspension of a hydrous kaolin clay; b) forming a primary product by subjecting the suspension to classification or a combination of classification and griding; c), separating the kaolin from impurities by selective flocculation; and d) defining the separated kaolin. (063) The hydrous kaolins of the present invention allow coated papers to be produced at high brightness while maintaining acidic conditions on a paper machine. The invention pigmets exhibit brightness levels unexpectedly higher, e.g., about 2 to about 2.
    Type: Grant
    Filed: January 29, 2003
    Date of Patent: December 11, 2007
    Assignee: Imerys Pigments, Inc.
    Inventors: Graham Pring, Christopher R. L. Golley
  • Patent number: 7279037
    Abstract: Disclosed are methods of processing Chinese kaolin involving providing Chinese kaolin having a desired powder size, delaminating the Chinese kaolin, pulverizing the delaminated Chinese kaolin at least two times, and heating the at least twice pulverized Chinese kaolin. Also disclosed are systems for automated processing of Chinese kaolin containing a pulverizer for pulverizing Chinese kaolin, a tester for testing and generating data of at least one parameter of the Chinese kaolin or at least one parameter of the pulverizer, a controller, operatively coupled to the pulverizer and the tester, for controlling operation of the pulverizer based on data received from the tester.
    Type: Grant
    Filed: February 12, 2004
    Date of Patent: October 9, 2007
    Assignee: Engelhard Corporation
    Inventors: Saad N. Nemeh, Danny Williams, Francis Yin, Randall P. Brown, Ernie Finch
  • Patent number: 7261770
    Abstract: In various embodiments, a pigment composition is provided comprising a base particle and a dispersing agent, the dispersing agent comprising a salt and/or ester of: (i) an amine, alcohol, and/or alkanol amine and (ii) a polyprotic acid, wherein the mole ratio of the amine, alcohol, and/or alkanol amine to the polyprotic acid is greater than 3:1. In various embodiments, the pigments have improved stability, hiding power, tint strength, and/or gloss.
    Type: Grant
    Filed: November 24, 2004
    Date of Patent: August 28, 2007
    Assignee: Millennium Inorganic Chemicals, Inc.
    Inventors: Modasser El-Shoubary, Robert M. Hopkins, Karen L. Bowen, David E. Bell
  • Patent number: 7258733
    Abstract: A clay slurry is described using smectite clay, water, and a defined phosphonate additive that is hydrolytically stable over time. The viscosity of the clay slurry remains pourable and relatively unchanged over time compared to prior art slurries. The slurry is useful to provide rheological control to paints and coatings and is particularly useful as an anti-bleed additive for concrete.
    Type: Grant
    Filed: July 17, 2003
    Date of Patent: August 21, 2007
    Assignee: Elementis Specialties, Inc.
    Inventors: Wouter Ijdo, Wilbur S. Mardis, Fred Whitton
  • Patent number: 7214264
    Abstract: The present invention relates to a hydrous kaolin product having improved optical properties, for example, when used in the production of paper products. The present invention comprises an improved barrier coating for paper and a method of making the coated paper. The present invention also comprises an improved method from making filled and coated paper products. The present invention uses a composition comprising kaolin having a shape factor of at least about 70:1, such as at least about 80:1 or at least about 100:1.
    Type: Grant
    Filed: April 19, 2005
    Date of Patent: May 8, 2007
    Assignee: Imerys Pigments, Inc.
    Inventors: J. Philip E. Jones, Robert J. Pruett, Jun Yuan, Michael J. Garska, David O. Cummings, Bomi M. Bilimoria, Robin Wesley
  • Patent number: 7172651
    Abstract: Pigment suitable for use in coating compositions for inkjet recording media. Surfaces of an inorganic particulate are interacted with a water-soluble polyvalent metal salt in an aqueous medium. The treated particle surfaces have a significant cationic surface charge imparted to them. The salt is a salt of a metal of Group II or Group III of the Periodic Table. Inkjet recording media treated with a coating composition containing the above pigment provide high density, fast-drying, and non-feathering ink images with suitable water fastness, while the coating compositions also offer cost advantages and improved rheology at higher pigment levels over coatings based on silica pigments.
    Type: Grant
    Filed: June 17, 2003
    Date of Patent: February 6, 2007
    Assignee: J.M. Huber Corporation
    Inventors: Ching-Yih Chen, Ricky L. Giddens, Richard D. Carter
  • Patent number: 7153356
    Abstract: The invention relates to a washable paint comprising about 2.5 to 10 weight percent of a high molecular weight polyethylene glycol having a molecular weight between 2,000 and 20,000, a water swellable clay in the amount of 0.5 to 1.5 weight percent; and a high molecular weight cellulosic thickener in the amount of about 1.0 to 2.5 weight percent, wherein the high molecular weight cellulosic thickener has a viscosity between 500 and 15,000 cps tested as a 2% by weight solution in water at 25° C. using a Brookfield DV-II+ viscometer with a number 21 spindle and a speed of 2 rpm, and wherein the paint has a viscosity of between 5,000 and 50,000 cps tested on a Brookfield DV-II+ viscometer with a number 6 spindle at 10 rpm and 52° C.
    Type: Grant
    Filed: October 17, 2005
    Date of Patent: December 26, 2006
    Assignee: Milliken & Company
    Inventors: Philip G. Harris, William G. Hopkins, Jr., Kerrie L. Bryant, E. Kyle Stephenson
  • Patent number: 7122080
    Abstract: The present invention provides an improved method of beneficiating and dewatering kaolin clays. The product of the improved process is a brightened, dewatered kaolin, suitable for use in pigments and paper coating compositions. The improved beneficiation process provides refined kaolin for pigments and other purposes of the same or better quality as prior art processes, but with the use of fewer steps and materials, at significant cost and environmental savings.
    Type: Grant
    Filed: August 8, 2002
    Date of Patent: October 17, 2006
    Inventors: Robert J. Pruett, Jun Yuan, Christopher R. L. Golley, Michael J. Garska
  • Patent number: 7052541
    Abstract: The present invention includes a paint or coating composition comprising an organic pigment or dye complexed to the surface of a layered or fibrous inorganic clay. A wide variety of paint colors can be obtained by varying the pH during the preparation as well as by varying the synthesis conditions and changing particle size of the clay. The paint has unprecedented stability.
    Type: Grant
    Filed: February 18, 2003
    Date of Patent: May 30, 2006
    Assignee: Board of Regents, The University of Texas System
    Inventors: Russell Chianelli, Lori A. Polette
  • Patent number: 6958091
    Abstract: Inorganic pigments treated with at least one amide of a fatty acid and an aliphatic amine possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: October 25, 2005
    Assignee: Kerr-McGee Chemical LLC
    Inventor: Daniel H. Craig
  • Patent number: 6946028
    Abstract: Inorganic pigments treated with one or more of the ?,?-dialkyl substituted linear or branched carboxylic acids and the salts thereof possess improved processibility and dispersibility in thermoplastic materials, and impart improved properties to thermoplastic compositions containing said surface-treated pigments.
    Type: Grant
    Filed: September 7, 2004
    Date of Patent: September 20, 2005
    Assignee: Kerr-McGee Chemical LLC
    Inventor: Daniel H. Craig
  • Patent number: 6921432
    Abstract: A number of stable mixtures are disclosed containing specific combinations and levels of extender pigments and thickeners. These stable mixtures may be employed, inter alia, as a mixture in a method of making paints using prepaints or as a conventional component in a coating, such as a paint, or other end-use where opacifying pigments are employed.
    Type: Grant
    Filed: August 8, 2002
    Date of Patent: July 26, 2005
    Assignee: Rohm & Haas Company
    Inventors: Edwin Hugh Nungesser, Jerry William Washel, John Michael Friel
  • Patent number: 6837925
    Abstract: A coloring pearlescent flake pigment capable of providing pearl-like luster caused by interference color and a vivid color caused by a tar color is provided as a new material which contributes to the diversification of cosmetics and paints thanks to its powdery smoothness and the visual effect as well as covering protection effect in an application layer. The coloring pearlescent flake pigment having a double coating layer which is formed on inorganic flake-like particles and which is composed of a high-refraction-index metal oxide (e.g.
    Type: Grant
    Filed: May 29, 2003
    Date of Patent: January 4, 2005
    Assignees: Daito Kasei Kogyo Co., Ltd.
    Inventors: Yasushi Kubo, Hideji Kagawa
  • Patent number: 6814797
    Abstract: The present invention provides a gel composition capable of maintaining a high viscosity controlling ability over a wide polarity range from a low to a high polarity and also capable of exhibiting an excellent viscosity stability over a prolonged period as well as such nail enamel. The composition comprises cation-modified clay mineral, wherein cations of said cation-modified clay mineral comprise quaternary ammonium cation represented by Formula (I): wherein R1 is a C1-9 alkyl group, a phenyl group or a C7-9 aralkyl group and R2 is a C10-36 alkyl group, and Formula (II): wherein R3 and R4 are independent from each other and each represents a C10-36 alkyl group. Preferably, said cation-modified clay mineral comprises cation-modified clay minerals A and B whose cations are Cations (I) and (II) respectively in a weight ratio of A:B from 55:45 to 99.9:0.1.
    Type: Grant
    Filed: March 12, 2002
    Date of Patent: November 9, 2004
    Assignee: Shiseido Co., Ltd.
    Inventors: Katsuyuki Kaneko, Hirotaka Takada, Tsuneo Suhara, Yoshikazu Soyama
  • Patent number: 6811599
    Abstract: A biodegradable thermoplastic material comprising a natural polymer, a plasticizer and an exfoliated clay having a layered structure and a cation exchange capacity of from 30-250 milliequivalents per 100 grams and a process of preparing a biodegradable thermoplastic material comprising preparing a suspension of clay, combining said suspension with a natural polymer and a plasticizer and extruding the resultant composition at a temperature of 35-200° C.
    Type: Grant
    Filed: December 9, 2002
    Date of Patent: November 2, 2004
    Assignee: Nederlandse Organisatie voor toegepast-natuurwetenschappelijk Onderzoek TNO
    Inventors: Hartmut Rudolf Fischer, Sabine Fischer
  • Patent number: 6811600
    Abstract: In a process for preparing a white pigment mixture suitable for coating paper wherein a cationically bulked kaolin clay pigment is dispersed in water in the presence of an anionic dispersant and mixed with a calcium carbonate pigment, the improvement which comprises using an epichlorohydrin amine complex to bulk said kaolin, and employing as the dispersant the combination of at least 0.2% based on the dry weight of said cationically bulked kaolin of a condensed naphthalene sulfonate complex having a molecular weight of 2000 to 10,000 and a sodium polyacrylate salt having a molecular weight of 2000 to 5000, said dispersant being free from lignosulfonate.
    Type: Grant
    Filed: January 23, 2003
    Date of Patent: November 2, 2004
    Assignee: Engelhard Corporation
    Inventors: Sharad Mathur, Richard R. Berube
  • Patent number: 6808808
    Abstract: A coating composition and a pigment comprising a surface-treated clay mixture used therein, and, optionally, microspheres, in which the coating composition comprises a curable or hardenable resin system into which is dispersed the pigment. High build, corrosion resistant coating compositions are provided having high pigment content, which translates into lower material costs, attributable at least in part to the particle packing benefits derived from the unique clay mixture used as a filler.
    Type: Grant
    Filed: January 14, 2003
    Date of Patent: October 26, 2004
    Inventors: Gary M. Freeman, William G. Setser
  • Publication number: 20040144509
    Abstract: In a process for preparing a white pigment mixture suitable for coating paper wherein a cationically bulked kaolin clay pigment is dispersed in water in the presence of an anionic dispersant and mixed with a calcium carbonate pigment, the improvement which comprises using an epichlorohydrin amine complex to bulk said kaolin, and employing as the dispersant the combination of at least 0.2% based on the dry weight of said cationically bulked kaolin of a condensed naphthalene sulfonate complex having a molecular weight of 2000 to 10,000 and a sodium polyacrylate salt having a molecular weight of 2000 to 5000, said dispersant being free from lignosulfonate.
    Type: Application
    Filed: January 23, 2003
    Publication date: July 29, 2004
    Inventors: Sharad Mathur, Richard R. Berube